CA2525559A1 - Method for recovering metallic elements, especially metallic chromium, from slag containing metal oxides in an electric-arc furnace - Google Patents

Method for recovering metallic elements, especially metallic chromium, from slag containing metal oxides in an electric-arc furnace Download PDF

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Publication number
CA2525559A1
CA2525559A1 CA 2525559 CA2525559A CA2525559A1 CA 2525559 A1 CA2525559 A1 CA 2525559A1 CA 2525559 CA2525559 CA 2525559 CA 2525559 A CA2525559 A CA 2525559A CA 2525559 A1 CA2525559 A1 CA 2525559A1
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CA
Canada
Prior art keywords
slag
melt
tapping
charge
chromium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA 2525559
Other languages
French (fr)
Other versions
CA2525559C (en
Inventor
Bernt Rollinger
Johann Reichel
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SMS Siemag AG
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Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of CA2525559A1 publication Critical patent/CA2525559A1/en
Application granted granted Critical
Publication of CA2525559C publication Critical patent/CA2525559C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B34/00Obtaining refractory metals
    • C22B34/30Obtaining chromium, molybdenum or tungsten
    • C22B34/32Obtaining chromium
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C5/00Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
    • C21C5/52Manufacture of steel in electric furnaces
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C5/00Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
    • C21C5/52Manufacture of steel in electric furnaces
    • C21C5/5264Manufacture of alloyed steels including ferro-alloys
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C5/00Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
    • C21C5/56Manufacture of steel by other methods
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C7/00Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
    • C21C7/0087Treatment of slags covering the steel bath, e.g. for separating slag from the molten metal
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B5/00General methods of reducing to metals
    • C22B5/02Dry methods smelting of sulfides or formation of mattes
    • C22B5/10Dry methods smelting of sulfides or formation of mattes by solid carbonaceous reducing agents
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B7/00Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
    • C22B7/04Working-up slag
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C5/00Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
    • C21C5/52Manufacture of steel in electric furnaces
    • C21C5/527Charging of the electric furnace
    • C21C2005/5276Charging of the electric furnace with liquid or solid rest, e.g. pool, "sumpf"
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Refinement Of Pig-Iron, Manufacture Of Cast Iron, And Steel Manufacture Other Than In Revolving Furnaces (AREA)
  • Treatment Of Steel In Its Molten State (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Carbon Steel Or Casting Steel Manufacturing (AREA)

Abstract

The invention relates to a method for recovering metallic elements, especially metallic chromium, from slag containing oxides, especially chromium oxides, in an electric-arc furnace. According to said method, the slag is not reduced in a separate step after melting, but the following steps are carried out: a charge is introduced into the electric-arc furnace, and melted, forming a molten metal and slag; said molten metal is tapped off, leaving the unreduced slag in the furnace vessel; a further charge of scrap metal including reducing agents for the slag is added; the slag is reduced during the melting of said charge; and the slag and the molten metal are then tapped off. The inventive method can also be used in ladle metallurgy or converter metallurgy.

Claims (7)

1. Method for recovering metallic elements, especially metallic chromium, from stags that contain oxides, especially chromium oxides, in an electric arc furnace, with the following steps:
(a) introduction of a charge into the arc furnace;
(b) meltdown of the charge to produce a metal melt and slag;
(c) tapping of the melt while leaving the unreduced slag in the furnace vessel;
(d) introduction of another charge that contains scrap and reducing agents for the slag, such as carbon and/or silicon and/or aluminum;
(e) meltdown and direct reduction of the slag, especially direct reduction of chromium oxide, by the reducing agents in the charge during the melting process;
(g) tapping of the melt and the reduced slag.
2. Method in accordance with Claim 1, characterized by -- the melting down of a buildup melt at the beginning of a melting campaign;
-- a partial tapping of the melt in step (c) while leaving metal bottoms in the furnace vessel;

-- the charging of another charge onto the remaining metal bottoms and the slag;
-- a partial tapping of the metal melt after the meltdown of the charge and the reduction of the slag; and -- repetition of the steps of charging, melting, and slag reduction for each melt of the campaign or termination by total tapping of a separation melt together with the metal bottoms.
3. Method in accordance with Claim 1 or Claim 2, characterized by the fact that the reducing agents carbon and/or silicon and/or aluminum are charged in the form of alloying materials with a high carbon and silicon content.
4. Method in accordance with any of Claims 1 to 3, characterized by the fact that residual dusts are charged as reducing agents for the slag, especially a chromium-containing slag.
5. Method in accordance with any of Claims 1 to 4, characterized by the fact that thorough mixing is carried out by means of inert gases, which are introduced through bottom nozzles and/or side nozzles in the arc furnace and/or through a top lance.
6. Method for recovering metallic elements, especially metallic chromium, from slags that contain oxides, especially chromium oxides, in ladle metallurgy or converter metallurgy, with the following steps:
(a) introduction of a first metal melt with slag into a ladle or a converter;
(b) after the treatment of the melt, especially with oxygen, tapping of the melt while leaving the unreduced slag in the ladle or converter;
(c) introduction of another melt together with reducing agents for the slag, such as carbon and/or silicon and/or aluminum;
(d) thorough mixing of the melt with the slag, resulting in direct reduction of the slag, especially chromium oxide, by the reducing agents;
(g) tapping of the melt and the reduced slag.
7. Method in accordance with Claim 6, characterized by -- a partial tapping of the melt in step (b) while leaving metal bottoms in the ladle;
-- the charging of another melt onto the remaining metal bottoms and the slag;
-- a partial tapping of the metal melt in step (g) after reduction of the slag;
-- repetition of the steps of charging and of slag reduction for each melt of the campaign or termination by total tapping of a separation melt together with the metal bottoms.
CA 2525559 2003-05-24 2004-04-23 Method for recovering metallic elements, especially metallic chromium, from slag containing metal oxides in an electric-arc furnace Expired - Fee Related CA2525559C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE2003123507 DE10323507A1 (en) 2003-05-24 2003-05-24 Process for the recovery of metallic elements, in particular metallic chromium, from slags containing metal oxide in an electric arc furnace
DE10323507.8 2003-05-24
PCT/EP2004/004313 WO2004104233A1 (en) 2003-05-24 2004-04-23 Method for recovering metallic elements, especially metallic chromium, from slag containing metal oxides in an electric-arc furnace

Publications (2)

Publication Number Publication Date
CA2525559A1 true CA2525559A1 (en) 2004-12-02
CA2525559C CA2525559C (en) 2011-07-26

Family

ID=33441237

Family Applications (1)

Application Number Title Priority Date Filing Date
CA 2525559 Expired - Fee Related CA2525559C (en) 2003-05-24 2004-04-23 Method for recovering metallic elements, especially metallic chromium, from slag containing metal oxides in an electric-arc furnace

Country Status (13)

Country Link
US (1) US20060196308A1 (en)
EP (1) EP1627085B1 (en)
JP (1) JP4912880B2 (en)
KR (1) KR20060012288A (en)
CN (1) CN100350057C (en)
CA (1) CA2525559C (en)
DE (2) DE10323507A1 (en)
ES (1) ES2277253T3 (en)
RU (1) RU2352672C2 (en)
TW (1) TW200502404A (en)
UA (1) UA82239C2 (en)
WO (1) WO2004104233A1 (en)
ZA (1) ZA200508277B (en)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102006052181A1 (en) * 2006-11-02 2008-05-08 Sms Demag Ag A process for the continuous or discontinuous recovery of a metal or metals from a slag containing the metal or compound of the metal
EP2053137A1 (en) * 2007-10-19 2009-04-29 Paul Wurth S.A. Recovery of waste containing copper and other valuable metals
JP5326475B2 (en) * 2008-10-07 2013-10-30 新日鐵住金株式会社 Method for recovering chromium from chromium-containing slag
JP5455193B2 (en) * 2009-04-30 2014-03-26 日新製鋼株式会社 Stainless steel manufacturing method
WO2011045755A1 (en) * 2009-10-13 2011-04-21 Petrus Hendrik Ferreira Bouwer Ferrochrome alloy production
JP2013124417A (en) * 2011-12-16 2013-06-24 Nippon Steel & Sumitomo Metal Corp METHOD FOR TREATING Cr-CONTAINING SLAG
CN102864311B (en) * 2012-09-21 2014-11-26 承德建龙特殊钢有限公司 Recovery method of chromium in high chromium-content slag in steel making-LF (ladle furnace) working procedure
CN104087709B (en) * 2014-07-18 2016-08-24 承德建龙特殊钢有限公司 A kind of method of melting and reducing height chromium slag in induction furnace
CN104087704B (en) * 2014-07-18 2016-08-24 承德建龙特殊钢有限公司 A kind of method that melting and reducing vanadium extraction waste carries out pneumatic steelmaking
CN104789736B (en) * 2015-05-18 2017-01-11 安徽富凯特材有限公司 Method for reducing chromium element in electric arc furnace slag
CN105670667B (en) * 2016-01-19 2019-05-07 青岛理工大学 Method for synchronously treating chromium slag and chlorine-free plastic
WO2024127339A1 (en) 2022-12-16 2024-06-20 Danieli & C. Officine Meccaniche S.P.A. Process and plant for slag treatment

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AT381583B (en) * 1984-06-01 1986-11-10 Voest Alpine Ag TILTABLE METALLURGICAL TUBE
DE3444962A1 (en) * 1984-12-10 1986-06-12 Klöckner-Humboldt-Deutz AG, 5000 Köln METHOD AND DEVICE FOR THE REDUCING TREATMENT OF MELT-LIQUID METALS AND / OR THEIR SLAGS
JPH0196322A (en) * 1987-10-08 1989-04-14 Nkk Corp Ladle refining method
DE4108687A1 (en) * 1991-03-16 1992-11-05 Metallgesellschaft Ag METHOD FOR REDUCING NE-METAL OXIDES IN SLAGS
JPH06200311A (en) * 1993-01-05 1994-07-19 Nkk Corp Method for dephosphorizing molten iron
ZA963234B (en) * 1995-05-02 1996-07-29 Holderbank Financ Glarus Process for the production of hydraulic binders and/or alloys such as e g ferrochromium of ferrovanadium
JPH09157724A (en) * 1995-12-01 1997-06-17 Nippon Steel Corp Production of stainless steel using scrap
DE19643459A1 (en) * 1996-10-10 1998-04-16 Mannesmann Ag Process for depleting high-melting materials
DE19728102C2 (en) * 1997-07-02 1999-08-05 Schloemann Siemag Ag Method and device for the production of steels with high Cr content and / or ferro alloys
NO308418B1 (en) * 1998-12-09 2000-09-11 Elkem Materials Process for the production of stainless steel
AT407644B (en) * 1999-06-08 2001-05-25 Voest Alpine Ind Anlagen METHOD FOR SLAG CONDITIONING AND APPARATUS THEREFOR
US6679931B1 (en) * 1999-06-23 2004-01-20 Sms Demag Ag Method for recovering metallic chromium from slag containing chromium oxide
JP4189112B2 (en) * 2000-02-24 2008-12-03 新日本製鐵株式会社 Processing method for slag refining stainless steel
KR100819126B1 (en) * 2000-10-18 2008-04-02 에스엠에스 데마그 악티엔게젤샤프트 Method for producing stainless steels, in particular high-grade steels containing chromium and chromium-nickel
JP2002256323A (en) * 2001-02-27 2002-09-11 Nippon Steel Corp Method for reforming roughly decarburized slag in molten stainless steel

Also Published As

Publication number Publication date
UA82239C2 (en) 2008-03-25
KR20060012288A (en) 2006-02-07
ZA200508277B (en) 2006-12-27
CN1795276A (en) 2006-06-28
JP4912880B2 (en) 2012-04-11
DE10323507A1 (en) 2004-12-09
JP2007502369A (en) 2007-02-08
CN100350057C (en) 2007-11-21
ES2277253T3 (en) 2007-07-01
RU2352672C2 (en) 2009-04-20
RU2005140569A (en) 2006-05-10
TW200502404A (en) 2005-01-16
DE502004002628D1 (en) 2007-02-22
US20060196308A1 (en) 2006-09-07
WO2004104233A1 (en) 2004-12-02
CA2525559C (en) 2011-07-26
EP1627085A1 (en) 2006-02-22
EP1627085B1 (en) 2007-01-10

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Effective date: 20150423