CA2014485A1 - Process for the production of titanium dioxide - Google Patents
Process for the production of titanium dioxideInfo
- Publication number
- CA2014485A1 CA2014485A1 CA002014485A CA2014485A CA2014485A1 CA 2014485 A1 CA2014485 A1 CA 2014485A1 CA 002014485 A CA002014485 A CA 002014485A CA 2014485 A CA2014485 A CA 2014485A CA 2014485 A1 CA2014485 A1 CA 2014485A1
- Authority
- CA
- Canada
- Prior art keywords
- fraction
- hydrolysis
- hydrolyzate
- sulfuric acid
- process according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 238000000034 method Methods 0.000 title claims abstract description 50
- 230000008569 process Effects 0.000 title claims abstract description 50
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 title claims abstract description 30
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 12
- 239000004408 titanium dioxide Substances 0.000 title claims abstract description 9
- 239000002253 acid Substances 0.000 claims abstract description 42
- 239000002699 waste material Substances 0.000 claims abstract description 37
- 230000007062 hydrolysis Effects 0.000 claims abstract description 36
- 238000006460 hydrolysis reaction Methods 0.000 claims abstract description 36
- 238000005406 washing Methods 0.000 claims abstract description 28
- 229910000349 titanium oxysulfate Inorganic materials 0.000 claims abstract description 23
- 239000007788 liquid Substances 0.000 claims abstract description 7
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 77
- 210000002196 fr. b Anatomy 0.000 claims description 18
- 230000029087 digestion Effects 0.000 claims description 16
- 239000002994 raw material Substances 0.000 claims description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
- 210000000540 fraction c Anatomy 0.000 claims description 12
- 239000000049 pigment Substances 0.000 claims description 12
- 238000004064 recycling Methods 0.000 claims description 11
- 239000000463 material Substances 0.000 claims description 10
- 239000000725 suspension Substances 0.000 claims description 10
- 239000010936 titanium Substances 0.000 claims description 10
- 229910052719 titanium Inorganic materials 0.000 claims description 10
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 9
- 239000002351 wastewater Substances 0.000 claims description 8
- 235000011149 sulphuric acid Nutrition 0.000 claims description 5
- 238000001354 calcination Methods 0.000 claims description 3
- 230000003247 decreasing effect Effects 0.000 claims description 2
- 238000004090 dissolution Methods 0.000 claims description 2
- 230000003301 hydrolyzing effect Effects 0.000 claims 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract description 8
- 229940032330 sulfuric acid Drugs 0.000 description 30
- 239000000706 filtrate Substances 0.000 description 13
- 239000011651 chromium Substances 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 239000012065 filter cake Substances 0.000 description 5
- 210000003918 fraction a Anatomy 0.000 description 5
- YDZQQRWRVYGNER-UHFFFAOYSA-N iron;titanium;trihydrate Chemical compound O.O.O.[Ti].[Fe] YDZQQRWRVYGNER-UHFFFAOYSA-N 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 238000000926 separation method Methods 0.000 description 5
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 5
- 230000002411 adverse Effects 0.000 description 4
- 150000002500 ions Chemical class 0.000 description 4
- 239000002893 slag Substances 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000001704 evaporation Methods 0.000 description 3
- 230000008020 evaporation Effects 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- GRWVQDDAKZFPFI-UHFFFAOYSA-H chromium(III) sulfate Chemical compound [Cr+3].[Cr+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O GRWVQDDAKZFPFI-UHFFFAOYSA-H 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- SURQXAFEQWPFPV-UHFFFAOYSA-L iron(2+) sulfate heptahydrate Chemical compound O.O.O.O.O.O.O.[Fe+2].[O-]S([O-])(=O)=O SURQXAFEQWPFPV-UHFFFAOYSA-L 0.000 description 2
- 241001269524 Dura Species 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- -1 chromium sulfate Chemical class 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 239000012452 mother liquor Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- VLOPEOIIELCUML-UHFFFAOYSA-L vanadium(2+);sulfate Chemical compound [V+2].[O-]S([O-])(=O)=O VLOPEOIIELCUML-UHFFFAOYSA-L 0.000 description 1
- 239000002918 waste heat Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G23/00—Compounds of titanium
- C01G23/04—Oxides; Hydroxides
- C01G23/047—Titanium dioxide
- C01G23/053—Producing by wet processes, e.g. hydrolysing titanium salts
- C01G23/0532—Producing by wet processes, e.g. hydrolysing titanium salts by hydrolysing sulfate-containing salts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Inorganic Chemistry (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEP3912554.8 | 1989-04-17 | ||
| DE3912554A DE3912554C1 (enrdf_load_stackoverflow) | 1989-04-17 | 1989-04-17 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2014485A1 true CA2014485A1 (en) | 1990-10-17 |
Family
ID=6378838
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002014485A Abandoned CA2014485A1 (en) | 1989-04-17 | 1990-04-12 | Process for the production of titanium dioxide |
Country Status (10)
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005038060A1 (en) * | 2003-10-17 | 2005-04-28 | Bhp Billiton Innovation Pty Ltd | Production of titania |
| US7429364B2 (en) | 2002-10-18 | 2008-09-30 | Bhp Billiton Innovation Pty. Ltd. | Production of titania |
| US7485269B2 (en) | 2002-10-18 | 2009-02-03 | Bhp Billiton Innovation Pty. Ltd. | Production of titania |
| US7485268B2 (en) | 2002-10-18 | 2009-02-03 | Bhp Billiton Innovation Pty. Ltd. | Production of titania |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FI89901C (fi) * | 1990-10-23 | 1993-12-10 | Kemira Oy | Reningsfoerfarande |
| BR9005862A (pt) * | 1990-11-20 | 1992-06-30 | Curua Mineracao Ltda | Processo de producao de dioxido de titanio a partir de minerio de anatasio,usando digestao fluida com acido sulfurico e sob condicao de minimo consumo de acido e minima emissao de efluentes poluidores |
| WO1993018193A1 (en) * | 1992-03-09 | 1993-09-16 | Pivot Mining Nl | Acid washing of leached solids from the beneficiation of titaniferous ores |
| EP0717783A4 (en) * | 1993-09-07 | 1997-04-23 | Tech Resources Pty Ltd | REFINING TITANIUM-CONTAINING MATERIAL |
| DE4344359C2 (de) * | 1993-12-24 | 1996-09-19 | Bayer Ag | Verfahren zur Herstellung von Titandioxid nach dem Sulfatverfahren |
| JP2006103999A (ja) * | 2004-10-01 | 2006-04-20 | Murata Mfg Co Ltd | 酸化チタン微粒子の製造方法 |
| CN112624189B (zh) * | 2021-01-14 | 2023-03-28 | 上海安赐环保科技股份有限公司 | 一种硫酸法钛白粉的废酸与白水的回用方法及系统 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3327769A1 (de) * | 1983-08-02 | 1985-02-14 | Bayer Ag, 5090 Leverkusen | Verfahren zur aufarbeitung von duennsaeuren |
| DE3718674A1 (de) * | 1987-06-04 | 1988-12-15 | Bayer Ag | Verfahren zur herstellung von titandioxid |
| DE3736111A1 (de) * | 1987-10-26 | 1989-05-03 | Kronos Titan Gmbh | Verfahren zur energie- und materialsparenden aufarbeitung der bei der titandioxidherstellung nach dem sulfatverfahren anfallenden duennsaeure |
| CH672633A5 (enrdf_load_stackoverflow) * | 1987-11-23 | 1989-12-15 | Escher Wyss Ag | |
| DE3742838A1 (de) * | 1987-12-17 | 1989-07-13 | Kronos Titan Gmbh | Verfahren zur herstellung von titandioxid-pigmenten |
-
1989
- 1989-04-17 DE DE3912554A patent/DE3912554C1/de not_active Expired - Lifetime
-
1990
- 1990-04-03 NO NO90901505A patent/NO901505L/no unknown
- 1990-04-05 DE DE9090106528T patent/DE59000737D1/de not_active Expired - Fee Related
- 1990-04-05 ES ES90106528T patent/ES2054134T3/es not_active Expired - Lifetime
- 1990-04-05 EP EP90106528A patent/EP0393430B1/de not_active Expired - Lifetime
- 1990-04-11 AU AU53165/90A patent/AU626657B2/en not_active Ceased
- 1990-04-12 CA CA002014485A patent/CA2014485A1/en not_active Abandoned
- 1990-04-12 JP JP2095242A patent/JPH02293323A/ja active Pending
- 1990-04-12 FI FI901874A patent/FI96840C/fi not_active IP Right Cessation
- 1990-04-12 ZA ZA902824A patent/ZA902824B/xx unknown
- 1990-04-16 BR BR909001755A patent/BR9001755A/pt not_active Application Discontinuation
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7429364B2 (en) | 2002-10-18 | 2008-09-30 | Bhp Billiton Innovation Pty. Ltd. | Production of titania |
| US7485269B2 (en) | 2002-10-18 | 2009-02-03 | Bhp Billiton Innovation Pty. Ltd. | Production of titania |
| US7485268B2 (en) | 2002-10-18 | 2009-02-03 | Bhp Billiton Innovation Pty. Ltd. | Production of titania |
| WO2005038060A1 (en) * | 2003-10-17 | 2005-04-28 | Bhp Billiton Innovation Pty Ltd | Production of titania |
| EA009207B1 (ru) * | 2003-10-17 | 2007-12-28 | Би Эйч Пи БИЛЛИТОН ИННОВЕЙШН ПТИ ЛТД. | Получение диоксида титана |
| US7326390B2 (en) | 2003-10-17 | 2008-02-05 | Bhp Billiton Innovation Pty Ltd. | Production of titania |
Also Published As
| Publication number | Publication date |
|---|---|
| FI96840C (fi) | 1996-09-10 |
| EP0393430B1 (de) | 1993-01-13 |
| BR9001755A (pt) | 1991-06-04 |
| AU5316590A (en) | 1990-10-18 |
| ZA902824B (en) | 1991-02-27 |
| NO901505D0 (no) | 1990-04-03 |
| DE3912554C1 (enrdf_load_stackoverflow) | 1990-07-12 |
| EP0393430A3 (de) | 1991-03-27 |
| ES2054134T3 (es) | 1994-08-01 |
| JPH02293323A (ja) | 1990-12-04 |
| FI96840B (fi) | 1996-05-31 |
| FI901874A0 (fi) | 1990-04-12 |
| DE59000737D1 (de) | 1993-02-25 |
| EP0393430A2 (de) | 1990-10-24 |
| NO901505L (no) | 1990-10-18 |
| AU626657B2 (en) | 1992-08-06 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FZDE | Discontinued |