CA2651610A1 - Air cell energy system and uses for same - Google Patents

Air cell energy system and uses for same Download PDF

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Publication number
CA2651610A1
CA2651610A1 CA002651610A CA2651610A CA2651610A1 CA 2651610 A1 CA2651610 A1 CA 2651610A1 CA 002651610 A CA002651610 A CA 002651610A CA 2651610 A CA2651610 A CA 2651610A CA 2651610 A1 CA2651610 A1 CA 2651610A1
Authority
CA
Canada
Prior art keywords
metal
battery
hydrogen
air
air cell
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA002651610A
Other languages
French (fr)
Inventor
Mark R. Simon
Rodolphe J. Simon
Barry Evans
Peter Seamens
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
HYDRO PHI TECHNOLOGIES Inc
Original Assignee
HYDRO PHI TECHNOLOGIES Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by HYDRO PHI TECHNOLOGIES Inc filed Critical HYDRO PHI TECHNOLOGIES Inc
Publication of CA2651610A1 publication Critical patent/CA2651610A1/en
Abandoned legal-status Critical Current

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Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Fuel Cell (AREA)

Abstract

A metal/air battery system includes an electrolyte filter/pump/storage unit under system control to drain the metal air battery when the battery is not in use. The system may be utilized alone to produce hydrogen for further use by a hydrogen consuming device such as a vehicle engine or alternatively, in combination with a proton exchange membrane PEM to create a proton exchange membrane fuel cell which consumes the hydrogen byproduct of the metal air battery producing additional electrical current and water.

Description

Docket No.: HydrePh=-COIPR

AIR CELL ENERGY SYSTEM AND USES FOR SAME
TECHNICAL FIELD

[0001] The present inventicn relates to energy systems and more particularlq, relates to a metal/air fuel cell or battery which can be used to generate hydrogen and/or electricity based on its configuration, and whose outpat generation can be suspended and metal air cell life exlr-ended by providing an electrolyte filtering and removal system.

HACKGkOUND IIvFORMATION

[00021 h7etal-air cell batteries are widely known and their use in svste:ns that do not need fossil fuels to provic.e energy becoming increasingly mote promitient giver the recent significant rise in fossil- fuel costs. See Exhibit A attached hexeto anci incorporated herein by reference. Examples of uses for metal-air cell batteries include, for example and without limitation, electric cars, electric generators and hydrogen producing electrolysis units.

(0003] Metal-air cell battQYies are comoact and are verv environmenta'_ly benign. Se-=reral types of metals such as alumin:im (See Ex~ibit B attached hereto and fully incorporated herein by rEference! or maanesium are typically utilized to _ 1 -. . ,. . . . i . . ...... . .. . . ..:... ..

produce electricity from the reaction of oxygen in r_ite air or water. Once the metal anode is consumed by its reaction, the battery will no longer produce electr_city and the anode or cathode must be replaced to reuse the battery. The byproduct of such batteries is hydrogen and water, both of which are environmentally friendly. One of their disadvantages, however, is that they continue to consume the anode/cathcde even waen not in use, thereby greatly reducing the lifespan of the battery and making it generally unsuitable for use in applications such as automobiles, which require only intermittent power.

[0009] Accordingly, a need exists for a sys-em which u-*__lizes a metal-air cell battery as either a source of electricity to charge batto_ies or -oro;ride power for some other application, such as a hvdroge7 genPrating unit, and/or which utiyizes the hydrogen byproducL= directly such as to power an engi.r~e to pro=~ide moti.ve =orce. In addition, such a sys-er.1 shoula provide for easily inter-changing and replacing the battery using quick connect fittinqs and the like and wherein the electrolyte solution in the battery can be filtered and rerr~cved during periods of nonuse to extend the life of the battery by stopping the electricitv generation in the syste:n when not in use.
[0005] These and other features and advantagEs of the preserft ir.venti;;n will be better understood by reading the following detailed descriptiorE, taken together with the drawings wherein:
[00061 FIG. 1 is a block diagram of an air cell system according to the present invention;

[00071 FIG. 2 is a block diagram of an a'_r cell system used to generate electricitv according to one embodiment of the present invention;

[0008] FIG. 3 is a block diagram of an air cell sys_en according r-o the present invention in use in a vehicle hydrogec on demand sysrQn ac:;ordirig to one eralood-ment of the present irvelt ion; and [0009] E'''G. 4 is a block da.acr&3n of an electrolyte filter, storage and purnp syster- for use wi th ari a:.r cell according to one aspect of the p=eser_t inveritiiori.

DETAILED DESCRIPTION OF THE PREFERRED EMBGDIME\1TS

[0010] The present invention features an air cell system 10, figure 1, also known in the industry as a fuel cell, which is adaptable and useful for multiple applications including for providing power to an electricity ut'_lizing systera 12 (such as a generator or the like) or for providing hydrogen 14 to a hy--Jrogen utilizing system 1.6 such as an automobile combustion . . 1 .. . . ... . .... . . . . ...

engine or an electrical generation systeni, as will be detailed further below.

[0011] The air ce'1 system 10 includes an actual metal/air cell batte=y 18 which makes use of a typical aluminum or magnesivm air cell. The metal/air cell 18 is ccupled to an electrol~tte filter/pumps/storage unit 20 that is shown in greater detail in figure- 4. As is well known in the industry, an aluminum or magnesium a_r cell opera-tes continuously once the electrolyte, typically salt water, is inserted in the bat;.ery.
The chemical reaction between the electrclyte and the anode and cathode eontinues un-zi= e:ther the ancde or cathode is exFendcd or there is no more electrolyte. Ac,co_ciingly, one aspecr of --he present invention conV.ernplates providing the storace and filter ur.it 20 coupled to the metali 1ir cell 18 * o serve mult iple parposes.

[00121 Firs., l:tie elec--ro'vte filter, pump az-id stc=rage unit 20 includes a filter which serves to remove any aluminu:n or magnesium material contained in the electrolyte which is the result (byproduct) of the reaction within tre air cell 18. By providing one or mo_e pumps 24, the electrolyte 26 may be circulated between the air cell 18 and the storage unit 28 to filter out any ai-urninum, r.agnesium or other particles which might serve to reduce the life of the air cell 18 or contaminate .it and make i.t work less sufficiently.
[0013] The presant system aiso c4ntemplates a conl.rol signal 30 provided to Yonrrol the =unctions of the water purr.r!si 24.
Fo-- examole, wheri t.ae systeni of the present invention is usa-d in a vehicle and the vehicle's key is turned to the off posltion, a control signal 30 could be received and utilized to activate one of the water pumps 24 to drain the electrolyte 26 from the air cell 18, thus stopping the reaction within the air cell 18 and conserving the 14-fe of the air cell 18. Ccnverse].y, when rhe vehicle's ignition key is turr.ed on, a water pump 24 could be used to reverse the flow, fill the air cell 18 with electrolyte solution 26 thus causir.g the air cell 18 -:o begin and continae producing hydrogen and eleci r:'Lcity.

[0014] As shown in one elubod:_nenw in figure 2, the metal/air cell syste.a 1C may be utilized to produce hydrogen 35, a normal byproduct of the netal air battery 19. By proyidic:g the nydrogen output 35 of the meta7. air bal.Cery 18 tc a proton exchange membrane 32 and in addition providing a source of forced air 34, the proton exchange meirkbrane 32 (as described in greater detail in Appendix C attached hereto and fully incorporated hereir by reference) utilizes the hydrogen fuel as well as the oxygen =rom the forced air input 34 to transform the chemical energy expended during the electrochemical reaction of hydrogen and oxygen into electrical energy 36 and water 38. An excmplarv FE[-I men.brane irict.ides the copolymer NAFIDiq by Dupont - J ~

. .. . .. , . . . . . .. .. . .. . . ... .. . .. ... . . I ,.. ...,. .. ., .
.. .. . . ,. .. . . .

de Netr.ours Company. See Appendix D attached hereto and incorporated fully herein by reference for fur:.her information rPgarcii.ng this product. Ac:cuidirigly, by capturing the proc."uct of the reaction within the met al air battery (namely hydrcgen gas) and then introducing it through the PEM nembrane, the ccnsumables in the metal layer battery are utilized with greater efficiency by increasing the line output ;voltage and amperage', without having to increase the surface area of the anode or cathode within the metal air battery. Another feature of this invention is the provision of -eiectxieal and/or l5.quid/gas disconnects 33, 37 whi_ch a---ow the metal air battery 18 to be quicklv aiid eLiic,.i.eriL1y removed from the system 1.0 and rep?aced when the anode ar.u or cathode are either f.ully expended or reduced in effici-ercy So as needing to be changed.

j0015] ?n ar:other embodiment of the metal air '-batteri system 10, Figure 4, 9.n Use in a vehicle hydrogen cn demand system, an electrolysis unit B, 51, powered by electricity 49 froir a=uel cell 18 separates hydrogen and oxygen from water 50. The hydrogen 52 created from the electrolysis unit as well as the hydrogen 54 created from the air cell 18 is stored in one or nore tanks Di or D2 and utilized 56 as hydrogen input to an engine 58 in an automobile or other vehicle. Appropriate electror_xcs are used to control hydroqen flow rate, pressure switches and in;cctors, to control the floc. and speed of the . ..... . . I .. . ... . .. . ..... . . ._ . .

hydrogeri sent to the automobile's engine. In a hybrid s=tuat i.on, -ni.x.inc hydT:ugen wl.t}: gasoline can i ncrease thn engines efficiency by 15% or more. Thus, both the electrical and hydrogen outnut of the metal air battery systeff. ray be used in multiple applications at the same time.

[0016] Accordingly, the present ?nvent?on provides a rneta-, air battery system incorporating quick connect coupling for the battery; a metal air bat-:~ery electrolyte filter/pumpistorage device to disable the metal/air battery during periods.wnen the battery is not needed; and the ability- to harness the electric'ty anci/ux- hvdrogen output of the metal air ;e1 ] ei tt-er alone o~ through a PEM nembr.anc- tc produce additional e_'ectrici.ty or to utilize the hydrogen for other p-arposes includ=ng pcwering a vehicle.

[0017] Modificaticns and substitutions by one of crdinar.;; sKi.1.1 in the art arc considered to be within the scope of the present invention, which is not to be _imited except by the allowed claims and they are legally equivaler.ts.

Claims (2)

THE EMBODIMENTS OF THE INVENTION IN WHICH AN EXCLUSIVE
PROPERTY OR PRIVILEGE IS CLAIMED ARE DEFINED AS FOLLOWS:
1. A metal/air fuel cell, comprising a metal/air cell battery containing electrolyte;

an electrolyte filter, pump and storage unit coupled to the battery and containing a filter to remove aluminum or magnesium material in the electrolyte; and means to generate a control signal to cause the pump to remove the electrolyte from the battery when the fuel cell is not in use.
2. A metal/air fuel cell as disclosed in the specification and Figures 1 through 4 herein.
CA002651610A 2008-07-14 2009-01-29 Air cell energy system and uses for same Abandoned CA2651610A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US8048608P 2008-07-14 2008-07-14
US61/080,486 2008-07-14

Publications (1)

Publication Number Publication Date
CA2651610A1 true CA2651610A1 (en) 2010-01-14

Family

ID=41565864

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002651610A Abandoned CA2651610A1 (en) 2008-07-14 2009-01-29 Air cell energy system and uses for same

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CA (1) CA2651610A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014041447A1 (en) * 2012-09-11 2014-03-20 Neos Alternatives Inc Fuel and electrical power generating unit
US9768479B2 (en) 2014-01-02 2017-09-19 Phinergy Ltd. Hybrid metal air system and method

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014041447A1 (en) * 2012-09-11 2014-03-20 Neos Alternatives Inc Fuel and electrical power generating unit
US9768479B2 (en) 2014-01-02 2017-09-19 Phinergy Ltd. Hybrid metal air system and method

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Legal Events

Date Code Title Description
FZDE Discontinued
FZDE Discontinued

Effective date: 20120130