CA2254069A1 - Detergent compositions comprising a combination of .alpha.-amylases for malodor stripping - Google Patents
Detergent compositions comprising a combination of .alpha.-amylases for malodor stripping Download PDFInfo
- Publication number
- CA2254069A1 CA2254069A1 CA002254069A CA2254069A CA2254069A1 CA 2254069 A1 CA2254069 A1 CA 2254069A1 CA 002254069 A CA002254069 A CA 002254069A CA 2254069 A CA2254069 A CA 2254069A CA 2254069 A1 CA2254069 A1 CA 2254069A1
- Authority
- CA
- Canada
- Prior art keywords
- amylase
- alkyl
- alpha
- amylases
- detergent composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 176
- 239000003599 detergent Substances 0.000 title claims abstract description 98
- 229940025131 amylases Drugs 0.000 title claims abstract description 46
- 238000004140 cleaning Methods 0.000 claims abstract description 32
- 239000004382 Amylase Substances 0.000 claims description 99
- -1 builder Substances 0.000 claims description 64
- 108010059892 Cellulase Proteins 0.000 claims description 58
- 229940088598 enzyme Drugs 0.000 claims description 52
- 102000004190 Enzymes Human genes 0.000 claims description 51
- 108090000790 Enzymes Proteins 0.000 claims description 51
- 229940106157 cellulase Drugs 0.000 claims description 35
- 239000004744 fabric Substances 0.000 claims description 31
- 108091005804 Peptidases Proteins 0.000 claims description 28
- 108090001060 Lipase Proteins 0.000 claims description 27
- 102000004882 Lipase Human genes 0.000 claims description 27
- 239000007844 bleaching agent Substances 0.000 claims description 27
- 239000004367 Lipase Substances 0.000 claims description 26
- 235000019421 lipase Nutrition 0.000 claims description 26
- 239000004365 Protease Substances 0.000 claims description 25
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 claims description 23
- 239000003795 chemical substances by application Substances 0.000 claims description 18
- 239000002736 nonionic surfactant Substances 0.000 claims description 18
- 239000002689 soil Substances 0.000 claims description 11
- 239000003945 anionic surfactant Substances 0.000 claims description 8
- 241000194108 Bacillus licheniformis Species 0.000 claims description 6
- 229910021647 smectite Inorganic materials 0.000 claims description 6
- 230000008901 benefit Effects 0.000 claims description 5
- 125000002091 cationic group Chemical group 0.000 claims description 5
- 239000003093 cationic surfactant Substances 0.000 claims description 5
- 241000193744 Bacillus amyloliquefaciens Species 0.000 claims description 4
- 239000000654 additive Substances 0.000 claims description 4
- 230000000996 additive effect Effects 0.000 claims description 4
- 125000000129 anionic group Chemical group 0.000 claims description 4
- 239000002888 zwitterionic surfactant Substances 0.000 claims description 4
- 241000193385 Geobacillus stearothermophilus Species 0.000 claims description 3
- 210000004899 c-terminal region Anatomy 0.000 claims description 3
- 239000000725 suspension Substances 0.000 claims description 3
- 239000002280 amphoteric surfactant Substances 0.000 claims 1
- 238000004851 dishwashing Methods 0.000 abstract description 16
- 108010065511 Amylases Proteins 0.000 description 63
- 102000013142 Amylases Human genes 0.000 description 63
- 235000019418 amylase Nutrition 0.000 description 60
- 125000000217 alkyl group Chemical group 0.000 description 52
- 239000004094 surface-active agent Substances 0.000 description 38
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 28
- 239000000463 material Substances 0.000 description 28
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 26
- 229920000642 polymer Polymers 0.000 description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 25
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 24
- 238000000034 method Methods 0.000 description 23
- 125000004432 carbon atom Chemical group C* 0.000 description 22
- 229920000768 polyamine Polymers 0.000 description 22
- 229920001577 copolymer Polymers 0.000 description 20
- 235000019419 proteases Nutrition 0.000 description 20
- 239000002253 acid Substances 0.000 description 19
- 230000000694 effects Effects 0.000 description 19
- 150000003839 salts Chemical class 0.000 description 19
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 18
- 108010084185 Cellulases Proteins 0.000 description 17
- 102000005575 Cellulases Human genes 0.000 description 17
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 17
- 239000007859 condensation product Substances 0.000 description 17
- 108010091371 endoglucanase 1 Proteins 0.000 description 17
- 239000007788 liquid Substances 0.000 description 17
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 16
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 16
- 239000000975 dye Substances 0.000 description 16
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 16
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 16
- 239000011734 sodium Substances 0.000 description 16
- 150000001204 N-oxides Chemical class 0.000 description 15
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 15
- 150000001412 amines Chemical class 0.000 description 15
- 150000001875 compounds Chemical class 0.000 description 15
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 14
- 229910021536 Zeolite Inorganic materials 0.000 description 14
- 239000010457 zeolite Substances 0.000 description 14
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 13
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 13
- 239000000047 product Substances 0.000 description 13
- 239000000243 solution Substances 0.000 description 13
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 12
- 229910052708 sodium Inorganic materials 0.000 description 12
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 11
- 229920002472 Starch Polymers 0.000 description 11
- 150000001413 amino acids Chemical class 0.000 description 11
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 11
- 229920005646 polycarboxylate Polymers 0.000 description 11
- 229920001296 polysiloxane Polymers 0.000 description 11
- 235000019698 starch Nutrition 0.000 description 11
- FRPJTGXMTIIFIT-UHFFFAOYSA-N tetraacetylethylenediamine Chemical compound CC(=O)C(N)(C(C)=O)C(N)(C(C)=O)C(C)=O FRPJTGXMTIIFIT-UHFFFAOYSA-N 0.000 description 11
- 238000012546 transfer Methods 0.000 description 11
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 10
- 102000003992 Peroxidases Human genes 0.000 description 10
- 150000007513 acids Chemical class 0.000 description 10
- 125000003275 alpha amino acid group Chemical group 0.000 description 10
- 239000008107 starch Substances 0.000 description 10
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 9
- 238000004061 bleaching Methods 0.000 description 9
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 9
- 229910052757 nitrogen Inorganic materials 0.000 description 9
- 229910052760 oxygen Inorganic materials 0.000 description 9
- 239000001301 oxygen Substances 0.000 description 9
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 8
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 8
- 150000001768 cations Chemical class 0.000 description 8
- 229960004106 citric acid Drugs 0.000 description 8
- 125000000623 heterocyclic group Chemical group 0.000 description 8
- 230000002401 inhibitory effect Effects 0.000 description 8
- WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical compound CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 description 8
- 235000019832 sodium triphosphate Nutrition 0.000 description 8
- 239000000758 substrate Substances 0.000 description 8
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 7
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 7
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 7
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Natural products OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 7
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical group OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 7
- 239000008103 glucose Substances 0.000 description 7
- 108010075550 termamyl Proteins 0.000 description 7
- 150000003512 tertiary amines Chemical class 0.000 description 7
- 238000005406 washing Methods 0.000 description 7
- VKZRWSNIWNFCIQ-WDSKDSINSA-N (2s)-2-[2-[[(1s)-1,2-dicarboxyethyl]amino]ethylamino]butanedioic acid Chemical compound OC(=O)C[C@@H](C(O)=O)NCCN[C@H](C(O)=O)CC(O)=O VKZRWSNIWNFCIQ-WDSKDSINSA-N 0.000 description 6
- BMVXCPBXGZKUPN-UHFFFAOYSA-N 1-hexanamine Chemical compound CCCCCCN BMVXCPBXGZKUPN-UHFFFAOYSA-N 0.000 description 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 6
- 244000060011 Cocos nucifera Species 0.000 description 6
- 235000013162 Cocos nucifera Nutrition 0.000 description 6
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 6
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical group [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 6
- 239000004902 Softening Agent Substances 0.000 description 6
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 6
- 125000002723 alicyclic group Chemical group 0.000 description 6
- 125000001931 aliphatic group Chemical group 0.000 description 6
- 150000008051 alkyl sulfates Chemical class 0.000 description 6
- 150000001408 amides Chemical class 0.000 description 6
- 125000000539 amino acid group Chemical group 0.000 description 6
- 125000003118 aryl group Chemical group 0.000 description 6
- 229920006037 cross link polymer Polymers 0.000 description 6
- 108010005400 cutinase Proteins 0.000 description 6
- 235000014113 dietary fatty acids Nutrition 0.000 description 6
- 239000000194 fatty acid Substances 0.000 description 6
- 229930195729 fatty acid Natural products 0.000 description 6
- 150000004665 fatty acids Chemical class 0.000 description 6
- 230000002209 hydrophobic effect Effects 0.000 description 6
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 6
- 239000004615 ingredient Substances 0.000 description 6
- 239000012188 paraffin wax Substances 0.000 description 6
- 229910052700 potassium Inorganic materials 0.000 description 6
- 239000011591 potassium Substances 0.000 description 6
- 239000000377 silicon dioxide Substances 0.000 description 6
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 6
- 229910021653 sulphate ion Inorganic materials 0.000 description 6
- 239000003760 tallow Substances 0.000 description 6
- QAEDZJGFFMLHHQ-UHFFFAOYSA-N trifluoroacetic anhydride Chemical compound FC(F)(F)C(=O)OC(=O)C(F)(F)F QAEDZJGFFMLHHQ-UHFFFAOYSA-N 0.000 description 6
- OSSNTDFYBPYIEC-UHFFFAOYSA-N 1-ethenylimidazole Chemical compound C=CN1C=CN=C1 OSSNTDFYBPYIEC-UHFFFAOYSA-N 0.000 description 5
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 5
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 description 5
- 102000035195 Peptidases Human genes 0.000 description 5
- 101710194948 Protein phosphatase PhpP Proteins 0.000 description 5
- 239000011575 calcium Substances 0.000 description 5
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 5
- 239000001768 carboxy methyl cellulose Substances 0.000 description 5
- 239000004927 clay Substances 0.000 description 5
- 230000001747 exhibiting effect Effects 0.000 description 5
- JPZROSNLRWHSQQ-UHFFFAOYSA-N furan-2,5-dione;prop-2-enoic acid Chemical compound OC(=O)C=C.O=C1OC(=O)C=C1 JPZROSNLRWHSQQ-UHFFFAOYSA-N 0.000 description 5
- 125000001183 hydrocarbyl group Chemical group 0.000 description 5
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 5
- 108040007629 peroxidase activity proteins Proteins 0.000 description 5
- 229920000058 polyacrylate Polymers 0.000 description 5
- 229920001223 polyethylene glycol Polymers 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical compound CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 5
- 108010008885 Cellulose 1,4-beta-Cellobiosidase Proteins 0.000 description 4
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical group CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 4
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 4
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 4
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- 241001480714 Humicola insolens Species 0.000 description 4
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 4
- 108010059820 Polygalacturonase Proteins 0.000 description 4
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 4
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 4
- 239000012190 activator Substances 0.000 description 4
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 4
- 150000004996 alkyl benzenes Chemical class 0.000 description 4
- 125000005907 alkyl ester group Chemical group 0.000 description 4
- 229910000323 aluminium silicate Inorganic materials 0.000 description 4
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 4
- 150000001720 carbohydrates Chemical group 0.000 description 4
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 4
- 150000007942 carboxylates Chemical class 0.000 description 4
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 4
- 229940105329 carboxymethylcellulose Drugs 0.000 description 4
- 150000001860 citric acid derivatives Chemical class 0.000 description 4
- JRBPAEWTRLWTQC-UHFFFAOYSA-N dodecylamine Chemical compound CCCCCCCCCCCCN JRBPAEWTRLWTQC-UHFFFAOYSA-N 0.000 description 4
- 230000002255 enzymatic effect Effects 0.000 description 4
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 4
- 230000003203 everyday effect Effects 0.000 description 4
- 108010093305 exopolygalacturonase Proteins 0.000 description 4
- 239000000945 filler Substances 0.000 description 4
- 229920001519 homopolymer Polymers 0.000 description 4
- 238000004900 laundering Methods 0.000 description 4
- 159000000003 magnesium salts Chemical class 0.000 description 4
- 230000004048 modification Effects 0.000 description 4
- 238000012986 modification Methods 0.000 description 4
- IOQPZZOEVPZRBK-UHFFFAOYSA-N octan-1-amine Chemical compound CCCCCCCCN IOQPZZOEVPZRBK-UHFFFAOYSA-N 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- 239000002304 perfume Substances 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 4
- 229920000728 polyester Polymers 0.000 description 4
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 4
- 239000002243 precursor Substances 0.000 description 4
- 229960004063 propylene glycol Drugs 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- MSFGZHUJTJBYFA-UHFFFAOYSA-M sodium dichloroisocyanurate Chemical compound [Na+].ClN1C(=O)[N-]C(=O)N(Cl)C1=O MSFGZHUJTJBYFA-UHFFFAOYSA-M 0.000 description 4
- 229910052938 sodium sulfate Inorganic materials 0.000 description 4
- 235000011152 sodium sulphate Nutrition 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 4
- 229920001897 terpolymer Polymers 0.000 description 4
- ZMPRRFPMMJQXPP-UHFFFAOYSA-N 2-sulfobenzoic acid Chemical compound OC(=O)C1=CC=CC=C1S(O)(=O)=O ZMPRRFPMMJQXPP-UHFFFAOYSA-N 0.000 description 3
- 241000193830 Bacillus <bacterium> Species 0.000 description 3
- 240000002791 Brassica napus Species 0.000 description 3
- 235000004977 Brassica sinapistrum Nutrition 0.000 description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
- MHZGKXUYDGKKIU-UHFFFAOYSA-N Decylamine Chemical compound CCCCCCCCCCN MHZGKXUYDGKKIU-UHFFFAOYSA-N 0.000 description 3
- 101710121765 Endo-1,4-beta-xylanase Proteins 0.000 description 3
- 239000004705 High-molecular-weight polyethylene Substances 0.000 description 3
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 3
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 3
- RWRDLPDLKQPQOW-UHFFFAOYSA-N Pyrrolidine Chemical compound C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 3
- 239000004115 Sodium Silicate Substances 0.000 description 3
- 229920002125 Sokalan® Polymers 0.000 description 3
- 108010056079 Subtilisins Proteins 0.000 description 3
- 102000005158 Subtilisins Human genes 0.000 description 3
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 3
- 150000003863 ammonium salts Chemical class 0.000 description 3
- 150000001450 anions Chemical class 0.000 description 3
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 description 3
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 3
- 239000000460 chlorine Substances 0.000 description 3
- 229910052801 chlorine Inorganic materials 0.000 description 3
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 239000012634 fragment Substances 0.000 description 3
- 230000002538 fungal effect Effects 0.000 description 3
- 229940083124 ganglion-blocking antiadrenergic secondary and tertiary amines Drugs 0.000 description 3
- 125000003147 glycosyl group Chemical group 0.000 description 3
- 239000011256 inorganic filler Substances 0.000 description 3
- 229910003475 inorganic filler Inorganic materials 0.000 description 3
- 239000002563 ionic surfactant Substances 0.000 description 3
- 229910052744 lithium Inorganic materials 0.000 description 3
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 3
- 244000005700 microbiome Species 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 239000010452 phosphate Substances 0.000 description 3
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 150000003138 primary alcohols Chemical class 0.000 description 3
- 150000003141 primary amines Chemical class 0.000 description 3
- 229920005604 random copolymer Polymers 0.000 description 3
- 150000004760 silicates Chemical class 0.000 description 3
- 238000002791 soaking Methods 0.000 description 3
- 239000000344 soap Substances 0.000 description 3
- 159000000000 sodium salts Chemical class 0.000 description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 3
- 229910052911 sodium silicate Inorganic materials 0.000 description 3
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- 230000002829 reductive effect Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 238000002741 site-directed mutagenesis Methods 0.000 description 1
- 239000000429 sodium aluminium silicate Substances 0.000 description 1
- 235000012217 sodium aluminium silicate Nutrition 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
- NVIFVTYDZMXWGX-UHFFFAOYSA-N sodium metaborate Chemical compound [Na+].[O-]B=O NVIFVTYDZMXWGX-UHFFFAOYSA-N 0.000 description 1
- 235000019795 sodium metasilicate Nutrition 0.000 description 1
- DZCAZXAJPZCSCU-UHFFFAOYSA-K sodium nitrilotriacetate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CC([O-])=O DZCAZXAJPZCSCU-UHFFFAOYSA-K 0.000 description 1
- 229940067741 sodium octyl sulfate Drugs 0.000 description 1
- 239000012418 sodium perborate tetrahydrate Substances 0.000 description 1
- 229940045872 sodium percarbonate Drugs 0.000 description 1
- 229940048086 sodium pyrophosphate Drugs 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- IBDSNZLUHYKHQP-UHFFFAOYSA-N sodium;3-oxidodioxaborirane;tetrahydrate Chemical compound O.O.O.O.[Na+].[O-]B1OO1 IBDSNZLUHYKHQP-UHFFFAOYSA-N 0.000 description 1
- PFIPWUCWKIBUBF-UHFFFAOYSA-M sodium;hydrogen sulfate;2-propan-2-ylbenzenesulfonic acid Chemical compound [Na+].OS(O)(=O)=O.CC(C)C1=CC=CC=C1S([O-])(=O)=O PFIPWUCWKIBUBF-UHFFFAOYSA-M 0.000 description 1
- WFRKJMRGXGWHBM-UHFFFAOYSA-M sodium;octyl sulfate Chemical compound [Na+].CCCCCCCCOS([O-])(=O)=O WFRKJMRGXGWHBM-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 235000010356 sorbitol Nutrition 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 150000003890 succinate salts Chemical class 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- DIORMHZUUKOISG-UHFFFAOYSA-N sulfoformic acid Chemical compound OC(=O)S(O)(=O)=O DIORMHZUUKOISG-UHFFFAOYSA-N 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 238000006277 sulfonation reaction Methods 0.000 description 1
- 150000003462 sulfoxides Chemical class 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 229950009390 symclosene Drugs 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 239000003784 tall oil Substances 0.000 description 1
- 108010038851 tannase Proteins 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 150000004026 tertiary sulfonium compounds Chemical class 0.000 description 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38627—Preparations containing enzymes, e.g. protease or amylase containing lipase
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| WOPCT/US96/07090 | 1996-05-15 | ||
| PCT/US1996/007090 WO1997043378A1 (en) | 1996-05-15 | 1996-05-15 | DETERGENT COMPOSITIONS COMPRISING A COMBINATION OF α-AMYLASES FOR MALODOR STRIPPING |
| PCT/US1997/008103 WO1997043385A1 (en) | 1996-05-15 | 1997-05-13 | DETERGENT COMPOSITIONS COMPRISING A COMBINATION OF α-AMYLASES FOR MALODOR STRIPPING |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2254069A1 true CA2254069A1 (en) | 1997-11-20 |
Family
ID=22255112
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002254069A Abandoned CA2254069A1 (en) | 1996-05-15 | 1997-05-13 | Detergent compositions comprising a combination of .alpha.-amylases for malodor stripping |
Country Status (9)
| Country | Link |
|---|---|
| EP (1) | EP0912687A1 (cs) |
| JP (1) | JP3095786B2 (cs) |
| CN (1) | CN1225674A (cs) |
| AU (1) | AU5861996A (cs) |
| BR (1) | BR9709004A (cs) |
| CA (1) | CA2254069A1 (cs) |
| CZ (1) | CZ364998A3 (cs) |
| MX (1) | MX9809587A (cs) |
| WO (2) | WO1997043378A1 (cs) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0756000A1 (en) * | 1995-07-24 | 1997-01-29 | The Procter & Gamble Company | Detergent compositions comprising specific amylase and linear alkyl benzene sulfonate surfactant |
| CA2243011C (en) * | 1998-07-13 | 2007-02-13 | Life Science Technology Group, Inc. | Odor control agent for carpet and the like and method of use thereof |
| EP1362089B1 (en) * | 2001-02-17 | 2007-01-03 | Novozymes A/S | Reduction of malodour from laundry |
| US6794350B2 (en) | 2001-02-17 | 2004-09-21 | Novozymes A/S | Reduction of malodor from laundry |
| JP5394922B2 (ja) * | 2006-08-11 | 2014-01-22 | ノボザイムス バイオロジカルズ，インコーポレイティド | 菌培養液及び菌培養液含有組成物 |
| JP5890193B2 (ja) * | 2012-02-15 | 2016-03-22 | 花王株式会社 | 自動洗浄機用粉末洗浄剤組成物 |
| EP2856896A1 (en) | 2013-09-23 | 2015-04-08 | Life Science TGO, SRL | Impregnated odour control products and methods of making the same |
| US20190185791A1 (en) * | 2016-05-26 | 2019-06-20 | Novozymes A/S | Use of enzymes, cleaning composition and method for washing |
| US20220315866A1 (en) * | 2019-09-19 | 2022-10-06 | Novozymes A/S | Detergent Composition |
| CN115916942A (zh) | 2020-07-31 | 2023-04-04 | 美国陶氏有机硅公司 | 硬表面清洁浓缩物包 |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2036477A1 (de) * | 1970-07-23 | 1972-01-27 | Rohm Gmbh, 6100 Darmstadt | Enzymhaltiges flussiges Geschirrspul mittel |
| US4933279A (en) | 1986-07-09 | 1990-06-12 | Novo Industri A/S | Starch liquefaction with alpha amylase mixtures |
| CA1283376C (en) * | 1986-07-09 | 1991-04-23 | John O. Carroll | .alpha.-AMYLASE MIXTURES FOR STARCH LIQUEFACTION |
| US5030377A (en) * | 1988-11-11 | 1991-07-09 | Kao Corporation | Detergent compositions containing starch debranching enzymes |
| ATE137267T1 (de) * | 1990-06-14 | 1996-05-15 | Novo Nordisk As | Aktivierung von polysaccharide hydrolase |
| JP2516551B2 (ja) * | 1993-04-09 | 1996-07-24 | ティーポール株式会社 | 粉末漂白洗浄剤組成物 |
| DE69433032T2 (de) * | 1993-05-19 | 2004-06-03 | Kao Corp. | VERFLÜSSIGENDE -[alpha]-AMYLASE, VERFAHREN ZU IHRER HERSTELLUNG, UND SIE ENTHALTENDE WASCHMITTELZUSAMMENSETZUNG |
| JPH09503916A (ja) * | 1993-10-08 | 1997-04-22 | ノボ ノルディスク アクティーゼルスカブ | アミラーゼ変異体 |
| AR000862A1 (es) * | 1995-02-03 | 1997-08-06 | Novozymes As | Variantes de una ó-amilasa madre, un metodo para producir la misma, una estructura de adn y un vector de expresion, una celula transformada por dichaestructura de adn y vector, un aditivo para detergente, composicion detergente, una composicion para lavado de ropa y una composicion para la eliminacion del |
| EP0842254B1 (en) * | 1995-07-24 | 2002-01-09 | The Procter & Gamble Company | Dingy fabric clean-up with amylase enzyme in detergent compositions |
| EP0756000A1 (en) * | 1995-07-24 | 1997-01-29 | The Procter & Gamble Company | Detergent compositions comprising specific amylase and linear alkyl benzene sulfonate surfactant |
| EP0885285B1 (en) * | 1996-03-07 | 2004-10-20 | The Procter & Gamble Company | Detergent compositions comprising proteases and improved amylases |
-
1996
- 1996-05-15 AU AU58619/96A patent/AU5861996A/en not_active Abandoned
- 1996-05-15 WO PCT/US1996/007090 patent/WO1997043378A1/en not_active Ceased
- 1996-05-15 MX MX9809587A patent/MX9809587A/es unknown
-
1997
- 1997-05-13 CN CN97196488A patent/CN1225674A/zh active Pending
- 1997-05-13 JP JP09541069A patent/JP3095786B2/ja not_active Expired - Fee Related
- 1997-05-13 WO PCT/US1997/008103 patent/WO1997043385A1/en not_active Ceased
- 1997-05-13 CA CA002254069A patent/CA2254069A1/en not_active Abandoned
- 1997-05-13 EP EP97925549A patent/EP0912687A1/en not_active Withdrawn
- 1997-05-13 CZ CZ983649A patent/CZ364998A3/cs unknown
- 1997-05-13 BR BR9709004A patent/BR9709004A/pt unknown
Also Published As
| Publication number | Publication date |
|---|---|
| JP3095786B2 (ja) | 2000-10-10 |
| WO1997043385A1 (en) | 1997-11-20 |
| MX9809587A (en) | 1999-03-01 |
| CZ364998A3 (cs) | 1999-04-14 |
| WO1997043378A1 (en) | 1997-11-20 |
| AU5861996A (en) | 1997-12-05 |
| EP0912687A1 (en) | 1999-05-06 |
| JPH11511784A (ja) | 1999-10-12 |
| CN1225674A (zh) | 1999-08-11 |
| WO1997043385A8 (en) | 1999-04-29 |
| BR9709004A (pt) | 1999-08-03 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| FZDE | Discontinued |