CA2784603C - A process for initiating a highly selective ethylene oxide catalyst - Google Patents

A process for initiating a highly selective ethylene oxide catalyst Download PDF

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Publication number
CA2784603C
CA2784603C CA2784603A CA2784603A CA2784603C CA 2784603 C CA2784603 C CA 2784603C CA 2784603 A CA2784603 A CA 2784603A CA 2784603 A CA2784603 A CA 2784603A CA 2784603 C CA2784603 C CA 2784603C
Authority
CA
Canada
Prior art keywords
temperature
catalyst
moderator
silver
hours
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CA2784603A
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English (en)
French (fr)
Other versions
CA2784603A1 (en
Inventor
Nabil Rizkalla
Norma B. Castagnola
Girish Desai
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Scientific Design Co Inc
Original Assignee
Scientific Design Co Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=44152005&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=CA2784603(C) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Scientific Design Co Inc filed Critical Scientific Design Co Inc
Publication of CA2784603A1 publication Critical patent/CA2784603A1/en
Application granted granted Critical
Publication of CA2784603C publication Critical patent/CA2784603C/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/32—Manganese, technetium or rhenium
    • B01J23/36—Rhenium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C07C11/04—Ethylene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Epoxy Compounds (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CA2784603A 2009-12-23 2010-12-20 A process for initiating a highly selective ethylene oxide catalyst Expired - Fee Related CA2784603C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US28971909P 2009-12-23 2009-12-23
US61/289,719 2009-12-23
PCT/US2010/061192 WO2011079056A2 (en) 2009-12-23 2010-12-20 A process for initiating a highly selective ethylene oxide catalyst

Publications (2)

Publication Number Publication Date
CA2784603A1 CA2784603A1 (en) 2011-06-30
CA2784603C true CA2784603C (en) 2018-06-12

Family

ID=44152005

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2784603A Expired - Fee Related CA2784603C (en) 2009-12-23 2010-12-20 A process for initiating a highly selective ethylene oxide catalyst

Country Status (12)

Country Link
US (1) US8487123B2 (h)
EP (1) EP2521718B1 (h)
JP (1) JP2013515730A (h)
KR (1) KR101815664B1 (h)
CN (1) CN102666515B (h)
BR (1) BR112012015219B1 (h)
CA (1) CA2784603C (h)
IN (1) IN2012DN05077A (h)
MX (1) MX2012007440A (h)
RU (1) RU2538969C2 (h)
TW (1) TWI485142B (h)
WO (1) WO2011079056A2 (h)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012141942A1 (en) * 2011-04-11 2012-10-18 Dow Technology Investments Llc Process for conditioning a high efficiency ethylene oxide catalyst
TW201335143A (zh) * 2011-10-18 2013-09-01 Scient Design Co 添加緩和劑之環氧化方法
EP2920159B1 (en) 2012-12-31 2020-02-12 Scientific Design Company Inc. Start-up process for high selectivity ethylene oxide catalysts
EP2943477B1 (en) * 2013-01-11 2018-03-07 Scientific Design Company Inc. Epoxidation process with post-conditioning step
US9221776B2 (en) * 2013-12-23 2015-12-29 Scientific Design Company, Inc. Epoxidation process
WO2019055773A1 (en) 2017-09-15 2019-03-21 MultiPhase Solutions, Inc. GAS PHASE CHROMATOGRAPHY OF SELECTIVE HALOGEN DETECTION FOR ONLINE ANALYSIS AND CONTROL OF SELECTIVE OXIDATION CHEMICAL PRODUCTION PROCESSES
CN114057669B (zh) * 2020-07-29 2023-12-08 中国石油化工股份有限公司 一种乙烯环氧化恒温开车方法
CN114057670B (zh) * 2020-07-29 2024-06-07 中国石油化工股份有限公司 一种用于启动乙烯环氧化工艺的方法
CN114436998A (zh) * 2020-11-05 2022-05-06 中国石油化工股份有限公司 一种乙烯环氧化开车方法

Family Cites Families (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2279469A (en) 1942-04-14 Process of making olefin oxides
SE321462B (h) 1962-10-10 1970-03-09 Halcon International Inc
GB1170663A (en) 1967-03-22 1969-11-12 Shell Int Research Process for preparing Silver Catalysts
US3702259A (en) 1970-12-02 1972-11-07 Shell Oil Co Chemical production of metallic silver deposits
US4766105A (en) 1986-10-31 1988-08-23 Shell Oil Company Ethylene oxide catalyst and process for preparing the catalyst
US4761394A (en) 1986-10-31 1988-08-02 Shell Oil Company Ethylene oxide catalyst and process for preparing the catalyst
US4908343A (en) 1987-02-20 1990-03-13 Union Carbide Chemicals And Plastics Company Inc. Catalyst composition for oxidation of ethylene to ethylene oxide
US5057481A (en) 1987-02-20 1991-10-15 Union Carbide Chemicals And Plastics Technology Corporation Catalyst composition for oxidation of ethylene to ethylene oxide
US4874879A (en) 1988-07-25 1989-10-17 Shell Oil Company Process for starting-up an ethylene oxide reactor
CA1339317C (en) 1988-07-25 1997-08-19 Ann Marie Lauritzen Process for producing ethylene oxide
EP0357293B1 (en) 1988-08-30 1996-02-28 Union Carbide Corporation Catalysts for the production of ethylene oxide and their preparation processes
US5187140A (en) 1989-10-18 1993-02-16 Union Carbide Chemicals & Plastics Technology Corporation Alkylene oxide catalysts containing high silver content
US5102848A (en) 1990-09-28 1992-04-07 Union Carbide Chemicals & Plastics Technology Corporation Catalyst composition for oxidation of ethylene to ethylene oxide
US5155242A (en) 1991-12-05 1992-10-13 Shell Oil Company Process for starting-up an ethylene oxide reactor
US5407888A (en) 1992-05-12 1995-04-18 Basf Aktiengesellschaft Silver catalyst
US6492065B2 (en) * 1997-12-05 2002-12-10 Victor Company Of Japan, Limited Hologram color filter, production method of the same hologram color filter and space light modulating apparatus using the same hologram color filter
US6008388A (en) * 1998-04-16 1999-12-28 Arco Chemical Technology, L.P. Epoxidation process
JP4042332B2 (ja) 2001-02-27 2008-02-06 三菱化学株式会社 レニウム含有触媒を用いるオレフィンオキシドの製造方法
CN1665797B (zh) * 2002-06-28 2011-09-14 国际壳牌研究有限公司 环氧化方法的开车方法和烯烃环氧化方法
CN100512966C (zh) 2002-06-28 2009-07-15 国际壳牌研究有限公司 提高催化剂选择性的方法和烯烃环氧化方法
EP1532125B1 (en) * 2002-06-28 2006-03-22 Shell Internationale Researchmaatschappij B.V. A method for the start-up of an epoxidation process, a catalyst and a process for the epoxidation of an olefin
US6992209B2 (en) 2002-12-09 2006-01-31 Battelle Memorial Institute Methods of forming alpha, beta-unsaturated acids and esters
CN1860109B (zh) * 2003-09-29 2010-11-10 陶氏技术投资有限责任公司 使用气相助催化剂系统制备烯化氧的方法
US8791280B2 (en) 2005-08-10 2014-07-29 Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg Process for preparation of catalyst carrier and its use in catalyst preparation
WO2008140714A1 (en) 2007-05-11 2008-11-20 Billig Barry J Start-up of high selectivity catalysts in olefin oxide plants
US7553980B2 (en) * 2007-09-26 2009-06-30 Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg Process for initiating a highly selective ethylene oxide catalyst
BRPI0912381A2 (pt) * 2008-05-07 2017-07-04 Shell Int Research processo para a partida de um processo de epoxidação, processo para a produção de óxido de etileno, 1,2-diol, 1, 2-diol éter, 1, 2-carbonato, ou uma alcanolamina

Also Published As

Publication number Publication date
IN2012DN05077A (h) 2015-10-09
KR20120108029A (ko) 2012-10-04
JP2013515730A (ja) 2013-05-09
EP2521718B1 (en) 2014-07-02
RU2538969C2 (ru) 2015-01-10
MX2012007440A (es) 2012-07-23
RU2012131369A (ru) 2014-01-27
US8487123B2 (en) 2013-07-16
BR112012015219A2 (pt) 2015-09-22
TWI485142B (zh) 2015-05-21
KR101815664B1 (ko) 2018-01-05
BR112012015219B1 (pt) 2018-04-03
TW201139392A (en) 2011-11-16
CA2784603A1 (en) 2011-06-30
EP2521718A2 (en) 2012-11-14
EP2521718A4 (en) 2013-06-19
US20110152549A1 (en) 2011-06-23
WO2011079056A3 (en) 2011-11-17
CN102666515B (zh) 2015-05-20
CN102666515A (zh) 2012-09-12
WO2011079056A2 (en) 2011-06-30

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Effective date: 20151215

MKLA Lapsed

Effective date: 20191220