CA1295219C - Method and apparatus for detecting hydrogen-containing or hydrogen-reactive gases - Google Patents
Method and apparatus for detecting hydrogen-containing or hydrogen-reactive gasesInfo
- Publication number
- CA1295219C CA1295219C CA000535654A CA535654A CA1295219C CA 1295219 C CA1295219 C CA 1295219C CA 000535654 A CA000535654 A CA 000535654A CA 535654 A CA535654 A CA 535654A CA 1295219 C CA1295219 C CA 1295219C
- Authority
- CA
- Canada
- Prior art keywords
- membrane
- hydrogen
- poly
- gas
- catalytic agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000007789 gas Substances 0.000 title claims abstract description 104
- 239000001257 hydrogen Substances 0.000 title claims abstract description 82
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 82
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract description 60
- 238000000034 method Methods 0.000 title claims abstract description 19
- 239000012528 membrane Substances 0.000 claims abstract description 161
- -1 hydrogen ions Chemical class 0.000 claims abstract description 126
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims abstract description 28
- 229920000642 polymer Polymers 0.000 claims abstract description 25
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 23
- 229920001577 copolymer Polymers 0.000 claims abstract description 20
- 150000002484 inorganic compounds Chemical class 0.000 claims abstract description 19
- 229910010272 inorganic material Inorganic materials 0.000 claims abstract description 19
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 17
- 150000002894 organic compounds Chemical class 0.000 claims abstract description 17
- 229920000620 organic polymer Polymers 0.000 claims abstract description 17
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 17
- 239000001301 oxygen Substances 0.000 claims abstract description 17
- 150000001875 compounds Chemical class 0.000 claims abstract description 14
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 12
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 12
- 239000000178 monomer Substances 0.000 claims abstract description 10
- 125000004434 sulfur atom Chemical group 0.000 claims abstract description 10
- 239000003795 chemical substances by application Substances 0.000 claims description 41
- 230000003197 catalytic effect Effects 0.000 claims description 40
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 33
- 239000000126 substance Substances 0.000 claims description 33
- 239000013558 reference substance Substances 0.000 claims description 31
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 24
- 239000007787 solid Substances 0.000 claims description 23
- 239000010409 thin film Substances 0.000 claims description 22
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- 238000001514 detection method Methods 0.000 claims description 17
- 229910052697 platinum Inorganic materials 0.000 claims description 17
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 15
- 235000011007 phosphoric acid Nutrition 0.000 claims description 15
- 239000002253 acid Substances 0.000 claims description 13
- 229910052763 palladium Inorganic materials 0.000 claims description 13
- 238000010494 dissociation reaction Methods 0.000 claims description 9
- 230000005593 dissociations Effects 0.000 claims description 8
- 150000007513 acids Chemical class 0.000 claims description 7
- 238000005192 partition Methods 0.000 claims description 6
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- 238000012360 testing method Methods 0.000 description 19
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- 239000004744 fabric Substances 0.000 description 8
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 7
- 238000001704 evaporation Methods 0.000 description 7
- 230000008020 evaporation Effects 0.000 description 7
- 150000002431 hydrogen Chemical class 0.000 description 7
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- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 5
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- 229910052791 calcium Inorganic materials 0.000 description 5
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- 239000011591 potassium Substances 0.000 description 5
- 229910052708 sodium Inorganic materials 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 4
- 229920002301 cellulose acetate Polymers 0.000 description 4
- 239000000919 ceramic Substances 0.000 description 4
- 239000008367 deionised water Substances 0.000 description 4
- 229910021641 deionized water Inorganic materials 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 229910052744 lithium Inorganic materials 0.000 description 4
- 239000011777 magnesium Substances 0.000 description 4
- 229910052749 magnesium Inorganic materials 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 210000000056 organ Anatomy 0.000 description 4
- 229920002492 poly(sulfone) Polymers 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 241000518994 Conta Species 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
- 239000012298 atmosphere Substances 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
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- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 3
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 3
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 3
- 229910052720 vanadium Inorganic materials 0.000 description 3
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- 239000004642 Polyimide Substances 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical group [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
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- 238000013461 design Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 150000004678 hydrides Chemical class 0.000 description 2
- 238000005984 hydrogenation reaction Methods 0.000 description 2
- 238000003780 insertion Methods 0.000 description 2
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- 229910052987 metal hydride Inorganic materials 0.000 description 2
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- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
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- 229910052750 molybdenum Inorganic materials 0.000 description 2
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- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
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- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- 229910052714 tellurium Inorganic materials 0.000 description 1
- PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical group [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 description 1
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- QKRQKXFTLBQFGH-UHFFFAOYSA-L uranyl hydrogenphosphate Chemical compound OP1(=O)O[U](=O)(=O)O1 QKRQKXFTLBQFGH-UHFFFAOYSA-L 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
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- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/403—Cells and electrode assemblies
- G01N27/406—Cells and probes with solid electrolytes
- G01N27/407—Cells and probes with solid electrolytes for investigating or analysing gases
- G01N27/4073—Composition or fabrication of the solid electrolyte
- G01N27/4074—Composition or fabrication of the solid electrolyte for detection of gases other than oxygen
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- General Physics & Mathematics (AREA)
- Electrochemistry (AREA)
- Physics & Mathematics (AREA)
- Analytical Chemistry (AREA)
- Molecular Biology (AREA)
- General Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Measuring Oxygen Concentration In Cells (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
Priority Applications (9)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/753,477 US4661211A (en) | 1985-07-10 | 1985-07-10 | Gas detection with three-component membrane and sensor using said membrane |
| IN309/DEL/87A IN172102B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1985-07-10 | 1987-04-13 | |
| ZA872631A ZA872631B (en) | 1985-07-10 | 1987-04-13 | Method and apparatus for detecting hydrogen-containing or hydrogen-reactive gases |
| AU71567/87A AU589509B2 (en) | 1985-07-10 | 1987-04-15 | Method and apparatus for detecting hydrogen-containing or hydrogen-reactive gases |
| ES198787303659T ES2028073T3 (es) | 1985-07-10 | 1987-04-24 | Metodo y aparato para detectar gases que contienen hidrogeno positivo en cuanto a hidrogeno. |
| EP87303659A EP0287730B1 (en) | 1985-07-10 | 1987-04-24 | Method and apparatus for detecting hydrogen-containing hydrogen-positive gases |
| DE8787303659T DE3776326D1 (de) | 1985-07-10 | 1987-04-24 | Verfahren und vorrichtung zum aufspueren von wasserstoffhaltigen oder wasserstoffreaktiven gasen. |
| JP62102968A JPS63274857A (ja) | 1985-07-10 | 1987-04-24 | 水素含有ガスまたは水素反応性ガスの検出法及びその装置 |
| CA000535654A CA1295219C (en) | 1985-07-10 | 1987-04-27 | Method and apparatus for detecting hydrogen-containing or hydrogen-reactive gases |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/753,477 US4661211A (en) | 1985-07-10 | 1985-07-10 | Gas detection with three-component membrane and sensor using said membrane |
| CA000535654A CA1295219C (en) | 1985-07-10 | 1987-04-27 | Method and apparatus for detecting hydrogen-containing or hydrogen-reactive gases |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1295219C true CA1295219C (en) | 1992-02-04 |
Family
ID=25671320
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000535654A Expired - Fee Related CA1295219C (en) | 1985-07-10 | 1987-04-27 | Method and apparatus for detecting hydrogen-containing or hydrogen-reactive gases |
Country Status (9)
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008031199A1 (en) * | 2006-09-11 | 2008-03-20 | Transfert Plus, S.E.C. | Ionic compounds having bronsted acidity and uses thereof |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4824528A (en) * | 1985-07-19 | 1989-04-25 | Allied-Signal Inc. | Gas detection apparatus and method with novel electrolyte membrane |
| JPS62172257A (ja) * | 1986-01-27 | 1987-07-29 | Figaro Eng Inc | プロトン導電体ガスセンサ |
| IL82160A (en) * | 1987-04-10 | 1991-03-10 | Technion Res & Dev Foundation | Electrochemical analyzer for measuring the concentration of atoms or molecules in a fluid and method of making same |
| US6369159B1 (en) | 1987-05-13 | 2002-04-09 | Pdm Holdings Corp. | Antistatic plastic materials containing epihalohydrin polymers |
| IT1215930B (it) * | 1988-02-22 | 1990-02-22 | Eniricerche Spa | Sensore a stato solido per determinare la concentrazione di gas con un elettrodo di riferimento solido. |
| JPH02114168A (ja) * | 1988-10-24 | 1990-04-26 | Mitsubishi Electric Corp | ガスセンサー |
| DE69122009T2 (de) * | 1990-08-06 | 1997-02-06 | Baxter Int | Elektrochemischer Kraftsensor |
| IT1244486B (it) * | 1990-12-21 | 1994-07-15 | Eniricerche Spa | Sensore a stato solido per la determinazione della concentrazione di gas che possono reagire con idrogeno |
| US5523095A (en) * | 1993-12-15 | 1996-06-04 | Eastman Chemical Company | Controlled release matrix system using cellulose acetate/polyvinylpyrrolidone blends |
| US5536505A (en) * | 1993-12-15 | 1996-07-16 | Eastman Chemical Company | Controlled release matrix system using cellulose acetate/poly-2-ethyl-2-oxazoline blends |
| DE19536719C2 (de) * | 1995-09-30 | 1997-09-11 | Dresden Ev Inst Festkoerper | Wasserstoffsensitives Bauelement |
| GB9713953D0 (en) * | 1997-07-03 | 1997-09-03 | Fray Derek J | Novel method of measurement of the composition of gases using ionically conducting electrolytes |
| US5979220A (en) * | 1998-06-30 | 1999-11-09 | Siemens Westinghouse Power Corporation | In-situ sensors for gas turbines |
| CN100445739C (zh) * | 2004-02-19 | 2008-12-24 | 株式会社新泻Tlo | 氢气传感器 |
| US20080145722A1 (en) * | 2006-12-19 | 2008-06-19 | Coignet Philippe A | Economical and Reliable Gas Sensor |
| US20080179199A1 (en) * | 2006-12-19 | 2008-07-31 | Coignet Philippe A | Economical and Reliable Gas Sensor |
| EP2058649B1 (de) * | 2007-11-06 | 2011-06-29 | Micronas GmbH | Sensor-Brennstoffzelle |
| JP5535556B2 (ja) * | 2009-08-28 | 2014-07-02 | アズビル株式会社 | 酸素濃度センサ |
| US8889422B2 (en) | 2011-02-17 | 2014-11-18 | General Electric Company | Optical gas sensor for use with electrical equipment and methods of assembling same |
| JP6165343B2 (ja) * | 2013-09-12 | 2017-07-19 | コリア・アドバンスト・インスティテュート・オブ・サイエンス・アンド・テクノロジー | 液体内の溶存水素ガス濃度測定用水素センサ素子およびこれを用いた水素ガス濃度測定方法 |
| JP6366408B2 (ja) * | 2014-07-31 | 2018-08-01 | 株式会社富士技研 | 水素濃度検出素子 |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3276910A (en) * | 1961-10-12 | 1966-10-04 | Standard Oil Co | Ion transfer medium for electrochemical reaction apparatus |
| US3265536A (en) * | 1962-12-11 | 1966-08-09 | American Cyanamid Co | Alkali saturated cross-linked polyvinyl alcohol membranes and fuel cell with same |
| US3727058A (en) * | 1971-02-16 | 1973-04-10 | Hughes Aircraft Co | Hydrogen ion device |
| US4024036A (en) * | 1975-02-03 | 1977-05-17 | Agency Of Industrial Science & Technology | Proton permselective solid-state member and apparatus utilizing said permselective member |
| US4040929A (en) * | 1975-09-15 | 1977-08-09 | Universal Oil Products Company | Oxygen sensor having thin film electrolyte |
| US4179491A (en) * | 1976-11-15 | 1979-12-18 | National Research Development Corporation | Electrical device with separator as conductor for hydrogen cations |
| CA1110439A (en) * | 1978-01-23 | 1981-10-13 | Goodrich (B.F.) Company (The) | Synthesis of smoke retardant and vinyl halide polymers containing same |
| US4306774A (en) * | 1978-10-04 | 1981-12-22 | Rockwell International Corporation | Solid state electrochromic display |
| US4373375A (en) * | 1980-12-19 | 1983-02-15 | General Electric Company | Hydrogen sensor |
| US4324760A (en) * | 1981-04-01 | 1982-04-13 | General Electric Company | Hydrogen detector |
| US4324761A (en) * | 1981-04-01 | 1982-04-13 | General Electric Company | Hydrogen detector |
| US4500667A (en) * | 1983-10-26 | 1985-02-19 | Uop Inc. | Polymer blended membranes |
| US4594297A (en) * | 1983-12-29 | 1986-06-10 | Uop Inc. | Fuel cell using novel electrolyte membrane |
| US4560444A (en) * | 1983-12-29 | 1985-12-24 | Uop Inc. | Gas detection with novel electrolyte membrane and solid internal reference |
| CA1223039A (en) * | 1984-03-26 | 1987-06-16 | Michael Thompson | Chemical selective sensors utilizing admittance modulated membranes |
-
1985
- 1985-07-10 US US06/753,477 patent/US4661211A/en not_active Expired - Lifetime
-
1987
- 1987-04-13 ZA ZA872631A patent/ZA872631B/xx unknown
- 1987-04-13 IN IN309/DEL/87A patent/IN172102B/en unknown
- 1987-04-15 AU AU71567/87A patent/AU589509B2/en not_active Ceased
- 1987-04-24 ES ES198787303659T patent/ES2028073T3/es not_active Expired - Lifetime
- 1987-04-24 EP EP87303659A patent/EP0287730B1/en not_active Expired - Lifetime
- 1987-04-24 DE DE8787303659T patent/DE3776326D1/de not_active Expired - Fee Related
- 1987-04-24 JP JP62102968A patent/JPS63274857A/ja active Granted
- 1987-04-27 CA CA000535654A patent/CA1295219C/en not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008031199A1 (en) * | 2006-09-11 | 2008-03-20 | Transfert Plus, S.E.C. | Ionic compounds having bronsted acidity and uses thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0287730B1 (en) | 1992-01-22 |
| US4661211A (en) | 1987-04-28 |
| JPS63274857A (ja) | 1988-11-11 |
| JPH05663B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1993-01-06 |
| DE3776326D1 (de) | 1992-03-05 |
| EP0287730A1 (en) | 1988-10-26 |
| ZA872631B (en) | 1987-10-02 |
| AU589509B2 (en) | 1989-10-12 |
| IN172102B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1993-04-03 |
| AU7156787A (en) | 1988-10-20 |
| ES2028073T3 (es) | 1992-07-01 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKLA | Lapsed |