CA2588830A1 - Prismatic retroreflective article and method - Google Patents
Prismatic retroreflective article and method Download PDFInfo
- Publication number
- CA2588830A1 CA2588830A1 CA002588830A CA2588830A CA2588830A1 CA 2588830 A1 CA2588830 A1 CA 2588830A1 CA 002588830 A CA002588830 A CA 002588830A CA 2588830 A CA2588830 A CA 2588830A CA 2588830 A1 CA2588830 A1 CA 2588830A1
- Authority
- CA
- Canada
- Prior art keywords
- cube
- corner
- optical elements
- retroreflective article
- coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 238000000034 method Methods 0.000 title claims description 35
- 238000000576 coating method Methods 0.000 claims abstract description 83
- 239000011248 coating agent Substances 0.000 claims abstract description 78
- 230000003287 optical effect Effects 0.000 claims abstract description 74
- 230000002209 hydrophobic effect Effects 0.000 claims abstract description 18
- 239000000463 material Substances 0.000 claims description 38
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 23
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 12
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 12
- 239000011737 fluorine Substances 0.000 claims description 12
- 229910052731 fluorine Inorganic materials 0.000 claims description 12
- 239000002480 mineral oil Substances 0.000 claims description 11
- 235000010446 mineral oil Nutrition 0.000 claims description 11
- QYSGYZVSCZSLHT-UHFFFAOYSA-N octafluoropropane Chemical compound FC(F)(F)C(F)(F)C(F)(F)F QYSGYZVSCZSLHT-UHFFFAOYSA-N 0.000 claims description 8
- 229920000642 polymer Polymers 0.000 claims description 8
- CZDYPVPMEAXLPK-UHFFFAOYSA-N tetramethylsilane Chemical compound C[Si](C)(C)C CZDYPVPMEAXLPK-UHFFFAOYSA-N 0.000 claims description 8
- 229960004065 perflutren Drugs 0.000 claims description 7
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims description 6
- 229910052710 silicon Inorganic materials 0.000 claims description 6
- 239000010703 silicon Substances 0.000 claims description 6
- 238000003892 spreading Methods 0.000 claims description 6
- 230000007480 spreading Effects 0.000 claims description 6
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 5
- 239000011324 bead Substances 0.000 claims description 5
- 239000004744 fabric Substances 0.000 claims description 5
- 229910000077 silane Inorganic materials 0.000 claims description 5
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims description 4
- 239000003921 oil Substances 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 3
- 125000001153 fluoro group Chemical group F* 0.000 claims description 3
- 125000002524 organometallic group Chemical group 0.000 claims description 3
- KAVGMUDTWQVPDF-UHFFFAOYSA-N perflubutane Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(F)(F)F KAVGMUDTWQVPDF-UHFFFAOYSA-N 0.000 claims description 3
- 229950003332 perflubutane Drugs 0.000 claims description 3
- 230000000379 polymerizing effect Effects 0.000 claims description 3
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 2
- 239000002318 adhesion promoter Substances 0.000 claims description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical class CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 18
- 239000000203 mixture Substances 0.000 description 18
- 239000007788 liquid Substances 0.000 description 17
- 238000011282 treatment Methods 0.000 description 16
- 239000003570 air Substances 0.000 description 14
- 239000010410 layer Substances 0.000 description 13
- 208000028659 discharge Diseases 0.000 description 12
- 239000013039 cover film Substances 0.000 description 11
- 210000002381 plasma Anatomy 0.000 description 10
- 239000010408 film Substances 0.000 description 9
- 238000000151 deposition Methods 0.000 description 8
- 239000000178 monomer Substances 0.000 description 7
- -1 polydimethylsiloxane Polymers 0.000 description 7
- 210000004027 cell Anatomy 0.000 description 6
- 238000001723 curing Methods 0.000 description 5
- 230000008021 deposition Effects 0.000 description 5
- 238000004458 analytical method Methods 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 230000005855 radiation Effects 0.000 description 4
- 241001354243 Corona Species 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
- 239000012159 carrier gas Substances 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 239000004205 dimethyl polysiloxane Substances 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- 239000003999 initiator Substances 0.000 description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 239000003350 kerosene Substances 0.000 description 3
- 238000004900 laundering Methods 0.000 description 3
- 239000011707 mineral Substances 0.000 description 3
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 3
- 239000002356 single layer Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 235000015096 spirit Nutrition 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- 238000005011 time of flight secondary ion mass spectroscopy Methods 0.000 description 3
- 238000002042 time-of-flight secondary ion mass spectrometry Methods 0.000 description 3
- 238000009834 vaporization Methods 0.000 description 3
- 230000008016 vaporization Effects 0.000 description 3
- 239000004593 Epoxy Substances 0.000 description 2
- 229920001730 Moisture cure polyurethane Polymers 0.000 description 2
- 229910018503 SF6 Inorganic materials 0.000 description 2
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 239000000356 contaminant Substances 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 238000003682 fluorination reaction Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- WMIYKQLTONQJES-UHFFFAOYSA-N hexafluoroethane Chemical compound FC(F)(F)C(F)(F)F WMIYKQLTONQJES-UHFFFAOYSA-N 0.000 description 2
- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical group FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 description 2
- FFUAGWLWBBFQJT-UHFFFAOYSA-N hexamethyldisilazane Chemical compound C[Si](C)(C)N[Si](C)(C)C FFUAGWLWBBFQJT-UHFFFAOYSA-N 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 238000009832 plasma treatment Methods 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 239000004800 polyvinyl chloride Substances 0.000 description 2
- 229920000915 polyvinyl chloride Polymers 0.000 description 2
- 150000004756 silanes Chemical class 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- SFZCNBIFKDRMGX-UHFFFAOYSA-N sulfur hexafluoride Chemical compound FS(F)(F)(F)(F)F SFZCNBIFKDRMGX-UHFFFAOYSA-N 0.000 description 2
- 229960000909 sulfur hexafluoride Drugs 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- TXEYQDLBPFQVAA-UHFFFAOYSA-N tetrafluoromethane Chemical compound FC(F)(F)F TXEYQDLBPFQVAA-UHFFFAOYSA-N 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- 229920001187 thermosetting polymer Polymers 0.000 description 2
- PQDJYEQOELDLCP-UHFFFAOYSA-N trimethylsilane Chemical compound C[SiH](C)C PQDJYEQOELDLCP-UHFFFAOYSA-N 0.000 description 2
- 238000003466 welding Methods 0.000 description 2
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 description 1
- SLQSAXBGNRDQOO-UHFFFAOYSA-N 1,1,1,2,2,3,3,4,4,4-decafluorobutane 2-methylprop-2-enoic acid Chemical compound CC(=C)C(O)=O.FC(F)(F)C(F)(F)C(F)(F)C(F)(F)F SLQSAXBGNRDQOO-UHFFFAOYSA-N 0.000 description 1
- PFSGCDAVFATYPC-UHFFFAOYSA-N 1,1,1,2,2,3,3,4,4,4-decafluorobutane prop-2-enoic acid Chemical compound OC(=O)C=C.FC(F)(F)C(F)(F)C(F)(F)C(F)(F)F PFSGCDAVFATYPC-UHFFFAOYSA-N 0.000 description 1
- LSSVYTAUPWOSRM-UHFFFAOYSA-N 1,1,1,2,3,5,6,6,6-nonafluoro-2,4,5-tris(trifluoromethyl)hex-3-ene Chemical compound FC(F)(F)C(F)(C(F)(F)F)C(F)=C(C(F)(F)F)C(F)(C(F)(F)F)C(F)(F)F LSSVYTAUPWOSRM-UHFFFAOYSA-N 0.000 description 1
- MTYRFJCUDAVINP-UHFFFAOYSA-N 1,1,1,3,4,5,6,6,6-nonafluoro-2,4,5-tris(trifluoromethyl)hex-2-ene Chemical compound FC(F)(F)C(C(F)(F)F)=C(F)C(F)(C(F)(F)F)C(F)(C(F)(F)F)C(F)(F)F MTYRFJCUDAVINP-UHFFFAOYSA-N 0.000 description 1
- WQVUNWUPDZCKNZ-UHFFFAOYSA-N 1,1,1,4,4,5,6,6,6-nonafluoro-2,3,5-tris(trifluoromethyl)hex-2-ene Chemical compound FC(F)(F)C(C(F)(F)F)=C(C(F)(F)F)C(F)(F)C(F)(C(F)(F)F)C(F)(F)F WQVUNWUPDZCKNZ-UHFFFAOYSA-N 0.000 description 1
- LVJZCPNIJXVIAT-UHFFFAOYSA-N 1-ethenyl-2,3,4,5,6-pentafluorobenzene Chemical compound FC1=C(F)C(F)=C(C=C)C(F)=C1F LVJZCPNIJXVIAT-UHFFFAOYSA-N 0.000 description 1
- VOBUAPTXJKMNCT-UHFFFAOYSA-N 1-prop-2-enoyloxyhexyl prop-2-enoate Chemical compound CCCCCC(OC(=O)C=C)OC(=O)C=C VOBUAPTXJKMNCT-UHFFFAOYSA-N 0.000 description 1
- YSQGYEYXKXGAQA-UHFFFAOYSA-N 2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluorooctyl prop-2-enoate Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)COC(=O)C=C YSQGYEYXKXGAQA-UHFFFAOYSA-N 0.000 description 1
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 description 1
- DOKVLJLABBCKOJ-UHFFFAOYSA-N 6-hydrazinyl-1,3,5-triazine-2,4-diamine Chemical group NNC1=NC(N)=NC(N)=N1 DOKVLJLABBCKOJ-UHFFFAOYSA-N 0.000 description 1
- 229920012485 Plasticized Polyvinyl chloride Polymers 0.000 description 1
- 229910007159 Si(CH3)4 Inorganic materials 0.000 description 1
- 150000003926 acrylamides Chemical class 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 125000003172 aldehyde group Chemical group 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000012080 ambient air Substances 0.000 description 1
- 230000000386 athletic effect Effects 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical group OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 238000005229 chemical vapour deposition Methods 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000003851 corona treatment Methods 0.000 description 1
- 229920006037 cross link polymer Polymers 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 description 1
- 230000005281 excited state Effects 0.000 description 1
- 238000007765 extrusion coating Methods 0.000 description 1
- 238000009501 film coating Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000004811 fluoropolymer Substances 0.000 description 1
- 229920002313 fluoropolymer Polymers 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000007756 gravure coating Methods 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 238000010884 ion-beam technique Methods 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 239000012948 isocyanate Chemical group 0.000 description 1
- 150000002513 isocyanates Chemical group 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical class CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 150000001282 organosilanes Chemical class 0.000 description 1
- 125000001181 organosilyl group Chemical group [SiH3]* 0.000 description 1
- 229960004692 perflenapent Drugs 0.000 description 1
- NJCBUSHGCBERSK-UHFFFAOYSA-N perfluoropentane Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F NJCBUSHGCBERSK-UHFFFAOYSA-N 0.000 description 1
- 238000005240 physical vapour deposition Methods 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 238000003847 radiation curing Methods 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 238000009958 sewing Methods 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- 125000005504 styryl group Chemical group 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 230000002459 sustained effect Effects 0.000 description 1
- MUTNCGKQJGXKEM-UHFFFAOYSA-N tamibarotene Chemical compound C=1C=C2C(C)(C)CCC(C)(C)C2=CC=1NC(=O)C1=CC=C(C(O)=O)C=C1 MUTNCGKQJGXKEM-UHFFFAOYSA-N 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 238000005809 transesterification reaction Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
- XYJRNCYWTVGEEG-UHFFFAOYSA-N trimethoxy(2-methylpropyl)silane Chemical compound CO[Si](OC)(OC)CC(C)C XYJRNCYWTVGEEG-UHFFFAOYSA-N 0.000 description 1
- NMEPHPOFYLLFTK-UHFFFAOYSA-N trimethoxy(octyl)silane Chemical compound CCCCCCCC[Si](OC)(OC)OC NMEPHPOFYLLFTK-UHFFFAOYSA-N 0.000 description 1
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 description 1
- 229920011532 unplasticized polyvinyl chloride Polymers 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Chemical group 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/12—Reflex reflectors
- G02B5/122—Reflex reflectors cube corner, trihedral or triple reflector type
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/12—Reflex reflectors
- G02B5/122—Reflex reflectors cube corner, trihedral or triple reflector type
- G02B5/124—Reflex reflectors cube corner, trihedral or triple reflector type plural reflecting elements forming part of a unitary plate or sheet
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Optical Elements Other Than Lenses (AREA)
- Laminated Bodies (AREA)
- Road Signs Or Road Markings (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/023,857 | 2004-12-28 | ||
| US11/023,857 US7195360B2 (en) | 2004-12-28 | 2004-12-28 | Prismatic retroreflective article and method |
| PCT/US2005/044218 WO2006071478A1 (en) | 2004-12-28 | 2005-12-06 | Prismatic retroreflective article and method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2588830A1 true CA2588830A1 (en) | 2006-07-06 |
Family
ID=36088567
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002588830A Abandoned CA2588830A1 (en) | 2004-12-28 | 2005-12-06 | Prismatic retroreflective article and method |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US7195360B2 (OSRAM) |
| EP (1) | EP1831734B1 (OSRAM) |
| JP (1) | JP2008525856A (OSRAM) |
| KR (2) | KR101308271B1 (OSRAM) |
| CN (1) | CN100593126C (OSRAM) |
| AU (1) | AU2005322446B2 (OSRAM) |
| BR (1) | BRPI0519505A2 (OSRAM) |
| CA (1) | CA2588830A1 (OSRAM) |
| MX (1) | MX2007007693A (OSRAM) |
| NO (1) | NO20073684L (OSRAM) |
| WO (1) | WO2006071478A1 (OSRAM) |
Families Citing this family (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8945684B2 (en) * | 2005-11-04 | 2015-02-03 | Essilor International (Compagnie Generale D'optique) | Process for coating an article with an anti-fouling surface coating by vacuum evaporation |
| US8080073B2 (en) * | 2007-12-20 | 2011-12-20 | 3M Innovative Properties Company | Abrasive article having a plurality of precisely-shaped abrasive composites |
| CN101925441B (zh) * | 2007-12-31 | 2013-08-14 | 3M创新有限公司 | 经等离子处理的磨料制品及其制造方法 |
| EP2271490B1 (en) * | 2008-04-30 | 2019-10-09 | Nanosys, Inc. | Non-fouling surfaces for reflective spheres |
| EP2368147A4 (en) * | 2008-12-08 | 2018-01-24 | 3M Innovative Properties Company | Protective overlay bearing a graphic and retroreflective articles comprising the overlay |
| KR101610427B1 (ko) | 2008-12-08 | 2016-04-07 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 그래픽을 갖는 프리즘형 재귀반사성 물품 및 이를 제조하는 방법 |
| IN2011CN07418A (OSRAM) | 2009-04-15 | 2015-08-21 | 3M Innovative Properties Co | |
| CN102460125B (zh) | 2009-04-15 | 2015-11-25 | 3M创新有限公司 | 防止光学耦合的光学膜 |
| TWI605276B (zh) | 2009-04-15 | 2017-11-11 | ３Ｍ新設資產公司 | 光學結構及包含該光學結構之顯示系統 |
| JP2012524381A (ja) | 2009-04-15 | 2012-10-11 | スリーエム イノベイティブ プロパティズ カンパニー | ボイドを含有する光学フィルムを備える光ガイド及びディスプレイシステム用ブラックライト |
| US9291752B2 (en) | 2013-08-19 | 2016-03-22 | 3M Innovative Properties Company | Retroreflecting optical construction |
| JP5727718B2 (ja) * | 2009-05-16 | 2015-06-03 | デクセリアルズ株式会社 | 光学体およびその製造方法、窓材、建具、ならびに日射遮蔽装置 |
| MX341955B (es) | 2010-04-15 | 2016-09-08 | 3M Innovative Properties Co | Articulos retrorreflectantes que incluyen areas opticamente activas y areas opticamente inactivas. |
| MX341957B (es) | 2010-04-15 | 2016-09-08 | 3M Innovative Properties Co | Articulos retrorreflectantes que incluyen areas opticamente activas y areas opticamente inactivas. |
| MX341289B (es) | 2010-04-15 | 2016-08-12 | 3M Innovative Properties Co | Articulos retrorreflectantes que incluyen areas opticamente activas y areas opticamente inactivas. |
| US11774648B2 (en) * | 2010-05-07 | 2023-10-03 | Pti Ip Llc | Corner-cube irradiation control |
| CN102200599B (zh) * | 2011-07-20 | 2013-01-02 | 天津大学 | 一种具有逆反射性能的微棱镜及其模具制作方法 |
| EP2978567B1 (en) | 2013-03-29 | 2023-12-27 | 3M Innovative Properties Company | Nonwoven abrasive articles and methods of making the same |
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-
2004
- 2004-12-28 US US11/023,857 patent/US7195360B2/en not_active Expired - Fee Related
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2005
- 2005-12-06 BR BRPI0519505-5A patent/BRPI0519505A2/pt not_active IP Right Cessation
- 2005-12-06 MX MX2007007693A patent/MX2007007693A/es active IP Right Grant
- 2005-12-06 CA CA002588830A patent/CA2588830A1/en not_active Abandoned
- 2005-12-06 KR KR1020127015270A patent/KR101308271B1/ko not_active Expired - Fee Related
- 2005-12-06 WO PCT/US2005/044218 patent/WO2006071478A1/en not_active Ceased
- 2005-12-06 CN CN200580045261A patent/CN100593126C/zh not_active Expired - Fee Related
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- 2005-12-06 EP EP05853205A patent/EP1831734B1/en not_active Expired - Lifetime
- 2005-12-06 KR KR1020077014580A patent/KR20070089715A/ko not_active Ceased
- 2005-12-06 JP JP2007549402A patent/JP2008525856A/ja active Pending
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2007
- 2007-07-17 NO NO20073684A patent/NO20073684L/no not_active Application Discontinuation
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| NO20073684L (no) | 2007-09-28 |
| KR20120079176A (ko) | 2012-07-11 |
| CN100593126C (zh) | 2010-03-03 |
| EP1831734B1 (en) | 2012-08-08 |
| AU2005322446A1 (en) | 2006-07-06 |
| KR20070089715A (ko) | 2007-08-31 |
| US7195360B2 (en) | 2007-03-27 |
| AU2005322446B2 (en) | 2009-10-01 |
| EP1831734A1 (en) | 2007-09-12 |
| KR101308271B1 (ko) | 2013-09-13 |
| MX2007007693A (es) | 2007-08-21 |
| US20060139754A1 (en) | 2006-06-29 |
| CN101091124A (zh) | 2007-12-19 |
| JP2008525856A (ja) | 2008-07-17 |
| WO2006071478A1 (en) | 2006-07-06 |
| BRPI0519505A2 (pt) | 2009-07-14 |
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