CA2456905A1 - Toilet bar having a latent acidifier - Google Patents
Toilet bar having a latent acidifier Download PDFInfo
- Publication number
- CA2456905A1 CA2456905A1 CA002456905A CA2456905A CA2456905A1 CA 2456905 A1 CA2456905 A1 CA 2456905A1 CA 002456905 A CA002456905 A CA 002456905A CA 2456905 A CA2456905 A CA 2456905A CA 2456905 A1 CA2456905 A1 CA 2456905A1
- Authority
- CA
- Canada
- Prior art keywords
- toilet bar
- soap
- fatty acid
- bar
- anionic surfactant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000002535 acidifier Substances 0.000 title claims abstract description 45
- 239000000344 soap Substances 0.000 claims abstract description 78
- 239000000203 mixture Substances 0.000 claims abstract description 58
- -1 aryl isethionates Chemical class 0.000 claims description 52
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 46
- 239000000194 fatty acid Substances 0.000 claims description 46
- 229930195729 fatty acid Natural products 0.000 claims description 46
- 150000004665 fatty acids Chemical class 0.000 claims description 40
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 27
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims description 26
- 239000003945 anionic surfactant Substances 0.000 claims description 24
- 239000002002 slurry Substances 0.000 claims description 19
- 239000003599 detergent Substances 0.000 claims description 13
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 6
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 claims description 6
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims description 6
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 claims description 6
- 150000008051 alkyl sulfates Chemical class 0.000 claims description 5
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 4
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims description 4
- HAMGNFFXQJOFRZ-UHFFFAOYSA-L aluminum;zirconium(4+);chloride;hydroxide;hydrate Chemical compound O.[OH-].[Al+3].[Cl-].[Zr+4] HAMGNFFXQJOFRZ-UHFFFAOYSA-L 0.000 claims description 4
- 239000001506 calcium phosphate Substances 0.000 claims description 4
- 229910000389 calcium phosphate Inorganic materials 0.000 claims description 4
- 235000011010 calcium phosphates Nutrition 0.000 claims description 4
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 claims description 4
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 3
- 239000004471 Glycine Substances 0.000 claims description 3
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 claims description 3
- 150000008052 alkyl sulfonates Chemical class 0.000 claims description 3
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 claims description 3
- 235000019270 ammonium chloride Nutrition 0.000 claims description 3
- VSGNNIFQASZAOI-UHFFFAOYSA-L calcium acetate Chemical compound [Ca+2].CC([O-])=O.CC([O-])=O VSGNNIFQASZAOI-UHFFFAOYSA-L 0.000 claims description 3
- 239000001639 calcium acetate Substances 0.000 claims description 3
- 229960005147 calcium acetate Drugs 0.000 claims description 3
- 235000011092 calcium acetate Nutrition 0.000 claims description 3
- 239000001110 calcium chloride Substances 0.000 claims description 3
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 3
- 235000011148 calcium chloride Nutrition 0.000 claims description 3
- RUTXIHLAWFEWGM-UHFFFAOYSA-H iron(3+) sulfate Chemical compound [Fe+3].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O RUTXIHLAWFEWGM-UHFFFAOYSA-H 0.000 claims description 3
- 229910000360 iron(III) sulfate Inorganic materials 0.000 claims description 3
- 229910052943 magnesium sulfate Inorganic materials 0.000 claims description 3
- 235000019341 magnesium sulphate Nutrition 0.000 claims description 3
- 239000004254 Ammonium phosphate Substances 0.000 claims description 2
- 229910000148 ammonium phosphate Inorganic materials 0.000 claims description 2
- 235000019289 ammonium phosphates Nutrition 0.000 claims description 2
- LVYZJEPLMYTTGH-UHFFFAOYSA-H dialuminum chloride pentahydroxide dihydrate Chemical compound [Cl-].[Al+3].[OH-].[OH-].[Al+3].[OH-].[OH-].[OH-].O.O LVYZJEPLMYTTGH-UHFFFAOYSA-H 0.000 claims description 2
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims description 2
- 229910017053 inorganic salt Inorganic materials 0.000 claims description 2
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 2
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims description 2
- 229960001763 zinc sulfate Drugs 0.000 claims description 2
- 229910000368 zinc sulfate Inorganic materials 0.000 claims description 2
- 229960002713 calcium chloride Drugs 0.000 claims 1
- 239000002585 base Substances 0.000 description 39
- 238000012360 testing method Methods 0.000 description 30
- 239000000047 product Substances 0.000 description 29
- 210000003491 skin Anatomy 0.000 description 29
- 239000000523 sample Substances 0.000 description 18
- 230000000694 effects Effects 0.000 description 17
- 238000000034 method Methods 0.000 description 17
- 239000003921 oil Substances 0.000 description 17
- 235000019198 oils Nutrition 0.000 description 17
- 125000000217 alkyl group Chemical group 0.000 description 15
- 238000011282 treatment Methods 0.000 description 15
- 206010015150 Erythema Diseases 0.000 description 14
- 150000001875 compounds Chemical class 0.000 description 13
- 241000282372 Panthera onca Species 0.000 description 12
- 125000004432 carbon atom Chemical group C* 0.000 description 12
- 239000003974 emollient agent Substances 0.000 description 12
- 239000000463 material Substances 0.000 description 12
- 230000000007 visual effect Effects 0.000 description 12
- 125000002091 cationic group Chemical group 0.000 description 11
- 235000019864 coconut oil Nutrition 0.000 description 11
- 239000003240 coconut oil Substances 0.000 description 11
- 230000000052 comparative effect Effects 0.000 description 11
- 238000005259 measurement Methods 0.000 description 11
- 239000004094 surface-active agent Substances 0.000 description 11
- 229940095602 acidifiers Drugs 0.000 description 10
- 239000003795 chemical substances by application Substances 0.000 description 10
- 231100000321 erythema Toxicity 0.000 description 10
- 238000011156 evaluation Methods 0.000 description 10
- 238000009472 formulation Methods 0.000 description 10
- 150000003839 salts Chemical class 0.000 description 10
- 210000000245 forearm Anatomy 0.000 description 9
- 230000036572 transepidermal water loss Effects 0.000 description 9
- 229910052925 anhydrite Inorganic materials 0.000 description 8
- 239000003925 fat Substances 0.000 description 8
- 235000019197 fats Nutrition 0.000 description 8
- 239000003760 tallow Substances 0.000 description 8
- 229910052708 sodium Inorganic materials 0.000 description 7
- 239000011734 sodium Substances 0.000 description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 6
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 6
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 6
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 6
- 239000002253 acid Substances 0.000 description 6
- 230000002209 hydrophobic effect Effects 0.000 description 6
- 238000005406 washing Methods 0.000 description 6
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 5
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 5
- 150000007513 acids Chemical class 0.000 description 5
- 239000011575 calcium Substances 0.000 description 5
- 229910052791 calcium Inorganic materials 0.000 description 5
- 238000005336 cracking Methods 0.000 description 5
- 238000009826 distribution Methods 0.000 description 5
- 229910052749 magnesium Inorganic materials 0.000 description 5
- 239000011777 magnesium Substances 0.000 description 5
- 230000020477 pH reduction Effects 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- 229910052938 sodium sulfate Inorganic materials 0.000 description 5
- 235000011152 sodium sulphate Nutrition 0.000 description 5
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 229910052783 alkali metal Inorganic materials 0.000 description 4
- 150000001408 amides Chemical class 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- HVYWMOMLDIMFJA-DPAQBDIFSA-N cholesterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 HVYWMOMLDIMFJA-DPAQBDIFSA-N 0.000 description 4
- 239000000945 filler Substances 0.000 description 4
- 235000021588 free fatty acids Nutrition 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 239000010466 nut oil Substances 0.000 description 4
- 229920001223 polyethylene glycol Polymers 0.000 description 4
- 229910052700 potassium Inorganic materials 0.000 description 4
- 239000011591 potassium Substances 0.000 description 4
- 230000003381 solubilizing effect Effects 0.000 description 4
- 238000006467 substitution reaction Methods 0.000 description 4
- 230000004083 survival effect Effects 0.000 description 4
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 3
- 235000013162 Cocos nucifera Nutrition 0.000 description 3
- 244000060011 Cocos nucifera Species 0.000 description 3
- 244000007835 Cyamopsis tetragonoloba Species 0.000 description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
- DCXXMTOCNZCJGO-UHFFFAOYSA-N Glycerol trioctadecanoate Natural products CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 description 3
- 102220549062 Low molecular weight phosphotyrosine protein phosphatase_C13S_mutation Human genes 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 3
- 125000003342 alkenyl group Chemical group 0.000 description 3
- 239000002280 amphoteric surfactant Substances 0.000 description 3
- 125000000129 anionic group Chemical group 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- 230000004888 barrier function Effects 0.000 description 3
- 230000000740 bleeding effect Effects 0.000 description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 description 3
- 238000004364 calculation method Methods 0.000 description 3
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- 210000000434 stratum corneum Anatomy 0.000 description 3
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 3
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- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- SUMDYPCJJOFFON-UHFFFAOYSA-N isethionic acid Chemical compound OCCS(O)(=O)=O SUMDYPCJJOFFON-UHFFFAOYSA-N 0.000 description 1
- XUGNVMKQXJXZCD-UHFFFAOYSA-N isopropyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC(C)C XUGNVMKQXJXZCD-UHFFFAOYSA-N 0.000 description 1
- 150000003903 lactic acid esters Chemical class 0.000 description 1
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- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
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- 150000002823 nitrates Chemical class 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid group Chemical group C(CCCCCCC\C=C/CCCCCCCC)(=O)O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000003605 opacifier Substances 0.000 description 1
- 238000011017 operating method Methods 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- MPQXHAGKBWFSNV-UHFFFAOYSA-N oxidophosphanium Chemical group [PH3]=O MPQXHAGKBWFSNV-UHFFFAOYSA-N 0.000 description 1
- 238000007427 paired t-test Methods 0.000 description 1
- 235000019865 palm kernel oil Nutrition 0.000 description 1
- 239000003346 palm kernel oil Substances 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000011236 particulate material Substances 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 235000019271 petrolatum Nutrition 0.000 description 1
- 229940066842 petrolatum Drugs 0.000 description 1
- 150000003904 phospholipids Chemical class 0.000 description 1
- 239000001739 pinus spp. Substances 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- XOJVVFBFDXDTEG-UHFFFAOYSA-N pristane Chemical compound CC(C)CCCC(C)CCCC(C)CCCC(C)C XOJVVFBFDXDTEG-UHFFFAOYSA-N 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
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- 230000037067 skin hydration Effects 0.000 description 1
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- 229940096501 sodium cocoamphoacetate Drugs 0.000 description 1
- 229940045998 sodium isethionate Drugs 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- GOJYXPWOUJYXJC-UHFFFAOYSA-M sodium;2-[1-(2-hydroxyethyl)-2-undecyl-4,5-dihydroimidazol-1-ium-1-yl]acetate;hydroxide Chemical compound [OH-].[Na+].CCCCCCCCCCCC1=NCC[N+]1(CCO)CC([O-])=O GOJYXPWOUJYXJC-UHFFFAOYSA-M 0.000 description 1
- LADXKQRVAFSPTR-UHFFFAOYSA-M sodium;2-hydroxyethanesulfonate Chemical compound [Na+].OCCS([O-])(=O)=O LADXKQRVAFSPTR-UHFFFAOYSA-M 0.000 description 1
- 239000007779 soft material Substances 0.000 description 1
- 235000010199 sorbic acid Nutrition 0.000 description 1
- 239000004334 sorbic acid Substances 0.000 description 1
- 229940075582 sorbic acid Drugs 0.000 description 1
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- 229940084106 spermaceti Drugs 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 229940031439 squalene Drugs 0.000 description 1
- TUHBEKDERLKLEC-UHFFFAOYSA-N squalene Natural products CC(=CCCC(=CCCC(=CCCC=C(/C)CCC=C(/C)CC=C(C)C)C)C)C TUHBEKDERLKLEC-UHFFFAOYSA-N 0.000 description 1
- 238000007619 statistical method Methods 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
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- 150000003445 sucroses Chemical class 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical class [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical group OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 230000000475 sunscreen effect Effects 0.000 description 1
- 239000000516 sunscreening agent Substances 0.000 description 1
- 210000000106 sweat gland Anatomy 0.000 description 1
- 229940095064 tartrate Drugs 0.000 description 1
- 150000003505 terpenes Chemical class 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- BORJONZPSTVSFP-UHFFFAOYSA-N tetradecyl 2-hydroxypropanoate Chemical compound CCCCCCCCCCCCCCOC(=O)C(C)O BORJONZPSTVSFP-UHFFFAOYSA-N 0.000 description 1
- DZKXJUASMGQEMA-UHFFFAOYSA-N tetradecyl tetradecanoate Chemical compound CCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCC DZKXJUASMGQEMA-UHFFFAOYSA-N 0.000 description 1
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 229960000790 thymol Drugs 0.000 description 1
- 239000001585 thymus vulgaris Substances 0.000 description 1
- 210000001519 tissue Anatomy 0.000 description 1
- 230000000699 topical effect Effects 0.000 description 1
- 150000003626 triacylglycerols Chemical class 0.000 description 1
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 1
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical group CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 229940036248 turpentine Drugs 0.000 description 1
- 229940099259 vaseline Drugs 0.000 description 1
- 235000019155 vitamin A Nutrition 0.000 description 1
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- 235000019154 vitamin C Nutrition 0.000 description 1
- 239000011718 vitamin C Substances 0.000 description 1
- 235000019165 vitamin E Nutrition 0.000 description 1
- 239000011709 vitamin E Substances 0.000 description 1
- 235000019168 vitamin K Nutrition 0.000 description 1
- 239000011712 vitamin K Substances 0.000 description 1
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- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
- C11D10/042—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on anionic surface-active compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/006—Detergents in the form of bars or tablets containing mainly surfactants, but no builders, e.g. syndet bar
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/122—Sulfur-containing, e.g. sulfates, sulfites or gypsum
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
- Cosmetics (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/967,280 US6660699B2 (en) | 2001-09-28 | 2001-09-28 | Toilet bar having a latent acidifier |
| US09/967,280 | 2001-09-28 | ||
| PCT/EP2002/010275 WO2003029395A1 (en) | 2001-09-28 | 2002-09-12 | Toilet bar having a latent acidifier |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2456905A1 true CA2456905A1 (en) | 2003-04-10 |
Family
ID=25512563
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002456905A Abandoned CA2456905A1 (en) | 2001-09-28 | 2002-09-12 | Toilet bar having a latent acidifier |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US6660699B2 (enExample) |
| EP (2) | EP1900802A3 (enExample) |
| JP (1) | JP2005504168A (enExample) |
| KR (1) | KR100915048B1 (enExample) |
| CN (1) | CN1561384A (enExample) |
| AR (1) | AR036691A1 (enExample) |
| AU (1) | AU2002333839B2 (enExample) |
| BR (1) | BR0213072A (enExample) |
| CA (1) | CA2456905A1 (enExample) |
| CZ (1) | CZ2004422A3 (enExample) |
| HU (1) | HUP0401583A3 (enExample) |
| MX (1) | MXPA04002636A (enExample) |
| PL (1) | PL200547B1 (enExample) |
| RU (1) | RU2297445C2 (enExample) |
| WO (1) | WO2003029395A1 (enExample) |
| ZA (1) | ZA200400888B (enExample) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6809070B2 (en) | 2001-09-28 | 2004-10-26 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Toilet bar having a latent acidifier |
| MXPA04006002A (es) * | 2001-12-21 | 2004-09-27 | Rhodia | Composiciones tensioactivas estables para suspender componentes. |
| KR20050019288A (ko) * | 2003-08-18 | 2005-03-03 | 씨제이 주식회사 | 화장비누 조성물 |
| US7737096B2 (en) * | 2004-10-26 | 2010-06-15 | Unilever Home & Personal Care Usa Division Of Conopco, Inc. | Mild acyl isethionate toilet bar composition |
| US7015179B1 (en) * | 2004-12-22 | 2006-03-21 | Unilever Home & Personal Care Usa | Reduced odor toilet bar composition |
| US7662761B2 (en) * | 2005-05-31 | 2010-02-16 | Conopco, Inc. | Soap bars comprising insoluble multivalent ion soap complexes |
| US8017567B2 (en) * | 2005-08-19 | 2011-09-13 | The Dial Corporation | Personal cleansing bar with free fatty acid and quaternary surfactant synergism |
| US20070066500A1 (en) * | 2005-09-21 | 2007-03-22 | Conopco, Inc., D/B/A Unilever | Composition with enhanced squeaky feel |
| US20070066501A1 (en) * | 2005-09-21 | 2007-03-22 | Conopco, Inc., D/B/A Unilever | Process for enhancing squeaky skin feel of surfactant solution rinsed in water by proper selection of components |
| CA2633017A1 (en) * | 2005-12-30 | 2007-07-12 | Norel, S.A. | Method for producing calcium soaps for animal feed |
| JP2007314638A (ja) * | 2006-05-24 | 2007-12-06 | Max:Kk | 固形洗浄剤 |
| DE102006025414A1 (de) | 2006-05-31 | 2007-12-06 | Vodafone Holding Gmbh | Einrichtung und Verfahren zur Übertragung von Daten innerhalb wenigstens eines Kommunikationsnetzes |
| US7545838B2 (en) * | 2006-06-12 | 2009-06-09 | Coherent, Inc. | Incoherent combination of laser beams |
| WO2009078857A1 (en) * | 2007-12-17 | 2009-06-25 | Colgate-Palmolive Company | Cleansing bars |
| RU2451064C2 (ru) * | 2007-12-17 | 2012-05-20 | Колгейт-Палмолив Компани | Очищающее кусковое мыло |
| EP2701669A1 (en) * | 2011-02-24 | 2014-03-05 | Serena Linley S.a.r.l. | Bar soap composition with enhanced sensory properties in soft and very soft water |
| CN102732395B (zh) * | 2012-07-03 | 2015-10-28 | 东莞市隆威实业有限公司 | 一种银杏手工皂及其制作方法 |
| HK1216016A1 (zh) | 2012-12-19 | 2016-10-07 | Colgate-Palmolive Company | 鋅氨基酸絡合物與半胱氨酸 |
| CN108384529B (zh) * | 2018-05-08 | 2020-09-15 | 中联煤层气有限责任公司 | 一种油包水乳状液流体、制备方法及石油开采方法 |
| US11104870B1 (en) * | 2020-04-01 | 2021-08-31 | Jonathan Diaz | Automatic flush activated toilet odor prevention tablet |
| KR102955240B1 (ko) * | 2023-12-22 | 2026-04-21 | (주)동방비앤에이치 | 모발 및 바디 세정용 고형비누 제조를 위한 원료 조성물 |
Family Cites Families (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3030310A (en) | 1957-10-28 | 1962-04-17 | Colgate Palmolive Co | Combination soap-synthetic detergent bar |
| GB885332A (en) | 1958-08-26 | 1961-12-28 | Colgate Palmolive Co | Detergent bar |
| GB989007A (en) | 1961-01-23 | 1965-04-14 | Procter & Gamble | Detergent bar |
| BE628622A (enExample) | 1962-03-07 | |||
| BE634272A (enExample) | 1963-02-27 | |||
| GB1004595A (en) * | 1963-02-28 | 1965-09-15 | John Constantine Grey | Improvements to flexible couplings |
| US3723325A (en) | 1967-09-27 | 1973-03-27 | Procter & Gamble | Detergent compositions containing particle deposition enhancing agents |
| US3951842A (en) | 1973-04-02 | 1976-04-20 | Lever Brothers Company | Synthetic detergent bar with antimushing agent |
| GB1477897A (en) | 1974-09-06 | 1977-06-29 | Unilever Ltd | Synthetic detergent bar |
| US4673525A (en) | 1985-05-13 | 1987-06-16 | The Procter & Gamble Company | Ultra mild skin cleansing composition |
| US4705644A (en) | 1986-03-06 | 1987-11-10 | Colgate Palmolive Company | Alpha-sulfo-higher fatty acid-lower alcohol ester- and amide-based detergent laundry bars and process for manufacture thereof |
| US4806273A (en) | 1986-03-06 | 1989-02-21 | Colgate-Palmolive Company | Breakage resistant higher fatty alcohol sulfate detergent laundry bars |
| DE3711776A1 (de) | 1987-04-08 | 1988-10-27 | Huels Chemische Werke Ag | Verwendung von n-polyhydroxyalkylfettsaeureamiden als verdickungsmittel fuer fluessige waessrige tensidsysteme |
| US5053159A (en) | 1989-11-08 | 1991-10-01 | Colgate-Palmolive Company | Laundry detergent bar |
| GB2253404B (en) | 1991-03-07 | 1995-01-18 | Kao Corp | Solid detergent composition |
| ES2094309T3 (es) | 1991-11-25 | 1997-01-16 | Unilever Nv | Esteres de acidos grasos de acido isetionico alcoxilado y composiciones detergentes que comprenden los mismos. |
| US5389279A (en) | 1991-12-31 | 1995-02-14 | Lever Brothers Company, Division Of Conopco, Inc. | Compositions comprising nonionic glycolipid surfactants |
| CA2087691A1 (en) | 1992-01-23 | 1993-07-24 | Peter Critchley | Cosmetic compositon |
| US5691287A (en) | 1995-12-21 | 1997-11-25 | S. C. Johnson & Son, Inc. | Low irritation cleansing bar |
| JP3655709B2 (ja) | 1996-04-01 | 2005-06-02 | ペンタックス株式会社 | 洗浄剤 |
| AU6777296A (en) | 1996-08-16 | 1998-03-06 | Procter & Gamble Company, The | Detergent compositions comprising antibody controlled lipolytic activity |
| AU1494097A (en) | 1997-02-27 | 1998-09-03 | Procter & Gamble Company, The | Laundry detergent bars with improved physical properties |
| WO1998053040A1 (en) | 1997-05-22 | 1998-11-26 | The Procter & Gamble Company | Laundry bars with improved sudsing and improved physical properties |
| US5965508A (en) * | 1997-10-21 | 1999-10-12 | Stepan Company | Soap bar compositions comprising alpha sulfonated fatty acid alkyl esters and long chain fatty acids |
| US6559110B1 (en) | 2000-08-24 | 2003-05-06 | John A. Lopes | Syndet bar soap having an acidifying agent |
-
2001
- 2001-09-28 US US09/967,280 patent/US6660699B2/en not_active Expired - Fee Related
-
2002
- 2002-09-12 JP JP2003532617A patent/JP2005504168A/ja active Pending
- 2002-09-12 WO PCT/EP2002/010275 patent/WO2003029395A1/en not_active Ceased
- 2002-09-12 CA CA002456905A patent/CA2456905A1/en not_active Abandoned
- 2002-09-12 KR KR1020047004421A patent/KR100915048B1/ko not_active Expired - Fee Related
- 2002-09-12 BR BR0213072-6A patent/BR0213072A/pt not_active IP Right Cessation
- 2002-09-12 HU HU0401583A patent/HUP0401583A3/hu unknown
- 2002-09-12 CZ CZ2004422A patent/CZ2004422A3/cs unknown
- 2002-09-12 CN CNA028192206A patent/CN1561384A/zh active Pending
- 2002-09-12 EP EP07121930A patent/EP1900802A3/en not_active Withdrawn
- 2002-09-12 MX MXPA04002636A patent/MXPA04002636A/es not_active Application Discontinuation
- 2002-09-12 RU RU2004113103/13A patent/RU2297445C2/ru not_active IP Right Cessation
- 2002-09-12 EP EP02800082A patent/EP1430107A1/en not_active Ceased
- 2002-09-12 PL PL369304A patent/PL200547B1/pl not_active IP Right Cessation
- 2002-09-12 AU AU2002333839A patent/AU2002333839B2/en not_active Ceased
- 2002-09-27 AR ARP020103658A patent/AR036691A1/es unknown
-
2004
- 2004-02-03 ZA ZA200400888A patent/ZA200400888B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| HUP0401583A3 (en) | 2009-07-28 |
| CZ2004422A3 (cs) | 2004-11-10 |
| WO2003029395A1 (en) | 2003-04-10 |
| ZA200400888B (en) | 2005-02-03 |
| PL369304A1 (en) | 2005-04-18 |
| BR0213072A (pt) | 2004-10-13 |
| HUP0401583A2 (hu) | 2005-09-28 |
| US6660699B2 (en) | 2003-12-09 |
| US20030134762A1 (en) | 2003-07-17 |
| KR100915048B1 (ko) | 2009-09-02 |
| CN1561384A (zh) | 2005-01-05 |
| EP1900802A2 (en) | 2008-03-19 |
| AU2002333839B2 (en) | 2006-12-14 |
| AR036691A1 (es) | 2004-09-29 |
| PL200547B1 (pl) | 2009-01-30 |
| KR20040037139A (ko) | 2004-05-04 |
| RU2004113103A (ru) | 2005-10-27 |
| EP1900802A3 (en) | 2008-06-11 |
| RU2297445C2 (ru) | 2007-04-20 |
| JP2005504168A (ja) | 2005-02-10 |
| EP1430107A1 (en) | 2004-06-23 |
| MXPA04002636A (es) | 2004-06-07 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| FZDE | Discontinued |