CA2110139A1 - Exhaust Gas Purification System for Reducing Hydrocarbon Emissions During the Cold Start of Combustion Engines - Google Patents

Exhaust Gas Purification System for Reducing Hydrocarbon Emissions During the Cold Start of Combustion Engines

Info

Publication number
CA2110139A1
CA2110139A1 CA2110139A CA2110139A CA2110139A1 CA 2110139 A1 CA2110139 A1 CA 2110139A1 CA 2110139 A CA2110139 A CA 2110139A CA 2110139 A CA2110139 A CA 2110139A CA 2110139 A1 CA2110139 A1 CA 2110139A1
Authority
CA
Canada
Prior art keywords
exhaust gas
gas purification
cold start
purification system
combustion engines
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA2110139A
Other languages
French (fr)
Other versions
CA2110139C (en
Inventor
Dieter Lindner
Egbert Lox
Bernd Engler
Klaus Ostgathe
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Evonik Operations GmbH
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of CA2110139A1 publication Critical patent/CA2110139A1/en
Application granted granted Critical
Publication of CA2110139C publication Critical patent/CA2110139C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9481—Catalyst preceded by an adsorption device without catalytic function for temporary storage of contaminants, e.g. during cold start
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/0454—Controlling adsorption
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N13/00—Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00
    • F01N13/009—Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00 having two or more separate purifying devices arranged in series
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/0807—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents
    • F01N3/0814—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents combined with catalytic converters, e.g. NOx absorption/storage reduction catalysts
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/0807—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents
    • F01N3/0828—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents characterised by the absorbed or adsorbed substances
    • F01N3/0835—Hydrocarbons
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/0807—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents
    • F01N3/0871—Regulation of absorbents or adsorbents, e.g. purging
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2250/00—Combinations of different methods of purification
    • F01N2250/12—Combinations of different methods of purification absorption or adsorption, and catalytic conversion
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2370/00—Selection of materials for exhaust purification
    • F01N2370/02—Selection of materials for exhaust purification used in catalytic reactors
    • F01N2370/04—Zeolitic material
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/18—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
    • F01N3/20—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion ; Methods of operation or control of catalytic converters
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02B—INTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
    • F02B1/00—Engines characterised by fuel-air mixture compression
    • F02B1/02—Engines characterised by fuel-air mixture compression with positive ignition
    • F02B1/04—Engines characterised by fuel-air mixture compression with positive ignition with fuel-air mixture admission into cylinder
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00—Road transport of goods or passengers
    • Y02T10/10—Internal combustion engine [ICE] based vehicles
    • Y02T10/12—Improving ICE efficiencies

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Biomedical Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Exhaust Gas After Treatment (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Catalysts (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Incineration Of Waste (AREA)
  • Cleaning Or Drying Semiconductors (AREA)
  • Nozzles For Electric Vacuum Cleaners (AREA)
  • Financial Or Insurance-Related Operations Such As Payment And Settlement (AREA)
  • Bakery Products And Manufacturing Methods Therefor (AREA)
  • Control Of Position, Course, Altitude, Or Attitude Of Moving Bodies (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention relates to an exhaust gas purification system for decreasing the emissions of hydrocarbons during the cold start of internal combustion engines. The exhaust gas purification system contains a hydrocarbon adsorber and a downstream catalyst system which can be composed of a single three-way catalyst or of a combination of oxidation, reduction and/or three-way catalysts in one or more beds. The hydrocarbon emissions during the cold start phase can be significantly decreased by using oxidation catalysts or three-way catalysts which, in comparison with conventional catalysts, have at least twice the loading of platinum and/or palladium.
CA002110139A 1992-11-27 1993-11-26 Exhaust gas purification system for reducing hydrocarbon emissions during the cold start of combustion engines Expired - Fee Related CA2110139C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DEP4239875.4 1992-11-27
DE4239875A DE4239875C2 (en) 1992-11-27 1992-11-27 Exhaust gas purification system to reduce hydrocarbon emissions during the cold start of internal combustion engines

Publications (2)

Publication Number Publication Date
CA2110139A1 true CA2110139A1 (en) 1994-05-28
CA2110139C CA2110139C (en) 1999-03-23

Family

ID=6473778

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002110139A Expired - Fee Related CA2110139C (en) 1992-11-27 1993-11-26 Exhaust gas purification system for reducing hydrocarbon emissions during the cold start of combustion engines

Country Status (18)

Country Link
EP (1) EP0601314B1 (en)
JP (1) JP3816113B2 (en)
KR (1) KR100283341B1 (en)
CN (1) CN1096712A (en)
AT (1) ATE157557T1 (en)
AU (1) AU666235B2 (en)
BR (1) BR9304864A (en)
CA (1) CA2110139C (en)
CZ (1) CZ288516B6 (en)
DE (2) DE4239875C2 (en)
ES (1) ES2108797T3 (en)
FI (1) FI104749B (en)
HU (1) HU212892B (en)
MX (1) MX9307424A (en)
NO (1) NO304502B1 (en)
PL (1) PL174499B1 (en)
TW (1) TW303307B (en)
ZA (1) ZA938864B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0716877A1 (en) 1994-12-13 1996-06-19 Johnson Matthey Public Limited Company Catalytic purification of engine exhaust gas

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5492679A (en) * 1993-03-08 1996-02-20 General Motors Corporation Zeolite/catalyst wall-flow monolith adsorber
DE4436890A1 (en) * 1994-10-15 1996-04-18 Degussa Process for the simultaneous reduction of the hydrocarbons, carbon monoxide and nitrogen oxides contained in the exhaust gas of an internal combustion engine
US5510086A (en) * 1995-04-10 1996-04-23 General Motors Corporation Adcat exhaust treatment device
US6696389B1 (en) 1996-02-23 2004-02-24 Daimlerchrysler Ag Process and apparatus for cleaning a gas flow
DE19614540A1 (en) * 1996-04-12 1997-10-16 Degussa Diesel catalyst
EP0842700B1 (en) * 1996-11-11 1999-03-24 Degussa Ag Exhaust gas purifying catalyst with improved hydrocarbon conversion
JP3417309B2 (en) * 1997-10-28 2003-06-16 トヨタ自動車株式会社 Hydrocarbon adsorbent
DE19881838D2 (en) 1997-11-30 2001-11-08 Wwu Wissenschaftliche Werkstat Measurement of pollutant components in the exhaust gas and reduction of excessive pollutant emissions during cold starts and driving
WO2000024507A1 (en) * 1998-10-28 2000-05-04 Toyota Jidosha Kabushiki Kaisha Adsorbent for hydrocarbon and catalyst for exhaust gas purification
DE10023049B4 (en) * 2000-05-11 2008-04-30 Volkswagen Ag Method for determining a mounting point of a precatalyst in the exhaust line of the internal combustion engine
ES2182721B1 (en) * 2001-07-27 2004-01-16 Univ Valencia Politecnica A CATALYTIC SYSTEM TO DECREASE EMISSIONS OF VOLATILE ORGANIC COMPOUNDS IN COMBUSTION GASES.
FR2841937B1 (en) 2002-07-08 2006-07-14 Faurecia Sys Echappement MECHANICAL POWER GENERATOR COMPRISING A DIESEL ENGINE AND A CATALYTIC CONVERTER
JP4507018B2 (en) * 2008-06-27 2010-07-21 三菱自動車工業株式会社 Exhaust gas purification device for internal combustion engine
DE102013210270A1 (en) 2013-06-03 2014-12-04 Umicore Ag & Co. Kg three-way
WO2015066312A1 (en) 2013-10-30 2015-05-07 Johnson Mathew Public Limited Comapny Three-way catalyst comprising a silver-containing extruded zeolite substrate and its use in exhaust systems
DE102014204682A1 (en) 2014-03-13 2015-10-01 Umicore Ag & Co. Kg Catalyst system for reducing noxious gases from gasoline internal combustion engines
CN104307476A (en) * 2014-11-05 2015-01-28 上海纳米技术及应用国家工程研究中心有限公司 Method for preparation of low-concentration carbureted hydrogen gas adsorbing agent
CN114308033A (en) 2015-06-29 2022-04-12 康宁股份有限公司 Reduced emissions porous ceramic body
US9987626B2 (en) * 2015-08-20 2018-06-05 Ford Global Technologies, Llc Use of transition metals to reduce cold start emissions
US9879587B2 (en) * 2015-10-23 2018-01-30 GM Global Technology Operations LLC Diagnosing oxidation catalyst device with hydrocarbon storage
US10898886B2 (en) * 2016-08-26 2021-01-26 Ford Global Technologies, Llc Hydrocarbon and nitrogen oxides catalyst trap

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0615016B2 (en) * 1988-09-09 1994-03-02 トヨタ自動車株式会社 Automotive exhaust gas purification device
JPH0625538B2 (en) * 1989-10-24 1994-04-06 ニチアス株式会社 Exhaust gas purification device for methanol engine
JPH03141816A (en) * 1989-10-27 1991-06-17 Toyota Motor Corp Exhaust gas purifier
US5078979A (en) * 1990-07-20 1992-01-07 Uop Molecular sieve bed/catalyst to treat automotive exhaust
US5296198A (en) * 1990-11-09 1994-03-22 Ngk Insulators, Ltd. Heater and catalytic converter
DE4236271C2 (en) * 1991-10-28 1994-09-22 Toyota Motor Co Ltd Exhaust emission control device using a catalytic converter with a hydrocarbon adsorbent
DE4226394C2 (en) * 1992-08-10 1999-01-21 Degussa Process for catalytic exhaust gas cleaning with improved cold start behavior

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0716877A1 (en) 1994-12-13 1996-06-19 Johnson Matthey Public Limited Company Catalytic purification of engine exhaust gas

Also Published As

Publication number Publication date
JP3816113B2 (en) 2006-08-30
PL174499B1 (en) 1998-08-31
KR100283341B1 (en) 2001-03-02
CN1096712A (en) 1994-12-28
AU5198893A (en) 1994-06-09
CZ255993A3 (en) 1994-06-15
AU666235B2 (en) 1996-02-01
FI935278A0 (en) 1993-11-26
ZA938864B (en) 1994-08-02
NO934269D0 (en) 1993-11-25
ATE157557T1 (en) 1997-09-15
ES2108797T3 (en) 1998-01-01
NO304502B1 (en) 1999-01-04
HU212892B (en) 1996-12-30
CZ288516B6 (en) 2001-07-11
FI935278A (en) 1994-05-28
JPH06210136A (en) 1994-08-02
PL301228A1 (en) 1994-05-30
EP0601314A1 (en) 1994-06-15
CA2110139C (en) 1999-03-23
DE4239875A1 (en) 1994-06-01
DE59307263D1 (en) 1997-10-09
EP0601314B1 (en) 1997-09-03
HUT70018A (en) 1995-09-28
NO934269L (en) 1994-05-30
BR9304864A (en) 1994-05-31
HU9303345D0 (en) 1994-03-28
DE4239875C2 (en) 1999-02-11
FI104749B (en) 2000-03-31
TW303307B (en) 1997-04-21
MX9307424A (en) 1994-07-29

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