CA2088114A1 - Catalyst and process for the polymerization and copolymerization of olefins - Google Patents

Catalyst and process for the polymerization and copolymerization of olefins

Info

Publication number
CA2088114A1
CA2088114A1 CA002088114A CA2088114A CA2088114A1 CA 2088114 A1 CA2088114 A1 CA 2088114A1 CA 002088114 A CA002088114 A CA 002088114A CA 2088114 A CA2088114 A CA 2088114A CA 2088114 A1 CA2088114 A1 CA 2088114A1
Authority
CA
Canada
Prior art keywords
formula
group
compound
metallocene
cocatalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA002088114A
Other languages
English (en)
French (fr)
Inventor
Andreas Winter
Volker Dolle
Walter Spaleck
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoechst AG
Original Assignee
Hoechst AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=6450335&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=CA2088114(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Hoechst AG filed Critical Hoechst AG
Publication of CA2088114A1 publication Critical patent/CA2088114A1/en
Abandoned legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/61922Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/61927Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
CA002088114A 1992-01-27 1993-01-26 Catalyst and process for the polymerization and copolymerization of olefins Abandoned CA2088114A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4202163 1992-01-27
DEP4202163.4 1992-01-27

Publications (1)

Publication Number Publication Date
CA2088114A1 true CA2088114A1 (en) 1993-07-28

Family

ID=6450335

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002088114A Abandoned CA2088114A1 (en) 1992-01-27 1993-01-26 Catalyst and process for the polymerization and copolymerization of olefins

Country Status (11)

Country Link
US (1) US5985784A (US06818585-20041116-C00001.png)
EP (1) EP0553757B1 (US06818585-20041116-C00001.png)
JP (1) JP3459272B2 (US06818585-20041116-C00001.png)
KR (1) KR100268539B1 (US06818585-20041116-C00001.png)
AT (1) ATE143384T1 (US06818585-20041116-C00001.png)
AU (1) AU669684B2 (US06818585-20041116-C00001.png)
CA (1) CA2088114A1 (US06818585-20041116-C00001.png)
DE (1) DE59303908D1 (US06818585-20041116-C00001.png)
ES (1) ES2093287T3 (US06818585-20041116-C00001.png)
TW (1) TW304963B (US06818585-20041116-C00001.png)
ZA (1) ZA93548B (US06818585-20041116-C00001.png)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5840645A (en) * 1992-08-06 1998-11-24 Mitsui Petrochemical Industries, Ltd. Olefin polymerization catalyst and method for the polymerization of olefin using said olefin polymerization catalyst

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW298593B (US06818585-20041116-C00001.png) * 1993-02-12 1997-02-21 Hoechst Ag
US6211109B1 (en) 1995-07-18 2001-04-03 Fina Technology, Inc. Process for treating silica with alumoxane
US6034192A (en) * 1998-12-30 2000-03-07 Univation Technologies, Llc Germanium bridged metallocenes producing polymers with increased melt strength
US6818585B2 (en) 1998-12-30 2004-11-16 Univation Technologies, Llc Catalyst compounds, catalyst systems thereof and their use in a polymerization process
DE19922020A1 (de) * 1999-05-12 2000-11-16 Targor Gmbh Übergangsmetallverbindung, Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen
US6444765B1 (en) * 2000-06-14 2002-09-03 Equistar Chemicals, Lp Olefin polymerization process for producing broad MWD polymers
JP3964867B2 (ja) * 2001-08-07 2007-08-22 電気化学工業株式会社 重合体の製造方法
CA2499951C (en) 2002-10-15 2013-05-28 Peijun Jiang Multiple catalyst system for olefin polymerization and polymers produced therefrom
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
AU2003293887A1 (en) 2002-12-16 2004-07-09 Basell Polyolefine Gmbh Preparation of supported catalyst systems containing reduced amounts of aluminoxanes
EP2195112B1 (en) 2007-08-29 2017-03-01 Albemarle Corporation Aluminoxane catalyst activators derived from dialkylaluminum cation precursor agents and use thereof in catalysts and polymerization of olefins
BRPI0703586B1 (pt) 2007-10-19 2018-02-06 Braskem S.A Catalisador metaloceno suportado, e, copolímeros de etileno com alfa-olefinas de alto e ultra alto peso molecular
WO2022035132A1 (ko) * 2020-08-12 2022-02-17 주식회사 엘지화학 메탈로센 담지 촉매의 제조 방법, 메탈로센 담지 촉매 및 이를 이용한 폴리올레핀의 제조 방법

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3709853A (en) * 1971-04-29 1973-01-09 Union Carbide Corp Polymerization of ethylene using supported bis-(cyclopentadienyl)chromium(ii)catalysts
DE3443087A1 (de) * 1984-11-27 1986-05-28 Hoechst Ag, 6230 Frankfurt Verfahren zur herstellung von polyolefinen
US4701432A (en) * 1985-11-15 1987-10-20 Exxon Chemical Patents Inc. Supported polymerization catalyst
US4794096A (en) * 1987-04-03 1988-12-27 Fina Technology, Inc. Hafnium metallocene catalyst for the polymerization of olefins
JP2538588B2 (ja) * 1987-04-03 1996-09-25 三井石油化学工業株式会社 オレフイン重合用固体触媒の製法
EP0314797B1 (en) * 1987-04-20 1997-07-02 Mitsui Petrochemical Industries, Ltd. Olefin polymerization catalyst and process for polymerizing olefin
DE3726067A1 (de) * 1987-08-06 1989-02-16 Hoechst Ag Verfahren zur herstellung von 1-olefinpolymeren
DE3742934A1 (de) 1987-12-18 1989-06-29 Hoechst Ag Verfahren zur herstellung einer chiralen, stereorigiden metallocen-verbindung
DE3743321A1 (de) 1987-12-21 1989-06-29 Hoechst Ag 1-olefinpolymerwachs und verfahren zu seiner herstellung
DE3907965A1 (de) * 1989-03-11 1990-09-13 Hoechst Ag Verfahren zur herstellung eines syndiotaktischen polyolefins
EP0427697B1 (en) * 1989-10-10 1996-05-08 Fina Technology, Inc. Metallocene catalysts with Lewis acids and aluminum alkyls
JP2927885B2 (ja) * 1990-05-24 1999-07-28 三井化学株式会社 シンジオタクチックポリα―オレフィンの製造方法
WO1992009640A1 (en) * 1990-11-30 1992-06-11 Idemitsu Kosan Co., Ltd. Process for producing olefinic polymer
CA2069995C (en) * 1991-05-31 1996-04-09 Mitsui Chemicals, Incorporated Olefin polymerization solid catalyst, olefin polymerization catalyst and olefin polymerization
US5308817A (en) * 1992-05-18 1994-05-03 Fina Technology, Inc. Metallocene catalyst component with good catalyst efficiency after aging
US5498582A (en) * 1993-12-06 1996-03-12 Mobil Oil Corporation Supported metallocene catalysts for the production of polyolefins

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5840645A (en) * 1992-08-06 1998-11-24 Mitsui Petrochemical Industries, Ltd. Olefin polymerization catalyst and method for the polymerization of olefin using said olefin polymerization catalyst

Also Published As

Publication number Publication date
DE59303908D1 (de) 1996-10-31
EP0553757A1 (de) 1993-08-04
AU3199693A (en) 1993-07-29
ZA93548B (en) 1993-08-05
AU669684B2 (en) 1996-06-20
TW304963B (US06818585-20041116-C00001.png) 1997-05-11
EP0553757B1 (de) 1996-09-25
ES2093287T3 (es) 1996-12-16
KR930016446A (ko) 1993-08-26
ATE143384T1 (de) 1996-10-15
JPH06122706A (ja) 1994-05-06
KR100268539B1 (ko) 2000-10-16
US5985784A (en) 1999-11-16
JP3459272B2 (ja) 2003-10-20

Similar Documents

Publication Publication Date Title
US5612428A (en) Process for preparing olefin polymer with catalyst containing metallocene
AU648172B2 (en) Process for the preparation of syndiotactic polyolefins having a broad molecular weight distribution
US4914253A (en) Method for preparing polyethylene wax by gas phase polymerization
EP0664304B1 (en) Olefin polymerization catalyst and process for olefin polymerization
AU630451B2 (en) Process for the preparation of ethylene polymers
US6713426B1 (en) Metallocene capable of being used for the process for the preparation of a syndiotactic polyolefin
US6197902B1 (en) Syndio-isoblock polymer and process for its preparation
KR100244381B1 (ko) α-올레핀 중합체의 제조방법
US5741868A (en) Olefin polymerization process by using a substituted indenyl containing metallocene catalyst
US5962719A (en) Process for the preparation of a polyolefin wax
JP3453580B2 (ja) オレフィンの重合法
CA2136493A1 (en) Metallocenes, process for their preparation and their use as catalysts
CA2069602A1 (en) Process for the preparation of polyolefins having a broad molecular weight distribution
CA2133181A1 (en) Process for the preparation of polyolefins
JPH0632830A (ja) 触媒系の調製法、オレフィンの単独重合及び共重合法並びに少なくとも一種のオレフィンのポリマー及びコポリマー
CA2042324A1 (en) Process for the preparation of a polyolefin
CA1319785C (en) Process for the preparation of 1-olefin polymers
CA2088114A1 (en) Catalyst and process for the polymerization and copolymerization of olefins
JPH05331230A (ja) 高分子量ポリオレフィンの製造用触媒および製造方法
JP3751344B2 (ja) メタロセン化合物
JPH06345816A (ja) 固体触媒成分およびこれを用いたオレフィンの重合方法
JPH07233211A (ja) オレフィン重合用触媒およびオレフィンの重合方法
JPH07247309A (ja) 新規遷移金属化合物およびこれを用いたオレフィンの重合方法
JPH06239913A (ja) オレフィン重合触媒およびオレフィンの重合方法
JPH0551408A (ja) シンジオタクチツクポリ−α−オレフイン製造用触媒およびシンジオタクチツクポリ−α−オレフインの製造方法

Legal Events

Date Code Title Description
FZDE Discontinued