CA1244186A - Filled molded polyamide compositions - Google Patents
Filled molded polyamide compositionsInfo
- Publication number
- CA1244186A CA1244186A CA000446712A CA446712A CA1244186A CA 1244186 A CA1244186 A CA 1244186A CA 000446712 A CA000446712 A CA 000446712A CA 446712 A CA446712 A CA 446712A CA 1244186 A CA1244186 A CA 1244186A
- Authority
- CA
- Canada
- Prior art keywords
- reactor
- fibers
- psi
- glass
- polyamide copolymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 41
- 239000004952 Polyamide Substances 0.000 title claims description 27
- 229920002647 polyamide Polymers 0.000 title claims description 27
- 239000000835 fiber Substances 0.000 claims description 26
- 239000011521 glass Substances 0.000 claims description 26
- 239000003365 glass fiber Substances 0.000 claims description 25
- 239000011324 bead Substances 0.000 claims description 17
- 229920002302 Nylon 6,6 Polymers 0.000 claims description 16
- 229920006039 crystalline polyamide Polymers 0.000 claims description 14
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 13
- 239000010439 graphite Substances 0.000 claims description 13
- 229910002804 graphite Inorganic materials 0.000 claims description 13
- 238000002347 injection Methods 0.000 claims description 7
- 239000007924 injection Substances 0.000 claims description 7
- 239000002557 mineral fiber Substances 0.000 claims 4
- 125000001142 dicarboxylic acid group Chemical group 0.000 claims 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 abstract description 94
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 abstract description 78
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 abstract description 68
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 abstract description 41
- 235000011037 adipic acid Nutrition 0.000 abstract description 39
- 239000001361 adipic acid Substances 0.000 abstract description 39
- 229920001577 copolymer Polymers 0.000 abstract 1
- 229920001897 terpolymer Polymers 0.000 abstract 1
- 238000000034 method Methods 0.000 description 65
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 29
- 229910001868 water Inorganic materials 0.000 description 29
- 150000003839 salts Chemical class 0.000 description 28
- 230000008569 process Effects 0.000 description 20
- 229920000642 polymer Polymers 0.000 description 19
- 239000000463 material Substances 0.000 description 15
- 238000006068 polycondensation reaction Methods 0.000 description 11
- 239000000155 melt Substances 0.000 description 10
- 229920005989 resin Polymers 0.000 description 9
- 239000011347 resin Substances 0.000 description 9
- 229910052500 inorganic mineral Inorganic materials 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- 239000011707 mineral Substances 0.000 description 7
- 235000010755 mineral Nutrition 0.000 description 7
- 238000012360 testing method Methods 0.000 description 6
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 5
- 239000003054 catalyst Substances 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 238000007654 immersion Methods 0.000 description 5
- 239000011261 inert gas Substances 0.000 description 5
- 239000000178 monomer Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 239000000306 component Substances 0.000 description 4
- 238000000465 moulding Methods 0.000 description 4
- 239000008188 pellet Substances 0.000 description 4
- 239000000376 reactant Substances 0.000 description 4
- 239000004677 Nylon Substances 0.000 description 3
- 230000032683 aging Effects 0.000 description 3
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 3
- 229920001778 nylon Polymers 0.000 description 3
- QPFMBZIOSGYJDE-UHFFFAOYSA-N 1,1,2,2-tetrachloroethane Chemical compound ClC(Cl)C(Cl)Cl QPFMBZIOSGYJDE-UHFFFAOYSA-N 0.000 description 2
- KWSLGOVYXMQPPX-UHFFFAOYSA-N 5-[3-(trifluoromethyl)phenyl]-2h-tetrazole Chemical compound FC(F)(F)C1=CC=CC(C2=NNN=N2)=C1 KWSLGOVYXMQPPX-UHFFFAOYSA-N 0.000 description 2
- FITNAOAKVDEJHB-UHFFFAOYSA-N 6-azaniumylhexylazanium;benzene-1,3-dicarboxylate Chemical compound NCCCCCCN.OC(=O)C1=CC=CC(C(O)=O)=C1 FITNAOAKVDEJHB-UHFFFAOYSA-N 0.000 description 2
- UFFRSDWQMJYQNE-UHFFFAOYSA-N 6-azaniumylhexylazanium;hexanedioate Chemical compound [NH3+]CCCCCC[NH3+].[O-]C(=O)CCCCC([O-])=O UFFRSDWQMJYQNE-UHFFFAOYSA-N 0.000 description 2
- CSVBIURHUGXNCS-UHFFFAOYSA-N 6-azaniumylhexylazanium;terephthalate Chemical compound NCCCCCCN.OC(=O)C1=CC=C(C(O)=O)C=C1 CSVBIURHUGXNCS-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 150000004985 diamines Chemical class 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 238000007710 freezing Methods 0.000 description 2
- 230000008014 freezing Effects 0.000 description 2
- 238000001746 injection moulding Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 239000012779 reinforcing material Substances 0.000 description 2
- 239000012266 salt solution Substances 0.000 description 2
- 229910001379 sodium hypophosphite Inorganic materials 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- 239000005711 Benzoic acid Substances 0.000 description 1
- 208000020401 Depressive disease Diseases 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000004957 Zytel Substances 0.000 description 1
- 229920006102 Zytel® Polymers 0.000 description 1
- AYHOQSGNVUZKJA-UHFFFAOYSA-N [B+3].[B+3].[B+3].[B+3].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] Chemical compound [B+3].[B+3].[B+3].[B+3].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] AYHOQSGNVUZKJA-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 229920006020 amorphous polyamide Polymers 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- QXJJQWWVWRCVQT-UHFFFAOYSA-K calcium;sodium;phosphate Chemical compound [Na+].[Ca+2].[O-]P([O-])([O-])=O QXJJQWWVWRCVQT-UHFFFAOYSA-K 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000007580 dry-mixing Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 229960003750 ethyl chloride Drugs 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000002074 melt spinning Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- DMCTVRQBJMBEDT-UHFFFAOYSA-N phenol;1,1,1,2-tetrachloroethane Chemical compound ClCC(Cl)(Cl)Cl.OC1=CC=CC=C1 DMCTVRQBJMBEDT-UHFFFAOYSA-N 0.000 description 1
- 238000013031 physical testing Methods 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000000518 rheometry Methods 0.000 description 1
- IOVGROKTTNBUGK-SJCJKPOMSA-N ritodrine Chemical compound N([C@@H](C)[C@H](O)C=1C=CC(O)=CC=1)CCC1=CC=C(O)C=C1 IOVGROKTTNBUGK-SJCJKPOMSA-N 0.000 description 1
- 239000005368 silicate glass Substances 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/26—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids
- C08G69/265—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids from at least two different diamines or at least two different dicarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/16—Solid spheres
- C08K7/18—Solid spheres inorganic
- C08K7/20—Glass
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyamides (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US46689983A | 1983-02-16 | 1983-02-16 | |
| US466,899 | 1990-01-18 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1244186A true CA1244186A (en) | 1988-11-01 |
Family
ID=23853507
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000446712A Expired CA1244186A (en) | 1983-02-16 | 1984-02-03 | Filled molded polyamide compositions |
Country Status (4)
| Country | Link |
|---|---|
| EP (2) | EP0291096A3 (en, 2012) |
| JP (1) | JPS59155426A (en, 2012) |
| CA (1) | CA1244186A (en, 2012) |
| DE (1) | DE3476211D1 (en, 2012) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3407492A1 (de) * | 1984-03-01 | 1985-09-05 | Bayer Ag, 5090 Leverkusen | Verfahren zur herstellung von copolyamiden aus adipinsaeure, terephthalsaeure und hexamethylendiamin |
| DE3506656A1 (de) * | 1985-02-26 | 1986-08-28 | Bayer Ag, 5090 Leverkusen | Verfahren zur herstellung von copolyamiden aus aromatischen dicarbonsaeuren, adipinsaeure und hexamethylendiamin |
| JPS61283654A (ja) * | 1985-06-11 | 1986-12-13 | Sumitomo Chem Co Ltd | 樹脂組成物 |
| JPS61283653A (ja) * | 1985-06-11 | 1986-12-13 | Sumitomo Chem Co Ltd | 樹脂組成物 |
| JPS6236459A (ja) * | 1985-08-10 | 1987-02-17 | Mitsui Petrochem Ind Ltd | ポリアミド組成物及びその製造方法 |
| DE3717218A1 (de) * | 1987-05-22 | 1989-03-23 | Bayer Ag | Glasfaserverstaerkte stabilisierte polyamidformmasse |
| DE58908791D1 (de) * | 1988-07-13 | 1995-02-02 | Basf Ag | Flammgeschützte thermoplastische Formmassen auf der Basis teilaromatischer Copolyamide. |
| EP0361636B1 (en) | 1988-09-30 | 1995-01-11 | Amoco Corporation | Polyamide-polyarylene sulfide blends |
| US5324766A (en) * | 1989-07-07 | 1994-06-28 | Mitsui Petrochemical Industries, Ltd. | Resin composition for forming plated layer and use thereof |
| CA2020481A1 (en) * | 1989-07-21 | 1991-01-22 | John D. Matlack | Polyamide compositions having improved gas barrier properties |
| KR930010631B1 (ko) * | 1989-08-05 | 1993-11-02 | 디에스엠 엔. 브이. | 폴리아미드 조성물 |
| JP2871752B2 (ja) * | 1989-10-27 | 1999-03-17 | 三井化学株式会社 | 転がり軸受用保持器 |
| DE4404250A1 (de) * | 1994-02-10 | 1995-08-17 | Basf Ag | Teilaromatische Copolyamidformmassen mit hoher Kristallinität |
| CA2134542C (en) * | 1994-03-01 | 1998-07-07 | Asten, Inc. | Papermakers fabric of polyphthalamide monofilament |
| KR100344888B1 (ko) | 1994-08-17 | 2002-11-23 | 도레이 가부시끼가이샤 | 공중합폴리아미드및그의제조방법 |
| EP0906929B1 (en) * | 1997-10-03 | 2003-12-03 | M & S Research and Development Co., Ltd. | Method of producing polyamide resin |
| CN1308374C (zh) | 2002-08-30 | 2007-04-04 | 东洋纺织株式会社 | 聚酰胺的连续制备方法 |
| DE102004029935B4 (de) | 2004-06-21 | 2007-08-09 | Pe Polymer Engineering Gmbh & Co Forschungs Kg | Verfahren zur kontinuierlichen Herstellung von Copolyamiden mit Schmelzpunkten oberhalb von 265 C |
| US8309640B2 (en) | 2008-05-23 | 2012-11-13 | Sabic Innovative Plastics Ip B.V. | High dielectric constant laser direct structuring materials |
| JP2013544296A (ja) | 2010-10-25 | 2013-12-12 | サビック・イノベーティブ・プラスチックス・アイピー・ベスローテン・フェンノートシャップ | レーザダイレクトストラクチャリング材料の改善された無電解メッキ性能 |
| JP2013545832A (ja) | 2010-10-26 | 2013-12-26 | サビック・イノベーティブ・プラスチックス・アイピー・ベスローテン・フェンノートシャップ | すべての色特性を有するレーザダイレクトストラクチャリング材料 |
| US9185800B2 (en) | 2012-09-17 | 2015-11-10 | Sabic Global Technologies B.V. | Laser direct structuring materials with improved plating performance and acceptable mechanical properties |
| ES2568054T3 (es) * | 2014-04-01 | 2016-04-27 | Ems-Patent Ag | Masas de moldeo de poliamida, especialmente para la fabricación de piezas moldeadas en el sector del agua potable |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1114541A (en) * | 1965-09-16 | 1968-05-22 | Ici Ltd | Polyamide copolymers |
| FR2331633A1 (fr) * | 1975-11-12 | 1977-06-10 | Monsanto Co | Copolyamides statistiques formant des fibres, derivees d'hexamethylenediamine, d'acide terephtalique, d'acide isophtalique et d'un diacide aliphatique en c5 a c10 |
| US4238603A (en) * | 1977-05-19 | 1980-12-09 | Monsanto Company | Polyamides derived from hexamethylene diamine, terephthalic acid, isophthalic acid and a C5 to C10 aliphatic dibasic acid |
-
1984
- 1984-02-03 CA CA000446712A patent/CA1244186A/en not_active Expired
- 1984-02-07 EP EP19880107815 patent/EP0291096A3/en not_active Withdrawn
- 1984-02-07 EP EP84300744A patent/EP0121984B2/en not_active Expired - Lifetime
- 1984-02-07 DE DE8484300744T patent/DE3476211D1/de not_active Expired
- 1984-02-15 JP JP59026903A patent/JPS59155426A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| EP0121984A2 (en) | 1984-10-17 |
| DE3476211D1 (en) | 1989-02-23 |
| EP0121984A3 (en) | 1985-05-08 |
| EP0121984B2 (en) | 1995-11-29 |
| JPH0356576B2 (en, 2012) | 1991-08-28 |
| EP0291096A2 (en) | 1988-11-17 |
| JPS59155426A (ja) | 1984-09-04 |
| EP0121984B1 (en) | 1989-01-18 |
| EP0291096A3 (en) | 1991-10-02 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |