CA1230855A - Ground anode prepacked with backfill in a flexible structure for cathode protection with impressed currents - Google Patents

Ground anode prepacked with backfill in a flexible structure for cathode protection with impressed currents

Info

Publication number
CA1230855A
CA1230855A CA000452543A CA452543A CA1230855A CA 1230855 A CA1230855 A CA 1230855A CA 000452543 A CA000452543 A CA 000452543A CA 452543 A CA452543 A CA 452543A CA 1230855 A CA1230855 A CA 1230855A
Authority
CA
Canada
Prior art keywords
flexible
anodic
backfill
elements
external casing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA000452543A
Other languages
French (fr)
Inventor
Giuseppe Bianchi
Giuseppe Faita
Gianluigi Mussinelli
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Oronzio de Nora SA
Eltech Systems Corp
Original Assignee
Oronzio de Nora SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Oronzio de Nora SA filed Critical Oronzio de Nora SA
Application granted granted Critical
Publication of CA1230855A publication Critical patent/CA1230855A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23FNON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F13/00Inhibiting corrosion of metals by anodic or cathodic protection
    • C23F13/02Inhibiting corrosion of metals by anodic or cathodic protection cathodic; Selection of conditions, parameters or procedures for cathodic protection, e.g. of electrical conditions

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Prevention Of Electric Corrosion (AREA)
  • Electrolytic Production Of Metals (AREA)
  • Primary Cells (AREA)

Abstract

Abstract:

"Ground anode prepacked with backfill in a flexible structure for cathode protection with impressed currents"

Flexible ground anode prepacked with backfill for cathode protection with impressed currents, made up by a flexible anodic conductor (1), surrounded by backfill and coaxially centered as to the flexible external casing (2) by means of spacers (3), which function also as current distributors to the casing itself, and supporting the anodic elements (4). The flexible casing (2) and elements (3) are constituted by metallic materials corrodable by the current.

Description

"Ground anode repacked with backfill in a flexible structure for cathode protection with impressed currents"

This invention relates to a ground anode repacked with backfill in a flexible structure for cathode protection with impressed currents, comprising an anodic conductor held by means of special spacers in a substantially co-axial way inside a flexible casing made of corrodablemetallic material filled with a conductive carbon back-fill in loose form. The anode of this invention is therefore particularly useful for the electro-chemical protection of pipelines such as oil pipelines and gas pipelines, drilling platforms and, in general, any other type of metallic structure located in special natural environments.
The known types of ground anodes (see for example US patent 4,279,729, EPIC 0084875 published August 10, 1983 and EPIC 129886 published January 2, 1985 of the applicant, and JOY. Jacobs in Material Performances, 1981, PP. 17, 23) are usually installed according to the deep well technique or the horizontal ground-bed technique. The first technique calls or a hole in the soil near the structures to be protected, of the appropriate depth (usually 50 to 150 meters) and a diameter of ten or more centimeters. One pro-coeds then to lower the anodic chain in the above mentioned hole and to pump in backfill mixed with I' lZ3(~35~

water from the bottom of the hole. Once filled, the hole is closed, still leaving a means for the anodic gas to escape.
The problems connected with the deep well technic 5 qua come from the difficulty of pumping the backfill, which must be used in an extremely subdivided form and, therefore, does not generally favor the easy elimination of gases together with the necessity to free the hole of drilling mud before pumping.
10 It is necessary, moreover, to evaluate the level of backfill, calculating the volume pumped, or through resistance measurements on the anodes of the chain. Lastly, in the frequent case of well cawing recovery, the compactness of the backfill is negate-15 very influenced or disturbed.
In surface embedding, it is necessary to have trench which is first initially filled with back-fill; after the installation of the anodes which are spaced from one another together with complex 20 lion of the electric connections between the various anodes and linking cable to the rectifier, the iron-ah is filled with a second amount of backfill which may be compacted.
In surface installation, on the other hand, I-25 zeable quantities of backfill must be used wicker not strictly necessary for a low ground resis~an go. The above is made more difficult by the square, rather than circular, cross section of the trench, by the difficulties of achieving a good compactness of I, the backfill and by the possibility of bed discontinuity because of trench covering.
Both techniques, therefore, suffer from obvious practical and operative difficulties which have been sought to be remedied by repacked anodes in special con-trainers or rigid cartridges (see US patent n. 4,400,259, 3,725,699 and "Design and construction of replaceable deep anode ground beds JO Datum Thea. Into Conga. Metallic Corrosion (Thea ICMC), Main, W. Germany, Sept. 1981).
The use of such repacked electrodes overcomes specific problems relating to the backfilling of the well and trench, but leaves unsolved the logistic convenience use problems including installation. Also, a rigid structure of significant length in meters involves severe problems in transport and site installation.
The aim of the present invention, as defined in the claim, to to overcome the above mentioned problems.
The anodic structure, which is the subject matter of the present application, is such that it retains or keeps captive the external geometrical characteristics and the compactness of the backfill until the cathode protection plant is started.
The invention in its broadest aspect relates to a ground anode repacked with backfill for cathodic pro-section against impressed currents comprising: (a) acorrodable and flexible entirely metallic external casing;
(b) a flexible conductor coccal centered as to said .' owls - pa -external casing; (c) one or more anodic elements sun-rounding said flexible conductor, said one or more anodic elements being of such length and spaced at such intervals along said cable so as to maintain said conductor and anodic elements in a flexible condition; (d) one or more spacers connected at lengthwise intervals between the flexible external casing and said anodic elements, said spacers functioning to hold said anodic elements coaxial relative to said external casing; (e) repacked backfill compacted within said external casing and surrounding said anodic elements and flexible conductor; and (f) sealing elements at each end of the casing.
Commencing with the supply of current one has, the metallic parts which define the external flex-isle casing and the spacers which hold the anodicconductor coccal to the flexible and corrodible .' so casing and which, at the same time, contribute to the distribution of current on the external casing. Once the external casing is corroded to exhaustion the anode will be homogeneously surrounded by backfill and will provide an ideal output. Another advantage of this anode system is that of eliminating pumping and covering, a procedure which is often time consuming and inconvenient. This system on the contrary, offers an easy and quick install lotion means thanks to the flexibility of the structure, lo a characteristic which is particularly adaptable for transport. The correct backfill compaction during in-stallation is obtained by means of an elastic continued pressure generated by elements (screen, bands, etc.) of a suitable material positioned at intervals and at the ends of the anodic assembly. Thus an excessive crumb-lying of the particles of backfill is avoided during the above mentioned stages.
The following illustrates in greater detail the in-mention referring to the illustrations which represents an example of execution.
Figure 1 is a longitudinal view of the anode subject matter of the present invention, while Figure 2 is a cross section view. Reference 1 indicates the flexible anodic conductor, as a non limiting example produced in accordance with the EPIC 129886, centered coccal as to the external casing 2 by the spacer 3. The latter may So have the form of perorated disk to allow filling with coke, and is sufficiently elastic to permit electric contact between the central anode and the external casing.
The reference 4 indicate the anodic elements in the form of cable and wire between segments of tug best Element 5 represents a screen of appropriate material capable of providing an elastic thrust to the backfill 6. The end piece 7 is constituted of the appropriate plastic material (polypropylene, PVC, reinforced polyester) and both ends are fitted with a cable clamp 8 which blocks the cable.
The anodic conductor 1 consists of an electric cable with a rubber-covered copper core to which the anodic elements 4 are connected, which may be in the form of wire, tube, extruded cable, rod, etc.
The spacing between the various elements and the length of these guarantee the flexibility of the con doctor 1. The anodic materials which can be convey neonatal used include natural graphite or graphite treated with organic substances, Fe So or alloys Fe So Or, Platinum plated Titanium, Niobium or Tantalum, with or without a copper conducting core, possibly activated by means of metal oxide conductors and/or ceramic coverings.
The flexible external casing 2 and the spacers 3 are, instead, made of an electro-corrodable metallic material, for example galvanized iron, Fe, Al, Cut or alloys of these. The casing 2 is flexible, mocha Nikolai resistant and extensible.
The backfill is, lastly, appropriately constituted of graphite, metallurgical coke or calcined petroleum coke, in lose form or fixed with no more than that 10% of organic glue or a fluidizing agent.
The backfill, the particles of which will prefer-by have a diameter no greater than 10 mm, is compact ted by vibration inside the casing 2 and therefore subjected to an elastic thrust by means of element S.
The dimensions of the anodic structure of the invent lion, in themselves not critical, will normally be between 1 and 10 meters in length and from 10 to 500 mm in diameter, preferably from 100 to 300 mm. Mario us units can be joined together in series to achieve the desired total length, up to 100 meters for exam-pie. The current produced, as will be obvious to the expert of the field, will be a function of the type of backfill, its compaction, etc. and will normally be between Owls A/m and 8 A/ , though this range would not be considered as a limit. It is moreover obvious that many changes of form, materials, dime sons, etc.) can be made to the anodic structure sub jet matter of this invention, without deviating from inventive concept of this invention.

Claims (8)

Claims:
1. A ground anode prepacked with backfill for cathodic protection against impressed currents comprising:
(a) a corrodable and flexible entirely metallic external casing;
(b) a flexible conductor coaxially centered as to said external casing;
(c) one or more anodic elements surrounding said flexible conductor, said one or more anodic elements being of such length and spaced at such intervals along said cable so as to maintain said conductor and anodic elements in a flexible condition;
(d) one or more spacers connected at lengthwise intervals between the flexible external casing and said anodic elements, said spacers functioning to hold said ano-dic elements coaxial relative to said external casing;
(e) prepacked backfill compacted within said external casing and surrounding said anodic elements and flexible conductor; and (f) sealing elements at each end of the casing.
2. The ground anode as defined in claim 1, further comprising one or more elastomeric screens at intervals along said flexible external casing to compress said backfill.
3. A ground anode according to claim 1, wherein said external casing is made from corrodable materials from the group consisting of iron, galvanized iron, aluminum, copper, and alloys thereof.
4. A ground anode according to claim 1, wherein the backfill is composed of materials from the group consist-ing of graphite, metallurgical coke, calcined petroleum coke and mixtures thereof, in loose form or held together with no more than 10% of organic glue or a fluiding agent, with particle diameter less than, or equal to, 10 mm.
5. A ground anode according to claim 1, wherein the anodic elements are composed of materials from the group consisting of natural graphite or graphite treated with organic substances, iron and silicon or iron and silicon and chromium alloys or platinum plated titanium, niobium or tantalum with or without a copper conducting core.
6. A ground anode according to claim 1, wherein the length of the anode is between 1 and 10 meters and a diameter of between 10 and 500 mm.
7. A ground anode according to claim 1, wherein several units are joined together in series to achieve the total length desired up to 100 meters.
8. A cathode protection process for metallic structures subject to electrochemical corrosion comprising:
(a) connecting the metallic structure to the negative pole of an electric current source;
(b) constructing an anodic structure by coaxially center-ing one or more flexible anodic elements surrounding a flexible conductor within a corrodable flexible entirely metallic external casing by using one or more spacers between said one or more flexible anodic elements and said flexible entirely metallic casing;
(c) packing said anodic structure with backfill between said external casing and said one or more flexible anodic elements;
(d) sealing said anodic structure; and (e) connecting said anodic structure to the positive pole of said electric current source.
CA000452543A 1983-12-23 1984-04-19 Ground anode prepacked with backfill in a flexible structure for cathode protection with impressed currents Expired CA1230855A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IT24356/83A IT1170053B (en) 1983-12-23 1983-12-23 PRE-PACKED DISPERSER ANODE WITH BACKFILL IN FLEXIBLE STRUCTURE FOR CATHODIC PROTECTION WITH IMPRESSED CURRENTS
IT24356A/83 1983-12-23

Publications (1)

Publication Number Publication Date
CA1230855A true CA1230855A (en) 1987-12-29

Family

ID=11213239

Family Applications (1)

Application Number Title Priority Date Filing Date
CA000452543A Expired CA1230855A (en) 1983-12-23 1984-04-19 Ground anode prepacked with backfill in a flexible structure for cathode protection with impressed currents

Country Status (7)

Country Link
US (1) US4544464A (en)
EP (1) EP0147505B1 (en)
JP (1) JPS60136183A (en)
AT (1) ATE39368T1 (en)
CA (1) CA1230855A (en)
DE (1) DE3475722D1 (en)
IT (1) IT1170053B (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9413855B2 (en) 2013-12-17 2016-08-09 International Business Machines Corporation Expanding an answer key to verify a question and answer system
US9607035B2 (en) 2014-05-21 2017-03-28 International Business Machines Corporation Extensible validation framework for question and answer systems

Families Citing this family (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3541845C1 (en) * 1985-11-27 1987-01-08 Heraeus Elektroden Tubular electrode for electrolytic processes
GB8804859D0 (en) * 1988-03-01 1988-03-30 Ici Plc Electrode & construction thereof
US5080773A (en) * 1990-05-11 1992-01-14 Cathodic Engineering Equipment Co., Inc. Ground electrode backfill
AU661822B2 (en) * 1991-04-15 1995-08-10 N.V. Raychem S.A. Method for electric protection of metal object, grounding electrode for implementing the method and composition for grounding electrode
GB9116114D0 (en) * 1991-07-25 1991-09-11 Raychem Ltd Corrosion protection system
GB9221706D0 (en) * 1992-10-15 1992-12-02 Raychem Sa Nv Repair of damaged electrode in impressed current corrosion protection system
US5547311A (en) * 1993-10-01 1996-08-20 Kenda; William P. Cathodic protection, leak detection, and thermal remediation system
US5948218A (en) * 1994-04-21 1999-09-07 N.V. Raychem S.A. Corrosion protection system
US6121543A (en) * 1998-07-06 2000-09-19 Hallmark; Clayton L. Groundbed electrode with graphite containing cement
WO2001037377A2 (en) * 1999-10-11 2001-05-25 Ashok Tripathy Safe earthing electrode
US6508349B1 (en) 2001-02-23 2003-01-21 Scott J. Lewin Parking meter with electric grounding arrangement for corrosion reduction
MXPA01012516A (en) * 2001-10-19 2003-06-16 Huerta Ceballos Hector Monolithic anodes prepackaging, new system of cathodic protection for saving of electric energy and anodes useful life.
KR20020019941A (en) * 2002-01-28 2002-03-13 조옥현 Ground
US20060005967A1 (en) * 2002-08-19 2006-01-12 Sirola D B Deep well anodes for electrical grounding
US7578910B2 (en) * 2002-08-19 2009-08-25 Sae Inc. Deep well anodes for electrical grounding
US20040099982A1 (en) * 2002-08-19 2004-05-27 Sirola D. Brien Conductive concrete compositions and methods of manufacturing same
WO2009145994A1 (en) * 2008-03-31 2009-12-03 Michael Steven Georgia Polymeric, non-corrosive cathodic protection anode
US7875157B2 (en) * 2008-04-30 2011-01-25 Moor Anode, Inc. Composite anode well and revitilization method
CN102544779A (en) * 2011-08-16 2012-07-04 湖北威达电气有限公司 Novel anti-corrosion grounding body with cathode protection function and method for manufacturing novel anti-corrosion grounding body
AU2013247398A1 (en) * 2012-04-11 2014-11-27 Anode Engineering Pty Ltd Cathodic protection system
DE102013216134A1 (en) * 2013-08-14 2015-02-19 Krones Ag Precoat candle filter and filter cartridge with inner body
US9850584B2 (en) 2014-06-23 2017-12-26 Matcor, Inc. Anode assembly with reduced attenuation properties for cathodic protection systems
RU2595787C1 (en) * 2015-06-04 2016-08-27 Открытое акционерное общество "МАГНИТ" Packed anode bed
RU167352U1 (en) * 2016-04-06 2017-01-10 Общество с ограниченной ответственностью "Газпром трансгаз Санкт-Петербург" ANODE GROUNDER
RU173093U1 (en) * 2016-11-29 2017-08-10 Александр Алексеевич Делекторский DEPTH ANODE EARTH
US10333234B2 (en) 2017-08-14 2019-06-25 Shore Acres Enterprises Inc. Corrosion-protective jacket for electrode
CA3019309A1 (en) 2017-10-04 2019-04-04 Shore Acres Enterprises Inc. (D/B/A Sae Inc.) Electrically-conductive corrosion-protective covering
USD956005S1 (en) * 2019-09-19 2022-06-28 Applied Materials, Inc. Shaped electrode
US11421392B2 (en) 2019-12-18 2022-08-23 Shore Acres Enterprises Inc. Metallic structure with water impermeable and electrically conductive cementitous surround
CN110923723A (en) * 2019-12-31 2020-03-27 贵州电网有限责任公司 Intelligent anticorrosion system and anticorrosion method for transformer substation grounding device

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2053214A (en) * 1934-04-21 1936-09-01 Union Carbide & Carbon Corp Electrode resistant to anodic attack
US3022242A (en) * 1959-01-23 1962-02-20 Engelhard Ind Inc Anode for cathodic protection systems
US3409530A (en) * 1965-10-20 1968-11-05 Continental Oil Co Helical electrode
CH457077A (en) * 1966-04-16 1968-05-31 Heraeus Gmbh W C Inner anode for cathodic corrosion protection of pipelines
US3527685A (en) * 1968-08-26 1970-09-08 Engelhard Min & Chem Anode for cathodic protection of tubular members
US3689395A (en) * 1969-06-20 1972-09-05 Mobil Oil Corp Cathodic protection system and delay-activation anode
US3616418A (en) * 1969-12-04 1971-10-26 Engelhard Min & Chem Anode assembly for cathodic protection systems
SE350003B (en) * 1971-02-16 1972-10-16 O Dale
US3725669A (en) * 1971-12-14 1973-04-03 J Tatum Deep anode bed for cathodic protection
GB2046789B (en) * 1979-01-19 1983-01-26 Imi Marston Ltd Impressed current systems for cathodic protection
US4279729A (en) * 1979-02-12 1981-07-21 Harco Corporation Anode and method of construction
US4268371A (en) * 1980-03-13 1981-05-19 The Duriron Company, Inc. Cable guide for a tubular anode
US4400259A (en) * 1981-08-18 1983-08-23 Matcor, Inc. Deep anode assembly
IT1150124B (en) * 1982-01-21 1986-12-10 Oronzio De Nora Impianti ANODIC STRUCTURE FOR CATHODIC PROTECTION

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9413855B2 (en) 2013-12-17 2016-08-09 International Business Machines Corporation Expanding an answer key to verify a question and answer system
US10567552B2 (en) 2013-12-17 2020-02-18 International Business Machines Corporation Expanding an answer key to verify a question and answer system
US9607035B2 (en) 2014-05-21 2017-03-28 International Business Machines Corporation Extensible validation framework for question and answer systems
US11042794B2 (en) 2014-05-21 2021-06-22 International Business Machines Corporation Extensible validation framework for question and answer systems

Also Published As

Publication number Publication date
IT8324356A0 (en) 1983-12-23
DE3475722D1 (en) 1989-01-26
ATE39368T1 (en) 1989-01-15
US4544464A (en) 1985-10-01
EP0147505B1 (en) 1988-12-21
JPS60136183A (en) 1985-07-19
EP0147505A1 (en) 1985-07-10
IT1170053B (en) 1987-06-03
JPS624835B2 (en) 1987-02-02

Similar Documents

Publication Publication Date Title
CA1230855A (en) Ground anode prepacked with backfill in a flexible structure for cathode protection with impressed currents
US4170532A (en) Deep well platinized anode carrier for cathodic protection system
US4786388A (en) Ground electrode backfill composition, anode bed and apparatus
US5080773A (en) Ground electrode backfill
US4452683A (en) Anodic structure for cathodic protection
US4710644A (en) Replaceable deep anode system
US3857776A (en) Deep submersible power electrode assembly for ground conduction of electricity
US4018715A (en) Ground electrode backfill composition
AU2009251723B2 (en) Polymeric, non-corrosive cathodic protection anode
US20050252775A1 (en) Electro-osmotic pulse (EOP) treatment system for structure and method of use therefor
CA2108469C (en) Method for electric protection of metal object, grounding electrode for effecting this method and composition for the grounding electrode
EP0195982B1 (en) System and use thereof for collecting chemical-physical, electrochemical and mechanical parameters for designing and/or operating cathodic protection plants
US5476576A (en) Impressed current cathodic protection system
RU2690581C1 (en) Anode bed
CN209836314U (en) Deep-well type anode ground bed for cathodic protection
CA1330318C (en) Cathodic protection of storage tank bottoms
US2552208A (en) Grounding device for electrical conductors
JPH05230678A (en) Inactive anode for electric current dispersion
JPH08239777A (en) Electrode device of well structure for galvanic protection
RU1565071C (en) Method of cathodic protection of extended metal objects against corrosion in electrolytic medium
JPS5838512B2 (en) Deep buried external power source cathode protection electrode device
RU2081941C1 (en) Deep anodic grounding conductor
Muller Cathodic corrosion protection for groundwater wells
BR102013009312A2 (en) DEVICE AND METHOD FOR BIODEGRATION INDUCTION AND MONITORING IN CONTAMINATED ENVIRONMENTS
Stalder Corrosion Behaviour of Cast Iron Pipes

Legal Events

Date Code Title Description
MKEX Expiry