CA2436230A1 - Fabric rinse composition containing a benztriazole uv absorber - Google Patents
Fabric rinse composition containing a benztriazole uv absorber Download PDFInfo
- Publication number
- CA2436230A1 CA2436230A1 CA002436230A CA2436230A CA2436230A1 CA 2436230 A1 CA2436230 A1 CA 2436230A1 CA 002436230 A CA002436230 A CA 002436230A CA 2436230 A CA2436230 A CA 2436230A CA 2436230 A1 CA2436230 A1 CA 2436230A1
- Authority
- CA
- Canada
- Prior art keywords
- formula
- quaternary ammonium
- composition according
- composition
- fabric
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 61
- 239000004744 fabric Substances 0.000 title claims abstract description 38
- 239000006096 absorbing agent Substances 0.000 title claims abstract description 23
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 title description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 10
- 239000001257 hydrogen Substances 0.000 claims abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000002979 fabric softener Substances 0.000 claims abstract description 9
- 229910052736 halogen Inorganic materials 0.000 claims abstract description 6
- 150000002367 halogens Chemical class 0.000 claims abstract description 6
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract description 4
- 239000010452 phosphate Substances 0.000 claims abstract description 4
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims abstract description 3
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims abstract description 3
- JVTAAEKCZFNVCJ-UHFFFAOYSA-M Lactate Chemical compound CC(O)C([O-])=O JVTAAEKCZFNVCJ-UHFFFAOYSA-M 0.000 claims abstract description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims abstract description 3
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims abstract description 3
- 229940095064 tartrate Drugs 0.000 claims abstract description 3
- -1 cationic quaternary ammonium salts Chemical class 0.000 claims description 21
- 238000000034 method Methods 0.000 claims description 13
- 125000000217 alkyl group Chemical group 0.000 claims description 12
- 238000005562 fading Methods 0.000 claims description 11
- 239000004753 textile Substances 0.000 claims description 10
- IPTLKMXBROVJJF-UHFFFAOYSA-N azanium;methyl sulfate Chemical compound N.COS(O)(=O)=O IPTLKMXBROVJJF-UHFFFAOYSA-N 0.000 claims description 8
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims description 8
- 239000003760 tallow Substances 0.000 claims description 8
- 125000003342 alkenyl group Chemical group 0.000 claims description 7
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 7
- 229920000742 Cotton Polymers 0.000 claims description 6
- 239000002671 adjuvant Substances 0.000 claims description 5
- 150000002148 esters Chemical class 0.000 claims description 5
- 239000004615 ingredient Substances 0.000 claims description 5
- 150000001412 amines Chemical class 0.000 claims description 4
- 239000000975 dye Substances 0.000 claims description 4
- 150000002191 fatty alcohols Chemical class 0.000 claims description 4
- 239000006081 fluorescent whitening agent Substances 0.000 claims description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 3
- 150000001735 carboxylic acids Chemical class 0.000 claims description 3
- IYAQFFOKAFGDKE-UHFFFAOYSA-N 4,5-dihydro-1h-imidazol-3-ium;methyl sulfate Chemical compound C1CN=CN1.COS(O)(=O)=O IYAQFFOKAFGDKE-UHFFFAOYSA-N 0.000 claims description 2
- 239000004952 Polyamide Substances 0.000 claims description 2
- 230000000844 anti-bacterial effect Effects 0.000 claims description 2
- 125000004429 atom Chemical group 0.000 claims description 2
- 239000003899 bactericide agent Substances 0.000 claims description 2
- OGBUMNBNEWYMNJ-UHFFFAOYSA-N batilol Chemical class CCCCCCCCCCCCCCCCCCOCC(O)CO OGBUMNBNEWYMNJ-UHFFFAOYSA-N 0.000 claims description 2
- 238000004040 coloring Methods 0.000 claims description 2
- 230000007797 corrosion Effects 0.000 claims description 2
- 238000005260 corrosion Methods 0.000 claims description 2
- FPDLLPXYRWELCU-UHFFFAOYSA-M dimethyl(dioctadecyl)azanium;methyl sulfate Chemical compound COS([O-])(=O)=O.CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC FPDLLPXYRWELCU-UHFFFAOYSA-M 0.000 claims description 2
- PGZPBNJYTNQMAX-UHFFFAOYSA-N dimethylazanium;methyl sulfate Chemical compound C[NH2+]C.COS([O-])(=O)=O PGZPBNJYTNQMAX-UHFFFAOYSA-N 0.000 claims description 2
- 239000003995 emulsifying agent Substances 0.000 claims description 2
- 235000019965 ethoxylated diglyceride Nutrition 0.000 claims description 2
- 235000019964 ethoxylated monoglyceride Nutrition 0.000 claims description 2
- 239000003349 gelling agent Substances 0.000 claims description 2
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims description 2
- 239000003112 inhibitor Substances 0.000 claims description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- 239000002480 mineral oil Substances 0.000 claims description 2
- 239000002736 nonionic surfactant Substances 0.000 claims description 2
- 239000003605 opacifier Substances 0.000 claims description 2
- 239000002304 perfume Substances 0.000 claims description 2
- 229920002647 polyamide Polymers 0.000 claims description 2
- 229920000728 polyester Polymers 0.000 claims description 2
- 229920005862 polyol Polymers 0.000 claims description 2
- 150000003077 polyols Chemical class 0.000 claims description 2
- 150000005846 sugar alcohols Polymers 0.000 claims description 2
- 210000002268 wool Anatomy 0.000 claims description 2
- 150000002431 hydrogen Chemical class 0.000 abstract 3
- 210000003491 skin Anatomy 0.000 description 15
- 150000001875 compounds Chemical class 0.000 description 11
- 238000009472 formulation Methods 0.000 description 8
- 230000005855 radiation Effects 0.000 description 7
- 229910052799 carbon Inorganic materials 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 150000003254 radicals Chemical class 0.000 description 5
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical class OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 4
- 101000912181 Arabidopsis thaliana Cysteine synthase, mitochondrial Proteins 0.000 description 4
- 125000000753 cycloalkyl group Chemical group 0.000 description 4
- 125000001453 quaternary ammonium group Chemical group 0.000 description 4
- 235000021355 Stearic acid Nutrition 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 230000006378 damage Effects 0.000 description 3
- 239000003599 detergent Substances 0.000 description 3
- 239000002657 fibrous material Substances 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 3
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 3
- 239000008117 stearic acid Substances 0.000 description 3
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical group [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 2
- CCPHAMSKHBDMDS-UHFFFAOYSA-N Chetoseminudin B Natural products C=1NC2=CC=CC=C2C=1CC1(SC)NC(=O)C(CO)(SC)N(C)C1=O CCPHAMSKHBDMDS-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- 206010042496 Sunburn Diseases 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 150000004820 halides Chemical class 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 description 2
- 230000005764 inhibitory process Effects 0.000 description 2
- 230000002452 interceptive effect Effects 0.000 description 2
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 2
- 239000000600 sorbitol Substances 0.000 description 2
- 239000008399 tap water Substances 0.000 description 2
- 235000020679 tap water Nutrition 0.000 description 2
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- 206010015150 Erythema Diseases 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 206010040799 Skin atrophy Diseases 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical group CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 description 1
- 101100073357 Streptomyces halstedii sch2 gene Proteins 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 238000004737 colorimetric analysis Methods 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000000254 damaging effect Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 description 1
- 239000004664 distearyldimethylammonium chloride (DHTDMAC) Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 210000002615 epidermis Anatomy 0.000 description 1
- 231100000321 erythema Toxicity 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 229960002479 isosorbide Drugs 0.000 description 1
- 238000004900 laundering Methods 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 150000002826 nitrites Chemical class 0.000 description 1
- 231100000760 phototoxic Toxicity 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 230000037307 sensitive skin Effects 0.000 description 1
- 230000037380 skin damage Effects 0.000 description 1
- 235000010344 sodium nitrate Nutrition 0.000 description 1
- 239000004317 sodium nitrate Substances 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 230000037072 sun protection Effects 0.000 description 1
- 239000000516 sunscreening agent Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000004758 synthetic textile Substances 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
- C11D3/42—Brightening agents ; Blueing agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/001—Softening compositions
- C11D3/0015—Softening compositions liquid
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP01810310.1 | 2001-03-27 | ||
| EP01810310 | 2001-03-27 | ||
| PCT/EP2002/003009 WO2002077148A1 (en) | 2001-03-27 | 2002-03-19 | Fabric rinse composition containing a benztriazole uv absorber |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2436230A1 true CA2436230A1 (en) | 2002-10-03 |
Family
ID=8183825
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002436230A Abandoned CA2436230A1 (en) | 2001-03-27 | 2002-03-19 | Fabric rinse composition containing a benztriazole uv absorber |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US7105479B2 (enExample) |
| EP (1) | EP1373454B1 (enExample) |
| JP (1) | JP4233874B2 (enExample) |
| KR (1) | KR20030085578A (enExample) |
| CN (1) | CN1246436C (enExample) |
| AT (1) | ATE279503T1 (enExample) |
| AU (1) | AU2002254958B2 (enExample) |
| BR (1) | BR0208428A (enExample) |
| CA (1) | CA2436230A1 (enExample) |
| DE (1) | DE60201589T2 (enExample) |
| ES (1) | ES2229131T3 (enExample) |
| MX (1) | MXPA03007599A (enExample) |
| WO (1) | WO2002077148A1 (enExample) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4550816B2 (ja) * | 2003-07-08 | 2010-09-22 | カール・ジェイ・シェイドラー | 織物および皮革の光退色抵抗性および防汚性を改良するための方法および組成物 |
| US7824566B2 (en) * | 2003-07-08 | 2010-11-02 | Scheidler Karl J | Methods and compositions for improving light-fade resistance and soil repellency of textiles and leathers |
| DE602006020839D1 (de) * | 2005-02-02 | 2011-05-05 | Basf Se | Langwellige verschobene benzotriazol-uv-absorber und deren verwendung |
| JP4838350B2 (ja) * | 2006-05-08 | 2011-12-14 | イーコラブ インコーポレイティド | 金属表面用酸性洗浄剤 |
| JP2009096972A (ja) | 2007-02-20 | 2009-05-07 | Fujifilm Corp | 紫外線吸収剤を含む高分子材料 |
| WO2008123504A1 (ja) | 2007-03-30 | 2008-10-16 | Fujifilm Corporation | 紫外線吸収剤組成物 |
| EP2177524A4 (en) | 2007-08-16 | 2011-12-14 | Fujifilm Corp | HETEROCYCLIC COMPOUND, ULTRAVIOLET RADIATION ABSORBER, AND COMPOSITION COMPRISING THE ULTRAVIOLET RADIATION ABSORBER |
| JP5244437B2 (ja) | 2008-03-31 | 2013-07-24 | 富士フイルム株式会社 | 紫外線吸収剤組成物 |
| JP5250289B2 (ja) | 2008-03-31 | 2013-07-31 | 富士フイルム株式会社 | 紫外線吸収剤組成物 |
| JP2009270062A (ja) | 2008-05-09 | 2009-11-19 | Fujifilm Corp | 紫外線吸収剤組成物 |
| CN104631110B (zh) * | 2013-08-15 | 2018-03-16 | 东丽纤维研究所（中国）有限公司 | 一种防紫外纺织品 |
| TWI530555B (zh) | 2014-09-02 | 2016-04-21 | 臺灣永光化學工業股份有限公司 | 柔軟劑組成物 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH497919A (de) * | 1961-06-16 | 1970-10-31 | Geigy Ag J R | Verwendung von substituierten 2-(2'-Hydroxyphenyl)-benztriazolverbindungen als Lichtschutzmittel |
| NL279768A (enExample) * | 1961-06-16 | |||
| JPS50121178A (enExample) * | 1974-03-12 | 1975-09-22 | ||
| JP2584622B2 (ja) * | 1986-12-25 | 1997-02-26 | ライオン株式会社 | 柔軟剤組成物 |
| DE3850780T2 (de) * | 1987-10-21 | 1994-10-27 | Allied Signal Inc | Sulfonierte 2-(2'-hydroxyaryl)-2-h-benzotriazole und/oder sulfonierte aromatische formaldehydkondensate und ihre verwendung, um fleckenwiderstandsfähigkeit und farbenlichtechtheit zu verbessern. |
| US5081258A (en) * | 1988-05-19 | 1992-01-14 | E. I. Du Pont De Nemours And Company | Bisbenzotriazoleureas as UV stabilizers for polymers |
| EP0657577A1 (de) | 1993-12-06 | 1995-06-14 | Ciba-Geigy Ag | Verfahren zur photochemischen und thermischen Stabilisierung von ungefärbten und gefärbten oder bedruckten Polyesterfasermaterialien |
| GB9326358D0 (en) * | 1993-12-23 | 1994-02-23 | Ciba Geigy Ag | Compositions for the treatment of textiles |
| GB2291658B (en) * | 1994-07-23 | 1998-08-12 | Ciba Geigy Ag | Aqueous textile treatment compositions containing an ultra-violet absorbing agent |
| US5474691A (en) * | 1994-07-26 | 1995-12-12 | The Procter & Gamble Company | Dryer-added fabric treatment article of manufacture containing antioxidant and sunscreen compounds for sun fade protection of fabrics |
| AU1041700A (en) | 1998-11-02 | 2000-05-22 | Ciba Specialty Chemicals Holding Inc. | Stabilization of body-care and household products |
-
2002
- 2002-03-19 MX MXPA03007599A patent/MXPA03007599A/es unknown
- 2002-03-19 JP JP2002576591A patent/JP4233874B2/ja not_active Expired - Fee Related
- 2002-03-19 AU AU2002254958A patent/AU2002254958B2/en not_active Ceased
- 2002-03-19 ES ES02724246T patent/ES2229131T3/es not_active Expired - Lifetime
- 2002-03-19 WO PCT/EP2002/003009 patent/WO2002077148A1/en not_active Ceased
- 2002-03-19 BR BR0208428-7A patent/BR0208428A/pt not_active Application Discontinuation
- 2002-03-19 KR KR10-2003-7012585A patent/KR20030085578A/ko not_active Withdrawn
- 2002-03-19 CN CNB02807209XA patent/CN1246436C/zh not_active Expired - Fee Related
- 2002-03-19 AT AT02724246T patent/ATE279503T1/de not_active IP Right Cessation
- 2002-03-19 DE DE60201589T patent/DE60201589T2/de not_active Expired - Lifetime
- 2002-03-19 CA CA002436230A patent/CA2436230A1/en not_active Abandoned
- 2002-03-19 US US10/472,791 patent/US7105479B2/en not_active Expired - Fee Related
- 2002-03-19 EP EP02724246A patent/EP1373454B1/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| CN1246436C (zh) | 2006-03-22 |
| CN1500138A (zh) | 2004-05-26 |
| BR0208428A (pt) | 2004-03-30 |
| MXPA03007599A (es) | 2003-12-04 |
| WO2002077148A1 (en) | 2002-10-03 |
| ATE279503T1 (de) | 2004-10-15 |
| US7105479B2 (en) | 2006-09-12 |
| JP2004525273A (ja) | 2004-08-19 |
| US20040111805A1 (en) | 2004-06-17 |
| EP1373454B1 (en) | 2004-10-13 |
| EP1373454A1 (en) | 2004-01-02 |
| DE60201589D1 (de) | 2004-11-18 |
| AU2002254958B2 (en) | 2006-01-12 |
| KR20030085578A (ko) | 2003-11-05 |
| DE60201589T2 (de) | 2006-03-09 |
| ES2229131T3 (es) | 2005-04-16 |
| JP4233874B2 (ja) | 2009-03-04 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FZDE | Discontinued |