CA2291769A1 - Oxydation perfectionnee en phase vapeur de propylene en acroleine - Google Patents

Oxydation perfectionnee en phase vapeur de propylene en acroleine Download PDF

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Publication number
CA2291769A1
CA2291769A1 CA002291769A CA2291769A CA2291769A1 CA 2291769 A1 CA2291769 A1 CA 2291769A1 CA 002291769 A CA002291769 A CA 002291769A CA 2291769 A CA2291769 A CA 2291769A CA 2291769 A1 CA2291769 A1 CA 2291769A1
Authority
CA
Canada
Prior art keywords
solids
propylene
reactor
gas
mol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA002291769A
Other languages
English (en)
Inventor
Daniel Campos
Mark William Andersen
Gerard Hecquet
Roland Kotwica
Rashmikant Maganlal Contractor
Michel Simon
Charlotte Pham
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Arkema France SA
EIDP Inc
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of CA2291769A1 publication Critical patent/CA2291769A1/fr
Abandoned legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90—Regeneration or reactivation
    • B01J23/94—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the iron group metals or copper
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/28—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of CHx-moieties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/005—Separating solid material from the gas/liquid stream
    • B01J8/0055—Separating solid material from the gas/liquid stream using cyclones
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/1845—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with particles moving upwards while fluidised
    • B01J8/1863—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with particles moving upwards while fluidised followed by a downward movement outside the reactor and subsequently re-entering it
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/24—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
    • B01J8/26—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique with two or more fluidised beds, e.g. reactor and regeneration installations
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)

Abstract

L'invention concerne un procédé perfectionné d'oxydation sélective, en phase vapeur, de propylène en acroléine, dans un système de réacteur à recirculation de solides, mettant en oeuvre un oxyde multimétallique de molybdate de bismuth et impliquant des teneurs spécifiques en réactifs (de préférence 5 à 30 moles % de propylène, 0 à 20 moles % d'oxygène, la balance étant composée d'un gaz inerte), une dimension de particules comprise entre 1 et 300 micromètres, une température de l'ordre de 250 à 450 ·C et des temps de séjour de 1 à 15 secondes pour le gaz et de 2 à 60 secondes pour les solides. Un tel procédé permet d'obtenir une meilleure sélectivité et une conversion perfectionnée du propylène.
CA002291769A 1997-07-15 1998-07-14 Oxydation perfectionnee en phase vapeur de propylene en acroleine Abandoned CA2291769A1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US5569397P 1997-07-15 1997-07-15
US60/055,693 1997-07-15
PCT/US1998/014511 WO1999003809A1 (fr) 1997-07-15 1998-07-14 Oxydation perfectionnee en phase vapeur de propylene en acroleine

Publications (1)

Publication Number Publication Date
CA2291769A1 true CA2291769A1 (fr) 1999-01-28

Family

ID=21999559

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002291769A Abandoned CA2291769A1 (fr) 1997-07-15 1998-07-14 Oxydation perfectionnee en phase vapeur de propylene en acroleine

Country Status (12)

Country Link
EP (1) EP0998440A1 (fr)
JP (1) JP2000513384A (fr)
KR (1) KR20010021832A (fr)
CN (1) CN1263519A (fr)
AR (1) AR013221A1 (fr)
AU (1) AU8400798A (fr)
BR (1) BR9810715A (fr)
CA (1) CA2291769A1 (fr)
ID (1) ID24324A (fr)
TW (1) TW477786B (fr)
WO (1) WO1999003809A1 (fr)
ZA (1) ZA986280B (fr)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6281384B1 (en) * 1998-06-26 2001-08-28 E. I. Du Pont Nemours And Company Vapor phase catalytic oxidation of propylene to acrylic acid
FR2782512B1 (fr) * 1998-08-21 2000-09-15 Atochem Elf Sa Procede de fabrication d'acroleine a partir du propylene par reaction redox et utilisation d'une composition solide d'oxydes mixtes comme systeme redox dans la dite reaction
FR2782513B1 (fr) * 1998-08-21 2000-09-15 Atochem Elf Sa Procede de fabrication de methacroleine a partir d'isobutene par reaction redox et utilisation d'une composition solide d'oxydes mixtes comme systeme redox dans ladite reaction
WO2001004079A1 (fr) * 1999-07-09 2001-01-18 E.I. Du Pont De Nemours And Company Oxydation catalytique en phase vapeur de propylene produisant de l'acide acrylique
US7102050B1 (en) * 2000-05-04 2006-09-05 Exxonmobil Chemical Patents Inc. Multiple riser reactor
FR2821840B1 (fr) 2001-03-07 2004-07-16 Atofina Procede de fabrication d'acide acrylique a partir de propane, en l'absence d'oxygene moleculaire
MXPA04012278A (es) 2002-12-23 2005-02-25 Du Pont Proceso de fibra bicomponente de poli(tereftalato de trimetileno).
JP2005314314A (ja) 2004-04-30 2005-11-10 Mitsubishi Chemicals Corp （メタ）アクリル酸または（メタ）アクロレインの製造方法
US7785507B2 (en) 2004-04-30 2010-08-31 E. I. Du Pont De Nemours And Company Spinning poly(trimethylene terephthalate) yarns
US20060041039A1 (en) 2004-08-20 2006-02-23 Gyorgyi Fenyvesi Fluorescent poly(alkylene terephthalate) compositions
FR2880346B1 (fr) * 2004-12-30 2007-02-23 Arkema Sa Procede de preparation d'acide acrylique a partir du propane en absence de vapeur d'eau
FR2897058B1 (fr) * 2006-02-07 2008-04-18 Arkema Sa Procede de preparation d'acroleine
FR2920767B1 (fr) 2007-09-06 2009-12-18 Arkema France Procede de vaporisation reactive de glycerol
DE102008051738A1 (de) 2008-10-15 2010-04-22 Trevira Gmbh PTT-Faser mit verbesserter Einkräuselung
US10479759B2 (en) 2017-02-08 2019-11-19 Clariant Corporation Synthetic methods for the preparation of propylene ammoxidation catalysts
US10479760B2 (en) 2017-02-08 2019-11-19 Clariant Corporation Synthetic methods for the preparation of propylene ammoxidation catalysts

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4341717A (en) * 1973-03-08 1982-07-27 The Standard Oil Company Reactor for contacting gases and a particulate solid
JPS56113726A (en) * 1980-02-08 1981-09-07 Standard Oil Co Manufacture of aldehyde and carboxylic acid
JPS6133234A (ja) * 1984-07-23 1986-02-17 Mitsubishi Petrochem Co Ltd 触媒の再生法
US4659689A (en) * 1986-03-05 1987-04-21 The Standard Oil Company Method of preparation of high active phase (AMM)oxidation catalysts with improved performance and attrition resistance
DE4436385A1 (de) * 1994-10-12 1996-04-18 Basf Ag Verfahren zur katalytischen oxidativen Dehydrierung von Alkylaromaten und Paraffinen

Also Published As

Publication number Publication date
AU8400798A (en) 1999-02-10
JP2000513384A (ja) 2000-10-10
CN1263519A (zh) 2000-08-16
AR013221A1 (es) 2000-12-13
ID24324A (id) 2000-07-13
KR20010021832A (ko) 2001-03-15
TW477786B (en) 2002-03-01
WO1999003809A1 (fr) 1999-01-28
ZA986280B (en) 2000-01-17
BR9810715A (pt) 2000-08-08
EP0998440A1 (fr) 2000-05-10

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