CA2617283C - Latex accelerator composition - Google Patents
Latex accelerator composition Download PDFInfo
- Publication number
- CA2617283C CA2617283C CA2617283A CA2617283A CA2617283C CA 2617283 C CA2617283 C CA 2617283C CA 2617283 A CA2617283 A CA 2617283A CA 2617283 A CA2617283 A CA 2617283A CA 2617283 C CA2617283 C CA 2617283C
- Authority
- CA
- Canada
- Prior art keywords
- latex
- rubber latex
- accelerator
- poly
- synthetic rubber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229920000126 latex Polymers 0.000 title claims abstract description 71
- 239000000203 mixture Substances 0.000 title claims abstract description 69
- 239000004816 latex Substances 0.000 title claims description 62
- -1 e.g. ZDEC) Chemical compound 0.000 claims abstract description 83
- 238000000034 method Methods 0.000 claims abstract description 25
- 238000004519 manufacturing process Methods 0.000 claims abstract description 21
- OWRCNXZUPFZXOS-UHFFFAOYSA-N 1,3-diphenylguanidine Chemical compound C=1C=CC=CC=1NC(=N)NC1=CC=CC=C1 OWRCNXZUPFZXOS-UHFFFAOYSA-N 0.000 claims abstract description 18
- 230000008569 process Effects 0.000 claims abstract description 18
- 229920006174 synthetic rubber latex Polymers 0.000 claims abstract description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 9
- FZWLAAWBMGSTSO-UHFFFAOYSA-N Thiazole Chemical compound C1=CSC=N1 FZWLAAWBMGSTSO-UHFFFAOYSA-N 0.000 claims abstract description 5
- 150000001993 dienes Chemical class 0.000 claims abstract description 4
- 229940116901 diethyldithiocarbamate Drugs 0.000 claims abstract description 4
- LMBWSYZSUOEYSN-UHFFFAOYSA-N diethyldithiocarbamic acid Chemical compound CCN(CC)C(S)=S LMBWSYZSUOEYSN-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229920002554 vinyl polymer Polymers 0.000 claims abstract description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 13
- 238000007598 dipping method Methods 0.000 claims description 9
- 229920003051 synthetic elastomer Polymers 0.000 claims description 8
- 239000012190 activator Substances 0.000 claims description 7
- 239000006185 dispersion Substances 0.000 claims description 7
- 238000002360 preparation method Methods 0.000 claims description 5
- 239000005061 synthetic rubber Substances 0.000 claims description 5
- 239000007787 solid Substances 0.000 claims description 4
- 239000000839 emulsion Substances 0.000 claims description 3
- 230000035800 maturation Effects 0.000 claims description 3
- 239000003054 catalyst Substances 0.000 claims 1
- RKQOSDAEEGPRER-UHFFFAOYSA-L zinc diethyldithiocarbamate Chemical compound [Zn+2].CCN(CC)C([S-])=S.CCN(CC)C([S-])=S RKQOSDAEEGPRER-UHFFFAOYSA-L 0.000 abstract description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 11
- 239000005864 Sulphur Substances 0.000 description 11
- 150000001875 compounds Chemical class 0.000 description 11
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 10
- 239000000701 coagulant Substances 0.000 description 9
- 239000012990 dithiocarbamate Substances 0.000 description 9
- 239000003381 stabilizer Substances 0.000 description 9
- 229920001971 elastomer Polymers 0.000 description 8
- DKVNPHBNOWQYFE-UHFFFAOYSA-N carbamodithioic acid Chemical compound NC(S)=S DKVNPHBNOWQYFE-UHFFFAOYSA-N 0.000 description 7
- 230000010198 maturation time Effects 0.000 description 7
- 239000005060 rubber Substances 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 description 5
- 229920002633 Kraton (polymer) Polymers 0.000 description 5
- 230000008901 benefit Effects 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- 239000011787 zinc oxide Substances 0.000 description 5
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 description 4
- 229940071162 caseinate Drugs 0.000 description 4
- 229920006173 natural rubber latex Polymers 0.000 description 4
- 230000000704 physical effect Effects 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 238000003860 storage Methods 0.000 description 4
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 4
- 244000043261 Hevea brasiliensis Species 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- ZRALSGWEFCBTJO-UHFFFAOYSA-N anhydrous guanidine Natural products NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 238000004132 cross linking Methods 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 238000002386 leaching Methods 0.000 description 3
- 229920003052 natural elastomer Polymers 0.000 description 3
- 229920001194 natural rubber Polymers 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- AUMBZPPBWALQRO-UHFFFAOYSA-L zinc;n,n-dibenzylcarbamodithioate Chemical compound [Zn+2].C=1C=CC=CC=1CN(C(=S)[S-])CC1=CC=CC=C1.C=1C=CC=CC=1CN(C(=S)[S-])CC1=CC=CC=C1 AUMBZPPBWALQRO-UHFFFAOYSA-L 0.000 description 3
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 102000014171 Milk Proteins Human genes 0.000 description 2
- 108010011756 Milk Proteins Proteins 0.000 description 2
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 description 2
- 150000004659 dithiocarbamates Chemical class 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000000806 elastomer Substances 0.000 description 2
- 230000036541 health Effects 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 235000021239 milk protein Nutrition 0.000 description 2
- IWDCLRJOBJJRNH-UHFFFAOYSA-N p-cresol Chemical compound CC1=CC=C(O)C=C1 IWDCLRJOBJJRNH-UHFFFAOYSA-N 0.000 description 2
- 229920001084 poly(chloroprene) Polymers 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 235000018102 proteins Nutrition 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- 239000000523 sample Substances 0.000 description 2
- 238000004073 vulcanization Methods 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- QRJZGVVKGFIGLI-UHFFFAOYSA-N 2-phenylguanidine Chemical compound NC(=N)NC1=CC=CC=C1 QRJZGVVKGFIGLI-UHFFFAOYSA-N 0.000 description 1
- 206010067484 Adverse reaction Diseases 0.000 description 1
- 102000011632 Caseins Human genes 0.000 description 1
- 108010076119 Caseins Proteins 0.000 description 1
- 241001323490 Colias gigantea Species 0.000 description 1
- 241000282414 Homo sapiens Species 0.000 description 1
- 206010020751 Hypersensitivity Diseases 0.000 description 1
- 241001082241 Lythrum hyssopifolia Species 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 229920001214 Polysorbate 60 Polymers 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 239000004141 Sodium laurylsulphate Substances 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 230000007059 acute toxicity Effects 0.000 description 1
- 231100000403 acute toxicity Toxicity 0.000 description 1
- 230000006838 adverse reaction Effects 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 239000013566 allergen Substances 0.000 description 1
- 208000026935 allergic disease Diseases 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 230000001413 cellular effect Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- SQEDZTDNVYVPQL-UHFFFAOYSA-N dodecylbenzene;sodium Chemical compound [Na].CCCCCCCCCCCCC1=CC=CC=C1 SQEDZTDNVYVPQL-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 231100000584 environmental toxicity Toxicity 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000003349 gelling agent Substances 0.000 description 1
- 230000008570 general process Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000002357 guanidines Chemical class 0.000 description 1
- 230000026030 halogenation Effects 0.000 description 1
- 238000005658 halogenation reaction Methods 0.000 description 1
- 238000012994 industrial processing Methods 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000003278 mimic effect Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 210000002445 nipple Anatomy 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229940080237 sodium caseinate Drugs 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000004763 sulfides Chemical class 0.000 description 1
- 125000004354 sulfur functional group Chemical group 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000012815 thermoplastic material Substances 0.000 description 1
- 150000007979 thiazole derivatives Chemical class 0.000 description 1
- 150000003557 thiazoles Chemical class 0.000 description 1
- 150000003585 thioureas Chemical class 0.000 description 1
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 1
- 229960002447 thiram Drugs 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0025—Crosslinking or vulcanising agents; including accelerators
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/29—Compounds containing one or more carbon-to-nitrogen double bonds
- C08K5/31—Guanidine; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/39—Thiocarbamic acids; Derivatives thereof, e.g. dithiocarbamates
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Orthopedics, Nursing, And Contraception (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP05107244.5 | 2005-08-05 | ||
| EP05107244 | 2005-08-05 | ||
| PCT/EP2006/064653 WO2007017375A1 (en) | 2005-08-05 | 2006-07-26 | Latex accelerator composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2617283A1 CA2617283A1 (en) | 2007-02-15 |
| CA2617283C true CA2617283C (en) | 2013-01-08 |
Family
ID=35276983
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2617283A Expired - Fee Related CA2617283C (en) | 2005-08-05 | 2006-07-26 | Latex accelerator composition |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US7700705B2 (enExample) |
| EP (1) | EP1910456B1 (enExample) |
| JP (1) | JP5137831B2 (enExample) |
| CN (1) | CN101238172B (enExample) |
| AT (1) | ATE547462T1 (enExample) |
| BR (1) | BRPI0615166B1 (enExample) |
| CA (1) | CA2617283C (enExample) |
| MY (1) | MY145566A (enExample) |
| RU (1) | RU2415159C2 (enExample) |
| WO (1) | WO2007017375A1 (enExample) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2617281C (en) * | 2005-08-05 | 2013-04-30 | Kraton Polymers Research B.V. | Latex accelerator composition |
| ZA200808544B (en) | 2006-03-31 | 2009-08-26 | Lrc Products | Polyisoprene condoms |
| WO2009088851A1 (en) * | 2008-01-04 | 2009-07-16 | C.R. Bard, Inc | Synthetic polyisoprene foley catheter |
| US8087412B2 (en) | 2008-05-01 | 2012-01-03 | Ansell Healthcare Products Llc | Dip-formed synthetic polyisoprene latex articles with improved intraparticle and interparticle crosslinks |
| US8795573B2 (en) * | 2008-06-30 | 2014-08-05 | C.R. Bard, Inc. | Polyurethane/polyisoprene blend catheter |
| CN102725342B (zh) | 2009-12-01 | 2015-11-25 | 高产有限公司 | 不使用硫化促进剂和硫的弹性体橡胶和橡胶产品 |
| JP2013517996A (ja) | 2010-01-22 | 2013-05-20 | アレジアンス、コーポレイション | 弾性物品を包装および殺菌する方法、並びにこれにより作製された包装済弾性物品 |
| CN101824175B (zh) * | 2010-04-15 | 2011-12-28 | 天津市橡胶工业研究所 | 用于制造掌指压力手套的胶层材料及其制备方法 |
| EP2771397A4 (en) | 2011-10-24 | 2015-06-10 | Bridgestone Americas Tire | SILICA-CHARGED RUBBER COMPOSITION AND METHOD FOR MANUFACTURING THE SAME |
| CN102975321B (zh) * | 2012-10-11 | 2015-03-25 | 上海名邦橡胶制品有限公司 | 一种采用聚异戊二烯胶乳制备避孕套的方法 |
| IN2013CH03083A (enExample) * | 2013-07-10 | 2015-09-25 | Ttk Protective Devices Ltd | |
| JP6368621B2 (ja) * | 2014-11-04 | 2018-08-01 | 株式会社レヂテックス | 柔軟性を有する高強度ポリイソプレン及びポリイソプレン組成物とその製造方法 |
| US10662269B2 (en) | 2017-08-31 | 2020-05-26 | Lifestyles Healthcare Pte. Ltd. | Ziegler-Natta catalyzed polyisoprene articles |
| MX2022007772A (es) | 2019-12-20 | 2022-09-09 | Church & Dwight Co Inc | Composiciones polimericas y productos formados con las mismas. |
| EP4077519A4 (en) | 2019-12-20 | 2024-04-10 | Church & Dwight Co., Inc. | Polymer compositions and products formed therewith |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB126626A (enExample) * | ||||
| IT454601A (enExample) * | 1943-03-22 | 1900-01-01 | ||
| GB696678A (en) * | 1950-05-12 | 1953-09-09 | Dunlop Rubber Co | Improvements in the vulcanisation of rubber |
| FR1562379A (enExample) | 1967-04-12 | 1969-04-04 | ||
| FR2039696A5 (enExample) * | 1969-03-20 | 1971-01-15 | Schildkroet Ag | |
| BR9916397B1 (pt) * | 1998-12-22 | 2008-11-18 | pneu para veÍculos tendo alta resistÊncia ao desgaste, banda de rodagem para pneus de veÍculo, composiÇço de borracha vulcanizÁvel, e, sistema de vulcanizaÇço de uma composiÇço de borracha. | |
| JP2002145965A (ja) * | 2000-08-30 | 2002-05-22 | Jsr Corp | 共役ジエン系ゴム及び油展ゴム並びにこれらを含むゴム組成物 |
| JP4774654B2 (ja) * | 2000-08-30 | 2011-09-14 | Ｊｓｒ株式会社 | 油展ゴム及びゴム組成物 |
| AU2275902A (en) | 2000-12-19 | 2002-07-01 | Hae-Jun Park | A method for producing the sustained-releasing agricultural chemicals |
| NZ522334A (en) * | 2001-03-12 | 2004-08-27 | Allegiance Corp | Elastomeric polyisoprene articles and process for making the same |
| US20030161975A1 (en) | 2002-02-27 | 2003-08-28 | Lucas David M. | Polyisoprene condom |
| JP2005021474A (ja) * | 2003-07-04 | 2005-01-27 | Sumitomo Rubber Ind Ltd | 卓球用ラバーシート |
| US7041746B2 (en) | 2003-09-24 | 2006-05-09 | R.T. Vanderbilt Company, Inc. | Accelerator system for synthetic polyisoprene latex |
| US8117672B2 (en) * | 2005-05-13 | 2012-02-21 | Kimberly-Clark Worldwide Inc. | Nitrile rubber article having natural rubber characteristics |
-
2006
- 2006-07-26 RU RU2008106847/04A patent/RU2415159C2/ru active
- 2006-07-26 JP JP2008524486A patent/JP5137831B2/ja not_active Expired - Fee Related
- 2006-07-26 CN CN2006800284806A patent/CN101238172B/zh active Active
- 2006-07-26 CA CA2617283A patent/CA2617283C/en not_active Expired - Fee Related
- 2006-07-26 US US11/997,842 patent/US7700705B2/en active Active
- 2006-07-26 BR BRPI0615166-3A patent/BRPI0615166B1/pt not_active IP Right Cessation
- 2006-07-26 EP EP06806730A patent/EP1910456B1/en not_active Not-in-force
- 2006-07-26 WO PCT/EP2006/064653 patent/WO2007017375A1/en not_active Ceased
- 2006-07-26 AT AT06806730T patent/ATE547462T1/de active
- 2006-08-03 MY MYPI20063762A patent/MY145566A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| ATE547462T1 (de) | 2012-03-15 |
| RU2415159C2 (ru) | 2011-03-27 |
| BRPI0615166A2 (pt) | 2013-01-08 |
| JP5137831B2 (ja) | 2013-02-06 |
| CN101238172A (zh) | 2008-08-06 |
| RU2008106847A (ru) | 2009-09-10 |
| MY145566A (en) | 2012-02-27 |
| US20090118435A1 (en) | 2009-05-07 |
| EP1910456B1 (en) | 2012-02-29 |
| EP1910456A1 (en) | 2008-04-16 |
| CN101238172B (zh) | 2012-01-18 |
| US7700705B2 (en) | 2010-04-20 |
| JP2009513752A (ja) | 2009-04-02 |
| BRPI0615166B1 (pt) | 2017-06-13 |
| WO2007017375A1 (en) | 2007-02-15 |
| CA2617283A1 (en) | 2007-02-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA2408626C (en) | Polyisoprene articles and process for making the same | |
| US8673172B2 (en) | Latex accelerator composition | |
| EP1910456B1 (en) | Latex accelerator composition | |
| KR101715213B1 (ko) | 알레르기 유발 가능성이 감소된 가황 조성물 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKLA | Lapsed |
Effective date: 20190726 |