CA2518565A1 - Process for producing a fibrous composition - Google Patents
Process for producing a fibrous composition Download PDFInfo
- Publication number
- CA2518565A1 CA2518565A1 CA002518565A CA2518565A CA2518565A1 CA 2518565 A1 CA2518565 A1 CA 2518565A1 CA 002518565 A CA002518565 A CA 002518565A CA 2518565 A CA2518565 A CA 2518565A CA 2518565 A1 CA2518565 A1 CA 2518565A1
- Authority
- CA
- Canada
- Prior art keywords
- fibres
- fibre
- electrically conductive
- polymer
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 80
- 238000000034 method Methods 0.000 title claims abstract description 31
- 230000008569 process Effects 0.000 title claims abstract description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 143
- 229920001940 conductive polymer Polymers 0.000 claims abstract description 69
- 229920000642 polymer Polymers 0.000 claims abstract description 59
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 45
- 239000002019 doping agent Substances 0.000 claims abstract description 41
- 239000000178 monomer Substances 0.000 claims abstract description 31
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical compound OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000012736 aqueous medium Substances 0.000 claims abstract description 6
- 235000013311 vegetables Nutrition 0.000 claims abstract description 5
- 239000002800 charge carrier Substances 0.000 claims abstract description 4
- 238000011065 in-situ storage Methods 0.000 claims abstract description 4
- 239000000463 material Substances 0.000 claims abstract description 4
- 229920001059 synthetic polymer Polymers 0.000 claims abstract 2
- 239000000835 fiber Substances 0.000 claims description 217
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 claims description 179
- 229920000767 polyaniline Polymers 0.000 claims description 87
- 229920001131 Pulp (paper) Polymers 0.000 claims description 69
- 238000002156 mixing Methods 0.000 claims description 45
- WBIQQQGBSDOWNP-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O WBIQQQGBSDOWNP-UHFFFAOYSA-N 0.000 claims description 33
- 239000000126 substance Substances 0.000 claims description 33
- 239000000725 suspension Substances 0.000 claims description 24
- 150000003839 salts Chemical class 0.000 claims description 22
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 claims description 22
- 239000011111 cardboard Substances 0.000 claims description 15
- 238000004519 manufacturing process Methods 0.000 claims description 14
- IULJSGIJJZZUMF-UHFFFAOYSA-N 2-hydroxybenzenesulfonic acid Chemical compound OC1=CC=CC=C1S(O)(=O)=O IULJSGIJJZZUMF-UHFFFAOYSA-N 0.000 claims description 12
- 125000003118 aryl group Chemical group 0.000 claims description 10
- MIOPJNTWMNEORI-UHFFFAOYSA-N camphorsulfonic acid Chemical compound C1CC2(CS(O)(=O)=O)C(=O)CC1C2(C)C MIOPJNTWMNEORI-UHFFFAOYSA-N 0.000 claims description 10
- 238000001035 drying Methods 0.000 claims description 10
- 229920005610 lignin Polymers 0.000 claims description 10
- 239000011087 paperboard Substances 0.000 claims description 8
- 125000001931 aliphatic group Chemical group 0.000 claims description 6
- 125000000217 alkyl group Chemical group 0.000 claims description 6
- 239000008346 aqueous phase Substances 0.000 claims description 6
- 239000003054 catalyst Substances 0.000 claims description 5
- 239000002609 medium Substances 0.000 claims description 3
- 125000002029 aromatic hydrocarbon group Chemical group 0.000 claims 2
- 125000001424 substituent group Chemical group 0.000 claims 1
- 239000000047 product Substances 0.000 description 93
- 239000000123 paper Substances 0.000 description 65
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium peroxydisulfate Substances [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 41
- 235000019395 ammonium persulphate Nutrition 0.000 description 40
- 239000004160 Ammonium persulphate Substances 0.000 description 39
- 238000001914 filtration Methods 0.000 description 35
- 239000011541 reaction mixture Substances 0.000 description 31
- 239000000243 solution Substances 0.000 description 31
- 238000006243 chemical reaction Methods 0.000 description 30
- 239000002253 acid Substances 0.000 description 24
- 238000005406 washing Methods 0.000 description 24
- 239000005457 ice water Substances 0.000 description 21
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 16
- 238000005119 centrifugation Methods 0.000 description 12
- 239000011159 matrix material Substances 0.000 description 12
- 238000005259 measurement Methods 0.000 description 12
- 238000004537 pulping Methods 0.000 description 12
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 11
- 235000011613 Pinus brutia Nutrition 0.000 description 11
- 241000018646 Pinus brutia Species 0.000 description 11
- 239000007800 oxidant agent Substances 0.000 description 10
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 9
- 239000010410 layer Substances 0.000 description 9
- 230000001590 oxidative effect Effects 0.000 description 9
- AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical class CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 description 8
- 150000007513 acids Chemical class 0.000 description 8
- 229920002678 cellulose Polymers 0.000 description 8
- 239000001913 cellulose Substances 0.000 description 8
- LBLYYCQCTBFVLH-UHFFFAOYSA-N 2-Methylbenzenesulfonic acid Chemical compound CC1=CC=CC=C1S(O)(=O)=O LBLYYCQCTBFVLH-UHFFFAOYSA-N 0.000 description 7
- 239000000523 sample Substances 0.000 description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical class CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- 239000007864 aqueous solution Substances 0.000 description 6
- 239000002243 precursor Substances 0.000 description 6
- HFWCMJLOMOWFJL-UHFFFAOYSA-N 4-methylbenzenesulfonate;phenylazanium Chemical compound NC1=CC=CC=C1.CC1=CC=C(S(O)(=O)=O)C=C1 HFWCMJLOMOWFJL-UHFFFAOYSA-N 0.000 description 5
- MMCPOSDMTGQNKG-UHFFFAOYSA-N anilinium chloride Chemical compound Cl.NC1=CC=CC=C1 MMCPOSDMTGQNKG-UHFFFAOYSA-N 0.000 description 5
- -1 aromatic diesters Chemical class 0.000 description 5
- 230000009467 reduction Effects 0.000 description 5
- 229920003043 Cellulose fiber Polymers 0.000 description 4
- STHDJLMKPBFPHO-UHFFFAOYSA-N aniline;2-dodecylbenzenesulfonic acid Chemical compound NC1=CC=CC=C1.CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O STHDJLMKPBFPHO-UHFFFAOYSA-N 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- KWKXNDCHNDYVRT-UHFFFAOYSA-N dodecylbenzene Chemical compound CCCCCCCCCCCCC1=CC=CC=C1 KWKXNDCHNDYVRT-UHFFFAOYSA-N 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 239000000758 substrate Substances 0.000 description 4
- 230000000930 thermomechanical effect Effects 0.000 description 4
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 3
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 3
- 235000011114 ammonium hydroxide Nutrition 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- 239000012065 filter cake Substances 0.000 description 3
- 230000002209 hydrophobic effect Effects 0.000 description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 description 3
- 230000014759 maintenance of location Effects 0.000 description 3
- 210000001724 microfibril Anatomy 0.000 description 3
- 238000001000 micrograph Methods 0.000 description 3
- 239000011707 mineral Substances 0.000 description 3
- 239000011122 softwood Substances 0.000 description 3
- 229910021653 sulphate ion Inorganic materials 0.000 description 3
- 239000001117 sulphuric acid Substances 0.000 description 3
- 235000011149 sulphuric acid Nutrition 0.000 description 3
- GEYOCULIXLDCMW-UHFFFAOYSA-N 1,2-phenylenediamine Chemical compound NC1=CC=CC=C1N GEYOCULIXLDCMW-UHFFFAOYSA-N 0.000 description 2
- 229920002488 Hemicellulose Polymers 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 240000008042 Zea mays Species 0.000 description 2
- 235000016383 Zea mays subsp huehuetenangensis Nutrition 0.000 description 2
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 150000004996 alkyl benzenes Chemical class 0.000 description 2
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 2
- CXIUKKKVJVMREW-UHFFFAOYSA-N aniline;(7,7-dimethyl-3-oxo-4-bicyclo[2.2.1]heptanyl)methanesulfonic acid Chemical compound NC1=CC=CC=C1.C1CC2(CS(O)(=O)=O)C(=O)CC1C2(C)C CXIUKKKVJVMREW-UHFFFAOYSA-N 0.000 description 2
- GGFOZRQCNXQCLO-UHFFFAOYSA-N aniline;methanesulfonic acid Chemical compound CS(O)(=O)=O.NC1=CC=CC=C1 GGFOZRQCNXQCLO-UHFFFAOYSA-N 0.000 description 2
- 150000004945 aromatic hydrocarbons Chemical group 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 235000013339 cereals Nutrition 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 229920000547 conjugated polymer Polymers 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 238000005470 impregnation Methods 0.000 description 2
- 235000009973 maize Nutrition 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 229920000128 polypyrrole Polymers 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000010561 standard procedure Methods 0.000 description 2
- TZGFOSSGMSTBMN-UHFFFAOYSA-N 1-anilino-2-hydroxypropane-1,2,3-tricarboxylic acid Chemical class N(C1=CC=CC=C1)C(C(CC(=O)O)(O)C(=O)O)C(=O)O TZGFOSSGMSTBMN-UHFFFAOYSA-N 0.000 description 1
- UGHLEPMKNSFGCE-UHFFFAOYSA-N 2-ethylbenzenesulfonic acid Chemical class CCC1=CC=CC=C1S(O)(=O)=O UGHLEPMKNSFGCE-UHFFFAOYSA-N 0.000 description 1
- 102100031260 Acyl-coenzyme A thioesterase THEM4 Human genes 0.000 description 1
- 244000198134 Agave sisalana Species 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 229930091051 Arenine Natural products 0.000 description 1
- 240000008564 Boehmeria nivea Species 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 1
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 1
- XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical class [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- BNQCSCKNSLIYBU-UHFFFAOYSA-N ClC1=C(C=CC=C1)S(=O)(=O)O.C(C)C(COP(=O)(O)O)CCCC.C(C)C(COP(=O)(O)O)CCCC Chemical class ClC1=C(C=CC=C1)S(=O)(=O)O.C(C)C(COP(=O)(O)O)CCCC.C(C)C(COP(=O)(O)O)CCCC BNQCSCKNSLIYBU-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- 101000638510 Homo sapiens Acyl-coenzyme A thioesterase THEM4 Proteins 0.000 description 1
- 240000006240 Linum usitatissimum Species 0.000 description 1
- 235000004431 Linum usitatissimum Nutrition 0.000 description 1
- 240000000907 Musa textilis Species 0.000 description 1
- 244000081757 Phalaris arundinacea Species 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 229920000265 Polyparaphenylene Polymers 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 241000220317 Rosa Species 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000002998 adhesive polymer Substances 0.000 description 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- VAZSKTXWXKYQJF-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)OOS([O-])=O VAZSKTXWXKYQJF-UHFFFAOYSA-N 0.000 description 1
- 125000002490 anilino group Chemical group [H]N(*)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 239000004760 aramid Substances 0.000 description 1
- 229920003235 aromatic polyamide Polymers 0.000 description 1
- 238000010009 beating Methods 0.000 description 1
- 150000008107 benzenesulfonic acids Chemical class 0.000 description 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid group Chemical group C(C1=CC=CC=C1)(=O)O WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 235000009120 camo Nutrition 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 235000005607 chanvre indien Nutrition 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 239000006258 conductive agent Substances 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 230000005670 electromagnetic radiation Effects 0.000 description 1
- 229920000775 emeraldine polymer Polymers 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- CCIVGXIOQKPBKL-UHFFFAOYSA-N ethanesulfonic acid Chemical class CCS(O)(=O)=O CCIVGXIOQKPBKL-UHFFFAOYSA-N 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 239000011487 hemp Substances 0.000 description 1
- 239000007970 homogeneous dispersion Substances 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 150000002430 hydrocarbons Chemical group 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 150000002505 iron Chemical class 0.000 description 1
- 230000003780 keratinization Effects 0.000 description 1
- 150000002605 large molecules Chemical group 0.000 description 1
- 239000012764 mineral filler Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- LQNUZADURLCDLV-UHFFFAOYSA-N nitrobenzene Substances [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 239000012454 non-polar solvent Substances 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- BHAAPTBBJKJZER-UHFFFAOYSA-N p-anisidine Chemical compound COC1=CC=C(N)C=C1 BHAAPTBBJKJZER-UHFFFAOYSA-N 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical class OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 150000004965 peroxy acids Chemical class 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 229960003742 phenol Drugs 0.000 description 1
- NIXKBAZVOQAHGC-UHFFFAOYSA-N phenylmethanesulfonic acid Chemical class OS(=O)(=O)CC1=CC=CC=C1 NIXKBAZVOQAHGC-UHFFFAOYSA-N 0.000 description 1
- OXNIZHLAWKMVMX-UHFFFAOYSA-N picric acid Chemical compound OC1=C([N+]([O-])=O)C=C([N+]([O-])=O)C=C1[N+]([O-])=O OXNIZHLAWKMVMX-UHFFFAOYSA-N 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 229920001197 polyacetylene Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920001021 polysulfide Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- KZVLNAGYSAKYMG-UHFFFAOYSA-N pyridine-2-sulfonic acid Chemical class OS(=O)(=O)C1=CC=CC=N1 KZVLNAGYSAKYMG-UHFFFAOYSA-N 0.000 description 1
- 150000004053 quinones Chemical class 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 239000013074 reference sample Substances 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 238000003828 vacuum filtration Methods 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical class OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/001—Modification of pulp properties
- D21C9/002—Modification of pulp properties by chemical means; preparation of dewatered pulp, e.g. in sheet or bulk form, containing special additives
- D21C9/005—Modification of pulp properties by chemical means; preparation of dewatered pulp, e.g. in sheet or bulk form, containing special additives organic compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
- D21H11/16—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only modified by a particular after-treatment
- D21H11/20—Chemically or biochemically modified fibres
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
- H01B1/12—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances organic substances
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/07—Nitrogen-containing compounds
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Biochemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Paper (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FI20030490A FI20030490A (fi) | 2003-04-01 | 2003-04-01 | Menetelmä kuitukoostumuksen valmistamiseksi |
| FI20030490 | 2003-04-01 | ||
| PCT/FI2004/000200 WO2004088035A1 (en) | 2003-04-01 | 2004-04-01 | Process for producing a fibrous composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2518565A1 true CA2518565A1 (en) | 2004-10-14 |
Family
ID=8565906
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002518565A Abandoned CA2518565A1 (en) | 2003-04-01 | 2004-04-01 | Process for producing a fibrous composition |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US20060144543A1 (zh) |
| EP (1) | EP1608809A1 (zh) |
| JP (1) | JP2006522233A (zh) |
| CN (1) | CN100393939C (zh) |
| AU (1) | AU2004225736A1 (zh) |
| CA (1) | CA2518565A1 (zh) |
| FI (1) | FI20030490A (zh) |
| WO (1) | WO2004088035A1 (zh) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20070287795A1 (en) * | 2006-06-08 | 2007-12-13 | Board Of Trustees Of Michigan State University | Composite materials from corncob granules and process for preparation |
| US8709213B2 (en) * | 2007-05-14 | 2014-04-29 | Northwestern University | Composite graphene oxide-polymer laminate and method |
| US8697934B2 (en) * | 2007-07-31 | 2014-04-15 | Kimberly-Clark Worldwide, Inc. | Sensor products using conductive webs |
| US8058194B2 (en) * | 2007-07-31 | 2011-11-15 | Kimberly-Clark Worldwide, Inc. | Conductive webs |
| US8920971B2 (en) | 2007-11-27 | 2014-12-30 | Maria Strömme | Composite materials including an intrinsically conducting polymer, and methods and devices |
| JP5271558B2 (ja) * | 2008-02-06 | 2013-08-21 | 国立大学法人 筑波大学 | パルプ／ポリアニリン類複合体の製造方法 |
| US8172982B2 (en) * | 2008-12-22 | 2012-05-08 | Kimberly-Clark Worldwide, Inc. | Conductive webs and process for making same |
| WO2010143722A1 (ja) * | 2009-06-12 | 2010-12-16 | 三菱化学株式会社 | 修飾セルロース繊維及びそのセルロース複合体 |
| EP2513149B1 (en) | 2009-12-15 | 2016-01-27 | National Research Council of Canada | Cellulose nanocrystals from renewable biomass |
| BR112013019045A2 (pt) * | 2011-01-25 | 2017-01-31 | Basf Se | processo para fabricar um artigo tipo papel, e, uso de ácido metanossulfônico |
| EP2668334B1 (de) * | 2011-01-25 | 2014-11-19 | Basf Se | Verfahren zur herstellung von halbstoffen für die produktion von papiererzeugnissen |
| US20120186762A1 (en) * | 2011-01-25 | 2012-07-26 | Basf Se | Producing half-stuffs for the manufacture of papery articles |
| EP2691467A4 (en) * | 2011-03-29 | 2014-12-03 | Fpinnovations | FLEXIBLE, SEMICONDUCTIVE NANO-BONDING MATERIALS BASED ON NANOCRYSTALLINE CELLULOSE AND POLYANILINE |
| JP5843463B2 (ja) * | 2011-04-04 | 2016-01-13 | 花王株式会社 | 繊維状物 |
| KR101289768B1 (ko) * | 2011-08-26 | 2013-07-26 | 주식회사 누리비스타 | 전도성 조성물 및 이의 제조방법 |
| CN103394330B (zh) * | 2013-07-23 | 2014-12-24 | 陕西科技大学 | 二代支化羧基化胶原纤维的合成方法 |
| JP6429355B2 (ja) * | 2013-08-23 | 2018-11-28 | 国立大学法人 筑波大学 | 放射性物質吸着シートとその製造方法 |
| CN103462602B (zh) * | 2013-09-30 | 2015-07-08 | 东华大学 | 一种用于测试心电信号的纺织电极的制备方法 |
| CN103965513B (zh) * | 2014-04-29 | 2016-04-27 | 中原工学院 | 聚苯胺纳米纤维/二醋酸纤维素复合导电材料的制备方法 |
| CN103965514B (zh) * | 2014-04-29 | 2017-01-18 | 中原工学院 | 一种聚苯胺/二醋酸纤维素复合导电塑料的制备方法 |
| BR112017019184B1 (pt) * | 2015-03-09 | 2022-03-03 | Investigaciones Forestales Bioforest S.A | Método para produzir placas mdf, painéis de fibra e de partículas a partir de fibras celulósica |
| CN113151971B (zh) * | 2021-03-31 | 2022-05-20 | 海安启弘纺织科技有限公司 | 一种采用放射型超细纤维制备经编超柔绒类面料的方法及其产品 |
| CN116604659B (zh) * | 2023-04-04 | 2024-05-28 | 浙江省林业科学研究院 | 一种氧化石墨烯/聚苯胺处理的导电竹木材料的制备方法 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4309246A (en) * | 1977-06-20 | 1982-01-05 | Crown Zellerbach Corporation | Papermaking apparatus and method |
| DE3321281A1 (de) * | 1982-06-22 | 1983-12-22 | ASEA AB, 72183 Västerås | Verfahren zur erhoehung der elektrischen leitfaehigkeit impraegnierbarer materialien |
| US4803096A (en) * | 1987-08-03 | 1989-02-07 | Milliken Research Corporation | Electrically conductive textile materials and method for making same |
| US5030508A (en) * | 1988-06-27 | 1991-07-09 | Milliken Research Corporation | Method for making electrically conductive textile materials |
| US5336374A (en) * | 1990-05-10 | 1994-08-09 | Tomoegawa Paper Co., Ltd. | Composite comprising paper and electro-conducting polymers and its production process |
| US5211810A (en) * | 1990-08-09 | 1993-05-18 | International Paper Company | Electrically conductive polymeric materials and related method of manufacture |
| FR2743371B1 (fr) * | 1996-01-08 | 1998-08-14 | Atochem Elf Sa | Microfibrilles de cellulose conductrices et composites les incorporant |
| CN1193388C (zh) * | 1999-09-10 | 2005-03-16 | 松下电器产业株式会社 | 固体电解电容器及其制造方法和导电性聚合物聚合用的氧化剂溶液 |
| CN1408039A (zh) * | 1999-12-06 | 2003-04-02 | 赫尔克里士公司 | 疏水缔合聚合物在制备纤维素纤维组合物中的使用方法,和包括疏水缔合聚合物的纤维素纤维组合物 |
| AU8035901A (en) * | 2000-08-07 | 2002-02-18 | Akzo Nobel Nv | Process for sizing paper |
| SE0100551D0 (sv) * | 2001-02-19 | 2001-02-19 | Luciano Beghello | Security paper |
-
2003
- 2003-04-01 FI FI20030490A patent/FI20030490A/fi unknown
-
2004
- 2004-04-01 WO PCT/FI2004/000200 patent/WO2004088035A1/en active Application Filing
- 2004-04-01 CN CNB200480015103XA patent/CN100393939C/zh not_active Expired - Fee Related
- 2004-04-01 EP EP04725077A patent/EP1608809A1/en not_active Withdrawn
- 2004-04-01 CA CA002518565A patent/CA2518565A1/en not_active Abandoned
- 2004-04-01 JP JP2006505628A patent/JP2006522233A/ja not_active Withdrawn
- 2004-04-01 AU AU2004225736A patent/AU2004225736A1/en not_active Abandoned
- 2004-04-01 US US10/551,036 patent/US20060144543A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| EP1608809A1 (en) | 2005-12-28 |
| US20060144543A1 (en) | 2006-07-06 |
| WO2004088035A1 (en) | 2004-10-14 |
| FI20030490A0 (fi) | 2003-04-01 |
| JP2006522233A (ja) | 2006-09-28 |
| AU2004225736A1 (en) | 2004-10-14 |
| FI20030490A (fi) | 2004-10-02 |
| CN1798890A (zh) | 2006-07-05 |
| CN100393939C (zh) | 2008-06-11 |
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| FZDE | Discontinued |