CA2253514A1 - Process for the preparation of a terpolymer of ethylene, an .alpha.-olefin and a diene - Google Patents

Process for the preparation of a terpolymer of ethylene, an .alpha.-olefin and a diene Download PDF

Info

Publication number
CA2253514A1
CA2253514A1 CA002253514A CA2253514A CA2253514A1 CA 2253514 A1 CA2253514 A1 CA 2253514A1 CA 002253514 A CA002253514 A CA 002253514A CA 2253514 A CA2253514 A CA 2253514A CA 2253514 A1 CA2253514 A1 CA 2253514A1
Authority
CA
Canada
Prior art keywords
group
transition metal
process according
ligand
groups
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA002253514A
Other languages
English (en)
French (fr)
Inventor
Jacob Renkema
Maurits Frederik Hendrik Van Tol
Peter Jozef Hubert Windmuller
Johannes Antonius Maria Van Beek
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Koninklijke DSM NV
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of CA2253514A1 publication Critical patent/CA2253514A1/en
Abandoned legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
CA002253514A 1996-05-03 1997-05-01 Process for the preparation of a terpolymer of ethylene, an .alpha.-olefin and a diene Abandoned CA2253514A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP96201112 1996-05-03
EP96201112.8 1996-05-03

Publications (1)

Publication Number Publication Date
CA2253514A1 true CA2253514A1 (en) 1997-11-13

Family

ID=8223921

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002253514A Abandoned CA2253514A1 (en) 1996-05-03 1997-05-01 Process for the preparation of a terpolymer of ethylene, an .alpha.-olefin and a diene

Country Status (9)

Country Link
EP (1) EP0896597A1 (pt)
JP (1) JP2000510175A (pt)
KR (1) KR20000010950A (pt)
AU (1) AU2412097A (pt)
BR (1) BR9708891A (pt)
CA (1) CA2253514A1 (pt)
EA (1) EA199800975A1 (pt)
ID (1) ID16858A (pt)
WO (1) WO1997042239A1 (pt)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1084152B1 (en) 1998-05-01 2002-12-11 ExxonMobil Chemical Patents Inc. Tridentate ligand-containing metal catalyst complexes for olefin polymerization
US7078164B1 (en) 2000-06-19 2006-07-18 Symyx Technologies, Inc. High throughput screen for identifying polymerization catalysts from potential catalysts
KR100826080B1 (ko) * 2001-12-27 2008-04-29 삼성토탈 주식회사 고용융체 강도를 갖는 에틸렌/디엔 공중합체의 제조방법
KR100501398B1 (ko) * 2003-01-15 2005-07-18 삼성토탈 주식회사 긴가지를 갖는 α-올레핀/환상올레핀/디엔 공중합체 및 그제조방법
KR100586922B1 (ko) * 2004-11-18 2006-06-08 금호폴리켐 주식회사 고수율의 이피(디)엠의 제조방법 및 수율의 제어방법,이피(디)엠의 회수방법
KR101829222B1 (ko) 2011-02-15 2018-02-19 엘지전자 주식회사 냉장고
KR101212637B1 (ko) * 2011-06-09 2012-12-14 에스케이종합화학 주식회사 신규한 사이클로펜타［ｂ］플루오레닐 전이금속 화합물, 이를 포함하는 전이금속 촉매 조성물, 및 이를 이용한 에틸렌 단독중합체 또는 에틸렌과 α-올레핀의 공중합체의 제조방법
KR101391693B1 (ko) 2012-11-14 2014-05-07 주식회사 엘지화학 3원계 탄성 공중합체 및 이의 제조 방법
KR101391692B1 (ko) 2012-11-14 2014-05-07 주식회사 엘지화학 3원계 탄성 공중합체 및 이의 제조 방법

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1327673C (en) * 1988-06-16 1994-03-08 Sigmund Floyd Process for production of high molecular weight epdm elastomers using a metallocene-alumoxane catalyst system
US5278272A (en) * 1991-10-15 1994-01-11 The Dow Chemical Company Elastic substantialy linear olefin polymers
US5374696A (en) * 1992-03-26 1994-12-20 The Dow Chemical Company Addition polymerization process using stabilized reduced metal catalysts
WO1996013529A1 (en) * 1994-10-31 1996-05-09 Dsm N.V. Catalyst composition and process for the polymerization of an olefin

Also Published As

Publication number Publication date
BR9708891A (pt) 1999-08-03
JP2000510175A (ja) 2000-08-08
AU2412097A (en) 1997-11-26
EA199800975A1 (ru) 1999-04-29
KR20000010950A (ko) 2000-02-25
WO1997042239A1 (en) 1997-11-13
EP0896597A1 (en) 1999-02-17
ID16858A (id) 1997-11-20

Similar Documents

Publication Publication Date Title
US5442020A (en) Bimetallic metallocene alumoxane catalyst system and its use in the preparation of ethylene-alpha olefin and ethylene-alpha olefin-non-conjugated diolefin elastomers
CA2210496C (en) Borabenzene based olefin polymerization catalysts
US5986029A (en) Catalyst composition and process for the polymerization of an olefin
JP2684154B2 (ja) 付加重合触媒及びその使用法
MXPA97008182A (en) S $! azaborolinilo metallic complexs as olefi polymerization catalysts
WO1994011406A1 (en) Indenyl compounds and catalyst components for the polymerization of olefins
AU1546399A (en) Mixed catalyst composition for the production of olefin polymers
KR102226823B1 (ko) 굴곡탄성율이 우수한 폴리올레핀 제조용 촉매 조성물
KR20160147642A (ko) 메탈로센 담지 촉매의 제조 방법
EP0896596A1 (en) Process for the production of functional polyolefins
CA2253576A1 (en) Process for the polymerisation of alpha-olefins
CA2253514A1 (en) Process for the preparation of a terpolymer of ethylene, an .alpha.-olefin and a diene
CA2253542A1 (en) Process for the preparation of an ethylene and .alpha.-olefin copolymer
WO1997042228A1 (en) Supported catalyst composition and process for the polymerization of olefin monomers
KR102565858B1 (ko) 올레핀 중합 촉매용 전이금속 화합물, 이를 포함하는 올레핀 중합 촉매 및 이를 이용하여 중합된 폴리올레핀
WO1997042237A1 (en) A process for making polyolefins having broad molecular weight distributions
US6383968B1 (en) Process for the polymerization of olefins
WO1997042240A1 (en) Process for the co-polymerization of an olefin and a vinyl aromatic monomer
WO1997042238A1 (en) Inverted polyolefin copolymers
EP1028983B1 (en) Catalyst composition comprising a reduced transition metal complex and a cocatalyst
WO1997042235A1 (en) Process for the production of polymers containing cyclic olefins
KR20160021102A (ko) 올레핀 중합용 촉매, 이의 제조 방법 및 용도
WO1997042233A1 (en) Process for the polymerization of vinyl aromatic monomers
MXPA98009115A (en) Procedure for the co-polymerization of an olefine and an aromat vinyl monomer
MXPA98009110A (en) Composition of supported catalyst and procedure for the polymerization of olef monomers

Legal Events

Date Code Title Description
FZDE Dead