CA2238758C - Procede de carbonylation de composes a insaturation ethylenique - Google Patents

Procede de carbonylation de composes a insaturation ethylenique Download PDF

Info

Publication number
CA2238758C
CA2238758C CA002238758A CA2238758A CA2238758C CA 2238758 C CA2238758 C CA 2238758C CA 002238758 A CA002238758 A CA 002238758A CA 2238758 A CA2238758 A CA 2238758A CA 2238758 C CA2238758 C CA 2238758C
Authority
CA
Canada
Prior art keywords
substituted
catalyst system
bidentate ligand
carbon atoms
platinum
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CA002238758A
Other languages
English (en)
Other versions
CA2238758A1 (fr
Inventor
Eit Drent
Mirjam Catharina Theodora De Kock
Dennis Humphrey Louis Pello
Willem Wabe Jager
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Publication of CA2238758A1 publication Critical patent/CA2238758A1/fr
Application granted granted Critical
Publication of CA2238758C publication Critical patent/CA2238758C/fr
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/14—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on a carbon-to-carbon unsaturated bond in organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • C07C67/38—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by addition to an unsaturated carbon-to-carbon bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
    • C07C69/533—Monocarboxylic acid esters having only one carbon-to-carbon double bond
    • C07C69/54—Acrylic acid esters; Methacrylic acid esters

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Ce procédé de carbonylation de composés à insaturation éthylénique consiste à faire réagir ceux-ci avec du monoxyde de carbone en même temps qu'avec un autre réactif, et ce en présence d'un système catalyseur comportant: (a) une source de platine, (b) un ligand bidenté de la formule R<1>R<2>M<1>-R-M<2>R<3>R<4>, dans laquelle M<1> et M<2> représentent indépendamment P, As ou Sb, R représente un groupe de pontage bivalent, substitué ou non et contenant 1 à 5 atomes dans le pont, R<1> et R<2> représentent ensemble un groupe bivalent substitué ou non, les deux valences libres étant liées à M<1>, et R<3> et R<4> représentent ensemble un groupe bivalent substitué ou non, les deux valences libres étant liées à M<2>, ou bien R<3> et R<4> représentent indépendamment des groupes hydrocarbyles substitués ou non, et (c) une source d'anions.
CA002238758A 1995-12-07 1996-12-02 Procede de carbonylation de composes a insaturation ethylenique Expired - Fee Related CA2238758C (fr)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
EP95203402 1995-12-07
EP95203402.3 1995-12-07
EP95203670 1995-12-29
EP95203670.5 1995-12-29
PCT/EP1996/005575 WO1997020803A1 (fr) 1995-12-07 1996-12-02 Procede de carbonylation de composes a insaturation ethylenique

Publications (2)

Publication Number Publication Date
CA2238758A1 CA2238758A1 (fr) 1997-06-12
CA2238758C true CA2238758C (fr) 2005-09-20

Family

ID=26139882

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002238758A Expired - Fee Related CA2238758C (fr) 1995-12-07 1996-12-02 Procede de carbonylation de composes a insaturation ethylenique

Country Status (9)

Country Link
EP (1) EP0877728B1 (fr)
JP (1) JP2000501405A (fr)
KR (1) KR100474008B1 (fr)
CN (1) CN1076015C (fr)
AU (1) AU706972B2 (fr)
BR (1) BR9611689A (fr)
CA (1) CA2238758C (fr)
DE (1) DE69607653T2 (fr)
WO (1) WO1997020803A1 (fr)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011111806A1 (fr) * 2010-03-09 2011-09-15 Sumitomo Chemical Company, Limited Procédé de fabrication d'un carboxylate α,β-insaturé et catalyseur pour sa fabrication
CN103785470B (zh) * 2012-11-01 2016-02-10 中国石油化工股份有限公司 一种用于合成丙烯酸的催化剂的制备方法
CN103524329B (zh) * 2013-10-23 2015-07-29 上海浦景化工技术股份有限公司 一种乙炔羰化合成丙烯酸的方法
CN109096109B (zh) * 2017-06-21 2021-03-30 中国石油化工股份有限公司 2-丁烯酸酯的合成方法
CN109092366B (zh) * 2017-06-21 2021-05-28 中国石油化工股份有限公司 催化剂组合物及2-丁烯酸的制备方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2034971A1 (fr) * 1990-02-05 1991-08-06 Eit Drent Systeme de catalyseur de carbonylation
GB9002521D0 (en) * 1990-02-05 1990-04-04 Shell Int Research Carbonylation catalyst system
EP0499329B1 (fr) * 1991-02-15 1994-05-04 Shell Internationale Researchmaatschappij B.V. Système catalytique pour carbonylation
US5414109A (en) * 1993-03-19 1995-05-09 Shell Oil Company Process for the carbonylation of acetylenically unsaturated compounds
CN1041626C (zh) * 1993-07-19 1999-01-13 国际壳牌研究有限公司 炔属不饱和化合物羰基化的方法
EP0714385B1 (fr) * 1993-08-19 1998-11-11 Shell Internationale Researchmaatschappij B.V. Procede d'hydroformylation

Also Published As

Publication number Publication date
CA2238758A1 (fr) 1997-06-12
AU1193897A (en) 1997-06-27
CN1203581A (zh) 1998-12-30
AU706972B2 (en) 1999-07-01
CN1076015C (zh) 2001-12-12
WO1997020803A1 (fr) 1997-06-12
JP2000501405A (ja) 2000-02-08
KR100474008B1 (ko) 2005-07-11
DE69607653D1 (de) 2000-05-11
KR19990071658A (ko) 1999-09-27
DE69607653T2 (de) 2000-11-23
EP0877728B1 (fr) 2000-04-05
BR9611689A (pt) 1999-02-17
EP0877728A1 (fr) 1998-11-18

Similar Documents

Publication Publication Date Title
JP2997887B2 (ja) カルボニル化触媒系
JP4204189B2 (ja) グリセロールの水素化分解
JP3233670B2 (ja) オレフィンのカルボニル化方法
AU2001274046B2 (en) Bidentate ligands useful in catalyst system
EP0499329B1 (fr) Système catalytique pour carbonylation
US20090012333A1 (en) Process of Preparing Glycolaldehyde
CA2155574C (fr) Systeme catalyseur a base de palladium non acide et son utilisation pour la carbonylation
EP1478463B1 (fr) Carbonylation d&#39;un compose ethyleniquement insature, et catalyseur a cet effet
AU2001274046A1 (en) Bidentate ligands useful in catalyst system
EP0662467A1 (fr) Procédé de préparation d&#39;un ester
CA2238758C (fr) Procede de carbonylation de composes a insaturation ethylenique
EP1222157B1 (fr) Procede de carbonylation d&#39;un compose insature en acetylene
KR100295155B1 (ko) 알켄산유도체제조방법
EP0710224B1 (fr) Procede de carbonylation de composes acetyleniquement insatures
US5952522A (en) Process for the carbonylation of acetylenically unsaturated compounds
EP0689529B1 (fr) Procede de carbonylation de composes acetyleniquement insatures
US5780684A (en) Hydroformylation reactions
EP0724558B1 (fr) Procede de carbonylation de composes acetyleniquement insatures
JP4087448B2 (ja) アセチレン系不飽和化合物のカルボニル化プロセス
AU2003210312A1 (en) Processes for the preparation of a carobxylic anhydride and use of the carboxylic anhydride as an acylation agent

Legal Events

Date Code Title Description
EEER Examination request
MKLA Lapsed