CA2504596C - Production d'hydrocarbures - Google Patents

Production d'hydrocarbures Download PDF

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Publication number
CA2504596C
CA2504596C CA2504596A CA2504596A CA2504596C CA 2504596 C CA2504596 C CA 2504596C CA 2504596 A CA2504596 A CA 2504596A CA 2504596 A CA2504596 A CA 2504596A CA 2504596 C CA2504596 C CA 2504596C
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CA
Canada
Prior art keywords
gas
steam
reformed gas
stream
reforming
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
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CA2504596A
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English (en)
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CA2504596A1 (fr
Inventor
Peter Edward James Abbott
Martin Fowles
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Johnson Matthey PLC
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Johnson Matthey PLC
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/382—Multi-step processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/384—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts the catalyst being continuously externally heated
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0244—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being an autothermal reforming step, e.g. secondary reforming processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06—Integration with other chemical processes
    • C01B2203/062—Hydrocarbon production, e.g. Fischer-Tropsch process
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0838—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel
    • C01B2203/0844—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel the non-combustive exothermic reaction being another reforming reaction as defined in groups C01B2203/02 - C01B2203/0294
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1052—Nickel or cobalt catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1241—Natural gas or methane
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1247—Higher hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/142—At least two reforming, decomposition or partial oxidation steps in series
    • C01B2203/143—Three or more reforming, decomposition or partial oxidation steps in series
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/146—At least two purification steps in series
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/146—At least two purification steps in series
    • C01B2203/147—Three or more purification steps in series
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/148—Details of the flowsheet involving a recycle stream to the feed of the process for making hydrogen or synthesis gas
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/80—Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
    • C01B2203/82—Several process steps of C01B2203/02 - C01B2203/08 integrated into a single apparatus

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • General Chemical & Material Sciences (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

L'invention concerne un procédé de production d'hydrocarbures qui consiste: a) à soumettre une charge (10) d'hydrocarbures à un reformage à la vapeur consistant: à diviser la charge en un premier (12) et un deuxième (13) flux, à mélanger le premier flux à de la vapeur (16), à faire passer le mélange du premier flux et de la vapeur sur un catalyseur disposé dans des tubes chauffés situés dans un reformeur à échange de chaleur (28) afin que soit formé un gaz de reformage primaire (30), à former un flux d'alimentation de reformeur secondaire (40) qui comprend le gaz de reformage primaire et le deuxième flux d'hydrocarbures, à procéder à la combustion partielle du flux d'alimentation de reformeur secondaire avec un gaz (44) contenant de l'oxygène et à amener le gaz partiellement brûlé obtenu à un équilibre sur un deuxième catalyseur de reformage, et à utiliser le gaz de reformage secondaire obtenu (48) afin de chauffer les tubes du reformeur à échange de chaleur, ce qui permet d'obtenir un gaz de reformage partiellement refroidi; b) à refroidir le gaz de reformage partiellement refroidi au-dessous du point de rosée de la vapeur afin que l'eau se condense, et à séparer l'eau condensée (56) de manière à obtenir un gaz de synthèse déshydraté (58); c) à synthétiser les hydrocarbures à partir du gaz de synthèse déshydraté par réaction Fischer-Tropsch, et à séparer au moins une partie des hydrocarbures synthétisés, afin d'obtenir un gaz résiduaire (70); et d) à incorporer au moins une partie dudit gaz résiduaire dans le flux d'alimentation de reformeur secondaire avant combustion partielle de celui-ci.
CA2504596A 2002-11-07 2003-10-23 Production d'hydrocarbures Expired - Fee Related CA2504596C (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GBGB0225961.2A GB0225961D0 (en) 2002-11-07 2002-11-07 Production of hydrocarbons
GB0225961.2 2002-11-07
PCT/GB2003/004622 WO2004041716A1 (fr) 2002-11-07 2003-10-23 Production d'hydrocarbures

Publications (2)

Publication Number Publication Date
CA2504596A1 CA2504596A1 (fr) 2004-05-21
CA2504596C true CA2504596C (fr) 2011-05-03

Family

ID=9947372

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2504596A Expired - Fee Related CA2504596C (fr) 2002-11-07 2003-10-23 Production d'hydrocarbures

Country Status (14)

Country Link
US (1) US7314891B2 (fr)
EP (1) EP1560788B1 (fr)
JP (1) JP4422029B2 (fr)
AT (1) ATE320403T1 (fr)
AU (1) AU2003276396B2 (fr)
CA (1) CA2504596C (fr)
DE (1) DE60304064T2 (fr)
DK (1) DK1560788T3 (fr)
EA (1) EA006869B1 (fr)
GB (1) GB0225961D0 (fr)
MY (1) MY134407A (fr)
NO (1) NO336963B1 (fr)
WO (1) WO2004041716A1 (fr)
ZA (1) ZA200503477B (fr)

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US8273139B2 (en) * 2003-03-16 2012-09-25 Kellogg Brown & Root Llc Catalytic partial oxidation reforming
US7932296B2 (en) * 2003-03-16 2011-04-26 Kellogg Brown & Root Llc Catalytic partial oxidation reforming for syngas processing and products made therefrom
WO2006039475A2 (fr) * 2004-09-30 2006-04-13 Aker Kvaerner, Inc. Recuperation de composes organiques a l'aide d'un saturateur
RU2412226C2 (ru) * 2005-06-14 2011-02-20 Сэсол Текнолоджи (Проприетери) Лимитед Способ получения и конверсии синтез-газа (варианты)
DE102006023248C5 (de) 2006-05-18 2018-01-25 Air Liquide Global E&C Solutions Germany Gmbh Verfahren und Anlage zur Herstellung von Synthesegas
US7910629B2 (en) * 2006-10-20 2011-03-22 Exxonmobil Research And Engineering Company Light ends recovery process for a GTL plant
US8053481B2 (en) * 2006-11-08 2011-11-08 Wm Gtl, Inc. Low-pressure Fischer-Tropsch process
EP1927577A1 (fr) * 2006-12-01 2008-06-04 Casale Chemicals S.A. Procédé et dispositif de production de gaz de synthèse
EP1927578A1 (fr) * 2006-12-02 2008-06-04 Casale Chemicals S.A. Procédé et dispositif de production de gaz de synthèse
WO2009089456A2 (fr) * 2008-01-09 2009-07-16 Rentech, Inc. Éthanol comme charge d'alimentation pour une installation de bctl
EP2294164A4 (fr) * 2008-06-20 2014-09-24 Gtlpetrol Llc Systèmes et procédés de traitement d'hydrogène et de monoxyde de carbone
US9074122B2 (en) * 2008-12-31 2015-07-07 Intevep, S.A. Mitigation of H2S in steam injection technology using amines of natural origin
MY155715A (en) 2009-04-22 2015-11-30 Shell Int Research Production of a synthesis gas blend and use in a fischer-tropsch process
US20100327231A1 (en) * 2009-06-26 2010-12-30 Noah Whitmore Method of producing synthesis gas
WO2012084135A1 (fr) * 2010-12-22 2012-06-28 Haldor Topsøe A/S Procédé pour le reformage d'hydrocarbures
GB201115929D0 (en) 2011-09-15 2011-10-26 Johnson Matthey Plc Improved hydrocarbon production process
WO2013087585A1 (fr) 2011-12-13 2013-06-20 Shell Internationale Research Maatschappij B.V. Procédé de fischer-tropsch
CA2776369C (fr) * 2012-05-09 2014-01-21 Steve Kresnyak Amelioration du procede fischer-tropsch pour la formulation de combustibles hydrocarbones dans un environnement de conversion de gaz en liquide (gtl)
EP2676924A1 (fr) 2012-06-21 2013-12-25 Haldor Topsoe A/S Procédé de reformage d'hydrocarbures
WO2014180888A1 (fr) 2013-05-08 2014-11-13 Shell Internationale Research Maatschappij B.V. Procédé de préparation de gaz de synthèse
EA033831B1 (ru) * 2013-12-02 2019-11-29 Haldor Topsoe As Способ конверсии природного газа в углеводородные продукты и установка для осуществления способа
AU2014363515B2 (en) * 2013-12-12 2018-02-15 Haldor Topsoe A/S Process for the production of synthesis gas
US10000379B2 (en) 2014-11-13 2018-06-19 Shell Oil Company Process for the preparation of syngas
EA201791153A1 (ru) * 2014-11-25 2017-11-30 Хальдор Топсёэ А/С Способ получения синтез-газа посредством рециркуляции газообразных продуктов горения
AU2016259682B2 (en) 2015-05-14 2018-09-13 Shell Internationale Research Maatschappij B.V. Process for preparing a syngas and syngas cooling device
US10144877B2 (en) * 2016-02-01 2018-12-04 Fluor Technologies Corporation Small scale modular gas to liquids plant for stranded remote gas
US20190084833A1 (en) * 2016-02-03 2019-03-21 Epiphany Energy Corporation Production of liquid hydrocarbons, biofuels and uncontaminated co2 from gaseous feedstock
JP7017024B2 (ja) * 2016-02-29 2022-02-08 株式会社Ihi オレフィン製造システム、および、オレフィン製造方法
DE102016002728A1 (de) * 2016-03-08 2017-09-14 Linde Aktiengesellschaft Verfahren zur Erzeugung von Synthesegas
WO2019021129A1 (fr) * 2017-07-27 2019-01-31 Sabic Global Technologies B.V. Appareil et procédé liés à l'utilisation de gaz de synthèse dans la production d'oléfines
FI128568B (en) * 2018-06-11 2020-08-14 Teknologian Tutkimuskeskus Vtt Oy Method and apparatus for the formation and use of hydrocarbons
JP7173777B2 (ja) * 2018-07-30 2022-11-16 三菱重工業株式会社 改質システム
IT201900008280A1 (it) * 2019-06-06 2020-12-06 Amec Foster Wheeler Italiana S R L Reattore, in particolare reattore di reforming con vapore, e suo uso in un processo di reforming con vapore
GB202216857D0 (en) * 2022-11-11 2022-12-28 Johnson Matthey Davy Technologies Ltd A method of forming a liquid hydrocarbon product

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GB0200891D0 (en) 2002-01-16 2002-03-06 Ici Plc Hydrocarbons

Also Published As

Publication number Publication date
AU2003276396A1 (en) 2004-06-07
WO2004041716A1 (fr) 2004-05-21
NO336963B1 (no) 2015-12-07
DE60304064T2 (de) 2006-11-09
ZA200503477B (en) 2006-07-26
MY134407A (en) 2007-12-31
EA200500780A1 (ru) 2005-10-27
JP2006505646A (ja) 2006-02-16
EP1560788B1 (fr) 2006-03-15
DK1560788T3 (da) 2006-07-10
EA006869B1 (ru) 2006-04-28
EP1560788A1 (fr) 2005-08-10
AU2003276396B2 (en) 2008-06-26
US7314891B2 (en) 2008-01-01
ATE320403T1 (de) 2006-04-15
NO20052354L (no) 2005-06-10
JP4422029B2 (ja) 2010-02-24
CA2504596A1 (fr) 2004-05-21
GB0225961D0 (en) 2002-12-11
US20060135629A1 (en) 2006-06-22
DE60304064D1 (de) 2006-05-11

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