FR2428617A2 - Amorphous lithium cationic conductors - contg. oxides of boron and lithium and lithium salt - Google Patents
Amorphous lithium cationic conductors - contg. oxides of boron and lithium and lithium saltInfo
- Publication number
- FR2428617A2 FR2428617A2 FR7817569A FR7817569A FR2428617A2 FR 2428617 A2 FR2428617 A2 FR 2428617A2 FR 7817569 A FR7817569 A FR 7817569A FR 7817569 A FR7817569 A FR 7817569A FR 2428617 A2 FR2428617 A2 FR 2428617A2
- Authority
- FR
- France
- Prior art keywords
- lithium
- compsns
- contg
- al2o3
- boron
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910052744 lithium Inorganic materials 0.000 title 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 title 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 title 1
- 229910052796 boron Inorganic materials 0.000 title 1
- 239000004020 conductor Substances 0.000 title 1
- 229910003002 lithium salt Inorganic materials 0.000 title 1
- 159000000002 lithium salts Chemical class 0.000 title 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 4
- GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 abstract 4
- YBMRDBCBODYGJE-UHFFFAOYSA-N germanium dioxide Chemical compound O=[Ge]=O YBMRDBCBODYGJE-UHFFFAOYSA-N 0.000 abstract 4
- DLYUQMMRRRQYAE-UHFFFAOYSA-N tetraphosphorus decaoxide Chemical compound O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 abstract 4
- GOLCXWYRSKYTSP-UHFFFAOYSA-N Arsenious Acid Chemical compound O1[As]2O[As]1O2 GOLCXWYRSKYTSP-UHFFFAOYSA-N 0.000 abstract 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 2
- COHDHYZHOPQOFD-UHFFFAOYSA-N arsenic pentoxide Chemical compound O=[As](=O)O[As](=O)=O COHDHYZHOPQOFD-UHFFFAOYSA-N 0.000 abstract 2
- 229910052681 coesite Inorganic materials 0.000 abstract 2
- 229910052593 corundum Inorganic materials 0.000 abstract 2
- 229910052906 cristobalite Inorganic materials 0.000 abstract 2
- 239000000377 silicon dioxide Substances 0.000 abstract 2
- 235000012239 silicon dioxide Nutrition 0.000 abstract 2
- 229910052682 stishovite Inorganic materials 0.000 abstract 2
- 229910052905 tridymite Inorganic materials 0.000 abstract 2
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract 2
- 241001572615 Amorphus Species 0.000 abstract 1
- FUJCRWPEOMXPAD-UHFFFAOYSA-N Li2O Inorganic materials [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 abstract 1
- 150000001450 anions Chemical class 0.000 abstract 1
- 125000002091 cationic group Chemical group 0.000 abstract 1
- 150000004770 chalcogenides Chemical class 0.000 abstract 1
- XUCJHNOBJLKZNU-UHFFFAOYSA-M dilithium;hydroxide Chemical compound [Li+].[Li+].[OH-] XUCJHNOBJLKZNU-UHFFFAOYSA-M 0.000 abstract 1
- 239000011521 glass Substances 0.000 abstract 1
- 150000004820 halides Chemical class 0.000 abstract 1
- 229910001416 lithium ion Inorganic materials 0.000 abstract 1
- 239000012528 membrane Substances 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
- 229910006587 β-Al2O3 Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/12—Silica-free oxide glass compositions
- C03C3/14—Silica-free oxide glass compositions containing boron
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C4/00—Compositions for glass with special properties
- C03C4/18—Compositions for glass with special properties for ion-sensitive glass
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/14—Cells with non-aqueous electrolyte
- H01M6/18—Cells with non-aqueous electrolyte with solid electrolyte
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Electrochemistry (AREA)
- Conductive Materials (AREA)
- Glass Compositions (AREA)
Abstract
Parent patent described amorphus compsns. contg. B2O3, Li2O and a Li salt, esp. a halide or chalcogenide, the B2O3 being partially replaceable with Al2O3, V2O5, P2O5, SiO2 and/or GeO2. In this addition, further compsns. are claimed, and all the compsns. are used in mfr. of cationic conditions used in electron generators, Li specific membranes or electrodes for analysis and Li ion dosage in soln. New compsns. are of B2O3.xM.yN .aLi2O.-bLi2Q (I). In (I) M is Al2O3, V2O5, P2O5, As2O3, As2O5; N is SiO2 and/or GeO2; Q is a mono or polyatomic tervalent or polyatomic divalent anion; and O = x =0.35, O = y =0.8, O a =2, O b 1.5, B =2a, Z = 2 or 3 as Q is di- or trivalent. Pref. Q are SO42-, MoO42-, WO42-, N3- and PO43-. Compsns. are stable in water and take the form of glasses having a conductivity of the same order of size as that of beta-Al2O3.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7817569A FR2428617A2 (en) | 1978-06-13 | 1978-06-13 | Amorphous lithium cationic conductors - contg. oxides of boron and lithium and lithium salt |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7817569A FR2428617A2 (en) | 1978-06-13 | 1978-06-13 | Amorphous lithium cationic conductors - contg. oxides of boron and lithium and lithium salt |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2428617A2 true FR2428617A2 (en) | 1980-01-11 |
| FR2428617B2 FR2428617B2 (en) | 1982-09-17 |
Family
ID=9209400
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR7817569A Granted FR2428617A2 (en) | 1978-06-13 | 1978-06-13 | Amorphous lithium cationic conductors - contg. oxides of boron and lithium and lithium salt |
Country Status (1)
| Country | Link |
|---|---|
| FR (1) | FR2428617A2 (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0050976A1 (en) * | 1980-10-24 | 1982-05-05 | RAYOVAC Corporation | Solid state electrolytes for electrochemical cells |
| WO1984004206A1 (en) * | 1983-04-15 | 1984-10-25 | Centre Nat Rech Scient | Electro-chemical generators comprising a positive electrode and an electrolyte based on vitreous materials |
| FR2573250A1 (en) * | 1984-11-12 | 1986-05-16 | Nippon Telegraph & Telephone | LITHIUM BATTERY COMPRISING AN AMORPHOUS CATHODE COMPRISING AN ACTIVE MATERIAL BASED ON VANADIUM PENTOXIDE |
| EP0718247A1 (en) * | 1994-06-13 | 1996-06-26 | Mitsui Petrochemical Industries, Ltd. | Lithium ion-conductive glass film and thin carbon dioxide gas sensor using the same film |
| FR2862432A1 (en) * | 2003-11-14 | 2005-05-20 | Stephanois Rech Mec | Solid vitreous electrolyte for an electrochemical cell with thin layers, notably for lithium micro-batteries |
| FR2964963A1 (en) * | 2010-09-21 | 2012-03-23 | St Microelectronics Tours Sas | Vitreous solid electrolyte useful for a thin layer electrochemical cell of a micro-battery, comprises a composition including boron, phosphorus, lithium, oxygen and nitrogen |
-
1978
- 1978-06-13 FR FR7817569A patent/FR2428617A2/en active Granted
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0050976A1 (en) * | 1980-10-24 | 1982-05-05 | RAYOVAC Corporation | Solid state electrolytes for electrochemical cells |
| WO1984004206A1 (en) * | 1983-04-15 | 1984-10-25 | Centre Nat Rech Scient | Electro-chemical generators comprising a positive electrode and an electrolyte based on vitreous materials |
| FR2573250A1 (en) * | 1984-11-12 | 1986-05-16 | Nippon Telegraph & Telephone | LITHIUM BATTERY COMPRISING AN AMORPHOUS CATHODE COMPRISING AN ACTIVE MATERIAL BASED ON VANADIUM PENTOXIDE |
| EP0718247A1 (en) * | 1994-06-13 | 1996-06-26 | Mitsui Petrochemical Industries, Ltd. | Lithium ion-conductive glass film and thin carbon dioxide gas sensor using the same film |
| EP0718247A4 (en) * | 1994-06-13 | 2000-09-06 | Mitsui Chemicals Inc | Lithium ion-conductive glass film and thin carbon dioxide gas sensor using the same film |
| FR2862432A1 (en) * | 2003-11-14 | 2005-05-20 | Stephanois Rech Mec | Solid vitreous electrolyte for an electrochemical cell with thin layers, notably for lithium micro-batteries |
| WO2005050764A1 (en) | 2003-11-14 | 2005-06-02 | H.E.F. | Solid electrolyte, in particular for a thin layer electrochemical cell and production method |
| FR2964963A1 (en) * | 2010-09-21 | 2012-03-23 | St Microelectronics Tours Sas | Vitreous solid electrolyte useful for a thin layer electrochemical cell of a micro-battery, comprises a composition including boron, phosphorus, lithium, oxygen and nitrogen |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2428617B2 (en) | 1982-09-17 |
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