CA2767281A1 - Composition solide minerale, son procede de preparation et son utilisation en abattement de metaux lourds des gaz de fumees - Google Patents

Composition solide minerale, son procede de preparation et son utilisation en abattement de metaux lourds des gaz de fumees Download PDF

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Publication number
CA2767281A1
CA2767281A1 CA2767281A CA2767281A CA2767281A1 CA 2767281 A1 CA2767281 A1 CA 2767281A1 CA 2767281 A CA2767281 A CA 2767281A CA 2767281 A CA2767281 A CA 2767281A CA 2767281 A1 CA2767281 A1 CA 2767281A1
Authority
CA
Canada
Prior art keywords
halide salt
mineral compound
halide
salt
halloysite
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA2767281A
Other languages
English (en)
French (fr)
Inventor
Alain Brasseur
Jean-Paul Pirard
Alain Laudet
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lhoist Recherche et Developpement SA
Universite de Liege
Original Assignee
Lhoist Recherche et Developpement SA
Universite de Liege
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lhoist Recherche et Developpement SA, Universite de Liege filed Critical Lhoist Recherche et Developpement SA
Publication of CA2767281A1 publication Critical patent/CA2767281A1/fr
Abandoned legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/64—Heavy metals or compounds thereof, e.g. mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
    • B01J20/041—Oxides or hydroxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
    • B01J20/043—Carbonates or bicarbonates, e.g. limestone, dolomite, aragonite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
    • B01J20/046—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium containing halogens, e.g. halides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16—Alumino-silicates
    • B01J20/165—Natural alumino-silicates, e.g. zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28002—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their physical properties
    • B01J20/28004—Sorbent size or size distribution, e.g. particle size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3078—Thermal treatment, e.g. calcining or pyrolizing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3202—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the carrier, support or substrate used for impregnation or coating
    • B01J20/3204—Inorganic carriers, supports or substrates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3234—Inorganic material layers
    • B01J20/3236—Inorganic material layers containing metal, other than zeolites, e.g. oxides, hydroxides, sulphides or salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/30—Alkali metal compounds
    • B01D2251/306—Alkali metal compounds of potassium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/40—Alkaline earth metal or magnesium compounds
    • B01D2251/402—Alkaline earth metal or magnesium compounds of magnesium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/40—Alkaline earth metal or magnesium compounds
    • B01D2251/404—Alkaline earth metal or magnesium compounds of calcium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/60—Inorganic bases or salts
    • B01D2251/604—Hydroxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/60—Inorganic bases or salts
    • B01D2251/606—Carbonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/60—Heavy metals or heavy metal compounds
    • B01D2257/602—Mercury or mercury compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2258/00—Sources of waste gases
    • B01D2258/02—Other waste gases
    • B01D2258/0283—Flue gases
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2220/00—Aspects relating to sorbent materials
    • B01J2220/40—Aspects relating to the composition of sorbent or filter aid materials
    • B01J2220/42—Materials comprising a mixture of inorganic materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2220/00—Aspects relating to sorbent materials
    • B01J2220/50—Aspects relating to the use of sorbent or filter aid materials
    • B01J2220/56—Use in the form of a bed

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Analytical Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Treating Waste Gases (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
CA2767281A 2009-07-13 2010-07-13 Composition solide minerale, son procede de preparation et son utilisation en abattement de metaux lourds des gaz de fumees Abandoned CA2767281A1 (fr)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
BE200900426 2009-07-13
BE2009/0426 2009-07-13
US33225610P 2010-05-07 2010-05-07
US61/332,256 2010-05-07
PCT/EP2010/060057 WO2011006890A1 (fr) 2009-07-13 2010-07-13 Composition solide minerale, son procede de preparation et son utilisation en abattement de metaux lourds des gaz de fumees

Publications (1)

Publication Number Publication Date
CA2767281A1 true CA2767281A1 (fr) 2011-01-20

Family

ID=41429652

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2767281A Abandoned CA2767281A1 (fr) 2009-07-13 2010-07-13 Composition solide minerale, son procede de preparation et son utilisation en abattement de metaux lourds des gaz de fumees

Country Status (15)

Country Link
US (1) US8871006B2 (https=)
EP (1) EP2454006B1 (https=)
JP (1) JP5689878B2 (https=)
CN (1) CN102574054A (https=)
AU (1) AU2010272565A1 (https=)
BE (1) BE1019419A5 (https=)
CA (1) CA2767281A1 (https=)
FR (1) FR2947736B1 (https=)
IL (1) IL217479A0 (https=)
MA (1) MA33459B1 (https=)
NZ (1) NZ598094A (https=)
PL (1) PL2454006T3 (https=)
SG (1) SG177538A1 (https=)
UA (1) UA108616C2 (https=)
WO (1) WO2011006890A1 (https=)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2601239C (en) 2005-03-17 2013-07-16 Nox Ii, Ltd. Reducing mercury emissions from the burning of coal
BRPI0519075A2 (pt) 2005-03-17 2008-12-23 Nox Ii International Ltd reduÇço de emissÕes de mercério provenientes da combustço de carvço mineral
US20120134903A1 (en) * 2009-07-13 2012-05-31 Alain Brasseur Solid Inorganic Composition, Method for Preparing Same, and Use Thereof for Reducing Dioxins and Heavy Metals in Flue Gas
WO2016193429A1 (en) * 2015-06-03 2016-12-08 Solvay Sa Process for treating a gas contaminated by metals or organics compounds using a calcium-phosphate reactant comprising apatite

Family Cites Families (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1907076A (en) * 1930-08-28 1933-05-02 Texaco Salt Products Company Hygroscopic salts and their preparation
US2276503A (en) * 1935-11-06 1942-03-17 Calcium Carbonate Company Iodized calcium carbonate
US3345265A (en) * 1963-10-09 1967-10-03 Kendall & Co Multiple layer tablet with calcium salt central core separated from soluble fluoride outer coating
US3576666A (en) * 1969-05-05 1971-04-27 Ivan B Cutler Coated refractory structural members
JPS4884727A (https=) * 1972-02-16 1973-11-10
JPS4974195A (https=) * 1972-11-16 1974-07-17
US4094686A (en) * 1974-06-07 1978-06-13 Plastiroute S.A. Road-surface additive for preventing ice and melting snow
NL7513232A (nl) * 1975-11-12 1977-05-16 Seikisui Chemical Co Ltd Werkwijze ter bereiding van stabilisatoren voor chloorhoudende harsen.
JPS56113330A (en) * 1980-02-09 1981-09-07 Mitsubishi Metal Corp Removal of mercury in smelting gas
DE3117542A1 (de) * 1981-05-04 1983-02-10 Franz Josef Gattys Ingenieurbüro für Chem. Maschinen- und Apparatebau, 6078 Neu-Isenburg Verfahren zur stabilisierung von dehydratisiertem magnesiumschlorid gegen rueck-hydratisierung
ES8704428A1 (es) 1986-02-11 1987-04-16 Consejo Superior Investigacion Procedimiento de fabricacion de un adsorbente azufrado, util para retener vapores de metal, como mercurio.
KR0184681B1 (ko) * 1995-01-24 1999-05-15 구보타 다다시 탄산가스 흡착제를 가지는 발포 단열재와 그 발포 단열재의 제조방법
ES2136496B1 (es) 1996-06-18 2000-10-01 Consejo Superior Investigacion Procedimiento de sulfuracion de silicatos naturales para retener vapores de metales.
JP4241693B2 (ja) * 1999-11-26 2009-03-18 メタウォーター株式会社 燃焼排ガスの処理方法
US6582497B1 (en) 2000-06-09 2003-06-24 Merck & Co., Inc. Adsorption power for removing mercury from high temperature high moisture gas streams
NL1017206C2 (nl) * 2001-01-26 2002-07-29 Cdem Holland Bv Werkwijze voor het verwijderen van kwik uit een gasstroom.
BE1015949A3 (fr) 2004-03-15 2005-12-06 Lhoist Rech & Dev Sa Procede d'abattement de mercure et de metaux lourds des gaz de fumees.
US20060016690A1 (en) * 2004-07-23 2006-01-26 Ilya Ostrovsky Method for producing a hard coating with high corrosion resistance on articles made anodizable metals or alloys
CA2628198A1 (en) * 2005-11-05 2007-05-10 Jerrold E. Radway Control of combustion system emissions
US7858061B2 (en) 2005-12-15 2010-12-28 The United States Of America As Represented By The Administrator Of The United States Environmental Protection Agency Compositions and methods for removing mercury from mercury-containing fluids
US20070267343A1 (en) 2006-05-17 2007-11-22 Keith Edward Forrester Heavy metal particulate emission speciation modification wet process
US8906823B2 (en) 2007-09-24 2014-12-09 Basf Corporation Pollutant emission control sorbents and methods of manufacture and use
US8450232B2 (en) 2009-01-14 2013-05-28 Lummus Technology Inc. Catalysts useful for the alkylation of aromatic hydrocarbons
JP5740070B2 (ja) 2009-09-28 2015-06-24 カルゴン カーボン コーポレーション 燃焼排ガスから水銀を取り除く吸着剤

Also Published As

Publication number Publication date
US20120167762A1 (en) 2012-07-05
PL2454006T3 (pl) 2016-04-29
WO2011006890A1 (fr) 2011-01-20
MA33459B1 (fr) 2012-07-03
UA108616C2 (ru) 2015-05-25
CN102574054A (zh) 2012-07-11
SG177538A1 (en) 2012-02-28
FR2947736B1 (fr) 2015-09-18
JP5689878B2 (ja) 2015-03-25
EP2454006B1 (fr) 2015-09-02
NZ598094A (en) 2013-06-28
US8871006B2 (en) 2014-10-28
FR2947736A1 (fr) 2011-01-14
BE1019419A5 (fr) 2012-07-03
EP2454006A1 (fr) 2012-05-23
JP2012532753A (ja) 2012-12-20
AU2010272565A1 (en) 2012-02-23
RU2012104805A (ru) 2013-08-20
IL217479A0 (en) 2012-02-29

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Legal Events

Date Code Title Description
FZDE Discontinued

Effective date: 20160713