CA1217651A - Method for rapid determination of the contents of lignin, monosaccharides and organic acids in the process solutions of sulfite pulping - Google Patents
Method for rapid determination of the contents of lignin, monosaccharides and organic acids in the process solutions of sulfite pulpingInfo
- Publication number
- CA1217651A CA1217651A CA000439202A CA439202A CA1217651A CA 1217651 A CA1217651 A CA 1217651A CA 000439202 A CA000439202 A CA 000439202A CA 439202 A CA439202 A CA 439202A CA 1217651 A CA1217651 A CA 1217651A
- Authority
- CA
- Canada
- Prior art keywords
- lignin
- monosaccharides
- sulfite
- cation
- ion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims abstract description 64
- 229920005610 lignin Polymers 0.000 title claims abstract description 47
- 150000002772 monosaccharides Chemical class 0.000 title claims abstract description 29
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 title claims abstract description 28
- 150000007524 organic acids Chemical class 0.000 title claims abstract description 15
- 235000005985 organic acids Nutrition 0.000 title claims abstract description 12
- 238000004537 pulping Methods 0.000 title claims abstract description 9
- 238000005259 measurement Methods 0.000 claims abstract description 60
- 238000010411 cooking Methods 0.000 claims abstract description 30
- 150000001875 compounds Chemical class 0.000 claims abstract description 23
- 239000000463 material Substances 0.000 claims abstract description 20
- 238000000926 separation method Methods 0.000 claims description 34
- 239000011347 resin Substances 0.000 claims description 11
- 229920005989 resin Polymers 0.000 claims description 11
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 claims description 10
- 238000005341 cation exchange Methods 0.000 claims description 10
- 238000010521 absorption reaction Methods 0.000 claims description 9
- 239000002245 particle Substances 0.000 claims description 6
- 238000009792 diffusion process Methods 0.000 claims description 4
- 239000002023 wood Substances 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 3
- 238000000711 polarimetry Methods 0.000 claims description 3
- CHRJZRDFSQHIFI-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;styrene Chemical compound C=CC1=CC=CC=C1.C=CC1=CC=CC=C1C=C CHRJZRDFSQHIFI-UHFFFAOYSA-N 0.000 claims 2
- 230000031700 light absorption Effects 0.000 claims 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical group OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 claims 2
- 239000006227 byproduct Substances 0.000 abstract description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 238000012512 characterization method Methods 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 20
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 6
- 239000002253 acid Substances 0.000 description 5
- 229920001732 Lignosulfonate Polymers 0.000 description 4
- 150000001720 carbohydrates Chemical class 0.000 description 4
- 235000014633 carbohydrates Nutrition 0.000 description 4
- HYBBIBNJHNGZAN-UHFFFAOYSA-N furfural Chemical compound O=CC1=CC=CO1 HYBBIBNJHNGZAN-UHFFFAOYSA-N 0.000 description 4
- 238000002798 spectrophotometry method Methods 0.000 description 4
- 235000000346 sugar Nutrition 0.000 description 4
- 150000008163 sugars Chemical class 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 230000007717 exclusion Effects 0.000 description 3
- 238000005342 ion exchange Methods 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 238000002211 ultraviolet spectrum Methods 0.000 description 3
- 241000510672 Cuminum Species 0.000 description 2
- 235000007129 Cuminum cyminum Nutrition 0.000 description 2
- 235000006679 Mentha X verticillata Nutrition 0.000 description 2
- 235000002899 Mentha suaveolens Nutrition 0.000 description 2
- 235000001636 Mentha x rotundifolia Nutrition 0.000 description 2
- 241000282320 Panthera leo Species 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 239000003729 cation exchange resin Substances 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 230000002452 interceptive effect Effects 0.000 description 2
- 239000003456 ion exchange resin Substances 0.000 description 2
- 229920003303 ion-exchange polymer Polymers 0.000 description 2
- 238000000691 measurement method Methods 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- NOEGNKMFWQHSLB-UHFFFAOYSA-N 5-hydroxymethylfurfural Chemical compound OCC1=CC=C(C=O)O1 NOEGNKMFWQHSLB-UHFFFAOYSA-N 0.000 description 1
- 235000009434 Actinidia chinensis Nutrition 0.000 description 1
- 244000298697 Actinidia deliciosa Species 0.000 description 1
- 235000009436 Actinidia deliciosa Nutrition 0.000 description 1
- IAJILQKETJEXLJ-UHFFFAOYSA-N Galacturonsaeure Natural products O=CC(O)C(O)C(O)C(O)C(O)=O IAJILQKETJEXLJ-UHFFFAOYSA-N 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- FRYDSOYOHWGSMD-UHFFFAOYSA-N [C].O Chemical class [C].O FRYDSOYOHWGSMD-UHFFFAOYSA-N 0.000 description 1
- IAJILQKETJEXLJ-QTBDOELSSA-N aldehydo-D-glucuronic acid Chemical compound O=C[C@H](O)[C@@H](O)[C@H](O)[C@H](O)C(O)=O IAJILQKETJEXLJ-QTBDOELSSA-N 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- GBAOBIBJACZTNA-UHFFFAOYSA-L calcium sulfite Chemical compound [Ca+2].[O-]S([O-])=O GBAOBIBJACZTNA-UHFFFAOYSA-L 0.000 description 1
- 235000010261 calcium sulphite Nutrition 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 150000001768 cations Chemical group 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 229940097043 glucuronic acid Drugs 0.000 description 1
- 150000002402 hexoses Chemical class 0.000 description 1
- RJGBSYZFOCAGQY-UHFFFAOYSA-N hydroxymethylfurfural Natural products COC1=CC=C(C=O)O1 RJGBSYZFOCAGQY-UHFFFAOYSA-N 0.000 description 1
- 210000004072 lung Anatomy 0.000 description 1
- JESHZQPNPCJVNG-UHFFFAOYSA-L magnesium;sulfite Chemical compound [Mg+2].[O-]S([O-])=O JESHZQPNPCJVNG-UHFFFAOYSA-L 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- -1 monosaccharides Chemical class 0.000 description 1
- 230000010355 oscillation Effects 0.000 description 1
- 150000002972 pentoses Chemical class 0.000 description 1
- 230000003389 potentiating effect Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 229940001482 sodium sulfite Drugs 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- DHCDFWKWKRSZHF-UHFFFAOYSA-N sulfurothioic S-acid Chemical compound OS(O)(=O)=S DHCDFWKWKRSZHF-UHFFFAOYSA-N 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
- G01N33/34—Paper
- G01N33/343—Paper pulp
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
- G01N30/96—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation using ion-exchange
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Immunology (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Physics & Mathematics (AREA)
- Pathology (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Medicinal Chemistry (AREA)
- Investigating Or Analysing Materials By Optical Means (AREA)
- Paper (AREA)
- Measuring Or Testing Involving Enzymes Or Micro-Organisms (AREA)
- Investigating Or Analysing Biological Materials (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FI823574 | 1982-10-19 | ||
| FI823574A FI69132C (fi) | 1982-10-19 | 1982-10-19 | Foerfarande foer en snabb bestaemning av halten av lignin monosackarider och organiska syror i sulfitcellulosakokningens processloesningar |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1217651A true CA1217651A (en) | 1987-02-10 |
Family
ID=8516177
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000439202A Expired CA1217651A (en) | 1982-10-19 | 1983-10-18 | Method for rapid determination of the contents of lignin, monosaccharides and organic acids in the process solutions of sulfite pulping |
Country Status (6)
| Country | Link |
|---|---|
| CA (1) | CA1217651A (fi) |
| CS (1) | CS253708B2 (fi) |
| DE (1) | DE3337833C2 (fi) |
| FI (1) | FI69132C (fi) |
| NO (1) | NO157473C (fi) |
| SE (1) | SE458615B (fi) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101105444B (zh) * | 2007-04-10 | 2010-05-26 | 新疆农业科学院核技术生物技术研究所 | 一种棉花纤维中木质素含量的检测分析方法 |
| WO2015037647A1 (ja) * | 2013-09-11 | 2015-03-19 | 日本製紙株式会社 | 溶解クラフトパルプの製造方法 |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4718979A (en) * | 1983-10-18 | 1988-01-12 | Oy Advanced Forest Automation Ab | Method for rapid determination of the contents of lignin, monosaccharides and organic acids in the process solutions of sulfite pulping |
| FI67581C (fi) * | 1983-12-30 | 1985-04-10 | Advanced Forest Automation Ab | Foerfarande foer snabb bestaemning av halten av totalsvaveldioxid och lignosulfonat i sulfitcellulosakokets processloesning |
| DE3625859A1 (de) * | 1986-07-31 | 1988-02-11 | Volker Heidger | Verfahren zur bestimmung des gehaltes einer waessrigen loesung an organischen substanzen |
-
1982
- 1982-10-19 FI FI823574A patent/FI69132C/fi not_active IP Right Cessation
-
1983
- 1983-05-20 SE SE8302870A patent/SE458615B/sv not_active IP Right Cessation
- 1983-05-20 NO NO831782A patent/NO157473C/no unknown
- 1983-10-18 CS CS837623A patent/CS253708B2/cs unknown
- 1983-10-18 CA CA000439202A patent/CA1217651A/en not_active Expired
- 1983-10-18 DE DE19833337833 patent/DE3337833C2/de not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101105444B (zh) * | 2007-04-10 | 2010-05-26 | 新疆农业科学院核技术生物技术研究所 | 一种棉花纤维中木质素含量的检测分析方法 |
| WO2015037647A1 (ja) * | 2013-09-11 | 2015-03-19 | 日本製紙株式会社 | 溶解クラフトパルプの製造方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| FI823574A0 (fi) | 1982-10-19 |
| FI823574L (fi) | 1984-04-20 |
| FI69132B (fi) | 1985-08-30 |
| NO157473B (no) | 1987-12-14 |
| SE8302870L (sv) | 1984-04-20 |
| SE458615B (sv) | 1989-04-17 |
| NO157473C (no) | 1988-03-23 |
| SE8302870D0 (sv) | 1983-05-20 |
| DE3337833C2 (de) | 1985-11-21 |
| CS253708B2 (en) | 1987-12-17 |
| CS762383A2 (en) | 1987-05-14 |
| FI69132C (fi) | 1985-12-10 |
| DE3337833A1 (de) | 1984-04-19 |
| NO831782L (no) | 1984-04-24 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |