CA2451683A1 - Lubricant based on a water in oil emulsion with a suspended solid base - Google Patents
Lubricant based on a water in oil emulsion with a suspended solid base Download PDFInfo
- Publication number
- CA2451683A1 CA2451683A1 CA002451683A CA2451683A CA2451683A1 CA 2451683 A1 CA2451683 A1 CA 2451683A1 CA 002451683 A CA002451683 A CA 002451683A CA 2451683 A CA2451683 A CA 2451683A CA 2451683 A1 CA2451683 A1 CA 2451683A1
- Authority
- CA
- Canada
- Prior art keywords
- base
- oil
- lubricant
- water
- magnesium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000000314 lubricant Substances 0.000 title claims abstract description 214
- 239000007762 w/o emulsion Substances 0.000 title claims description 9
- 239000007787 solid Substances 0.000 title description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 158
- 239000002904 solvent Substances 0.000 claims abstract description 77
- 238000002485 combustion reaction Methods 0.000 claims abstract description 46
- 239000000446 fuel Substances 0.000 claims abstract description 22
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 19
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 16
- 239000011593 sulfur Substances 0.000 claims abstract description 16
- 239000003921 oil Substances 0.000 claims description 223
- 239000002585 base Substances 0.000 claims description 187
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 118
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 117
- 239000000203 mixture Substances 0.000 claims description 75
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 60
- 239000003995 emulsifying agent Substances 0.000 claims description 56
- 239000011575 calcium Substances 0.000 claims description 55
- 239000010687 lubricating oil Substances 0.000 claims description 52
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 52
- 229910052751 metal Inorganic materials 0.000 claims description 48
- 239000002184 metal Substances 0.000 claims description 48
- 150000001412 amines Chemical class 0.000 claims description 47
- 239000011777 magnesium Substances 0.000 claims description 45
- -1 borate compound Chemical class 0.000 claims description 42
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 39
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 39
- 239000003599 detergent Substances 0.000 claims description 39
- 235000011118 potassium hydroxide Nutrition 0.000 claims description 39
- 235000011121 sodium hydroxide Nutrition 0.000 claims description 39
- 238000000034 method Methods 0.000 claims description 36
- 150000001875 compounds Chemical class 0.000 claims description 35
- 239000011734 sodium Substances 0.000 claims description 35
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 34
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 34
- 229910052791 calcium Inorganic materials 0.000 claims description 34
- 239000011591 potassium Substances 0.000 claims description 34
- 238000006243 chemical reaction Methods 0.000 claims description 32
- 229910021529 ammonia Inorganic materials 0.000 claims description 30
- 229910052749 magnesium Inorganic materials 0.000 claims description 30
- 239000002253 acid Substances 0.000 claims description 28
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims description 26
- 239000000920 calcium hydroxide Substances 0.000 claims description 26
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims description 26
- 235000011116 calcium hydroxide Nutrition 0.000 claims description 26
- 229910052708 sodium Inorganic materials 0.000 claims description 25
- 229910052700 potassium Inorganic materials 0.000 claims description 24
- 239000002245 particle Substances 0.000 claims description 22
- 230000002378 acidificating effect Effects 0.000 claims description 20
- 239000000395 magnesium oxide Substances 0.000 claims description 19
- 235000012245 magnesium oxide Nutrition 0.000 claims description 19
- 239000002270 dispersing agent Substances 0.000 claims description 18
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 17
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 15
- 239000003963 antioxidant agent Substances 0.000 claims description 15
- 235000006708 antioxidants Nutrition 0.000 claims description 15
- 229910052744 lithium Inorganic materials 0.000 claims description 15
- 230000001050 lubricating effect Effects 0.000 claims description 15
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 14
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 13
- 239000004202 carbamide Substances 0.000 claims description 12
- 239000008367 deionised water Substances 0.000 claims description 12
- 239000003513 alkali Substances 0.000 claims description 11
- 230000003078 antioxidant effect Effects 0.000 claims description 11
- 150000007524 organic acids Chemical class 0.000 claims description 11
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims description 10
- 239000000654 additive Substances 0.000 claims description 10
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 10
- 229910021641 deionized water Inorganic materials 0.000 claims description 10
- 230000001804 emulsifying effect Effects 0.000 claims description 10
- 238000011065 in-situ storage Methods 0.000 claims description 10
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 claims description 10
- 229910052808 lithium carbonate Inorganic materials 0.000 claims description 10
- 229910003002 lithium salt Inorganic materials 0.000 claims description 10
- 159000000002 lithium salts Chemical class 0.000 claims description 10
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims description 10
- 229910000027 potassium carbonate Inorganic materials 0.000 claims description 10
- 230000008569 process Effects 0.000 claims description 10
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 10
- STIAPHVBRDNOAJ-UHFFFAOYSA-N carbamimidoylazanium;carbonate Chemical compound NC(N)=N.NC(N)=N.OC(O)=O STIAPHVBRDNOAJ-UHFFFAOYSA-N 0.000 claims description 9
- 239000013535 sea water Substances 0.000 claims description 9
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 8
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 7
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 7
- 239000000347 magnesium hydroxide Substances 0.000 claims description 7
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 7
- 235000012254 magnesium hydroxide Nutrition 0.000 claims description 7
- 238000004519 manufacturing process Methods 0.000 claims description 7
- 235000005985 organic acids Nutrition 0.000 claims description 7
- 238000005461 lubrication Methods 0.000 claims description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 5
- 239000007866 anti-wear additive Substances 0.000 claims description 5
- 239000007795 chemical reaction product Substances 0.000 claims description 5
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims description 4
- 150000001336 alkenes Chemical class 0.000 claims description 4
- 238000000149 argon plasma sintering Methods 0.000 claims description 4
- 235000010216 calcium carbonate Nutrition 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 3
- 150000003873 salicylate salts Chemical class 0.000 claims description 3
- 150000005846 sugar alcohols Polymers 0.000 claims description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
- 230000000996 additive effect Effects 0.000 claims description 2
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 claims description 2
- 150000008052 alkyl sulfonates Chemical class 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims description 2
- 239000011701 zinc Substances 0.000 claims description 2
- 150000002897 organic nitrogen compounds Chemical class 0.000 claims 7
- 229910052782 aluminium Inorganic materials 0.000 claims 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 6
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 claims 2
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 claims 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims 1
- 229910052796 boron Inorganic materials 0.000 claims 1
- 150000005323 carbonate salts Chemical class 0.000 claims 1
- 239000011574 phosphorus Substances 0.000 claims 1
- 229910052698 phosphorus Inorganic materials 0.000 claims 1
- 235000013824 polyphenols Nutrition 0.000 claims 1
- 230000003134 recirculating effect Effects 0.000 claims 1
- 239000000839 emulsion Substances 0.000 abstract description 180
- 230000009286 beneficial effect Effects 0.000 abstract description 2
- 150000007522 mineralic acids Chemical class 0.000 abstract description 2
- 239000003795 chemical substances by application Substances 0.000 description 57
- 238000012360 testing method Methods 0.000 description 55
- 239000000047 product Substances 0.000 description 47
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 45
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 44
- 125000004432 carbon atom Chemical group C* 0.000 description 43
- 150000003839 salts Chemical class 0.000 description 41
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 36
- 125000001424 substituent group Chemical group 0.000 description 30
- 239000004094 surface-active agent Substances 0.000 description 29
- 239000004215 Carbon black (E152) Substances 0.000 description 27
- 229930195733 hydrocarbon Natural products 0.000 description 27
- 150000002430 hydrocarbons Chemical class 0.000 description 27
- 229920002367 Polyisobutene Polymers 0.000 description 24
- 239000000463 material Substances 0.000 description 24
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 23
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 23
- 238000006386 neutralization reaction Methods 0.000 description 22
- 150000003460 sulfonic acids Chemical class 0.000 description 22
- FALRKNHUBBKYCC-UHFFFAOYSA-N 2-(chloromethyl)pyridine-3-carbonitrile Chemical compound ClCC1=NC=CC=C1C#N FALRKNHUBBKYCC-UHFFFAOYSA-N 0.000 description 20
- 229940014800 succinic anhydride Drugs 0.000 description 20
- 125000001183 hydrocarbyl group Chemical group 0.000 description 19
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 description 16
- 239000012972 dimethylethanolamine Substances 0.000 description 16
- 150000002148 esters Chemical class 0.000 description 16
- 150000002989 phenols Chemical class 0.000 description 16
- 229920000768 polyamine Polymers 0.000 description 16
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 15
- 238000009472 formulation Methods 0.000 description 14
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 12
- 238000004458 analytical method Methods 0.000 description 12
- 238000005260 corrosion Methods 0.000 description 12
- 230000007797 corrosion Effects 0.000 description 12
- 125000000217 alkyl group Chemical group 0.000 description 11
- 229910052799 carbon Inorganic materials 0.000 description 10
- 229910052739 hydrogen Inorganic materials 0.000 description 10
- 229910052742 iron Inorganic materials 0.000 description 10
- 239000000725 suspension Substances 0.000 description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 9
- 239000012141 concentrate Substances 0.000 description 9
- 239000003085 diluting agent Substances 0.000 description 9
- HHLFWLYXYJOTON-UHFFFAOYSA-N glyoxylic acid Chemical compound OC(=O)C=O HHLFWLYXYJOTON-UHFFFAOYSA-N 0.000 description 9
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 9
- 150000002736 metal compounds Chemical class 0.000 description 9
- 150000002739 metals Chemical class 0.000 description 9
- 239000003208 petroleum Substances 0.000 description 9
- 238000002360 preparation method Methods 0.000 description 9
- 239000000126 substance Substances 0.000 description 9
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 8
- 150000007513 acids Chemical class 0.000 description 8
- 150000001299 aldehydes Chemical class 0.000 description 8
- 239000001257 hydrogen Substances 0.000 description 8
- CQRYARSYNCAZFO-UHFFFAOYSA-N salicyl alcohol Chemical compound OCC1=CC=CC=C1O CQRYARSYNCAZFO-UHFFFAOYSA-N 0.000 description 8
- 238000010008 shearing Methods 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- 150000003871 sulfonates Chemical class 0.000 description 8
- 125000001931 aliphatic group Chemical group 0.000 description 7
- 125000003118 aryl group Chemical group 0.000 description 7
- 229910002092 carbon dioxide Inorganic materials 0.000 description 7
- 235000019271 petrolatum Nutrition 0.000 description 7
- 229920000098 polyolefin Polymers 0.000 description 7
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
- 150000008064 anhydrides Chemical class 0.000 description 6
- 239000010949 copper Substances 0.000 description 6
- 239000006185 dispersion Substances 0.000 description 6
- 150000002500 ions Chemical class 0.000 description 6
- 229910001425 magnesium ion Inorganic materials 0.000 description 6
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 6
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 description 6
- 241000894007 species Species 0.000 description 6
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 5
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 5
- 150000003949 imides Chemical class 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 230000003472 neutralizing effect Effects 0.000 description 5
- 150000002894 organic compounds Chemical class 0.000 description 5
- 239000012188 paraffin wax Substances 0.000 description 5
- 238000003860 storage Methods 0.000 description 5
- 230000004580 weight loss Effects 0.000 description 5
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 239000002199 base oil Substances 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 239000006227 byproduct Substances 0.000 description 4
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 4
- 239000011651 chromium Substances 0.000 description 4
- 239000007859 condensation product Substances 0.000 description 4
- 125000004122 cyclic group Chemical group 0.000 description 4
- 229960002887 deanol Drugs 0.000 description 4
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000012530 fluid Substances 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 239000011133 lead Substances 0.000 description 4
- 239000002480 mineral oil Substances 0.000 description 4
- 239000000178 monomer Substances 0.000 description 4
- 239000010705 motor oil Substances 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- 150000003141 primary amines Chemical class 0.000 description 4
- 238000000926 separation method Methods 0.000 description 4
- KZNICNPSHKQLFF-UHFFFAOYSA-N succinimide Chemical compound O=C1CCC(=O)N1 KZNICNPSHKQLFF-UHFFFAOYSA-N 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
- 239000005977 Ethylene Substances 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical class ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 125000003342 alkenyl group Chemical group 0.000 description 3
- 125000002947 alkylene group Chemical group 0.000 description 3
- 150000001408 amides Chemical class 0.000 description 3
- 125000000129 anionic group Chemical group 0.000 description 3
- 230000003466 anti-cipated effect Effects 0.000 description 3
- 239000007798 antifreeze agent Substances 0.000 description 3
- VTJUKNSKBAOEHE-UHFFFAOYSA-N calixarene Chemical class COC(=O)COC1=C(CC=2C(=C(CC=3C(=C(C4)C=C(C=3)C(C)(C)C)OCC(=O)OC)C=C(C=2)C(C)(C)C)OCC(=O)OC)C=C(C(C)(C)C)C=C1CC1=C(OCC(=O)OC)C4=CC(C(C)(C)C)=C1 VTJUKNSKBAOEHE-UHFFFAOYSA-N 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 230000003749 cleanliness Effects 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 3
- 238000007710 freezing Methods 0.000 description 3
- 230000008014 freezing Effects 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000003112 inhibitor Substances 0.000 description 3
- 238000004890 malting Methods 0.000 description 3
- 235000010446 mineral oil Nutrition 0.000 description 3
- 230000007935 neutral effect Effects 0.000 description 3
- 125000004433 nitrogen atom Chemical group N* 0.000 description 3
- 229920000570 polyether Polymers 0.000 description 3
- 229920005862 polyol Polymers 0.000 description 3
- 239000000376 reactant Substances 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- YGSDEFSMJLZEOE-UHFFFAOYSA-M salicylate Chemical compound OC1=CC=CC=C1C([O-])=O YGSDEFSMJLZEOE-UHFFFAOYSA-M 0.000 description 3
- 229960001860 salicylate Drugs 0.000 description 3
- 229920006395 saturated elastomer Polymers 0.000 description 3
- 150000003335 secondary amines Chemical class 0.000 description 3
- 238000005987 sulfurization reaction Methods 0.000 description 3
- 150000003512 tertiary amines Chemical class 0.000 description 3
- 229960001124 trientine Drugs 0.000 description 3
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 2
- GBBHWGRJHHNAGT-UHFFFAOYSA-N 3-hexadecyloxolane-2,5-dione Chemical compound CCCCCCCCCCCCCCCCC1CC(=O)OC1=O GBBHWGRJHHNAGT-UHFFFAOYSA-N 0.000 description 2
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N Butyraldehyde Chemical compound CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 2
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 2
- 241000158728 Meliaceae Species 0.000 description 2
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
- 229930040373 Paraformaldehyde Natural products 0.000 description 2
- 239000004264 Petrolatum Substances 0.000 description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 2
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 150000001342 alkaline earth metals Chemical class 0.000 description 2
- 125000003545 alkoxy group Chemical group 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
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Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M141/00—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M141/00—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/25—Internal-combustion engines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/25—Internal-combustion engines
- C10N2040/252—Diesel engines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2050/00—Form in which the lubricant is applied to the material being lubricated
- C10N2050/01—Emulsions, colloids, or micelles
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2050/00—Form in which the lubricant is applied to the material being lubricated
- C10N2050/01—Emulsions, colloids, or micelles
- C10N2050/013—Water-in-oil
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2050/00—Form in which the lubricant is applied to the material being lubricated
- C10N2050/015—Dispersions of solid lubricants
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2050/00—Form in which the lubricant is applied to the material being lubricated
- C10N2050/015—Dispersions of solid lubricants
- C10N2050/02—Dispersions of solid lubricants dissolved or suspended in a carrier which subsequently evaporates to leave a lubricant coating
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2070/00—Specific manufacturing methods for lubricant compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Applications Claiming Priority (9)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US30218001P | 2001-06-29 | 2001-06-29 | |
| US30207401P | 2001-06-29 | 2001-06-29 | |
| US60/302,180 | 2001-06-29 | ||
| US60/302,074 | 2001-06-29 | ||
| US34273401P | 2001-12-20 | 2001-12-20 | |
| US60/342,734 | 2001-12-20 | ||
| US37845902P | 2002-05-07 | 2002-05-07 | |
| US60/378,459 | 2002-05-07 | ||
| PCT/US2002/020750 WO2003044138A2 (en) | 2001-06-29 | 2002-06-27 | Lubricant based on a water in oil emulsion with a suspended solid base |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2451683A1 true CA2451683A1 (en) | 2003-05-30 |
Family
ID=27501805
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002451683A Abandoned CA2451683A1 (en) | 2001-06-29 | 2002-06-27 | Lubricant based on a water in oil emulsion with a suspended solid base |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US7651984B2 (enExample) |
| EP (1) | EP1401991A2 (enExample) |
| JP (1) | JP2005509731A (enExample) |
| AU (1) | AU2002357637A1 (enExample) |
| CA (1) | CA2451683A1 (enExample) |
| WO (1) | WO2003044138A2 (enExample) |
Families Citing this family (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2549095C (en) * | 2003-12-12 | 2013-05-21 | The Lubrizol Corporation | Lubricating composition containing metal salixarate as detergent |
| US8618029B2 (en) * | 2003-12-22 | 2013-12-31 | Chevron Oronite S.A. | Overbased detergents for lubricating oil applications |
| SG151328A1 (en) | 2004-03-31 | 2009-04-30 | Lubrizol Corp | High solids content dispersions |
| US7579303B2 (en) * | 2004-07-16 | 2009-08-25 | Exxonmobil Research And Engineering Company | Polar solvent-asphaltene dispersant method for upgrading heavy oils |
| US20060052255A1 (en) * | 2004-09-07 | 2006-03-09 | The Lubrizol Corporation, A Corporation Of The State Of Ohio | Aromatic diblock copolymers for lubricant and concentrate compositions and methods thereof |
| JP5158780B2 (ja) * | 2004-10-06 | 2013-03-06 | ザ ルブリゾル コーポレイション | スルホネートを含有する潤滑組成物 |
| EP1844129A1 (en) * | 2005-01-13 | 2007-10-17 | The Lubrizol Corporation | Emulsion composition |
| US7741257B2 (en) | 2005-03-15 | 2010-06-22 | Ecolab Inc. | Dry lubricant for conveying containers |
| US7745381B2 (en) | 2005-03-15 | 2010-06-29 | Ecolab Inc. | Lubricant for conveying containers |
| WO2007030157A2 (en) * | 2005-05-03 | 2007-03-15 | Southwest Research Institute | Mixed base phenates and sulfonates |
| WO2006119502A2 (en) * | 2005-05-03 | 2006-11-09 | Southwest Research Institute | Lubricant oils and greases containing nanoparticle additives |
| RU2008115110A (ru) * | 2005-09-20 | 2009-10-27 | Зе Лубризол Копэрейшн (Us) | Композиция смазки и способ смазывания двигателя с ее помощью |
| KR20070055386A (ko) * | 2005-11-25 | 2007-05-30 | 인피늄 인터내셔날 리미티드 | 선박용 또는 정치식 디젤 엔진의 작동 방법 |
| US20080153723A1 (en) | 2006-12-20 | 2008-06-26 | Chevron Oronite Company Llc | Diesel cylinder lubricant oil composition |
| US20090156445A1 (en) * | 2007-12-13 | 2009-06-18 | Lam William Y | Lubricant composition suitable for engines fueled by alternate fuels |
| US20130098322A1 (en) * | 2009-11-30 | 2013-04-25 | The Lubrizol Corporation | Methods of Controlling Sulfur Trioxide Levels in Internal Combustion Engines |
| BR112013006087B1 (pt) * | 2010-09-24 | 2019-05-14 | Ecolab Usa Inc. | Métodos para lubrificar a passagem de um recipiente ao longo de um transportador. |
| US9493709B2 (en) | 2011-03-29 | 2016-11-15 | Fuelina Technologies, Llc | Hybrid fuel and method of making the same |
| FR2974111B1 (fr) | 2011-04-14 | 2013-05-10 | Total Raffinage Marketing | Lubrifiant cylindre pour moteur marin deux temps |
| CN103422933A (zh) * | 2012-05-14 | 2013-12-04 | 瓦锡兰瑞士公司 | 用于润滑往复活塞式燃烧发动机的缸中活塞结构的方法和汽缸润滑装置 |
| WO2014033634A2 (en) | 2012-08-29 | 2014-03-06 | Indian Oil Corporation Limited | Lubricant additive and lubricant oil compositions and process of preparing thereof |
| US20150275126A1 (en) * | 2012-09-24 | 2015-10-01 | Exxonmobil Research And Engineering Company | Inverse micellar compositions containing lubricant additives |
| US9873853B2 (en) | 2013-03-11 | 2018-01-23 | Ecolab Usa Inc. | Lubrication of transfer plates using an oil or oil in water emulsions |
| JP6744308B2 (ja) | 2014-12-03 | 2020-08-19 | ドレクセル ユニバーシティ | 天然ガスの状炭化水素液体燃料への直接的な取り込み |
| FR3030570B1 (fr) * | 2014-12-23 | 2018-08-31 | Total Marketing Services | Composition lubrifiante a materiau a changement de phase |
| FR3030569B1 (fr) * | 2014-12-23 | 2018-10-05 | Total Marketing Services | Composition lubrifiante a materiau a changement de phase |
| SG11201707204UA (en) * | 2015-06-09 | 2017-12-28 | Exxonmobil Res & Eng Co | Inverse micellar compositions containing lubricant additives |
| WO2017031058A1 (en) * | 2015-08-17 | 2017-02-23 | Cummins Inc. | Ashless tbn maintenance of lubricant |
| CA2923043A1 (en) * | 2016-03-08 | 2017-09-08 | Cmw 4Th Dimension Enterprises Ltd | Multi purpose additive for combustion engine |
| US11312896B2 (en) * | 2016-10-16 | 2022-04-26 | The Lubrizol Corporation | Acid emulsifier technology for continuous mixed emulsified acid systems |
| AU2018250302A1 (en) * | 2017-04-06 | 2019-11-28 | Wd-40 Company | Non-flammable aerosol multiuse invert emulsion lubricant |
| CN109468155B (zh) * | 2018-10-22 | 2021-07-06 | 南开大学 | 一种油脂基甲醇燃料转子发动机专用润滑油及其制备方法 |
| WO2021247027A1 (en) * | 2020-06-04 | 2021-12-09 | Wd-40 Company | Non-flammable aerosol multiuse invert emulsion lubricant |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL82973C (enExample) * | 1950-12-30 | |||
| US2865857A (en) * | 1955-07-13 | 1958-12-23 | California Research Corp | Acid-neutralizing lubricating oil compositions |
| FR1148216A (fr) * | 1955-10-20 | 1957-12-05 | Socony Mobil Oil Co | Lubrifiant pour moteur diesel marin |
| BE555022A (enExample) * | 1956-02-16 | |||
| US2975132A (en) * | 1956-06-18 | 1961-03-14 | California Research Corp | Emulsifiable lubricant compositions |
| US2944023A (en) * | 1957-01-15 | 1960-07-05 | Socony Mobil Oil Co Inc | Anticorrosive marine diesel lubricant |
| GB868893A (en) * | 1957-11-15 | 1961-05-25 | Taiyo Kako Kabushiki Kaisha | Emulsified lubricating oil of water-in-oil type |
| US3206399A (en) * | 1961-09-29 | 1965-09-14 | Socony Mobil Oil Co Inc | Diesel lubricating oil |
| US3269946A (en) * | 1961-08-30 | 1966-08-30 | Lubrizol Corp | Stable water-in-oil emulsions |
| US3281356A (en) * | 1963-05-17 | 1966-10-25 | Lubrizol Corp | Thermally stable water-in-oil emulsions |
| NL6404814A (enExample) * | 1964-04-29 | 1965-11-01 | ||
| US3378494A (en) * | 1964-08-07 | 1968-04-16 | Shell Oil Co | Water-in-oil emulsion fluids |
| US3342733A (en) * | 1964-10-05 | 1967-09-19 | Exxon Research Engineering Co | Preparation of colloidal carbonates in hydrocarbon media |
| US3981813A (en) * | 1975-05-12 | 1976-09-21 | Standard Oil Company (Indiana) | Hydraulic fluid |
| NZ186808A (en) * | 1977-04-06 | 1979-10-25 | Rocol Ltd | Lubricant composition containing group ii-a metal carbonate and halogenated organic lubricant |
| US4447348A (en) * | 1981-02-25 | 1984-05-08 | The Lubrizol Corporation | Carboxylic solubilizer/surfactant combinations and aqueous compositions containing same |
| US4708753A (en) * | 1985-12-06 | 1987-11-24 | The Lubrizol Corporation | Water-in-oil emulsions |
| SG49890A1 (en) * | 1992-08-22 | 1998-06-15 | Hoechst Ag | Alkenylsuccinic acid derivatives as metal working auxiliaries |
| FR2722117B1 (fr) * | 1994-07-06 | 1996-08-30 | Inst Francais Du Petrole | Hydroxyde de calcium colloidal, sa preparation et ses utilisations |
| SG55446A1 (en) * | 1996-10-29 | 1998-12-21 | Idemitsu Kosan Co | Lube oil compositions for diesel engines |
| JP3530964B2 (ja) * | 1999-02-19 | 2004-05-24 | 泰雄 福谷 | 潤滑液 |
| US6204225B1 (en) * | 1999-12-13 | 2001-03-20 | Midwest Biologicals, Inc. | Water-dispersible metal working fluid |
-
2002
- 2002-06-27 EP EP02792171A patent/EP1401991A2/en not_active Withdrawn
- 2002-06-27 CA CA002451683A patent/CA2451683A1/en not_active Abandoned
- 2002-06-27 US US10/481,486 patent/US7651984B2/en not_active Expired - Lifetime
- 2002-06-27 AU AU2002357637A patent/AU2002357637A1/en not_active Abandoned
- 2002-06-27 JP JP2003545764A patent/JP2005509731A/ja not_active Withdrawn
- 2002-06-27 WO PCT/US2002/020750 patent/WO2003044138A2/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| AU2002357637A1 (en) | 2003-06-10 |
| WO2003044138A3 (en) | 2003-11-06 |
| WO2003044138A2 (en) | 2003-05-30 |
| US7651984B2 (en) | 2010-01-26 |
| EP1401991A2 (en) | 2004-03-31 |
| US20040235684A1 (en) | 2004-11-25 |
| JP2005509731A (ja) | 2005-04-14 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FZDE | Discontinued |