CA2522898A1 - Strongly adherent surface coatings - Google Patents

Info

Publication number

CA2522898A1

CA2522898A1 CA002522898A CA2522898A CA2522898A1 CA 2522898 A1 CA2522898 A1 CA 2522898A1 CA 002522898 A CA002522898 A CA 002522898A CA 2522898 A CA2522898 A CA 2522898A CA 2522898 A1 CA2522898 A1 CA 2522898A1

Authority

CA

Canada

Prior art keywords

phenyl

substituted

independently

unsubstituted

hydrogen

Prior art date

2003-05-23

Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Abandoned

Links

• Espacenet
• Global Dossier
• CIPO
• Discuss

• 238000000576 coating method Methods 0.000 title claims abstract description 57
• 230000001464 adherent effect Effects 0.000 title claims abstract description 18
• 238000000034 method Methods 0.000 claims abstract description 155
• 239000000203 mixture Substances 0.000 claims abstract description 96
• 150000001875 compounds Chemical class 0.000 claims abstract description 88
• 239000000758 substrate Substances 0.000 claims abstract description 88
• 230000008569 process Effects 0.000 claims abstract description 82
• 239000000178 monomer Substances 0.000 claims abstract description 39
• 239000011248 coating agent Substances 0.000 claims abstract description 37
• 239000000243 solution Substances 0.000 claims abstract description 25
• 238000011282 treatment Methods 0.000 claims abstract description 24
• 239000000126 substance Substances 0.000 claims abstract description 22
• 239000000725 suspension Substances 0.000 claims abstract description 17
• 238000003851 corona treatment Methods 0.000 claims abstract description 16
• 239000000839 emulsion Substances 0.000 claims abstract description 16
• 238000004519 manufacturing process Methods 0.000 claims abstract description 16
• 238000009832 plasma treatment Methods 0.000 claims abstract description 16
• 125000006850 spacer group Chemical group 0.000 claims abstract description 12
• UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims abstract description 6
• -1 biphenylyl Chemical group 0.000 claims description 138
• 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 80
• 238000007639 printing Methods 0.000 claims description 76
• 229910052739 hydrogen Inorganic materials 0.000 claims description 65
• 239000001257 hydrogen Substances 0.000 claims description 62
• 150000002367 halogens Chemical group 0.000 claims description 42
• 150000002431 hydrogen Chemical class 0.000 claims description 41
• 229910052736 halogen Inorganic materials 0.000 claims description 40
• 150000003254 radicals Chemical class 0.000 claims description 37
• 229910052751 metal Inorganic materials 0.000 claims description 32
• 239000002184 metal Substances 0.000 claims description 32
• 229910052799 carbon Inorganic materials 0.000 claims description 30
• 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 29
• 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims description 23
• 229910052760 oxygen Inorganic materials 0.000 claims description 23
• 239000002904 solvent Substances 0.000 claims description 23
• UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 21
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 21
• 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 20
• 239000003999 initiator Substances 0.000 claims description 20
• 238000001035 drying Methods 0.000 claims description 18
• 229910052717 sulfur Inorganic materials 0.000 claims description 18
• 125000004430 oxygen atom Chemical group O* 0.000 claims description 17
• 229910044991 metal oxide Inorganic materials 0.000 claims description 14
• 125000001624 naphthyl group Chemical group 0.000 claims description 14
• 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 claims description 13
• 239000007789 gas Substances 0.000 claims description 13
• 125000001424 substituent group Chemical group 0.000 claims description 12
• 125000004070 6 membered heterocyclic group Chemical group 0.000 claims description 11
• 125000003118 aryl group Chemical group 0.000 claims description 11
• 230000005855 radiation Effects 0.000 claims description 11
• 125000002373 5 membered heterocyclic group Chemical group 0.000 claims description 10
• 150000004706 metal oxides Chemical class 0.000 claims description 10
• 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 10
• 125000001931 aliphatic group Chemical group 0.000 claims description 9
• 229910052786 argon Inorganic materials 0.000 claims description 9
• 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 9
• 229910052757 nitrogen Inorganic materials 0.000 claims description 9
• 238000010894 electron beam technology Methods 0.000 claims description 8
• 239000007788 liquid Substances 0.000 claims description 8
• 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims description 7
• ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 7
• 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 claims description 7
• 125000004432 carbon atom Chemical group C* 0.000 claims description 7
• 239000000460 chlorine Substances 0.000 claims description 7
• 229910052801 chlorine Inorganic materials 0.000 claims description 7
• 239000011261 inert gas Substances 0.000 claims description 7
• 229920002554 vinyl polymer Polymers 0.000 claims description 6
• 125000005428 anthryl group Chemical group [H]C1=C([H])C([H])=C2C([H])=C3C(*)=C([H])C([H])=C([H])C3=C([H])C2=C1[H] 0.000 claims description 5
• 125000004433 nitrogen atom Chemical group N* 0.000 claims description 5
• 238000010521 absorption reaction Methods 0.000 claims description 4
• 125000004573 morpholin-4-yl group Chemical group N1(CCOCC1)* 0.000 claims description 4
• SONNWYBIRXJNDC-VIFPVBQESA-N phenylephrine Chemical compound CNC[C@H](O)C1=CC=CC(O)=C1 SONNWYBIRXJNDC-VIFPVBQESA-N 0.000 claims description 4
• 125000003356 phenylsulfanyl group Chemical group [*]SC1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims description 4
• 229910052724 xenon Inorganic materials 0.000 claims description 4
• 101100054666 Streptomyces halstedii sch3 gene Proteins 0.000 claims description 3
• 239000007792 gaseous phase Substances 0.000 claims description 3
• 229910052734 helium Inorganic materials 0.000 claims description 3
• 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims description 3
• BNJMRELGMDUDDB-UHFFFAOYSA-N $l^{1}-sulfanylbenzene Chemical compound [S]C1=CC=CC=C1 BNJMRELGMDUDDB-UHFFFAOYSA-N 0.000 claims description 2
• 125000004202 aminomethyl group Chemical group [H]N([H])C([H])([H])* 0.000 claims description 2
• 150000005840 aryl radicals Chemical class 0.000 claims description 2
• 125000000051 benzyloxy group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])O* 0.000 claims description 2
• 125000001584 benzyloxycarbonyl group Chemical group C(=O)(OCC1=CC=CC=C1)* 0.000 claims description 2
• 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 2
• 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 claims description 2
• ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 claims description 2
• 125000005745 ethoxymethyl group Chemical group [H]C([H])([H])C([H])([H])OC([H])([H])* 0.000 claims description 2
• 125000001153 fluoro group Chemical group F* 0.000 claims description 2
• 125000002485 formyl group Chemical group [H]C(*)=O 0.000 claims description 2
• 229910052743 krypton Inorganic materials 0.000 claims description 2
• 125000004184 methoxymethyl group Chemical group [H]C([H])([H])OC([H])([H])* 0.000 claims description 2
• 125000000896 monocarboxylic acid group Chemical group 0.000 claims description 2
• 125000001064 morpholinomethyl group Chemical group [H]C([H])(*)N1C([H])([H])C([H])([H])OC([H])([H])C1([H])[H] 0.000 claims description 2
• 125000006678 phenoxycarbonyl group Chemical group 0.000 claims description 2
• UYWQUFXKFGHYNT-UHFFFAOYSA-N phenylmethyl ester of formic acid Natural products O=COCC1=CC=CC=C1 UYWQUFXKFGHYNT-UHFFFAOYSA-N 0.000 claims description 2
• 125000001422 pyrrolinyl group Chemical group 0.000 claims description 2
• 125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 2
• 125000000229 (C1-C4)alkoxy group Chemical group 0.000 claims 10
• 125000004642 (C1-C12) alkoxy group Chemical group 0.000 claims 5
• 125000004169 (C1-C6) alkyl group Chemical group 0.000 claims 4
• 125000003358 C2-C20 alkenyl group Chemical group 0.000 claims 4
• 125000004765 (C1-C4) haloalkyl group Chemical group 0.000 claims 2
• 125000006710 (C2-C12) alkenyl group Chemical group 0.000 claims 2
• 125000005913 (C3-C6) cycloalkyl group Chemical group 0.000 claims 2
• 125000004399 C1-C4 alkenyl group Chemical group 0.000 claims 1
• 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 claims 1
• 239000000976 ink Substances 0.000 description 71
• 229920001577 copolymer Polymers 0.000 description 48
• PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 47
• 229920000642 polymer Polymers 0.000 description 26
• 210000002381 plasma Anatomy 0.000 description 23
• 125000000217 alkyl group Chemical group 0.000 description 20
• PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 18
• YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 18
• 239000010410 layer Substances 0.000 description 18
• 238000002360 preparation method Methods 0.000 description 18
• 239000004743 Polypropylene Substances 0.000 description 16
• 150000001252 acrylic acid derivatives Chemical class 0.000 description 16
• 238000006243 chemical reaction Methods 0.000 description 16
• 238000005481 NMR spectroscopy Methods 0.000 description 15
• XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 14
• LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 14
• 239000002253 acid Substances 0.000 description 14
• NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 13
• 239000004952 Polyamide Substances 0.000 description 13
• NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 12
• VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 12
• 239000000654 additive Substances 0.000 description 12
• 150000002148 esters Chemical class 0.000 description 12
• 229920002647 polyamide Polymers 0.000 description 12
• 229920005862 polyol Polymers 0.000 description 12
• 239000005977 Ethylene Substances 0.000 description 11
• 239000005062 Polybutadiene Substances 0.000 description 11
• 239000002270 dispersing agent Substances 0.000 description 11
• 239000003921 oil Substances 0.000 description 11
• 235000019198 oils Nutrition 0.000 description 11
• 229920002857 polybutadiene Polymers 0.000 description 11
• 208000028659 discharge Diseases 0.000 description 10
• 150000003077 polyols Chemical class 0.000 description 10
• 229920001155 polypropylene Polymers 0.000 description 10
• CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 9
• PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 9
• VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 9
• 150000001412 amines Chemical class 0.000 description 9
• 239000012965 benzophenone Substances 0.000 description 9
• TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 8
• LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 8
• KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 8
• XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 8
• 239000011230 binding agent Substances 0.000 description 8
• 239000000975 dye Substances 0.000 description 8
• 150000002739 metals Chemical class 0.000 description 8
• 229920000728 polyester Polymers 0.000 description 8
• 238000003756 stirring Methods 0.000 description 8
• 238000005160 1H NMR spectroscopy Methods 0.000 description 7
• ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 7
• FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 7
• FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 7
• RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 7
• 239000007859 condensation product Substances 0.000 description 7
• 150000002170 ethers Chemical class 0.000 description 7
• 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 7
• 238000007645 offset printing Methods 0.000 description 7
• 239000000049 pigment Substances 0.000 description 7
• 229920003023 plastic Polymers 0.000 description 7
• 239000004033 plastic Substances 0.000 description 7
• 239000004814 polyurethane Substances 0.000 description 7
• 239000000600 sorbitol Substances 0.000 description 7
• 238000012360 testing method Methods 0.000 description 7
• WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
• UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 6
• 239000004698 Polyethylene Substances 0.000 description 6
• 239000004721 Polyphenylene oxide Substances 0.000 description 6
• WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 6
• NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 6
• 229940024874 benzophenone Drugs 0.000 description 6
• 229910052794 bromium Inorganic materials 0.000 description 6
• 239000003054 catalyst Substances 0.000 description 6
• 239000003795 chemical substances by application Substances 0.000 description 6
• 229920006037 cross link polymer Polymers 0.000 description 6
• 238000009472 formulation Methods 0.000 description 6
• 229920001903 high density polyethylene Polymers 0.000 description 6
• 239000004700 high-density polyethylene Substances 0.000 description 6
• 239000000463 material Substances 0.000 description 6
• 239000004417 polycarbonate Substances 0.000 description 6
• 229920000647 polyepoxide Polymers 0.000 description 6
• 229920000570 polyether Polymers 0.000 description 6
• 229920000573 polyethylene Polymers 0.000 description 6
• 229920006324 polyoxymethylene Polymers 0.000 description 6
• 239000000047 product Substances 0.000 description 6
• 229920001169 thermoplastic Polymers 0.000 description 6
• 239000004416 thermosoftening plastic Substances 0.000 description 6
• UKRQMDIFLKHCRO-UHFFFAOYSA-N 2,4,6-trimethylbenzoyl chloride Chemical compound CC1=CC(C)=C(C(Cl)=O)C(C)=C1 UKRQMDIFLKHCRO-UHFFFAOYSA-N 0.000 description 5
• IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 5
• CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 5
• 229910019142 PO4 Inorganic materials 0.000 description 5
• XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 5
• 150000001298 alcohols Chemical class 0.000 description 5
• 125000003545 alkoxy group Chemical group 0.000 description 5
• 229920000180 alkyd Polymers 0.000 description 5
• RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 5
• 150000008366 benzophenones Chemical class 0.000 description 5
• 125000000753 cycloalkyl group Chemical group 0.000 description 5
• 150000001991 dicarboxylic acids Chemical class 0.000 description 5
• 150000002009 diols Chemical class 0.000 description 5
• 238000005516 engineering process Methods 0.000 description 5
• 230000004927 fusion Effects 0.000 description 5
• 239000011521 glass Substances 0.000 description 5
• 150000002576 ketones Chemical class 0.000 description 5
• 239000004611 light stabiliser Substances 0.000 description 5
• 235000021317 phosphate Nutrition 0.000 description 5
• 229920002635 polyurethane Polymers 0.000 description 5
• 239000004800 polyvinyl chloride Substances 0.000 description 5
• 229920000915 polyvinyl chloride Polymers 0.000 description 5
• QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 5
• 239000007858 starting material Substances 0.000 description 5
• KAKZBPTYRLMSJV-UHFFFAOYSA-N vinyl-ethylene Natural products C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 5
• KUDUQBURMYMBIJ-UHFFFAOYSA-N 2-prop-2-enoyloxyethyl prop-2-enoate Chemical compound C=CC(=O)OCCOC(=O)C=C KUDUQBURMYMBIJ-UHFFFAOYSA-N 0.000 description 4
• KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 description 4
• WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 4
• 229910014033 C-OH Inorganic materials 0.000 description 4
• VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 4
• 229910014570 C—OH Inorganic materials 0.000 description 4
• YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 4
• MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 4
• CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 4
• CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 4
• LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical class CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 4
• MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 description 4
• ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
• XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 4
• BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 4
• QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 4
• 150000007513 acids Chemical class 0.000 description 4
• 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 4
• 125000003342 alkenyl group Chemical group 0.000 description 4
• 239000012964 benzotriazole Substances 0.000 description 4
• GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 4
• 150000001735 carboxylic acids Chemical class 0.000 description 4
• 238000001723 curing Methods 0.000 description 4
• 150000004985 diamines Chemical class 0.000 description 4
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• 239000003822 epoxy resin Substances 0.000 description 4
• 239000011737 fluorine Substances 0.000 description 4
• 229910052731 fluorine Inorganic materials 0.000 description 4
• LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 4
• 125000000623 heterocyclic group Chemical group 0.000 description 4
• 229920001684 low density polyethylene Polymers 0.000 description 4
• 239000004702 low-density polyethylene Substances 0.000 description 4
• OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 4
• 239000003960 organic solvent Substances 0.000 description 4
• FAQJJMHZNSSFSM-UHFFFAOYSA-N phenylglyoxylic acid Chemical class OC(=O)C(=O)C1=CC=CC=C1 FAQJJMHZNSSFSM-UHFFFAOYSA-N 0.000 description 4
• 150000003013 phosphoric acid derivatives Chemical class 0.000 description 4
• 229910000073 phosphorus hydride Inorganic materials 0.000 description 4
• 229920000058 polyacrylate Polymers 0.000 description 4
• 229920000515 polycarbonate Polymers 0.000 description 4
• 229920001223 polyethylene glycol Polymers 0.000 description 4
• 229920000098 polyolefin Polymers 0.000 description 4
• 229920006380 polyphenylene oxide Polymers 0.000 description 4
• 229920005989 resin Polymers 0.000 description 4
• 239000011347 resin Substances 0.000 description 4
• 231100000489 sensitizer Toxicity 0.000 description 4
• 229920001897 terpolymer Polymers 0.000 description 4
• 239000002562 thickening agent Substances 0.000 description 4
• 239000010936 titanium Substances 0.000 description 4
• WXPWZZHELZEVPO-UHFFFAOYSA-N (4-methylphenyl)-phenylmethanone Chemical compound C1=CC(C)=CC=C1C(=O)C1=CC=CC=C1 WXPWZZHELZEVPO-UHFFFAOYSA-N 0.000 description 3
• VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 3
• 125000004973 1-butenyl group Chemical group C(=CCC)* 0.000 description 3
• 125000004974 2-butenyl group Chemical group C(C=CC)* 0.000 description 3
• JLZIXYIYQIKFHP-UHFFFAOYSA-N 2-methyl-1-(4-methylphenyl)-2-morpholin-4-ylpropane-1-thione Chemical compound C1=CC(C)=CC=C1C(=S)C(C)(C)N1CCOCC1 JLZIXYIYQIKFHP-UHFFFAOYSA-N 0.000 description 3
• WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
• YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
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