CA2581187C - Ex-situ reduction and dry passivation of noble metal catalysts - Google Patents

Ex-situ reduction and dry passivation of noble metal catalysts Download PDF

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Publication number
CA2581187C
CA2581187C CA2581187A CA2581187A CA2581187C CA 2581187 C CA2581187 C CA 2581187C CA 2581187 A CA2581187 A CA 2581187A CA 2581187 A CA2581187 A CA 2581187A CA 2581187 C CA2581187 C CA 2581187C
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CA
Canada
Prior art keywords
catalyst
oil
noble metal
reduced
dry
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
CA2581187A
Other languages
English (en)
French (fr)
Other versions
CA2581187A1 (en
Inventor
Stephen J. Mccarthy
Jean W. Beeckman
William G. Borghard
Sylvain Hantzer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
ExxonMobil Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ExxonMobil Research and Engineering Co filed Critical ExxonMobil Research and Engineering Co
Publication of CA2581187A1 publication Critical patent/CA2581187A1/en
Application granted granted Critical
Publication of CA2581187C publication Critical patent/CA2581187C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/03—Catalysts comprising molecular sieves not having base-exchange properties
    • B01J29/0308—Mesoporous materials not having base exchange properties, e.g. Si-MCM-41
    • B01J29/0316—Mesoporous materials not having base exchange properties, e.g. Si-MCM-41 containing iron group metals, noble metals or copper
    • B01J29/0325—Noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/42—Platinum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/041—Mesoporous materials having base exchange properties, e.g. Si/Al-MCM-41
    • B01J29/042—Mesoporous materials having base exchange properties, e.g. Si/Al-MCM-41 containing iron group metals, noble metals or copper
    • B01J29/043—Noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/064—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/06—Washing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/12—Oxidising
    • B01J37/14—Oxidising with gases containing free oxygen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B01J37/18—Reducing with gases containing free hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/20—Sulfiding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391—Physical properties of the active metal ingredient
    • B01J35/394—Metal dispersion value, e.g. percentage or fraction

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Manufacture And Refinement Of Metals (AREA)
CA2581187A 2004-10-01 2005-09-27 Ex-situ reduction and dry passivation of noble metal catalysts Expired - Lifetime CA2581187C (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US61501604P 2004-10-01 2004-10-01
US60/615,016 2004-10-01
US11/228,366 2005-09-16
US11/228,366 US7407909B2 (en) 2004-10-01 2005-09-16 Ex-situ reduction and dry passivation of noble metal catalysts
PCT/US2005/034752 WO2006039316A2 (en) 2004-10-01 2005-09-27 Ex-situ reduction and dry passivation of noble metal catalysts

Publications (2)

Publication Number Publication Date
CA2581187A1 CA2581187A1 (en) 2006-04-13
CA2581187C true CA2581187C (en) 2012-08-07

Family

ID=36126285

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2581187A Expired - Lifetime CA2581187C (en) 2004-10-01 2005-09-27 Ex-situ reduction and dry passivation of noble metal catalysts

Country Status (7)

Country Link
US (1) US7407909B2 (enExample)
EP (1) EP1814664A4 (enExample)
JP (1) JP5134958B2 (enExample)
KR (1) KR101192455B1 (enExample)
CA (1) CA2581187C (enExample)
RU (1) RU2376060C2 (enExample)
WO (1) WO2006039316A2 (enExample)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2850882B1 (fr) * 2003-02-11 2005-03-18 Eurecat Sa Passivation de catalyseur d'hydroconversion sulfure
KR101274995B1 (ko) * 2006-08-31 2013-06-14 재단법인 포항산업과학연구원 고활성 다이옥신 분해용 슬러리형 Ｐｄ／Ｃ 촉매, 그제조방법 및 이를 이용한 다이옥신 분해 방법
WO2015050635A1 (en) 2013-10-03 2015-04-09 Exxonmobil Chemical Patents Inc. Hydrocarbon raffinate stream processing
EP3137212A1 (en) * 2014-04-30 2017-03-08 ExxonMobil Chemical Patents Inc. Method of improving metal-impregnated catalyst performance
CN110997144A (zh) 2017-08-03 2020-04-10 埃克森美孚研究工程公司 利用含水气流活化硅质载体上的贵金属催化剂
KR102533944B1 (ko) * 2019-01-25 2023-05-17 엑손모빌 케미칼 패턴츠 인코포레이티드 저 금속 함량 촉매의 활성화
US11433386B2 (en) 2019-01-25 2022-09-06 Exxonmobil Chemical Patents Inc. Activation of low metal content catalyst
CN114522682B (zh) * 2020-11-23 2024-04-26 中国科学院大连化学物理研究所 一种炭载双金属单原子催化剂及其制备方法

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2850719A1 (de) * 1978-11-23 1980-07-10 Winsel August Prof Dipl Phys D Verfahren zur herstellung eines gegen die oxidation durch luftsauerstoff geschuetzten nickel-katalysators
US4372841A (en) * 1979-12-31 1983-02-08 Exxon Research And Engineering Co. Process for reducing coke formation in heavy feed catalytic cracking
GB2118453B (en) * 1982-03-12 1985-06-26 British Gas Corp Passivated nickel-alumina catalysts
WO1994025157A1 (en) * 1993-05-04 1994-11-10 Cri International, Inc. A method of treating spontaneously combustible catalysts
FI955379L (fi) * 1993-05-10 1995-11-08 Akzo Nobel Nv Hiilivetypitoisissa syötteissä esiintyvien aromaattisten yhdisteiden hydraus
US5451312A (en) * 1993-10-26 1995-09-19 Mobil Oil Corporation Catalyst and process for producing low-aromatics distillates
JP3609830B2 (ja) * 1993-12-20 2005-01-12 モービル・オイル・コーポレイション 水素化方法
FR2725381B1 (fr) * 1994-10-07 1996-12-13 Eurecat Europ Retrait Catalys Procede de pretraitement hors site d'un catalyseur de traitement d'hydrocarbures
FR2749779B1 (fr) * 1996-06-12 1998-09-11 Eurecat Europ Retrait Catalys Procede de presulfuration de catalyseurs d'hydrotraitement
FR2767072B1 (fr) * 1997-08-11 1999-09-10 Eurecat Europ Retrait Catalys Protection de catalyseurs par depot de couche protectrice
DE19909175A1 (de) * 1999-03-03 2000-09-07 Kataleuna Gmbh Catalysts Verfahren zur Passivierung pyrophorer Katalysatoren
US6930219B2 (en) * 1999-09-07 2005-08-16 Abb Lummus Global Inc. Mesoporous material with active metals
JP4394787B2 (ja) * 1999-12-16 2010-01-06 独立行政法人産業技術総合研究所 芳香族炭化水素の水素化触媒組成物
AU2001262173A1 (en) * 2000-04-11 2001-10-23 Akzo Nobel N.V. Process for sulphiding an additive-containing catalyst
US7094333B2 (en) * 2001-09-04 2006-08-22 The Regents Of The University Of Michigan Selective sorbents for purification of hydrocarbons
JP2003284961A (ja) * 2002-03-27 2003-10-07 National Institute Of Advanced Industrial & Technology 炭化水素の水素化処理触媒組成物の製造方法
US7528092B2 (en) * 2002-10-18 2009-05-05 Basf Catalysts Llc Nickel catalyst for hydrogenation reactions
FR2850882B1 (fr) * 2003-02-11 2005-03-18 Eurecat Sa Passivation de catalyseur d'hydroconversion sulfure
FR2854335B1 (fr) * 2003-04-30 2009-03-20 Eurecat Sa Traitement hors site de catalyseurs d'hydrogenation
US20060073961A1 (en) * 2004-09-08 2006-04-06 Mccarthy Stephen J Noble metal-containing catalyst having a specific average pore diameter

Also Published As

Publication number Publication date
RU2376060C2 (ru) 2009-12-20
KR20070063572A (ko) 2007-06-19
EP1814664A2 (en) 2007-08-08
US7407909B2 (en) 2008-08-05
RU2007114109A (ru) 2008-11-10
US20060073965A1 (en) 2006-04-06
CA2581187A1 (en) 2006-04-13
WO2006039316A3 (en) 2006-09-08
EP1814664A4 (en) 2011-05-11
JP2008514420A (ja) 2008-05-08
WO2006039316A2 (en) 2006-04-13
KR101192455B1 (ko) 2012-10-17
JP5134958B2 (ja) 2013-01-30

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