CA2063375A1 - Composante catalytique pour l'obtention d'elastomeres de polypropylene ou de polybutene, principalement isotactiques - Google Patents
Composante catalytique pour l'obtention d'elastomeres de polypropylene ou de polybutene, principalement isotactiquesInfo
- Publication number
- CA2063375A1 CA2063375A1 CA2063375A CA2063375A CA2063375A1 CA 2063375 A1 CA2063375 A1 CA 2063375A1 CA 2063375 A CA2063375 A CA 2063375A CA 2063375 A CA2063375 A CA 2063375A CA 2063375 A1 CA2063375 A1 CA 2063375A1
- Authority
- CA
- Canada
- Prior art keywords
- polybutene
- catalyst component
- elastomeric polypropylene
- primarily isotactic
- elastomeric
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003054 catalyst Substances 0.000 title abstract 4
- -1 polypropylene Polymers 0.000 title abstract 4
- 239000004743 Polypropylene Substances 0.000 title abstract 2
- 229920001083 polybutene Polymers 0.000 title abstract 2
- 229920001155 polypropylene Polymers 0.000 title abstract 2
- ABDKAPXRBAPSQN-UHFFFAOYSA-N veratrole Chemical compound COC1=CC=CC=C1OC ABDKAPXRBAPSQN-UHFFFAOYSA-N 0.000 abstract 2
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 229910052749 magnesium Inorganic materials 0.000 abstract 1
- 239000011777 magnesium Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
- 239000010936 titanium Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/08—Butenes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
L'invention concerne un composant de catalyseur ainsi qu'une composition de catalyseurs utiles dans la production de polypropylène et de polybutène élastomères principalement isotactiques, comprenant le produit de réaction d'un composé d'alkoxyde de magnésium et d'un halogénure de titane tétravalent, la réaction ayant lieu en présence d'un donneur d'électrons choisi dans le groupe composé de vératrol et de dérivés de celui-ci. L'invention concerne également un procédé de production desdits polymères à l'aide du catalyseur précité.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US377,654 | 1989-07-10 | ||
US07/377,654 US4971936A (en) | 1989-07-10 | 1989-07-10 | Catalyst component for making primarily isotactic elastomeric polypropylene or polybutene |
PCT/US1990/002037 WO1991000875A1 (fr) | 1989-07-10 | 1990-04-19 | Composant de catalyseur pour la fabrication de polypropylene ou de polybutene elastomeres principalement isotactiques |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2063375A1 true CA2063375A1 (fr) | 1991-01-11 |
CA2063375C CA2063375C (fr) | 2000-04-11 |
Family
ID=23490009
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002063375A Expired - Fee Related CA2063375C (fr) | 1989-07-10 | 1990-04-19 | Composante catalytique pour l'obtention d'elastomeres de polypropylene ou de polybutene, principalement isotactiques |
Country Status (10)
Country | Link |
---|---|
US (1) | US4971936A (fr) |
EP (1) | EP0500530B1 (fr) |
JP (1) | JPH05501120A (fr) |
KR (1) | KR0165560B1 (fr) |
AT (1) | ATE142650T1 (fr) |
AU (1) | AU630726B2 (fr) |
CA (1) | CA2063375C (fr) |
DE (1) | DE69028546T2 (fr) |
ES (1) | ES2095877T3 (fr) |
WO (1) | WO1991000875A1 (fr) |
Families Citing this family (34)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2241244B (en) * | 1990-02-22 | 1994-07-06 | James C W Chien | Thermoplastic elastomers |
US5089573A (en) * | 1990-02-26 | 1992-02-18 | Shell Oil Company | Process for the production of elastomeric, primarily isotactic polyolefins and catalysts for use in said process |
US5118649A (en) * | 1990-02-26 | 1992-06-02 | Shell Oil Company | Process for the production of elastomeric primarily isotactic polyolefins and catalysts for use in said process |
US5118767A (en) * | 1990-02-26 | 1992-06-02 | Shell Oil Company | Process for producing mildly elastomeric primarily isotatic polypropylene and poly-1-butene |
US5164352A (en) * | 1990-05-11 | 1992-11-17 | Shell Oil Company | Process for the production of elastomeric, primarily isotactic polyolefins and catalysts for use in said process |
USH1583H (en) * | 1993-06-01 | 1996-08-06 | Shell Oil Company | Elastomeric polybutylene polymer |
WO1996020225A2 (fr) * | 1994-12-20 | 1996-07-04 | Montell Technology Company B.V. | Polypropylene issu d'un melange en reacteur, procede de preparation correspondant et procede de preparation de ligands metallocenes |
USH1722H (en) * | 1995-05-05 | 1998-04-07 | Goode; Mark Gregory | Process for producing polypropylene impact block copolymers |
US5968865A (en) * | 1997-12-10 | 1999-10-19 | Union Carbide Chemicals & Plastics Technology Corporation | Electron donor containing compositions |
US6124507A (en) * | 1997-12-10 | 2000-09-26 | Union Carbide Chemicals & Plastics Technology Corporation | Electron donors |
US6100337A (en) | 1998-05-18 | 2000-08-08 | Shell Oil Company | Functionalized thermoplastic elastomer |
JP4571798B2 (ja) * | 2001-06-12 | 2010-10-27 | バーゼル・ポリオレフィン・ゲーエムベーハー | 1−ブテンの重合方法 |
WO2003064488A1 (fr) * | 2002-01-31 | 2003-08-07 | Mitsubishi Chemical Corporation | Composition de resine propylene non rigide |
US6897276B2 (en) * | 2002-04-24 | 2005-05-24 | Symyx Technologies, Inc. | Bridged bi-aromatic ligands, catalysts, processes for polymerizing and polymers therefrom |
US7091292B2 (en) * | 2002-04-24 | 2006-08-15 | Symyx Technologies, Inc. | Bridged bi-aromatic catalysts, complexes, and methods of using the same |
US7060848B2 (en) * | 2002-04-24 | 2006-06-13 | Symyx Technologies, Inc. | Bridged bi-aromatic catalysts, complexes, and methods of using the same |
US7589160B2 (en) * | 2002-12-04 | 2009-09-15 | Basell Polyolefine Gmbh | Process for preparing 1-butene polymers |
US7534848B2 (en) * | 2002-12-04 | 2009-05-19 | Basell Polyolefine Gmbh | 1-butene copolymers and process for preparing them |
EP1735360B1 (fr) | 2004-03-17 | 2013-09-11 | Dow Global Technologies LLC | Compositions catalytiques de formation de copolymeres d'ethlyene contenant un agent navette |
US7858706B2 (en) * | 2004-03-17 | 2010-12-28 | Dow Global Technologies Inc. | Catalyst composition comprising shuttling agent for ethylene multi-block copolymer formation |
ES2342895T3 (es) | 2004-03-17 | 2010-07-16 | Dow Global Technologies Inc. | Composicion catalitica que comprende agente de transferencia para la formacion de copolimero de multiples bloques de etileno. |
AR048104A1 (es) * | 2004-03-17 | 2006-03-29 | Dow Global Technologies Inc | Composicion catalizadora que comprende un agente de enlace para la formacion de copolimeros superiores de olefina en bloques multiples |
US7387980B2 (en) | 2004-09-22 | 2008-06-17 | Symyx Technologies, Inc. | Methods of using heterocycle-amine ligands, compositions, complexes, and catalysts |
US7256296B2 (en) * | 2004-09-22 | 2007-08-14 | Symyx Technologies, Inc. | Heterocycle-amine ligands, compositions, complexes, and catalysts |
WO2006066126A2 (fr) * | 2004-12-16 | 2006-06-22 | Symyx Technologies, Inc. | Ligands heterocycliques de phenol, complexes metalliques et leurs utilisations en tant que catalyseurs |
JP2008533276A (ja) | 2005-03-17 | 2008-08-21 | ダウ グローバル テクノロジーズ インコーポレイティド | タクチック/アタクチックマルチブロックコポリマー形成用の可逆的移動剤を含む触媒組成物 |
MX2007011340A (es) | 2005-03-17 | 2007-10-03 | Dow Global Technologies Inc | Composicion de catalizador que comprende un agente de transporte para la formacion de copolimero de bloques multiples regio-irregular. |
US9410009B2 (en) | 2005-03-17 | 2016-08-09 | Dow Global Technologies Llc | Catalyst composition comprising shuttling agent for tactic/ atactic multi-block copolymer formation |
US8281332B2 (en) * | 2007-05-02 | 2012-10-02 | Google Inc. | Animated video overlays |
US20090286944A1 (en) * | 2008-05-15 | 2009-11-19 | Symyx Technologies, Inc. | Select phenol-heterocycle ligands, metal complexes formed therefrom, and their uses as catalysts |
KR101717310B1 (ko) * | 2009-04-16 | 2017-03-16 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 1-부텐 중합체의 제조 방법 |
DE102012222035B4 (de) | 2012-12-03 | 2019-10-31 | Robert Bosch Gmbh | Verfahren zum Betreiben eines Systems zur Energierückgewinnung aus einem Abwärmestrom einer Brennkraftmaschine |
JP6124648B2 (ja) | 2013-03-28 | 2017-05-10 | 住友化学株式会社 | 共役ジエン系重合体の製造方法 |
US11292899B2 (en) * | 2017-06-30 | 2022-04-05 | Mitsui Chemicals, Inc. | Propylene-based polymer, method for producing the same, propylene-based resin composition and molded article |
Family Cites Families (36)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3112301A (en) * | 1963-11-26 | Table | ||
NO90003A (fr) * | 1953-11-17 | |||
IT557911A (fr) * | 1954-06-08 | 1900-01-01 | ||
IT609922A (fr) * | 1959-06-06 | |||
NL273776A (fr) * | 1961-01-30 | |||
US3305538A (en) * | 1961-11-22 | 1967-02-21 | Montedison Spa | Polymerization process |
US3329741A (en) * | 1963-05-08 | 1967-07-04 | Rexall Drug Chemical | Process for preparing rubbery polymers with a catalyst comprising ti(or)4 |
US3335121A (en) * | 1963-07-03 | 1967-08-08 | Montedison Spa | Polymerization process |
US3364190A (en) * | 1964-04-27 | 1968-01-16 | Standard Oil Co | Process for polymerizing propylene to syndiotactic polypropylene |
US4226963A (en) * | 1971-06-25 | 1980-10-07 | Montedison S.P.A. | Process for the stereoregular polymerization of alpha-olephins |
NL160286C (fr) * | 1971-06-25 | |||
US4107413A (en) * | 1971-06-25 | 1978-08-15 | Montedison S.P.A. | Process for the stereoregular polymerization of alpha olefins |
US4107414A (en) * | 1971-06-25 | 1978-08-15 | Montecatini Edison S.P.A. | Process for the stereoregular polymerization of alpha olefins |
GB1486194A (en) * | 1973-12-04 | 1977-09-21 | Ici Ltd | Olefine polymer olefine polymerisation process and catalyst |
IE40215B1 (en) * | 1973-12-04 | 1979-04-11 | Ici Ltd | Olefine polymer, olefine polymerisation process and catalyst |
US3932307A (en) * | 1974-05-20 | 1976-01-13 | E. I. Du Pont De Nemours And Company | Tetra(neophyl) zirconium and its use in process for the polymerization of olefins |
US4011383A (en) * | 1974-05-20 | 1977-03-08 | E. I. Du Pont De Nemours And Company | Tetra(neophyl) zirconium and its use in process for the polymerization of olefins |
US3971767A (en) * | 1974-05-20 | 1976-07-27 | E. I. Du Pont De Nemours And Company | Olefin polymerization catalyst system and process for polymerization of olefins |
US3950269A (en) * | 1974-05-20 | 1976-04-13 | E. I. Du Pont De Nemours & Co. | Olefin polymerization catalyst system and process for polymerization of olefins |
US4017525A (en) * | 1975-05-20 | 1977-04-12 | E. I. Dupont De Nemours And Company | Tetra(neophyl) zirconium |
JPS5952166B2 (ja) * | 1976-06-29 | 1984-12-18 | 三井化学株式会社 | ポリオレフインの製造方法 |
US4335225A (en) * | 1978-06-20 | 1982-06-15 | E. I. Du Pont De Nemours And Company | Elastomeric polypropylene |
DE3064564D1 (en) * | 1979-04-30 | 1983-09-22 | Shell Int Research | Olefin polymerization catalyst compositions and a process for the polymerization of olefins employing such compositions |
FR2460964A1 (fr) * | 1979-07-06 | 1981-01-30 | Naphtachimie Sa | Copolymeres elastomeres d'ethylene et de propylene, leur fabrication et leurs applications |
US4298722A (en) * | 1980-03-11 | 1981-11-03 | E. I. Du Pont De Nemours And Company | Fractionable, elastomeric poly (1-butene) |
US4487845A (en) * | 1980-05-09 | 1984-12-11 | Stauffer Chemical Company | Method of enhancing stereospecificity of a catalyst system |
US4347160A (en) * | 1980-06-27 | 1982-08-31 | Stauffer Chemical Company | Titanium halide catalyst system |
US4325836A (en) * | 1980-07-18 | 1982-04-20 | Stauffer Chemical Company | Novel titanium halide containing catalyst |
US4394291A (en) * | 1981-03-04 | 1983-07-19 | Phillips Petroleum Company | Polyolefin polymerization process and catalyst |
US4442276A (en) * | 1982-02-12 | 1984-04-10 | Mitsui Petrochemical Industries, Ltd. | Process for polymerizing or copolymerizing olefins |
US4451633A (en) * | 1982-08-19 | 1984-05-29 | Shell Oil Company | Olefin polymerization |
US4472521A (en) * | 1982-12-20 | 1984-09-18 | Stauffer Chemical Company | Supported catalyst for polymerization of olefins |
US4581342A (en) * | 1984-11-26 | 1986-04-08 | Standard Oil Company (Indiana) | Supported olefin polymerization catalyst |
USH179H (en) * | 1984-11-28 | 1986-12-02 | Polybutylene | |
JPH06104687B2 (ja) * | 1985-06-18 | 1994-12-21 | 東燃株式会社 | オレフイン重合用触媒 |
US4710482A (en) * | 1986-06-18 | 1987-12-01 | Shell Oil Company | Olefin polymerization catalyst component |
-
1989
- 1989-07-10 US US07/377,654 patent/US4971936A/en not_active Expired - Lifetime
-
1990
- 1990-04-19 KR KR1019920700045A patent/KR0165560B1/ko not_active IP Right Cessation
- 1990-04-19 DE DE69028546T patent/DE69028546T2/de not_active Expired - Fee Related
- 1990-04-19 CA CA002063375A patent/CA2063375C/fr not_active Expired - Fee Related
- 1990-04-19 JP JP2510077A patent/JPH05501120A/ja active Pending
- 1990-04-19 EP EP90911180A patent/EP0500530B1/fr not_active Expired - Lifetime
- 1990-04-19 AU AU59618/90A patent/AU630726B2/en not_active Ceased
- 1990-04-19 WO PCT/US1990/002037 patent/WO1991000875A1/fr active IP Right Grant
- 1990-04-19 ES ES90911180T patent/ES2095877T3/es not_active Expired - Lifetime
- 1990-04-19 AT AT90911180T patent/ATE142650T1/de not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
ATE142650T1 (de) | 1996-09-15 |
EP0500530A1 (fr) | 1992-09-02 |
KR0165560B1 (ko) | 1999-03-20 |
JPH05501120A (ja) | 1993-03-04 |
AU5961890A (en) | 1991-02-06 |
US4971936A (en) | 1990-11-20 |
AU630726B2 (en) | 1992-11-05 |
ES2095877T3 (es) | 1997-03-01 |
DE69028546T2 (de) | 1997-02-27 |
CA2063375C (fr) | 2000-04-11 |
WO1991000875A1 (fr) | 1991-01-24 |
DE69028546D1 (de) | 1996-10-17 |
EP0500530A4 (fr) | 1992-05-14 |
KR927003651A (ko) | 1992-12-18 |
EP0500530B1 (fr) | 1996-09-11 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
EEER | Examination request | ||
MKLA | Lapsed |