CA1265842C - Lithium battery including vanadium pentoxide base amorphous cathode active material - Google Patents

Lithium battery including vanadium pentoxide base amorphous cathode active material

Info

Publication number
CA1265842C
CA1265842C CA495009A CA495009A CA1265842C CA 1265842 C CA1265842 C CA 1265842C CA 495009 A CA495009 A CA 495009A CA 495009 A CA495009 A CA 495009A CA 1265842 C CA1265842 C CA 1265842C
Authority
CA
Canada
Prior art keywords
active material
cathode active
lithium battery
lithium
battery including
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA495009A
Other languages
French (fr)
Other versions
CA1265842A (en
Inventor
Yoji Sakurai
Toshiro Hirai
Shigeto Okada
Takeshi Okada
Jun-Ichi Yamaki
Hideaki Ohtsuka
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP59237776A external-priority patent/JPS61116756A/en
Priority claimed from JP59237777A external-priority patent/JPS61116757A/en
Priority claimed from JP59237778A external-priority patent/JPS61116758A/en
Priority claimed from JP60041213A external-priority patent/JPS61200667A/en
Priority claimed from JP60046480A external-priority patent/JPS61206168A/en
Application filed filed Critical
Application granted granted Critical
Publication of CA1265842A publication Critical patent/CA1265842A/en
Publication of CA1265842C publication Critical patent/CA1265842C/en
Expired legal-status Critical Current

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/485—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566—Liquid materials
    • H01M10/0568—Liquid materials characterised by the solutes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566—Liquid materials
    • H01M10/0569—Liquid materials characterised by the solvents
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Secondary Cells (AREA)

Abstract

ABSTRACT: A lithium battery essentially consisting of an amorphous cathode active material mainly composed of V2O5 and prepared by adding with at least one first additive selected from the group consisting of P2O5, TeO2, GeO2, Sb2O3, Bi2O3 and B2O3 and/or at least one second additive selected from the group consisting of MoO3 and WO3, heating to melt the admixture and then quenching the molten admixture; an anode active material made of metallic lithium or a lithium alloy; and an electrolyte made of a mixture of a aprotic solvent and a lithium salt. The battery is a small-sized and light-weight secondary battery having a high energy density and being improved in charge-discharge cycle lifetime.
CA495009A 1984-11-12 1985-11-12 Lithium battery including vanadium pentoxide base amorphous cathode active material Expired CA1265842C (en)

Applications Claiming Priority (10)

Application Number Priority Date Filing Date Title
JP59237776A JPS61116756A (en) 1984-11-12 1984-11-12 Lithium battery
JP59-237778 1984-11-12
JP59237777A JPS61116757A (en) 1984-11-12 1984-11-12 Lithium battery
JP59-237777 1984-11-12
JP59237778A JPS61116758A (en) 1984-11-12 1984-11-12 Lithium battery
JP59-237776 1984-11-12
JP60041213A JPS61200667A (en) 1985-03-04 1985-03-04 Lithium cell
JP60-41213 1985-03-04
JP60046480A JPS61206168A (en) 1985-03-11 1985-03-11 Lithium secondary battery
JP60-46480 1985-03-11

Publications (2)

Publication Number Publication Date
CA1265842A CA1265842A (en) 1990-02-13
CA1265842C true CA1265842C (en) 1990-02-13

Family

ID=27522145

Family Applications (1)

Application Number Title Priority Date Filing Date
CA495009A Expired CA1265842C (en) 1984-11-12 1985-11-12 Lithium battery including vanadium pentoxide base amorphous cathode active material

Country Status (4)

Country Link
US (1) US4675260A (en)
CA (1) CA1265842C (en)
DE (1) DE3540074A1 (en)
FR (1) FR2573250B1 (en)

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FR2605458B1 (en) * 1986-10-20 1995-03-24 Accumulateurs Fixes POSITIVE ACTIVE MATERIAL FOR RECHARGEABLE ELECTROCHEMICAL GENERATOR, PREPARATION METHOD AND GENERATOR USING THE SAME
DE3785834T2 (en) * 1986-11-13 1993-08-19 Seiko Electronic Components CELL WITH ORGANIC ELECTROLYTE.
US4840856A (en) * 1986-12-26 1989-06-20 Otsuka Kagaku Kabushiki Kaisha Allyl group-containing oligoethyleneoxypolyphosphazenes, process for their preparation, and their use
US4751157A (en) * 1987-06-08 1988-06-14 The United States Of America As Represented By The Secretary Of The Army Cathode material for use in lithium electrochemical cell and lithium electrochemical cell including said cathode material
US4751158A (en) * 1987-08-03 1988-06-14 The United States Of America As Represented By The Secretary Of The Army Amorphous cathode material for use in lithium electrochemical cell and lithium electrochemical cell including the amorphous cathode material
DE68913736T2 (en) * 1988-12-16 1994-06-30 Otsuka Kagaku Kk BATTERY WITH COMPLETELY FIXED SECONDARY CELLS.
JP2759479B2 (en) * 1989-02-22 1998-05-28 大塚化学株式会社 All-solid-state lithium secondary battery
JPH02223158A (en) * 1989-02-22 1990-09-05 Otsuka Chem Co Ltd All-solid type battery
FR2649970B1 (en) * 1989-07-18 1992-08-28 Univ Lille Flandres Artois
EP0503901B1 (en) * 1991-03-15 1996-12-04 Honda Giken Kogyo Kabushiki Kaisha Cathode materials for lithium battery and methods for producing the same
US5474858A (en) * 1992-07-21 1995-12-12 Medtronic, Inc. Method for preventing gas formation in electro-chemical cells
US5620810A (en) * 1992-07-22 1997-04-15 Valence Technology, Inc. Solid, solvent-containing electrolytes and electrolytic cells produced therefrom
US5278000A (en) * 1992-09-02 1994-01-11 The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration Overcharge and overdischarge protection of ambient temperature secondary lithium cells
FR2695569B1 (en) * 1992-09-14 1994-11-10 Air Liquide Electrochemical cell and its use for electrochemical separation or extraction of oxygen.
US5366830A (en) * 1993-02-12 1994-11-22 Valence Technology, Inc. Vanadium oxide cathode active material and method of making same
US5780185A (en) * 1993-06-07 1998-07-14 Honda Giken Kogyo Kabushiki Kaisha Cathode materials for lithium batteries and methods for producing the same
US5480744A (en) * 1994-04-04 1996-01-02 Motorola, Inc. Bismuth based electrodes for electrochemical cells
CA2164385C (en) * 1995-12-04 2000-06-13 Qiming Zhong Low viscosity electrolyte comprising p2o5 for use in non-aqueous rechargeable lithium batteries
US5700598A (en) * 1996-07-11 1997-12-23 Bell Communications Research, Inc. Method for preparing mixed amorphous vanadium oxides and their use as electrodes in reachargeable lithium cells
US5955218A (en) * 1996-12-18 1999-09-21 Medtronic, Inc. Heat-treated silver vanadium oxide for use in batteries for implantable medical devices
US5895733A (en) * 1997-02-03 1999-04-20 Medtronic, Inc. Synthesis method for silver vanadium oxide
US7214446B1 (en) 1997-07-21 2007-05-08 Nanogram Corporation Batteries with electroactive nanoparticles
US5952125A (en) * 1997-07-21 1999-09-14 Nanogram Corporation Batteries with electroactive nanoparticles
FR2780717B1 (en) * 1998-07-03 2000-08-18 Air Liquide PROCESS FOR THE PREPARATION OF A BIMEVOX-BASED COMPOSITE ELECTROLYTE, USE OF SAID COMPOSITE IN THE SEPARATION OF OXYGEN FROM A GASEOUS MIXTURE
US20100185264A1 (en) * 2002-01-24 2010-07-22 Greatbatch Ltd. Method For Coating A Cathode Active Material With A Metal Oxide For Incorporation Into A Lithium Electrochemical Cell
US7211349B2 (en) * 2002-08-06 2007-05-01 Wilson Greatbatch Technologies, Inc. Silver vanadium oxide provided with a metal oxide coating
KR100647307B1 (en) * 2004-12-23 2006-11-23 삼성에스디아이 주식회사 Proton conductors and electrochemical devices using them
KR101123398B1 (en) * 2009-10-29 2012-03-23 한국세라믹기술원 Vanadia sol containing tungsten trioxide and manufacturing method thereof
EP2634845B1 (en) 2012-02-29 2020-09-16 Belenos Clean Power Holding AG Coating and lithiation of inorganic oxidants by reaction with lithiated reductants
EP2822905B1 (en) 2012-03-09 2016-02-03 Belenos Clean Power Holding AG V2O5-LiBO2, V2O5-NiO-LiBO2 GLASSES AND THEIR COMPOSITES OBTAINED BY NITROGEN DOPING AND REDUCED GRAPHITE OXIDE BLENDING AS CATHODE ACTIVE MATERIALS
US9461306B2 (en) 2013-11-13 2016-10-04 Toyota Motor Engineering & Manufacturing North America, Inc. Vanadium oxide based amorphous cathode materials for rechargeable magnesium battery
CN103915603B (en) * 2014-04-21 2016-01-27 四川长虹电源有限责任公司 High temperature performance takes into account high-power lithium ion battery
US20150380732A1 (en) * 2014-06-30 2015-12-31 Indiana University Research And Technology Corporation Novel vanadium oxide cathode material
US9819021B2 (en) * 2014-10-16 2017-11-14 Toyota Motor Engineering & Manufacturing North America, Inc. Metastable vanadium oxide cathode materials for rechargeable magnesium battery
KR102739946B1 (en) 2016-09-23 2024-12-06 삼성전자주식회사 cathode active material, method of preparing the cathode active material, and all solid state battery comprising the same
US11302967B2 (en) 2018-01-15 2022-04-12 International Business Machines Corporation Low-voltage microbattery
US12040481B2 (en) 2018-12-21 2024-07-16 The Trustees Of Indiana University Graphene and network former-modified vanadium pentoxide silicon dioxide cathodes for lithium-ion batteries

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FR2428617A2 (en) * 1978-06-13 1980-01-11 France Etat Amorphous lithium cationic conductors - contg. oxides of boron and lithium and lithium salt
JPS5512675A (en) * 1978-07-12 1980-01-29 Sanyo Electric Co Ltd Nonaqueous electrolyte cell
US4228226A (en) * 1978-10-10 1980-10-14 Bell Telephone Laboratories, Incorporated Nonaqueous secondary cell using vanadium oxide positive electrode
US4243624A (en) * 1979-05-21 1981-01-06 Exxon Research & Engineering Co. Method of making cathodes derived from ammonium-metal-chalcogen compounds
US4233375A (en) * 1979-08-02 1980-11-11 Exxon Research & Engineering Co. High energy density plural chalcogenide cathode-containing cell
US4316777A (en) * 1979-10-01 1982-02-23 Duracell International Inc. Rechargeable nonaqueous silver alloy anode cell
US4310609A (en) * 1979-12-17 1982-01-12 Wilson Greatbatch Ltd. Metal oxide composite cathode material for high energy density batteries
FR2527842B1 (en) * 1982-06-01 1992-02-07 Western Electric Co NONAQUEOUS BATTERY OR ACCUMULATOR ELEMENT USING A POSITIVE ELECTRODE OF MIXED METAL OXIDES
JPS59134561A (en) * 1983-01-24 1984-08-02 Nippon Telegr & Teleph Corp <Ntt> Lithium cell
FR2544301A1 (en) * 1983-04-15 1984-10-19 Centre Nat Rech Scient NEW INTERCALAR VITREUX MATERIALS HAVING PARTICULARLY SEMICONDUCTOR PROPERTIES, THEIR MANUFACTURE AND THE ELECTROCHEMICAL APPLICATIONS OF THESE MATERIALS AND THEIR BASIC VITREOUS STRUCTURE

Also Published As

Publication number Publication date
FR2573250B1 (en) 1990-12-21
US4675260A (en) 1987-06-23
DE3540074C2 (en) 1988-09-08
DE3540074A1 (en) 1986-05-22
FR2573250A1 (en) 1986-05-16
CA1265842A (en) 1990-02-13

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Legal Events

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MKEX Expiry

Effective date: 20070213