CA2270260C - Apparatus for gas-dynamic coating - Google Patents

Apparatus for gas-dynamic coating Download PDF

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Publication number
CA2270260C
CA2270260C CA002270260A CA2270260A CA2270260C CA 2270260 C CA2270260 C CA 2270260C CA 002270260 A CA002270260 A CA 002270260A CA 2270260 A CA2270260 A CA 2270260A CA 2270260 C CA2270260 C CA 2270260C
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Prior art keywords
powder
supersonic
nozzle
supersonic nozzle
gas
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CA002270260A
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French (fr)
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CA2270260A1 (en
Inventor
Alexandr Ivanovich Kashirin
Oleg Fedorovich Kljuev
Timur Valerievich Buzdygar
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Ooo Obninsky Tsentr Poroshkovogo Napylenia
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Ooo Obninsky Tsentr Poroshkovogo Napylenia
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C24/00Coating starting from inorganic powder
    • C23C24/08Coating starting from inorganic powder by application of heat or pressure and heat
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B7/00Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
    • B05B7/14Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas designed for spraying particulate materials
    • B05B7/1404Arrangements for supplying particulate material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B7/00Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
    • B05B7/16Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas incorporating means for heating or cooling the material to be sprayed
    • B05B7/1606Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas incorporating means for heating or cooling the material to be sprayed the spraying of the material involving the use of an atomising fluid, e.g. air
    • B05B7/1613Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas incorporating means for heating or cooling the material to be sprayed the spraying of the material involving the use of an atomising fluid, e.g. air comprising means for heating the atomising fluid before mixing with the material to be sprayed
    • B05B7/162Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas incorporating means for heating or cooling the material to be sprayed the spraying of the material involving the use of an atomising fluid, e.g. air comprising means for heating the atomising fluid before mixing with the material to be sprayed and heat being transferred from the atomising fluid to the material to be sprayed
    • B05B7/1626Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas incorporating means for heating or cooling the material to be sprayed the spraying of the material involving the use of an atomising fluid, e.g. air comprising means for heating the atomising fluid before mixing with the material to be sprayed and heat being transferred from the atomising fluid to the material to be sprayed at the moment of mixing
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C24/00Coating starting from inorganic powder
    • C23C24/02Coating starting from inorganic powder by application of pressure only
    • C23C24/04Impact or kinetic deposition of particles
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/12Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the method of spraying

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Nozzles (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

The apparatus is comprised of a compressed air source which is connected by a gas conduit to a heating unit whose outlet is connected to a supersonic nozzle inlet in which a supersonic portion is connected by a conduit to a powder feeder. Compressed air of pressure P0 from the compressed air source by the gas conduit is delivered to the heating unit to be heated to the required temperature. The heated air enters the supersonic nozzle in which it is accelerated to a speed of several hundred meters per second. The powdered material is passed from the powder feeder by the powder feeding conduit to the supersonic nozzle portion in which it is accelerated by the air flow at section of the nozzle from the injection point to the nozzle outlet.

Description

APPARATUS FOR GAS-DYNAMIC COATING
FIELD OF THE INVENTION
The present invention relates to appa~at=~s for gas-dynamic spraying of powder materials, and in particular to apparatus for use in machine building and ether industries for producing coatings imparting different properties ~:c the surfaces being worked.
BACKGROUND OF THE INVENTTON
Protection of structures, equipment, mach.in.ery and mechanisms from corrosion and the effec~t.s r~~f corros:i.ve media, enhancing the characteristics of materials and, in particular, production of materials with specif.i.e~~ properties and development of relevant resour~::r~-sav.~r~g t:echnologie s present scientific and engineer~.n~~ chala..engf>s whi.ch have major practical significance.
These problems are solved by cli:~ ferer~t. r~~~thods, among them methods of gas-dynamic spr~ayir~.c~ c~~ pc,mrc:~er coatings ~~ahich are based on a powder. ma tex'i.a:~. bei.rnc~ in j Eec°. tee'; iru a gaa *low, and the resulting gas-powder m:lx~:~arc=. for c::c,>~~tiry being ,:acc:elerated to a supersonic :~pea.d. :~uc~h. ~wt~eods ~::ar a shown, for example, in patent documents R.U ~.61~ 732, F~i.J 1.~1~3'a'v8. Tc> ins:reasm t:he 2S powder utilization f'act~:~r.~ anc~ t:.he ~~u;;r~.~.t:y of spraying, prior to feeding the supersonic rno~z::L~~ f~:h~: cJa:;-pawde:r mix:-ure is heated to a tempearature lrowe.r t:.r:ar~. t::~~~~ rne~lt.ing tempf~>rature of the powder material:>, as c~is:.::lc~;ed f:c~r E:x.ample in p<~tent documents RU 177?~07~'., I~0 ~~1/:1~~07.6, Rl~ ~0:~t411.

For implementation of these rr~e~tuod:~, the known dev~.ces comprise a source of compressed gas, a gas heating unit, a powder feeder connected witYr either a gas heating unit inlet, as in RU 1603581, or a mix:i_r~c~ chamber no,~nted in front of the supersonic nozzle, as d:isc:Losed for exarnpl.e ir. ~~U 1674585, WO
91/19016, RU 2010619.
In the first case, the powder material contacts heat-generating elements of the rveata.ry un:~.t ~~e.sulting in oxidation of powder material particLe.~ and trie:L ~~ s :~i~::king to the element.
In the second case, the powd.e;r kr~ater::L~::rl ~:3c~es not pass through a gas heating un_Lt but, as i.n the f.i.:r:>t cease, has to pass through the narrowest portion c~~= the muzzle (known as the throat) , which is particu:iar:c.y subject t.cwear from powder material, especial~_tr when ab~ras.v~~ pouade~~s are used, such as metals, or ceramic particles. I t i.;~ t.v.he throat whip..~.h primarily determines th~~= supersonic rma~°z.e operatio:ru and efficiency of the device ~.n general.
In such apparatus, t:he supersor~uc a::Lx~ t:l.c:~w is highly critical tc structural flow distarban~~e, resu'~t:~.nc~ in the risk of a decrease in tree particle vel;.oc.ity, anc~ hence a redu~:aion in the effectiveness of the c;oal-. irae~ p.ro~:.ess . Thus, pri~:~r art gas-dynamic devices haVE'. prov_~.ded fc:~r th~~ ~ir~ j ection means to be upstream of the throat of t~h~.~ m.~per:~c~r~~.c: nozzle, rec:~ui.ring the use of a special mixing chamber, whrcYn. is typically a separate component. Further, as the powder feeder is required to be
2 hermetically sealed and to ~::~c:e o~,~eratoc~~i under ruigh pressure, it would have a considerable weigrut.
Locating the mixing chamber between. the heating unit and the S supersonic nozzle a.Lso :Lead: tc;~ add~.t i.on~:L heat l.o:~s, which means consumption o:f mc7:re pc~jwe.i: ~°«r.° heat:i.nc~ the aix: and maintaining a prescribed temperature at =rhe supersonic nozzle heat.
This results in increased r:a.sk during op~~r_ation of the device, as in the event of a loss ow integrity o~ the hermetic seal of the powder feeder, t:he powd~-~r wi.l:1 b~~ em;_tt.ed under high pressure.
The use of flame heating in suc~r deviates creates a further risk, particularly where the. pa:G~t ic~.e:~ ~~_~:w fed through a flame, with the ~oonsequent ri°~~k~-. of f Lre and of emission of hazardous combustion products.
SUMMARY OF THE INVENTIC)N
The invention ther.efor_e seeks tc:~ pro;r:~.de an apparatus for gas-dynamie coating of powder mater:~als, cromprising:
( i ) a supply means ,:~dapt:.ec~ t:cr ~;~.~.p~~l.y ~:yam):eressed ai:r to a non-combustic>n heating ~,znit;
(~~i) a supersonic nozzle directly connected to the heating unit, and having in sequence an inlet potion, a throat and an outlet port:i.on; and (iii) a powder feeder means adapted tc:> sr~pply powder into the supersonic nozzle thrcugh a conduit a~ a juncture location downstream of the throat Ec~r a~:zc:elerr:~=::inc:,r powder wit~h.Ln the supersonic nozzle for dispex s~~l thrcaugl; l~he~ outlet portion and application i.n a bloating process to a wo~~kpiece adjacent to the outlet portion of the st.~personi.c nozzle.
The invention further seeks to provide a method of gas-dynamic coating of a powder materia::. on a substrate, comprising the steps of:
(i) heating a compressed nix stream t~~ a t:ernperature below the melting point of the powder material (ii) passing the heated compressed ai_r: st:.ream through a superson3_c nozzle t~: inc:reae>c~ t.~Y~.e~ ve:lr3~~it;.y of the air stream to a supersonic ;spend;
(~ ii) injecting the' powder mate.~~iaa. :..rutc:~ the air stz=eam having a supersc>nic speed far. ac~c~eler.~at::ian t:3uexw~by within t:he supersonic nozzle; and (i.v) directing the accelerated powder ma.t:erial upon the substrate while maintaining ;,~he powde:r material. at a temperature below i_t s mel ~_ i.ng ~ac~int .
Tr~e apparatus of the invention is des:~.gned to enhance the stability of operation of the nozzle assembly and prolong its service life, reduce power consumption fc:r maintain:i.ng the air temperature at the supersonics: rxazzle ir~~let, increass~
operational safety and avoid tune use c; f: combustion, and reduce apparatus weight.
The invention thus provides <:~n a.ppar_at::us fa:r spraying of powdered material, c:ompri.:~ed of ~:~ heat ing unit for c:,:ompressed air, a powder feeder and a s;..zpex~ s~~cz:i_c; ~:;c~zz:lk~, by c;ora.necti.ng the outlet of the campressed air heating unit to the supersonic nozzle inlet whic.:h is c.:arlrr~ec:ted, irr its supersonic portion, through r3 c~.onduit t: c> tue ~:<>w~~e ~ lveeder out let .
This construction for ~>pray caat~ng, as ~acampared with known devices, makes it possible to increase tixe apera.tianal stability of the apparatus due to lacy of nozzle throat wear, This is achieved as the. powder daes n:~t ~aass through 'the throat arid therefore dc;~es nc;~t i.~~eiuc:e ~we~:rr°, does not clzanqe its characteristics and hence does ancst. of fe<~t:: th.e performance of the nozzle assembly and the apparatus a , ~ whole, whi:Le not adversely affecting the sape:rsanic air fl..aw.
When using powders of sa.lid rcretals ar ceramics, wear of the nozzle walls occurs only in t:tie ::uper~.~orla.c~ portion of the nozzle and does not: invo.l.~~e the n::~zz:.E~ t:huroat. As tare performance of the :~upex~sonicw nc~z:~l~~ .; ire par.ti~~ular the air flow, Mach number, etc. ) is deterrn.iner~~ pz: imarily by the throat area, wear of only the supersonic pardon of the nowzle results in reduced deterioratioru in aperational can: it:ions of trxe nozzle, compared with when t~E'rv; pc.~wder ~~.s injected to the chamber in front (~_.e. upst.rearn,'f ~~f t:he ro.ozzle or t~:~ t:he subsonic portian of the nozzLFe, the:~e>;::>~,~ ensuring <~ :i_onger service life of the nozzle.
Ir. this case, a mixing chamber is not. rnecessary, which simplifies t:he design and re~d~.:Ec~.,:~ tkm=, ~~pparatus ~aeir.~ht:, while connection of the hesating un:i.t 1:o thc~ rrc~~:.zle inlet substantially eliminates )neat: loss ~:rr the mixing cah~~mber.
s Coupling of the powder feedc.~~ un:it witch :he supersonic portion of the nozzle permits rriaint~~v.r-~.irac~ c-;f~ a l,:~wEa:r pressure in the powder feeder than that. at 1::.~:ce rv:~z~ ~.e ~_n Let, as the pressure is alway:~ lower in the :~upe.c:c:m.:i..c~ pc>r~ ior~ of a.ny Laval (supersonic) nozzle than in t::he :>ukasoni.~~ one. This results in the reduction of powder feeder weight anc~ an increase in operational safety.
The design of the apparatus also enables the use of atmospheric, rat;ner than ~~ompre.ssed, air for transporting the powder from the powder feeder tc~s the Anozzle. This reduces the apparatus weight and increases operation~~l safety even more, because i.n this case it is r~c~*~ r~.ec:e.s,~awy that the powder feeder be hermet:ical_ly sea~l.ed. ~'c~>r t.:rl:~_s ~:>urpose, at the point of powder inject-Lon into ~he~ ~,n:~rzle a pressure below atmospheric should be ma:intairuec~ to p~,~oT~r:idE~ powder transport by the atmospheric ~~ir. flow.
In order for the powder to be e.ffecta_arely transported by atmospheric air, the cross-sectional areas ef the supersonic nozzle at the juncture of the nozzle and the powder-feeder conduit should be related to tine throat area according to the following relation:
S~/SK > 1.3P'. + 0.8 where Si is the cross-sec.~tiorv~al. area a~ the supersonic nuzzle at. th.e jl.zncvurt~~ c:af t:r-~re r;oL zle anc~ 'she powder feeder cor~duiC;
Sx is the :>upersonic nort.~.e thr.~at: area; and P_, is the full gas pressure at the superscxnic nozzle inlet, expressed in Mpa.

BRIEF DESCRIPTION GF THE DRAWTNC
The advantages of the present. invention are evident. from the detailed description of the emboc~i.rr~ent. aw°~c~ the f.oll.owing drawing, Figure 1, which is s~ schematic representation of the apparatus of the :i.n~fent:.iora .
Referring to Figure 1, the apparatus 12 is comprised of a compressed air source 1 which is connected by a gas conduit 2 with a heating unit 3, whose outlet end :L3 a.s connewted to an inlet 9 of a supersonic nc>~~z;.l.a ~~~., i.n ~h:ic::h a supersonic portion 5 downstream of a trax~~,aar.: 8 i.:~ c:c~u°znected by a ~zonduit 6 from a powder f_eecler ? .
In operation, compressed air of pressure Po from the compressed air source 1 is de~.i:aere~d to the heating unit 3 by gas conduit 2 to be heated to the req~.~i r~~d temperature. The heated air enter; the supc~rs.:>r;::~..~::: rio:?;~l.e ~~ irl which ~~t is accelerated to a speed c5f ~,evrer~zl hun:c::~rec:~ meters per second.
The powder material (not shown'! is pa:~asec~ from the powder feeder 7 by the coro~uit 6 to tam supE~r.~sorxic. nozzle _cortion 5 of the nozzle 4, in which it i;a p.ickec~ up by the air flow and accelerated within the nozzle ~ between an injectio;~ point 10 and a nozzle outlet 11 . At tnr~ z n jec:r.~.can point 10 true static pressure is maint:ai.rved below t~~:rr~osptm~r ~.c: pr:essurEe, ~=an~~uring that the air with the powder i;s ~~t f~:~:.t::ively drawn im from the powder feeder 7.

In operation, the nozzle outlet 11 is positioned ate an appropriate distance from the workpiece (not shawn~ or other material to be coated.
At the injection paint 10, the pressure :::an be maintained below atmospheric pressure :i..t t.~ie cr::;;~s-.:~PC:tional area of the supersonic nozzle 4 in the ~~~upe~::>on~..::; parte~.an 5 is made t:o exceed that of the thrc>at 1.~~,w :~ ~=~u.i table ,nr~ltiplier. Numerous experiments and calc:.ulatians !~a~~e sh~~~~rn r~hat for efficient operation of the apparatus 12, true cross--sectional area of the supersonic nozzle 4 at its j uncaL~:ee with the powder feeder conduit 6 should be related to the throas~ area by the equation Si/Sk > 1.3P~., + C). C'i where S; is the cross-sectional area of the supersonic nozzle 4 ~t the injection pr:~i.nt;. LO;
SE, is the area of t~t~e :~up~:~w.«nic nozzle throat 8;
and P,: is the ful_C gas ~.~re;7sure at the supersonic nozzle inlet ~~, expressed in ~E?a, Trois design ensures that t~-derE:~ ~.s no ~.~xcw:E:~ssive pressure (above atmospherics in the powder feeder 7, wr~i~.h, in turn, Enhances tree safety of the powder feeder operatioru and simplifies maintenance thereof.
The apparatus 12 of the inventian can be used for the application of powder materials to pr~~duct surfaces to achieve different properties, such as ca.rrosic-~n resa.stance, heat resistance, radiati.c>n praperti.e~ c:~f t.ri.e surface, ett.~. The apparatus 12 can also be us~:7c:~ fc:~:rv c.~~:p~,si ~:.in~ dec:or~~tive coatings.

Claims (4)

Claims
1. An apparatus for gas-dynamic coating of powder materials, comprising:

(i) a supply means adapted to supply compressed air to a non-combustion heating unit;

(ii) a supersonic nozzle directly connected to the heating unit, and having in sequence an inlet portion, a throat and an outlet portion; and (ii) a powder feeder means adapted to supply powder into the supersonic nozzle through a conduit at a juncture location downstream of the throat for accelerating powder within the supersonic nozzle for dispersal through the outlet portion and application in a coating process to a workpiece adjacent to the outlet portion of the supersonic nozzle.
2. A gas-dynamic coating apparatus as claimed in claim 1, wherein a hermetic seal is not provided for the powder feeder means.
3. A gas-dynamic coating apparatus as claimed in claim 2, wherein a ratio between a cross-sectional area of the supersonic nozzle at the juncture location and at the throat is defined by the equation S i /S k >= 1.3P0 + 0.8 wherein S i is the cross-sectional area at the juncture location;
S k is the cross-sectional area at the throat; and P o is the full gas pressure at the inlet end of the supersonic nozzle, expressed in MPa.
4. A method of gas-dynamic coating of a powder material on a substrate, comprising the steps of:

(i) heating a compressed air stream to a temperature below the melting point of the powder material;

(ii) passing the heated compressed air stream through a supersonic nozzle to increase the velocity of the air stream to a supersonic speed;

(vii) injecting the powder material into the air stream having a supersonic speed for acceleration hereby within the supersonic nozzle; and (iv) directing the accelerated powder material upon the substrate while maintaining the powder material at a temperature below its melting point.
CA002270260A 1996-11-13 1997-10-27 Apparatus for gas-dynamic coating Expired - Fee Related CA2270260C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
RU96121833 1996-11-13
RU9696121833A RU2100474C1 (en) 1996-11-18 1996-11-18 Apparatus for gasodynamically applying coatings of powdered materials
PCT/RU1997/000332 WO1998022639A1 (en) 1996-11-13 1997-10-27 Apparatus for gas-dynamic coating

Publications (2)

Publication Number Publication Date
CA2270260A1 CA2270260A1 (en) 1998-05-28
CA2270260C true CA2270260C (en) 2004-01-06

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Country Link
US (1) US6402050B1 (en)
EP (1) EP0951583B1 (en)
KR (1) KR100387386B1 (en)
CN (1) CN1137003C (en)
CA (1) CA2270260C (en)
DE (1) DE69718514T2 (en)
HK (1) HK1023792A1 (en)
RU (1) RU2100474C1 (en)
WO (1) WO1998022639A1 (en)

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CN1235648A (en) 1999-11-17
CA2270260A1 (en) 1998-05-28
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CN1137003C (en) 2004-02-04
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