CA2785777C - Epoxy compositions and surfacing films therefrom - Google Patents
Epoxy compositions and surfacing films therefrom Download PDFInfo
- Publication number
- CA2785777C CA2785777C CA2785777A CA2785777A CA2785777C CA 2785777 C CA2785777 C CA 2785777C CA 2785777 A CA2785777 A CA 2785777A CA 2785777 A CA2785777 A CA 2785777A CA 2785777 C CA2785777 C CA 2785777C
- Authority
- CA
- Canada
- Prior art keywords
- weight
- polycarbodiimide
- composition according
- composition
- cured
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 59
- 239000004593 Epoxy Substances 0.000 title description 28
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 17
- 239000002131 composite material Substances 0.000 claims abstract description 15
- 239000003822 epoxy resin Substances 0.000 claims abstract description 13
- 125000003118 aryl group Chemical group 0.000 claims abstract description 10
- 125000001931 aliphatic group Chemical group 0.000 claims abstract description 5
- WDGCBNTXZHJTHJ-UHFFFAOYSA-N 2h-1,3-oxazol-2-id-4-one Chemical group O=C1CO[C-]=N1 WDGCBNTXZHJTHJ-UHFFFAOYSA-N 0.000 claims description 5
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 4
- -1 methyl-phenylene Chemical group 0.000 claims description 3
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 claims description 3
- 125000005425 toluyl group Chemical group 0.000 claims 1
- 239000003973 paint Substances 0.000 abstract description 19
- 239000000463 material Substances 0.000 abstract description 9
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 30
- 238000012360 testing method Methods 0.000 description 14
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 11
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical class C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 11
- 239000000126 substance Substances 0.000 description 11
- KUBDPQJOLOUJRM-UHFFFAOYSA-N 2-(chloromethyl)oxirane;4-[2-(4-hydroxyphenyl)propan-2-yl]phenol Chemical compound ClCC1CO1.C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 KUBDPQJOLOUJRM-UHFFFAOYSA-N 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 7
- DGTNSSLYPYDJGL-UHFFFAOYSA-N phenyl isocyanate Chemical compound O=C=NC1=CC=CC=C1 DGTNSSLYPYDJGL-UHFFFAOYSA-N 0.000 description 7
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 7
- 241000894007 species Species 0.000 description 6
- 229940106691 bisphenol a Drugs 0.000 description 5
- 239000012948 isocyanate Substances 0.000 description 5
- 150000002513 isocyanates Chemical class 0.000 description 5
- 239000004570 mortar (masonry) Substances 0.000 description 5
- 239000004033 plastic Substances 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 239000011159 matrix material Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 239000004841 bisphenol A epoxy resin Substances 0.000 description 3
- 150000002118 epoxides Chemical class 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- 239000004848 polyfunctional curative Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 230000003746 surface roughness Effects 0.000 description 3
- 239000004971 Cross linker Substances 0.000 description 2
- 238000004566 IR spectroscopy Methods 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 239000002313 adhesive film Substances 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000012299 nitrogen atmosphere Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000011342 resin composition Substances 0.000 description 2
- 125000001424 substituent group Chemical group 0.000 description 2
- 240000005020 Acaciella glauca Species 0.000 description 1
- 229920003319 Araldite® Polymers 0.000 description 1
- PUNIDMUCDALJAS-UHFFFAOYSA-N C(C1=CC=C(C=C1)N(C(=O)NC)C)C1=CC=C(C=C1)N(C(=O)NC)C Chemical compound C(C1=CC=C(C=C1)N(C(=O)NC)C)C1=CC=C(C=C1)N(C(=O)NC)C PUNIDMUCDALJAS-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229920009405 Polyvinylidenefluoride (PVDF) Film Polymers 0.000 description 1
- 241000220010 Rhode Species 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 229920006243 acrylic copolymer Polymers 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 235000019445 benzyl alcohol Nutrition 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 150000001718 carbodiimides Chemical class 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000002041 carbon nanotube Substances 0.000 description 1
- 229910021393 carbon nanotube Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000013626 chemical specie Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011258 core-shell material Substances 0.000 description 1
- 125000004093 cyano group Chemical group *C#N 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 description 1
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 125000001475 halogen functional group Chemical group 0.000 description 1
- RBTKNAXYKSUFRK-UHFFFAOYSA-N heliogen blue Chemical compound [Cu].[N-]1C2=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=NC([N-]1)=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=N2 RBTKNAXYKSUFRK-UHFFFAOYSA-N 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004356 hydroxy functional group Chemical group O* 0.000 description 1
- 229960004592 isopropanol Drugs 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 239000002048 multi walled nanotube Substances 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 1
- 239000013034 phenoxy resin Substances 0.000 description 1
- 229920006287 phenoxy resin Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 235000003499 redwood Nutrition 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/4007—Curing agents not provided for by the groups C08G59/42 - C08G59/66
- C08G59/4014—Nitrogen containing compounds
- C08G59/4021—Ureas; Thioureas; Guanidines; Dicyandiamides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/4007—Curing agents not provided for by the groups C08G59/42 - C08G59/66
- C08G59/4014—Nitrogen containing compounds
- C08G59/4042—Imines; Imides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L79/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen or carbon only, not provided for in groups C08L61/00 - C08L77/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2363/00—Characterised by the use of epoxy resins; Derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/16—Applications used for films
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
- C08L2666/14—Macromolecular compounds according to C08L59/00 - C08L87/00; Derivatives thereof
- C08L2666/20—Macromolecular compounds having nitrogen in the main chain according to C08L75/00 - C08L79/00; Derivatives thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Epoxy Resins (AREA)
- Laminated Bodies (AREA)
- Inorganic Chemistry (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US29071909P | 2009-12-29 | 2009-12-29 | |
| US61/290,719 | 2009-12-29 | ||
| PCT/US2010/061693 WO2011090668A2 (en) | 2009-12-29 | 2010-12-22 | Epoxy compositions and surfacing films therefrom |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2785777A1 CA2785777A1 (en) | 2011-07-28 |
| CA2785777C true CA2785777C (en) | 2018-04-17 |
Family
ID=44168313
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2785777A Expired - Fee Related CA2785777C (en) | 2009-12-29 | 2010-12-22 | Epoxy compositions and surfacing films therefrom |
Country Status (10)
| Country | Link |
|---|---|
| US (2) | US20110159266A1 (https=) |
| EP (1) | EP2519583B1 (https=) |
| JP (1) | JP5922585B2 (https=) |
| KR (1) | KR101767701B1 (https=) |
| CN (2) | CN102686668A (https=) |
| CA (1) | CA2785777C (https=) |
| ES (1) | ES2652152T3 (https=) |
| PL (1) | PL2519583T3 (https=) |
| PT (1) | PT2519583T (https=) |
| WO (1) | WO2011090668A2 (https=) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR102063666B1 (ko) | 2010-12-16 | 2020-01-09 | 스톨텐, 엘리자베스 메어리 | 조립식 완구 시스템 |
| IN2014CN04162A (https=) | 2011-12-09 | 2015-07-17 | Cytec Tech Corp | |
| CN107428970B (zh) * | 2015-03-26 | 2021-09-10 | 日铁化学材料株式会社 | 纤维增强塑料成型用材料、其制造方法和成型物 |
| CN105566613A (zh) * | 2016-03-08 | 2016-05-11 | 广东广山新材料有限公司 | 一种异氰酸酯改性环氧树脂及用途 |
Family Cites Families (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04342713A (ja) * | 1991-05-20 | 1992-11-30 | Nippon Paint Co Ltd | 硬化性組成物 |
| JP3438957B2 (ja) * | 1994-08-11 | 2003-08-18 | 日清紡績株式会社 | 補強材用の水性表面処理剤、該水性表面処理剤で処理された補強材及び補強材により強化された複合材 |
| EP0747434B1 (en) * | 1995-06-06 | 2000-08-16 | Nisshinbo Industries, Inc. | Epoxy resin composition and adhesive based thereon |
| WO1998044017A1 (fr) * | 1997-03-27 | 1998-10-08 | Mitsubishi Rayon Co., Ltd. | Composition de resine epoxyde pour plastique renforce de fibre de verre, preimpregne et moulage tubulaire produit au moyen de cette composition |
| JP3467400B2 (ja) * | 1998-01-13 | 2003-11-17 | 日清紡績株式会社 | 液状封止材用樹脂組成物及び液状封止材 |
| JPH11310765A (ja) * | 1998-04-28 | 1999-11-09 | Nisshinbo Ind Inc | 接着性樹脂組成物及び該接着性樹脂組成物を使用した封止剤樹脂組成物 |
| EP0957122B1 (en) * | 1998-05-15 | 2003-11-26 | Nisshinbo Industries, Inc. | Epoxy resin composition |
| US6063890A (en) * | 1998-07-01 | 2000-05-16 | Basf Corporation | Polycarbodiimide polymers and their use as adhesive intermediate layers in automotive coatings |
| JP2000128959A (ja) * | 1998-10-27 | 2000-05-09 | Nippon Paint Co Ltd | オキサゾリドン環含有エポキシ樹脂 |
| JP2000345132A (ja) * | 1999-06-01 | 2000-12-12 | Nisshinbo Ind Inc | Ｌｃｐ接合方法 |
| JP4200250B2 (ja) * | 1999-10-26 | 2008-12-24 | パナソニック電工株式会社 | エポキシ樹脂組成物、プリプレグ、樹脂付き金属箔及び積層板 |
| JP3588317B2 (ja) * | 2000-09-18 | 2004-11-10 | 日清紡績株式会社 | 熱硬化性樹脂組成物及びそれを用いた樹脂付き金属箔、プリプレグ並びにフィルム状接着剤 |
| JP3868341B2 (ja) * | 2002-04-22 | 2007-01-17 | 日清紡績株式会社 | 耐熱性に優れたプラズマエッチング電極及びそれを装着したドライエッチング装置 |
| JP4253166B2 (ja) * | 2002-06-24 | 2009-04-08 | 日清紡績株式会社 | 燃料電池セパレータ |
| US20050255311A1 (en) * | 2004-04-23 | 2005-11-17 | Formella Stephen C | Hybrid composite product and system |
| JP4237726B2 (ja) * | 2005-04-25 | 2009-03-11 | パナソニック電工株式会社 | フレキシブルプリント配線板用基材入り接着シート及びその製造方法、多層フレキシブルプリント配線板、フレックスリジッドプリント配線板 |
| JP2007238652A (ja) * | 2006-03-06 | 2007-09-20 | Gun Ei Chem Ind Co Ltd | 熱硬化型接着性樹脂組成物 |
| US20070248810A1 (en) | 2006-04-25 | 2007-10-25 | Mcgee Dennis E | Coated polymeric film |
| CA2650528C (en) | 2006-04-25 | 2012-06-19 | Cytec Technology Corp. | Composite surfacing film with ultraviolet light and abrasion resistance |
| CN102227308B (zh) * | 2008-11-26 | 2016-01-06 | 3M创新有限公司 | 复合结构的表面膜 |
| EP3778227A1 (en) * | 2008-12-15 | 2021-02-17 | 3M Innovative Properties Company | Surfacing film for composites with barrier layer |
| EP2370250A1 (en) * | 2008-12-15 | 2011-10-05 | 3M Innovative Properties Company | Composite article including viscoelastic layer with barrier layer |
| CA2758798C (en) * | 2009-04-17 | 2019-04-23 | 3M Innovative Properties Company | Lightning protection sheet with patterned discriminator |
| KR101711226B1 (ko) * | 2009-04-17 | 2017-02-28 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 패턴화된 전도체를 갖는 낙뢰 보호 시트 |
-
2010
- 2010-12-22 CA CA2785777A patent/CA2785777C/en not_active Expired - Fee Related
- 2010-12-22 CN CN2010800600759A patent/CN102686668A/zh active Pending
- 2010-12-22 WO PCT/US2010/061693 patent/WO2011090668A2/en not_active Ceased
- 2010-12-22 JP JP2012547148A patent/JP5922585B2/ja active Active
- 2010-12-22 KR KR1020127019391A patent/KR101767701B1/ko not_active Expired - Fee Related
- 2010-12-22 US US12/975,478 patent/US20110159266A1/en not_active Abandoned
- 2010-12-22 EP EP10803541.1A patent/EP2519583B1/en active Active
- 2010-12-22 CN CN201710362211.3A patent/CN107254139B/zh active Active
- 2010-12-22 PL PL10803541T patent/PL2519583T3/pl unknown
- 2010-12-22 PT PT108035411T patent/PT2519583T/pt unknown
- 2010-12-22 ES ES10803541.1T patent/ES2652152T3/es active Active
-
2018
- 2018-06-12 US US16/006,659 patent/US10865271B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CA2785777A1 (en) | 2011-07-28 |
| KR101767701B1 (ko) | 2017-08-11 |
| JP2013515839A (ja) | 2013-05-09 |
| PL2519583T3 (pl) | 2018-03-30 |
| WO2011090668A2 (en) | 2011-07-28 |
| PT2519583T (pt) | 2017-12-22 |
| KR20120109569A (ko) | 2012-10-08 |
| EP2519583B1 (en) | 2017-10-04 |
| US20110159266A1 (en) | 2011-06-30 |
| CN102686668A (zh) | 2012-09-19 |
| JP5922585B2 (ja) | 2016-05-24 |
| WO2011090668A3 (en) | 2011-11-24 |
| US10865271B2 (en) | 2020-12-15 |
| CN107254139B (zh) | 2022-09-20 |
| CN107254139A (zh) | 2017-10-17 |
| US20180291139A1 (en) | 2018-10-11 |
| ES2652152T3 (es) | 2018-01-31 |
| EP2519583A2 (en) | 2012-11-07 |
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