CA2672954C - Synthesis of crystalline nanometric lifempo4 - Google Patents

Synthesis of crystalline nanometric lifempo4 Download PDF

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Publication number
CA2672954C
CA2672954C CA2672954A CA2672954A CA2672954C CA 2672954 C CA2672954 C CA 2672954C CA 2672954 A CA2672954 A CA 2672954A CA 2672954 A CA2672954 A CA 2672954A CA 2672954 C CA2672954 C CA 2672954C
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CA
Canada
Prior art keywords
powder
particle size
life1
crystalline
less
Prior art date
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Active
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CA2672954A
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English (en)
French (fr)
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CA2672954A1 (en
Inventor
Stephane Levasseur
Michele Van Thournout
Pierre Gibot
Christian Masquelier
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Umicore NV SA
Centre National de la Recherche Scientifique
Original Assignee
Umicore NV SA
Centre National de la Recherche Scientifique
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Application filed by Umicore NV SA, Centre National de la Recherche Scientifique filed Critical Umicore NV SA
Publication of CA2672954A1 publication Critical patent/CA2672954A1/en
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B25/00—Phosphorus; Compounds thereof
    • C01B25/16—Oxyacids of phosphorus; Salts thereof
    • C01B25/26—Phosphates
    • C01B25/45—Phosphates containing plural metal, or metal and ammonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
    • H01B1/08—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances oxides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/136—Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/5825—Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/021—Physical characteristics, e.g. porosity, surface area
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Nanotechnology (AREA)
  • Electrochemistry (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Composite Materials (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Compounds Of Iron (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
CA2672954A 2006-12-22 2007-11-19 Synthesis of crystalline nanometric lifempo4 Active CA2672954C (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
EP06292048 2006-12-22
EP06292048.3 2006-12-22
US88150907P 2007-01-22 2007-01-22
US60/881,509 2007-01-22
PCT/EP2007/009969 WO2008077448A1 (en) 2006-12-22 2007-11-19 SYNTHESIS OF CRYSTALLINE NANOMETRIC LiFeMPO4

Publications (2)

Publication Number Publication Date
CA2672954A1 CA2672954A1 (en) 2008-07-03
CA2672954C true CA2672954C (en) 2014-07-22

Family

ID=39184669

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2672954A Active CA2672954C (en) 2006-12-22 2007-11-19 Synthesis of crystalline nanometric lifempo4

Country Status (5)

Country Link
US (3) US8066916B2 (enExample)
EP (1) EP2094605B1 (enExample)
JP (1) JP5479106B2 (enExample)
CA (1) CA2672954C (enExample)
WO (1) WO2008077448A1 (enExample)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ATE365233T1 (de) 2003-09-29 2007-07-15 Umicore Nv Verfahren und vorrichtung zur gewinnung von nichteisenmetallen aus zinkrückständen
CA2672954C (en) 2006-12-22 2014-07-22 Umicore Synthesis of crystalline nanometric lifempo4
KR101502184B1 (ko) 2007-03-19 2015-03-12 유미코르 Ｌｉ계 배터리에 사용하기 위한 상온 단상 Ｌｉ 삽입／추출 물질
JP5510036B2 (ja) * 2009-05-28 2014-06-04 Ｔｄｋ株式会社 活物質、活物質の製造方法及びリチウムイオン二次電池
DE102010006077B4 (de) * 2010-01-28 2014-12-11 Süd-Chemie Ip Gmbh & Co. Kg Substituiertes Lithium-Mangan-Metallphosphat
DE102010006083B4 (de) * 2010-01-28 2014-12-11 Süd-Chemie Ip Gmbh & Co. Kg Substituiertes Lithium-Mangan-Metallphosphat
CN102781827B (zh) * 2010-03-19 2016-05-04 户田工业株式会社 磷酸锰铁锂颗粒粉末的制造方法、磷酸锰铁锂颗粒粉末和使用该颗粒粉末的非水电解质二次电池
WO2011118350A1 (en) * 2010-03-26 2011-09-29 Semiconductor Energy Laboratory Co., Ltd. Power storage device
KR101698762B1 (ko) 2010-04-30 2017-01-23 삼성에스디아이 주식회사 리튬 전이금속 인산염의 제조방법
WO2011158948A1 (en) 2010-06-18 2011-12-22 Semiconductor Energy Laboratory Co., Ltd. Method of manufacturing power storage device
JP5917027B2 (ja) 2010-06-30 2016-05-11 株式会社半導体エネルギー研究所 電極用材料の作製方法
RU2444815C1 (ru) * 2010-08-27 2012-03-10 Учреждение Российской академии наук Институт химии твердого тела и механохимии Сибирского отделения РАН (ИХТТМ СО РАН) СПОСОБ ПОЛУЧЕНИЯ ВЫСОКОДИСПЕРСНЫХ КАТОДНЫХ МАТЕРИАЛОВ LixFeyMzPO4/C СО СТРУКТУРОЙ ОЛИВИНА
WO2012033389A2 (ko) * 2010-09-09 2012-03-15 에스케이이노베이션 주식회사 리튬 이차 전지용 양극 활물질, 이의 제조 방법 및 이를 포함하는 리튬 이차 전지
US9065136B2 (en) 2011-09-14 2015-06-23 Samsung Sdi Co., Ltd. Positive electrode for rechargeable lithium battery, method of preparing the same, and rechargeable lithium battery including the same
WO2013055792A1 (en) * 2011-10-10 2013-04-18 The Regents Of The University Of California Size and morphologically controlled nanostructures for energy storage
CN102522522A (zh) * 2011-12-02 2012-06-27 苏州冠硕新能源有限公司 一种纳米正极材料以及制备方法
CN104411627A (zh) * 2012-06-27 2015-03-11 陶氏环球技术有限责任公司 用于制备具有高能量密度的锂过渡金属橄榄石的低成本方法
US20150372303A1 (en) * 2012-12-21 2015-12-24 Dow Global Technologies Llc Method for Making Lithium Transition Metal Olivines Using Water/Cosolvent Mixtures
CN105612640B (zh) * 2013-10-02 2017-12-12 尤米科尔公司 碳涂覆的电化学活性粉末
CN103682340B (zh) * 2013-12-26 2016-03-23 中国科学院上海硅酸盐研究所 一种具有分级结构的铁基氟化物纳米材料及其制备方法和应用
FR3049114B1 (fr) * 2016-03-18 2018-03-09 Blue Solutions Batterie lithium metal polymere a haute densite d'energie
KR102553570B1 (ko) * 2018-06-27 2023-07-10 삼성전자 주식회사 리튬 이온 전지용 양극 활물질 및 이를 포함하는 리튬 이온 전지
DE112021005840T5 (de) * 2020-11-06 2023-08-17 Gs Yuasa International Ltd. Positives aktivmaterial für energiespeichervorrichtung, positive elektrode für energiespeichervorrichtung, energiespeichervorrichtung und energiespeichergerät
CN120600774A (zh) * 2024-03-04 2025-09-05 宁德时代新能源科技股份有限公司 正极材料及其制备方法、正极极片、二次电池、用电装置

Family Cites Families (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5910382A (en) * 1996-04-23 1999-06-08 Board Of Regents, University Of Texas Systems Cathode materials for secondary (rechargeable) lithium batteries
US6514640B1 (en) * 1996-04-23 2003-02-04 Board Of Regents, The University Of Texas System Cathode materials for secondary (rechargeable) lithium batteries
US20020192137A1 (en) 2001-04-30 2002-12-19 Benjamin Chaloner-Gill Phosphate powder compositions and methods for forming particles with complex anions
TW525313B (en) 2000-04-25 2003-03-21 Sony Corp Positive electrode active material and non-aqueous electrolyte cell
CA2320661A1 (fr) * 2000-09-26 2002-03-26 Hydro-Quebec Nouveau procede de synthese de materiaux limpo4 a structure olivine
JP2002117908A (ja) 2000-10-06 2002-04-19 Sony Corp 非水電解液電池
US6551533B1 (en) * 2000-11-28 2003-04-22 Chemat Technology, Inc. Method of forming fibrous materials and articles therefrom
DE10117904B4 (de) * 2001-04-10 2012-11-15 Zentrum für Sonnenenergie- und Wasserstoff-Forschung Baden-Württemberg Gemeinnützige Stiftung Binäre, ternäre und quaternäre Lithiumeisenphosphate, Verfahren zu ihrer Herstellung und ihre Verwendung
EP1261050A1 (en) * 2001-05-23 2002-11-27 n.v. Umicore s.a. Lithium transition-metal phosphate powder for rechargeable batteries
WO2004001881A2 (en) * 2002-06-21 2003-12-31 Umicore Carbon-coated li-containing powders and process for production thereof
JP4058680B2 (ja) 2002-08-13 2008-03-12 ソニー株式会社 正極活物質の製造方法及び非水電解質二次電池の製造方法
DE10242694A1 (de) * 2002-09-13 2004-03-25 MAX-PLANCK-Gesellschaft zur Förderung der Wissenschaften e.V. Neuartige Elektrodenmaterialien und Elektroden für elektrochemische Energiespeichereinrichtungen auf Li-Basis
US7390472B1 (en) * 2002-10-29 2008-06-24 Nei Corp. Method of making nanostructured lithium iron phosphate—based powders with an olivine type structure
FR2848549B1 (fr) 2002-12-16 2005-01-21 Commissariat Energie Atomique Procede de preparation de composes d'insertion d'un metal alcalin, materiaux actifs les contenant, et dispositifs comprenant ces materiaux actifs
JP4190912B2 (ja) 2003-02-24 2008-12-03 住友大阪セメント株式会社 リチウムイオン電池用正極活物質及びそれを有するリチウムイオン電池
US7041239B2 (en) * 2003-04-03 2006-05-09 Valence Technology, Inc. Electrodes comprising mixed active particles
JP4522683B2 (ja) * 2003-10-09 2010-08-11 住友大阪セメント株式会社 電極材料粉体の製造方法と電極材料粉体及び電極並びにリチウム電池
DE10353266B4 (de) * 2003-11-14 2013-02-21 Süd-Chemie Ip Gmbh & Co. Kg Lithiumeisenphosphat, Verfahren zu seiner Herstellung und seine Verwendung als Elektrodenmaterial
CN1571195A (zh) 2004-05-13 2005-01-26 复旦大学 用于薄膜锂离子电池的纳米阴极材料及其制备方法
US7338647B2 (en) * 2004-05-20 2008-03-04 Valence Technology, Inc. Synthesis of cathode active materials
KR100718020B1 (ko) 2004-09-17 2007-05-14 주식회사 엘지화학 ＬｉＦｅＰ０４의 제조방법
DE102005015613A1 (de) * 2005-04-05 2006-10-12 Süd-Chemie AG Kristallines Ionenleitendes Nanomaterial und Verfahren zu seiner Herstellung
EP1722428A1 (en) 2005-05-13 2006-11-15 Süd-Chemie Ag Lithium secondary battery and electrodes for use therein
BRPI0612557A2 (pt) 2005-06-29 2012-02-28 Umicore Nv processo para preparar pó de lifepo4 cristalino, pó de lifepo4 cristalino, isento de carbono, uso do mesmo, e, mistura de eletrodo para baterias secundárias de lìtio com eletrólito lìquido não aquoso
US7939201B2 (en) 2005-08-08 2011-05-10 A123 Systems, Inc. Nanoscale ion storage materials including co-existing phases or solid solutions
EP1936721B1 (en) 2005-09-21 2015-11-11 Kanto Denka Kogyo Co., Ltd. Positive electrode active material, method for producing same, and nonaqueous electrolyte battery having positive electrode containing positive electrode active material
KR20130106440A (ko) 2006-02-28 2013-09-27 프리메트 프리시젼 머테리알스, 인크. 리튬계 화합물 나노입자 조성물 및 이의 제조 방법
WO2008018633A1 (en) 2006-08-09 2008-02-14 Kanto Denka Kogyo Co., Ltd. Compound having olivine structure, method for producing the same, positive electrode active material using compound having olivine structure, and nonaqueous electrolyte battery
JP2008088585A (ja) 2006-09-29 2008-04-17 Kaneka Corp 難燃性ポリエステル系人工毛髪
CA2672954C (en) 2006-12-22 2014-07-22 Umicore Synthesis of crystalline nanometric lifempo4
EP2103570A3 (en) 2006-12-22 2011-12-21 Umicore Synthesis of electroactive crystalline nanometric LiMnPO4 powder
KR101502184B1 (ko) * 2007-03-19 2015-03-12 유미코르 Ｌｉ계 배터리에 사용하기 위한 상온 단상 Ｌｉ 삽입／추출 물질

Also Published As

Publication number Publication date
EP2094605A1 (en) 2009-09-02
JP5479106B2 (ja) 2014-04-23
US20100084615A1 (en) 2010-04-08
EP2094605B1 (en) 2012-09-05
US20100327222A1 (en) 2010-12-30
CA2672954A1 (en) 2008-07-03
US8105508B2 (en) 2012-01-31
US8066916B2 (en) 2011-11-29
US20120085975A1 (en) 2012-04-12
JP2010513193A (ja) 2010-04-30
WO2008077448A1 (en) 2008-07-03
US9051184B2 (en) 2015-06-09

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