CA2253381A1 - Procede pour la copolymerisation d'une olefine et d'un monomere aromatique de vinyle - Google Patents

Procede pour la copolymerisation d'une olefine et d'un monomere aromatique de vinyle Download PDF

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Publication number
CA2253381A1
CA2253381A1 CA002253381A CA2253381A CA2253381A1 CA 2253381 A1 CA2253381 A1 CA 2253381A1 CA 002253381 A CA002253381 A CA 002253381A CA 2253381 A CA2253381 A CA 2253381A CA 2253381 A1 CA2253381 A1 CA 2253381A1
Authority
CA
Canada
Prior art keywords
group
transition metal
ligand
process according
groups
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA002253381A
Other languages
English (en)
Inventor
Maurits Frederik Hendrik Van Tol
Johannes Antonius Maria Van Beek
Paulus Johannes Jacobus Pieters
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Koninklijke DSM NV
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of CA2253381A1 publication Critical patent/CA2253381A1/fr
Abandoned legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

Cette invention se rapporte à un procédé pour la copolymérisation d'au moins une .alpha.-oléfine et d'au moins un monomère aromatique. Cette copolymérisation est effectuée en présence d'une composition de catalyseur renfermant au moins un cocatalyseur et un complexe de métal de transition réduit. Le complexe de métal de transition réduit contient un métal de transition réduit choisi dans les groupes 4 à 6 du tableau périodique des éléments, un ligand monoanionique multidenté, et au moins deux ligands monoanioniques. Dans un mode de réalisation, le métal de transition réduit qui est choisi est le titane.
CA002253381A 1996-05-03 1997-05-01 Procede pour la copolymerisation d'une olefine et d'un monomere aromatique de vinyle Abandoned CA2253381A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP96201110 1996-05-03
EP96201110.2 1996-05-03

Publications (1)

Publication Number Publication Date
CA2253381A1 true CA2253381A1 (fr) 1997-11-13

Family

ID=8223919

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002253381A Abandoned CA2253381A1 (fr) 1996-05-03 1997-05-01 Procede pour la copolymerisation d'une olefine et d'un monomere aromatique de vinyle

Country Status (8)

Country Link
EP (1) EP0896598A1 (fr)
JP (1) JP2000513760A (fr)
KR (1) KR20000010948A (fr)
AU (1) AU2411597A (fr)
BR (1) BR9709144A (fr)
CA (1) CA2253381A1 (fr)
EA (1) EA199800978A1 (fr)
WO (1) WO1997042240A1 (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002513823A (ja) 1998-05-01 2002-05-14 エクソンモービル・ケミカル・パテンツ・インク オレフィン重合用の三座配位子含有金属触媒錯体
AR022608A1 (es) * 1999-02-17 2002-09-04 Dow Chemical Co Producto interpolimerico aromatico de alfa-olefina/vinilo o vinilideno y proceso para su elaboracion mediante sistemas catalizadores multiples

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NZ235032A (en) * 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
US5208357A (en) * 1990-12-31 1993-05-04 Exxon Chemical Patents, Inc. Chiral metallocene compounds and preparation thereof by attachment of chiral center
US5349100A (en) * 1991-01-02 1994-09-20 Exxon Chemical Patents Inc. Chiral metallocene compounds and preparation thereof by creation of a chiral center by enantioselective hydride transfer
US5278272A (en) * 1991-10-15 1994-01-11 The Dow Chemical Company Elastic substantialy linear olefin polymers
US5374696A (en) * 1992-03-26 1994-12-20 The Dow Chemical Company Addition polymerization process using stabilized reduced metal catalysts
AU3817595A (en) * 1994-10-31 1996-05-23 Dsm N.V. Catalyst composition and process for the polymerization of an olefin

Also Published As

Publication number Publication date
AU2411597A (en) 1997-11-26
EA199800978A1 (ru) 1999-04-29
WO1997042240A1 (fr) 1997-11-13
JP2000513760A (ja) 2000-10-17
EP0896598A1 (fr) 1999-02-17
BR9709144A (pt) 1999-08-03
KR20000010948A (ko) 2000-02-25

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