CA2049118A1 - Hydrogenation selective de polymeres a base de diolefines conjuguees - Google Patents
Hydrogenation selective de polymeres a base de diolefines conjugueesInfo
- Publication number
- CA2049118A1 CA2049118A1 CA2049118A CA2049118A CA2049118A1 CA 2049118 A1 CA2049118 A1 CA 2049118A1 CA 2049118 A CA2049118 A CA 2049118A CA 2049118 A CA2049118 A CA 2049118A CA 2049118 A1 CA2049118 A1 CA 2049118A1
- Authority
- CA
- Canada
- Prior art keywords
- conjugated diolefin
- selective hydrogenation
- aralkyl
- aryl
- alkyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920000642 polymer Polymers 0.000 title abstract 5
- 150000001993 dienes Chemical class 0.000 title abstract 3
- 238000005984 hydrogenation reaction Methods 0.000 title abstract 3
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 2
- 125000003118 aryl group Chemical group 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- -1 organo alkali metal Chemical class 0.000 abstract 2
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 125000003545 alkoxy group Chemical group 0.000 abstract 1
- 150000001412 amines Chemical group 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000007334 copolymerization reaction Methods 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical group 0.000 abstract 1
- 150000002431 hydrogen Chemical class 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 125000001181 organosilyl group Chemical group [SiH3]* 0.000 abstract 1
- 239000003505 polymerization initiator Substances 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/02—Hydrogenation
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Graft Or Block Polymers (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US568,113 | 1990-08-15 | ||
US07/568,113 US5141997A (en) | 1990-08-15 | 1990-08-15 | Selective hydrogenation of conjugated diolefin polymers |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2049118A1 true CA2049118A1 (fr) | 1992-02-16 |
CA2049118C CA2049118C (fr) | 2000-09-26 |
Family
ID=24269965
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002049118A Expired - Fee Related CA2049118C (fr) | 1990-08-15 | 1991-08-13 | Hydrogenation selective de polymeres a base de diolefines conjuguees |
Country Status (8)
Country | Link |
---|---|
US (1) | US5141997A (fr) |
EP (1) | EP0471415B1 (fr) |
JP (1) | JP2991824B2 (fr) |
KR (1) | KR100214404B1 (fr) |
BR (1) | BR9103459A (fr) |
CA (1) | CA2049118C (fr) |
DE (1) | DE69110990T2 (fr) |
ES (1) | ES2074648T3 (fr) |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5583185A (en) * | 1992-11-03 | 1996-12-10 | Repsol Quimica S.A. | Process for hydrogenation in solution of the double bonds of conjugated dienes, and hydrogenated block copolymer produced |
US5244980A (en) * | 1992-12-07 | 1993-09-14 | Shell Oil Company | Selective hydrogenation of conjugated diolefin polymers with Tebbe's reagent |
FI97141C (fi) * | 1994-03-14 | 1996-10-25 | Neste Oy | Menetelmä tyydyttämättömien polymeerien selektiiviseksi hydrogenoimiseksi |
AU4419496A (en) * | 1994-12-12 | 1996-07-03 | Dow Chemical Company, The | Hydrogenation of unsaturated polymers using monocyclopentadienyl group iv metal catalysts |
CN1130383C (zh) * | 1996-03-15 | 2003-12-10 | 国际壳牌研究有限公司 | 共轭二烯聚合物的氢化方法及其适用的催化剂组合物 |
US5814709A (en) * | 1996-04-12 | 1998-09-29 | Shell Oil Company | Process for hydrogenation on conjugataed diene polymers and catalyst composition suitable for use therein |
JPH10101727A (ja) * | 1996-09-24 | 1998-04-21 | Shell Internatl Res Maatschappij Bv | オレフィン又はポリマーを水素化するための触媒及び方法 |
TW583027B (en) * | 1998-10-30 | 2004-04-11 | Shell Int Research | A method for preparing a hydrogenation catalyst system |
WO2001004164A2 (fr) * | 1999-07-09 | 2001-01-18 | The Dow Chemical Company | Hydrogenation de polymeres insatures a l'aide de diolefine bivalente contenant des catalyseurs metalliques biscyclopentadienyl du groupe iv |
KR100356533B1 (ko) * | 2000-02-09 | 2002-10-18 | 금호석유화학 주식회사 | 공액디엔 중합체의 선택적 수소화 방법 |
BR0113490A (pt) * | 2000-08-25 | 2003-07-15 | Kraton Polymers Res Bv | Método para preparar copolìmeros em bloco seletivamente hidrogenados de hidrocarbonetos aromáticos de vinila e dienos conjugados, e, copolìmero em bloco de um hidrocarboneto aromático de vinila e um dieno conjugado |
ES2185467B2 (es) * | 2000-12-20 | 2004-10-01 | Chi Mei Corporation | Composicion catalizadora para hidrogenacion de cauchos sinteticos a base de dieno conjugado. |
ITMI20022055A1 (it) * | 2002-09-27 | 2004-03-28 | Enitecnologie Spa | Procedimento per la idrogenazione di omopolimeri e copolimeri di dieni coniugati. |
CN101423569B (zh) * | 2007-11-02 | 2010-12-08 | 中国石油化工集团公司 | 一种苯乙烯/共轭二烯烃聚合物选择加氢的方法 |
Family Cites Families (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB363810A (en) * | 1930-12-11 | 1931-12-31 | Ig Farbenindustrie Ag | Improvements in the polymerisation of diolefines |
US2449949A (en) * | 1944-09-04 | 1948-09-21 | Shell Dev | Hydrogenated linear polymers and copolymers of branch-chain hexadienes |
US3113986A (en) * | 1962-01-08 | 1963-12-10 | Hercules Powder Co Ltd | Hydrogenation of unsaturated hydrocarbons |
US3475399A (en) * | 1966-04-26 | 1969-10-28 | Standard Oil Co | Saturation of polyalkylenes |
US3580897A (en) * | 1967-11-27 | 1971-05-25 | Bridgestone Tire Co Ltd | Process for producing hydrogenated hydrocarbon polymers |
US3525729A (en) * | 1967-12-04 | 1970-08-25 | Phillips Petroleum Co | Process for production of polymers with controlled saturation |
US3472829A (en) * | 1968-06-10 | 1969-10-14 | Exxon Research Engineering Co | Process for broadening the molecular weight distribution in polymers |
US3541064A (en) * | 1968-07-11 | 1970-11-17 | Bridgestone Tire Co Ltd | Hydrogenation catalysts and a process for hydrogenating polymers by the use of them |
US3720654A (en) * | 1971-05-21 | 1973-03-13 | Cities Service Co | Molecular sizing process for preparing low molecular isobutylene-conjugated polyene copolymers |
GB1419012A (en) * | 1973-03-29 | 1975-12-24 | Ici Ltd | Production of polyethylene |
US3937759A (en) * | 1974-05-01 | 1976-02-10 | Shell Oil Company | Hydrogenation process |
US4156673A (en) * | 1976-02-10 | 1979-05-29 | Shell Oil Company | Hydrogenated star-shaped polymer |
FR2480289A1 (fr) * | 1980-04-09 | 1981-10-16 | Michelin & Cie | Procede de preparation de polymeres de dienes conjugues ou de copolymeres de dienes conjugues soit entre eux, soit avec un compose |
GB2134909B (en) * | 1983-01-20 | 1986-08-20 | Asahi Chemical Ind | Catalytic hydrogenation of conjugated diene polymer |
US4547555A (en) * | 1983-09-01 | 1985-10-15 | Mobil Oil Corporation | Method for rapid kill gas injection to gas phase polymerization reactors during power failures |
JPS60220147A (ja) * | 1984-04-18 | 1985-11-02 | Asahi Chem Ind Co Ltd | オレフイン水添触媒および該触媒を用いた重合体の水添方法 |
US4629767A (en) * | 1985-07-12 | 1986-12-16 | Phillips Petroleum Co. | Hydrogenation process and catalyst |
JPS62209103A (ja) * | 1986-03-10 | 1987-09-14 | Asahi Chem Ind Co Ltd | ポリマ−の水添方法 |
JPS62209102A (ja) * | 1986-03-10 | 1987-09-14 | Asahi Chem Ind Co Ltd | ポリマ−の水添法 |
JP2718059B2 (ja) * | 1988-04-28 | 1998-02-25 | 日本合成ゴム株式会社 | 重合体の水素添加方法および触媒 |
-
1990
- 1990-08-15 US US07/568,113 patent/US5141997A/en not_active Expired - Lifetime
-
1991
- 1991-08-12 ES ES91202069T patent/ES2074648T3/es not_active Expired - Lifetime
- 1991-08-12 EP EP91202069A patent/EP0471415B1/fr not_active Expired - Lifetime
- 1991-08-12 DE DE69110990T patent/DE69110990T2/de not_active Expired - Fee Related
- 1991-08-12 KR KR1019910013879A patent/KR100214404B1/ko not_active IP Right Cessation
- 1991-08-13 CA CA002049118A patent/CA2049118C/fr not_active Expired - Fee Related
- 1991-08-13 BR BR919103459A patent/BR9103459A/pt not_active IP Right Cessation
- 1991-08-13 JP JP3202974A patent/JP2991824B2/ja not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
KR920004429A (ko) | 1992-03-27 |
BR9103459A (pt) | 1992-05-05 |
CA2049118C (fr) | 2000-09-26 |
KR100214404B1 (ko) | 1999-08-02 |
ES2074648T3 (es) | 1995-09-16 |
EP0471415B1 (fr) | 1995-07-05 |
DE69110990T2 (de) | 1995-11-30 |
EP0471415A1 (fr) | 1992-02-19 |
JPH04248815A (ja) | 1992-09-04 |
US5141997A (en) | 1992-08-25 |
DE69110990D1 (de) | 1995-08-10 |
JP2991824B2 (ja) | 1999-12-20 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
EEER | Examination request | ||
MKLA | Lapsed |