CA1205747A - Soft cleansing compound - Google Patents
Soft cleansing compoundInfo
- Publication number
- CA1205747A CA1205747A CA000438406A CA438406A CA1205747A CA 1205747 A CA1205747 A CA 1205747A CA 000438406 A CA000438406 A CA 000438406A CA 438406 A CA438406 A CA 438406A CA 1205747 A CA1205747 A CA 1205747A
- Authority
- CA
- Canada
- Prior art keywords
- composition according
- fact
- weight
- chosen
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000001875 compounds Chemical class 0.000 title claims description 6
- 239000000203 mixture Substances 0.000 claims abstract description 83
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 23
- 238000004140 cleaning Methods 0.000 claims abstract description 16
- 229920000642 polymer Polymers 0.000 claims abstract description 15
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 6
- 210000004209 hair Anatomy 0.000 claims abstract description 6
- 229920013820 alkyl cellulose Polymers 0.000 claims abstract description 5
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims abstract description 5
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims abstract description 5
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims abstract description 5
- HOVAGTYPODGVJG-UVSYOFPXSA-N (3s,5r)-2-(hydroxymethyl)-6-methoxyoxane-3,4,5-triol Chemical compound COC1OC(CO)[C@@H](O)C(O)[C@H]1O HOVAGTYPODGVJG-UVSYOFPXSA-N 0.000 claims abstract description 4
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 claims abstract description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 4
- HOVAGTYPODGVJG-UHFFFAOYSA-N methyl beta-galactoside Natural products COC1OC(CO)C(O)C(O)C1O HOVAGTYPODGVJG-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229920001577 copolymer Polymers 0.000 claims abstract description 3
- 229930182478 glucoside Natural products 0.000 claims abstract description 3
- 150000002338 glycosides Chemical group 0.000 claims abstract description 3
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims abstract description 3
- -1 glucoside alkyl ethers Chemical class 0.000 claims description 14
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 9
- 239000000243 solution Substances 0.000 claims description 9
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 7
- 239000000194 fatty acid Substances 0.000 claims description 7
- 229930195729 fatty acid Natural products 0.000 claims description 7
- 239000004094 surface-active agent Substances 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 206010000496 acne Diseases 0.000 claims description 5
- 239000004480 active ingredient Substances 0.000 claims description 5
- 239000004599 antimicrobial Substances 0.000 claims description 5
- 229960001915 hexamidine Drugs 0.000 claims description 5
- OQLKNTOKMBVBKV-UHFFFAOYSA-N hexamidine Chemical compound C1=CC(C(=N)N)=CC=C1OCCCCCCOC1=CC=C(C(N)=N)C=C1 OQLKNTOKMBVBKV-UHFFFAOYSA-N 0.000 claims description 5
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 4
- 150000003254 radicals Chemical group 0.000 claims description 4
- 208000002874 Acne Vulgaris Diseases 0.000 claims description 3
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 3
- 239000007864 aqueous solution Substances 0.000 claims description 3
- 229960003260 chlorhexidine Drugs 0.000 claims description 3
- 239000006071 cream Substances 0.000 claims description 3
- 239000000839 emulsion Substances 0.000 claims description 3
- 150000004665 fatty acids Chemical class 0.000 claims description 3
- 239000000499 gel Substances 0.000 claims description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- 235000013336 milk Nutrition 0.000 claims description 3
- 239000008267 milk Substances 0.000 claims description 3
- 210000004080 milk Anatomy 0.000 claims description 3
- 239000003755 preservative agent Substances 0.000 claims description 3
- 239000000600 sorbitol Substances 0.000 claims description 3
- ARIWANIATODDMH-AWEZNQCLSA-N 1-lauroyl-sn-glycerol Chemical compound CCCCCCCCCCCC(=O)OC[C@@H](O)CO ARIWANIATODDMH-AWEZNQCLSA-N 0.000 claims description 2
- XZIIFPSPUDAGJM-UHFFFAOYSA-N 6-chloro-2-n,2-n-diethylpyrimidine-2,4-diamine Chemical compound CCN(CC)C1=NC(N)=CC(Cl)=N1 XZIIFPSPUDAGJM-UHFFFAOYSA-N 0.000 claims description 2
- 239000005725 8-Hydroxyquinoline Substances 0.000 claims description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
- GHXZTYHSJHQHIJ-UHFFFAOYSA-N Chlorhexidine Chemical compound C=1C=C(Cl)C=CC=1NC(N)=NC(N)=NCCCCCCN=C(N)N=C(N)NC1=CC=C(Cl)C=C1 GHXZTYHSJHQHIJ-UHFFFAOYSA-N 0.000 claims description 2
- 235000013162 Cocos nucifera Nutrition 0.000 claims description 2
- 244000060011 Cocos nucifera Species 0.000 claims description 2
- ARIWANIATODDMH-UHFFFAOYSA-N Lauric acid monoglyceride Natural products CCCCCCCCCCCC(=O)OCC(O)CO ARIWANIATODDMH-UHFFFAOYSA-N 0.000 claims description 2
- 239000002671 adjuvant Substances 0.000 claims description 2
- 239000000443 aerosol Substances 0.000 claims description 2
- 125000004429 atom Chemical group 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- 239000000975 dye Substances 0.000 claims description 2
- 239000003995 emulsifying agent Substances 0.000 claims description 2
- 229920001249 ethyl cellulose Polymers 0.000 claims description 2
- 235000019325 ethyl cellulose Nutrition 0.000 claims description 2
- WCYWZMWISLQXQU-UHFFFAOYSA-N methyl Chemical compound [CH3] WCYWZMWISLQXQU-UHFFFAOYSA-N 0.000 claims description 2
- 229920000609 methyl cellulose Polymers 0.000 claims description 2
- 235000010981 methylcellulose Nutrition 0.000 claims description 2
- 229960003540 oxyquinoline Drugs 0.000 claims description 2
- 239000002304 perfume Substances 0.000 claims description 2
- 239000003380 propellant Substances 0.000 claims description 2
- MCJGNVYPOGVAJF-UHFFFAOYSA-N quinolin-8-ol Chemical compound C1=CN=C2C(O)=CC=CC2=C1 MCJGNVYPOGVAJF-UHFFFAOYSA-N 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- 229940035044 sorbitan monolaurate Drugs 0.000 claims description 2
- 239000002562 thickening agent Substances 0.000 claims description 2
- ICUTUKXCWQYESQ-UHFFFAOYSA-N triclocarban Chemical compound C1=CC(Cl)=CC=C1NC(=O)NC1=CC=C(Cl)C(Cl)=C1 ICUTUKXCWQYESQ-UHFFFAOYSA-N 0.000 claims description 2
- 241001331845 Equus asinus x caballus Species 0.000 claims 1
- 229960000686 benzalkonium chloride Drugs 0.000 claims 1
- XKXHCNPAFAXVRZ-UHFFFAOYSA-N benzylazanium;chloride Chemical compound [Cl-].[NH3+]CC1=CC=CC=C1 XKXHCNPAFAXVRZ-UHFFFAOYSA-N 0.000 claims 1
- 239000002537 cosmetic Substances 0.000 claims 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 1
- 239000003352 sequestering agent Substances 0.000 claims 1
- 150000005215 alkyl ethers Chemical class 0.000 abstract description 2
- 150000008131 glucosides Chemical class 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 15
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 7
- 210000002374 sebum Anatomy 0.000 description 7
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 6
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 6
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 6
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 6
- 238000005406 washing Methods 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 230000002421 anti-septic effect Effects 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 230000009089 cytolysis Effects 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- GPRLSGONYQIRFK-MNYXATJNSA-N triton Chemical compound [3H+] GPRLSGONYQIRFK-MNYXATJNSA-N 0.000 description 4
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 description 3
- 239000004292 methyl p-hydroxybenzoate Substances 0.000 description 3
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 description 3
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- GQPLMRYTRLFLPF-UHFFFAOYSA-N Nitrous Oxide Chemical compound [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 description 2
- 229920001213 Polysorbate 20 Polymers 0.000 description 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
- HVYWMOMLDIMFJA-DPAQBDIFSA-N cholesterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 HVYWMOMLDIMFJA-DPAQBDIFSA-N 0.000 description 2
- ALEXXDVDDISNDU-JZYPGELDSA-N cortisol 21-acetate Chemical compound C1CC2=CC(=O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@@](C(=O)COC(=O)C)(O)[C@@]1(C)C[C@@H]2O ALEXXDVDDISNDU-JZYPGELDSA-N 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- 210000003743 erythrocyte Anatomy 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 229920000831 ionic polymer Polymers 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 description 2
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 210000002268 wool Anatomy 0.000 description 2
- YYGNTYWPHWGJRM-UHFFFAOYSA-N (6E,10E,14E,18E)-2,6,10,15,19,23-hexamethyltetracosa-2,6,10,14,18,22-hexaene Chemical compound CC(C)=CCCC(C)=CCCC(C)=CCCC=C(C)CCC=C(C)CCC=C(C)C YYGNTYWPHWGJRM-UHFFFAOYSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- RUFPHBVGCFYCNW-UHFFFAOYSA-N 1-naphthylamine Chemical compound C1=CC=C2C(N)=CC=CC2=C1 RUFPHBVGCFYCNW-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 201000004624 Dermatitis Diseases 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 206010018910 Haemolysis Diseases 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- UOZODPSAJZTQNH-UHFFFAOYSA-N Paromomycin II Natural products NC1C(O)C(O)C(CN)OC1OC1C(O)C(OC2C(C(N)CC(N)C2O)OC2C(C(O)C(O)C(CO)O2)N)OC1CO UOZODPSAJZTQNH-UHFFFAOYSA-N 0.000 description 1
- 229920003081 Povidone K 30 Polymers 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 229920013806 TRITON CG-110 Polymers 0.000 description 1
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 1
- BHEOSNUKNHRBNM-UHFFFAOYSA-N Tetramethylsqualene Natural products CC(=C)C(C)CCC(=C)C(C)CCC(C)=CCCC=C(C)CCC(C)C(=C)CCC(C)C(C)=C BHEOSNUKNHRBNM-UHFFFAOYSA-N 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 230000016571 aggressive behavior Effects 0.000 description 1
- 125000006177 alkyl benzyl group Chemical group 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 208000010668 atopic eczema Diseases 0.000 description 1
- 229960001716 benzalkonium Drugs 0.000 description 1
- CYDRXTMLKJDRQH-UHFFFAOYSA-N benzododecinium Chemical compound CCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 CYDRXTMLKJDRQH-UHFFFAOYSA-N 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- ZCILODAAHLISPY-UHFFFAOYSA-N biphenyl ether Natural products C1=C(CC=C)C(O)=CC(OC=2C(=CC(CC=C)=CC=2)O)=C1 ZCILODAAHLISPY-UHFFFAOYSA-N 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000000988 bone and bone Anatomy 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- SXPWTBGAZSPLHA-UHFFFAOYSA-M cetalkonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 SXPWTBGAZSPLHA-UHFFFAOYSA-M 0.000 description 1
- 229960000228 cetalkonium chloride Drugs 0.000 description 1
- 235000012000 cholesterol Nutrition 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N dodecahydrosqualene Natural products CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 230000008588 hemolysis Effects 0.000 description 1
- 229940051250 hexylene glycol Drugs 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 1
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 239000001272 nitrous oxide Substances 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- RARSHUDCJQSEFJ-UHFFFAOYSA-N p-Hydroxypropiophenone Chemical compound CCC(=O)C1=CC=C(O)C=C1 RARSHUDCJQSEFJ-UHFFFAOYSA-N 0.000 description 1
- 239000008363 phosphate buffer Substances 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 210000002966 serum Anatomy 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 229940031439 squalene Drugs 0.000 description 1
- TUHBEKDERLKLEC-UHFFFAOYSA-N squalene Natural products CC(=CCCC(=CCCC(=CCCC=C(/C)CCC=C(/C)CC=C(C)C)C)C)C TUHBEKDERLKLEC-UHFFFAOYSA-N 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
- A61K8/416—Quaternary ammonium compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/43—Guanidines
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/60—Sugars; Derivatives thereof
- A61K8/604—Alkylpolyglycosides; Derivatives thereof, e.g. esters
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/731—Cellulose; Quaternized cellulose derivatives
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
- A61K8/8176—Homopolymers of N-vinyl-pyrrolidones. Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/88—Polyamides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/52—Stabilizers
Abstract
L'invention concerne une composition de nettoyage doux contenant dans un milieu cosmétiquement acceptable au moins un agent tensio-actif non ionique choisi parmi (i) les alkyléthers de glucoside répondant à la formule: <IMG> (I) dans laquelle R désigne un radical alkyle ayant 8 à 10 atomes de carbone, n est égal à 0, 1, 2, 3 ou 4; (ii) le dioléate de méthylglucoside oxyéthyléné, (iii) les alcoyl ou hydroxyalcoyl polyglycosides comportant un radical alcoyle ayant 11 à 18 atomes de carbone et un nombre de motifs glycosides compris entre 3 et 25 ou leurs mélanges; et au moins un polymère non ionique choisi parmi (i) les alkylcelluloses; (ii) les polyhydroxyalkylcelluloses; (iii) les poly-.beta.-alanines; (iv) la polyvinylpyrrolidone ou les copolymères de vinylpyrrolidone avec des comonomères non-ioniques, ou leurs mélanges. La composition selon l'invention est utilisable notamment pour le nettoyage des cheveux et de la peau et présente des propriétés d'innocuité et de détergence améliorées par rapport aux compositions ne contenant que le tensio-actif non ionique.The invention relates to a gentle cleaning composition containing in a cosmetically acceptable medium at least one nonionic surfactant chosen from (i) the alkyl ethers of glucoside corresponding to the formula: <IMG> (I) in which R denotes a radical alkyl having 8 to 10 carbon atoms, n is 0, 1, 2, 3 or 4; (ii) the oxyethylenated methylglucoside dioleate, (iii) the alkyl or hydroxyalkyl polyglycosides comprising an alkyl radical having 11 to 18 carbon atoms and a number of glycoside units between 3 and 25 or their mixtures; and at least one nonionic polymer chosen from (i) alkylcelluloses; (ii) polyhydroxyalkylcelluloses; (iii) poly-.beta.-alanines; (iv) polyvinylpyrrolidone or copolymers of vinylpyrrolidone with nonionic comonomers, or their mixtures. The composition according to the invention can be used in particular for cleaning the hair and the skin and has improved safety and detergency properties compared to the compositions containing only the nonionic surfactant.
Description
I,a présente invention est relative à de nouvelles compositions de nettoyaye doux utilisables notamment pour le nettoyage des cheveux et de la peau, ou de démaquillage des yeux.
Les tensio-actifs non ioniques sont bien connus dans l'état de la technique et ont été utilisés couramment dans les préparations de nettoyage de la peau ou des cheveux.
La Demanderesse a découvert qu'en associant certains des agents tensio-actifs non ioni~ues avec des polymères non ionique bien particuliers, il était possible d'obtenir une composition de nettoyage doux, présentant des propriét~s d'in-nocuité et de détergence améliorées par rapport aux composi-tions ne contenant que le tensio-actif non ionique~
La Demanderesse a en effet découvert qu'en associant certains tensio-actifs non ioniques avec certains polymères non ioniques, on obtenait une composition très peu agressive dont les points de demi-lyse des hématie~ sont relativement élevés par rapport aux compositions dites de nettoyage doux à
base de tensio-actifsnon ioniques.
La Demanderesse a découvert également que l'on amé-liorait de façon importante la détergence de la composition par rapport aux propriétes de détergence du tensio-acti~ non ionique utilisé seul dans une composition classique.
Afin de déterminer la détergence et l'agressivité
des compositions de nettoyage, la Demanderesse a mis au point les deux essais suivants.
Mesure de l'agressivité
L'agressivité est déterminée par hémolyse des héma-! ties d'échantillon de sang. On examine ~ cet effet les points de demi-lyse des différentes compositions. On appella point de demi lyse la concentration du produit dilué dans du sérum p~ysiologique qui provoque la lyse de 50% des hématies~
Plus le point de demi~lyse est elevé, moins la composition de net~oyage est agressive.
D ermination de la détergence On dépose sur des échantillons de laine une quanti-té déterminée de sébum sous la forme d'une tache. Après lavage des échantillons dans des conditions standards avec une machine automatique et séchage, la quantité de sébum rési-duelle est mise en évidence par révélation à l'aide d'acide osmique. On obtient ainsi une tache qui, suivan-t la quantité
de sébum restant, a une coloration allant du gris pale au noir~ Plus la tache est foncée, plus la quantité de sébum restant est importante et plus la détergence de la composi-tion étudiée est faible.
La méthode suivante est utilisée et on effectue toutes les mesures en double. Sur un échantillon de laine vierge, on applique 70 mg de sébum artificiel ayant la com-position suivante:
Squalène 97% 19%
Cholestérol puriss5%
Triolélne technique45%
Acid oléique pur 31%.
On procède ensuite au lavage avec une machine automatique~
principalement constituée d'un plate-au mobile, d'un rouleau presseur et de gicleurs délivrant l'eau pour le rinçage~ -Le plateau, lorsqu'il se trouve en action, est animé d'un mouvement alternatif et dlune fréquence de 20 pas-sages par minute (+ ou - 3 secondes).
Après avoir fixé l'échantillon sur le plateau, on dépose sur le tissu, 0,75 ml de la compo~ition ~ tester et on effeckue 60 passages de rouleau (3 minutes)~ On rince ensuite en dispersant 240 ml d'eau et en déplaçant p'lateau et ~ 2 --rouleau pendant 3 minutes (60 passages).
Le lavage est ensuite répété avec 0,5 ml de compo-sition ~ tester, 6Q passages de rouleau et rin~ags avec I, the present invention relates to new gentle cleansing compositions which can be used in particular for hair and skin cleansing, or makeup removal eyes.
Nonionic surfactants are well known in state of the art and have been widely used in skin or hair cleansing preparations.
The Applicant has discovered that by associating certain non-ionic surfactants ~ ues with non-polymeric very specific ionic, it was possible to obtain a gentle cleaning composition, having properties of s improved harmlessness and detergency compared to compounds tions containing only the nonionic surfactant ~
The Applicant has indeed discovered that by associating certain non-ionic surfactants with certain polymers non-ionic, we got a very mild composition whose semi-lysis points of the red blood cells are relatively high compared to so-called gentle cleaning compositions based on non-ionic surfactants.
The Applicant has also discovered that would significantly improve the detergency of the composition compared to the detergency properties of the surfactant ~ no ionic used alone in a conventional composition.
To determine detergency and aggressiveness cleaning compositions, the Applicant has developed the next two tests.
Measuring aggressiveness Aggression is determined by hemolysis of hema-! blood sample ties. We examine ~ for this purpose the points half-lysis of the different compositions. We called point half lysis the concentration of the product diluted in serum p ~ ysiological which causes the lysis of 50% of red blood cells ~
The higher the half lysis point, the lower the composition of net ~ oyage is aggressive.
Determination of detergency A quantity of wool is deposited on determined tee of sebum in the form of a spot. After washing of samples under standard conditions with an automatic drying machine, the amount of sebum remains dual is revealed by revelation using acid osmic. We thus obtain a spot which, following the quantity of sebum remaining, has a color ranging from pale gray to black ~ The darker the stain, the more sebum the more important the detergency of the compound tion studied is weak.
The following method is used and we perform all duplicate measurements. On a wool sample virgin, apply 70 mg of artificial sebum having the next position:
Squalene 97% 19%
Cholesterol puriss5%
Technical triolelon 45%
Pure oleic acid 31%.
Then we wash with an automatic machine ~
mainly consisting of a mobile platform, a roller presser and sprinklers delivering water for rinsing ~ -The tray, when in action, is driven by an alternating movement and a frequency of 20 steps-wise per minute (+ or - 3 seconds).
After fixing the sample on the plate, we deposit on the fabric, 0.75 ml of the composition ~ test ~ and 60 roll passages are removed (3 minutes) ~ Rinsed then by dispersing 240 ml of water and moving the shelf and ~ 2 -roller for 3 minutes (60 passes).
The washing is then repeated with 0.5 ml of compound sition ~ test, 6Q roller passages and rin ~ ags with
2~0 ml dieau et 120 passages du rouleau t6 minutes)~
On révèle le sebum résiduel à l'aide de vapeurs d'acide osmique. Dans une bo~te étanche, on libere de l'acide osmique que l'on laisse en contact avec l'échantillon pendant 5 minutesy ce laps de temps est suffisant pour que la réac-tion avec le sébum soit complète.
La mesure de l'intensité de la couleur de la tache est effectuée par une méthode visuelle en prenant comme témoin une solution de laurylsulfate de sodium à une teneur de lauryl-sulfate de sodium de ~/O. On compare l'intensité de la tache de la composition ~ tester ~ l'intensité la plus proche de la solution de laurylsulfate de sodium. On utilise à cette fin des solutions témoins à des concentrations variables de lauryl-sulfate de sodium.
L'activité détergente est exprimée en équivalent de laurylsulfate de sodium.
Un objet de l'invention est donc constitué par une composition de nettoyage contenant au moins certains tensio-actifs non ioniques associés avec certains polymères non ionlques .
Un autre objet de l'invention est constitué par un procédé de nettoyage mettant en oeuvre la composition précitée.
La composition de nettoyage doux conforme à l'inven-tion est essentiellement caractérisée par le fait ~ulelle con-tient dans un milieu cosmétiquement acceptable au moins un tensio-actif non ionique choisi dans le groupe constitué
par:
(i) les alkyléthers de glucoside répondant ~ la formule:
C~ OH ~2OH
OH~ OEI t n dans laquelle R désigne un radical alkyle ayant 8 à 10 atomes de carbone, n est égal à 0, 1, 2, 3 ou 4;
(ii) le dioléate de méthyl glucoside oxyéthyléné, (iii) les alcoyls ou hydroxyalcoyl polyglycosides comportant un radical alcoyle ayant de ll à 18 atomes de car-bone et un nombre de motifs glycosides compris entre 3 et 25;
ces composés sont décrits plus particulièrement dans le brevet fran,cais ~o, 2.397,185, et au moins un polymere non ionique choisi dans le groupe constitué paro (i) les alkylcelluloses;
(ii) les polyhydroxyalkylcelluloses, ~ iii) les poly-~-alanines, (iv) la polyvinylpyrrolidone ou les copolymères de vinylpyrrolidone avec des comonomeres non-ioniques les homo-polymères étant préférés.
L'a~ent tensio-actif non ionique tel que défini ci-dessus est de préférence utilisé dans une proportion de 0,3 15% en poids exprimé en matière active par rappor~ au poids total de la composition, I.es polym~3res non ioniques sont utilisés de préfé-rence dans des proportions comprises entre 0,1 et 10% en poids exprim~s en matibre active par rapport au poids total de la composition.
Les alkylcellulose.s sont choisies plus particulière ment parmi les méthyl- et éthylcelluloses et les polyhydroxy-alkylcellul.oses sont choisies plus particulièrement parmi les polyhydroxyéthyl-, hydroxypropylméthyl-, ou hydroxypropyl-celluloses ayant un poids moléculaire compris entre 60.000 et 1~.000.000.
Les poly-~-alanines sont plus particulièrement dé-crites dans le brevet ~el~e n 893.738 au nom de la ~emanderesse.
Ces polymères comportent de 50 à 100% de motifsrépétitifs de formule:
CH - CH - C0 ~ ~
i ¦ l (II) _R3 R2 Rl -et de 0 à 50% de motifs répétitifs du type polyacrylamide correspondant a la formule suivanten _ , _ - CH - C - _ l l (III) f ~1 dans lesquelles Rl représente un atome d'hydrogène, ou un radical pris dans le groupe constitué par les radicaux sui-vants:
( i ) - CI3:2 ~ ~:1 ( ii) - C~2H ' (iii) - (CH2)n, - CH3 ou n' est 0 ou un nombre entier de 1 à 11, et (iv) - (CE2-CH2-O~m H o~ m est compris A
~2~
entre 1 et 10, et R2 et R3 représentent un atome d'hydrogène ou un radical méthyle~
Ces polymères sont préparés plus particulièrement par polymérisation de l'acrylamide, comme décrit dans le bre-vet américain ~o. 4.082.730. Ces polymères ont de préférence un poids moleculaire compris entre 500 et 100.000 et plus par-ticulièrement entre 2.000 et 60.000.
Les compositions conformes à l'inventlon peuvent contenir d'autres agents tensio actifs non ioniques di~férents des agents tensio-actifs non ioniques mentionnés ci-dessus.
Ces agents tensio-actifs non ioniques sont choisis parmi les esters d'acide gras du sorbitol polyoxyéthylénés tel que le monolaurate de sorbitan polyoxyéthyléné à 20 moles d'oxyde d'éthylène ou encore les esters partiels d'acide gras et de glycérol oxyéthylénés comme le monolaurate de glycérol poly-.
oxyéthyléné.
De tels agents tensio-actifs sont connus en eux-memes pour être peut agressifs et conduisent encore à l'amé-lioration des propriétés de la composition de nettoyage con-forme à l'invention.
Une forme de réalisation préférée est constituée par des compositions contenant au moins un agent tensio-actif non ionique choisi dans Les groupes (i) ~ (iii) définis ci- -dessus associé avec au moins un polymère non ionique tel que défini ci-dessus et au moins un agent tensio actif non ioni-que supplémentaire choisi parmi les esters d'acide gras du sorbitol polyoxyéthyléné et les esters partiels d'acide gras et de glycérol oxyéthylénés définis ci-dessus.
La Demanderesse a découvert en particulier q~'avec les compositions conformes à l'invent.ion, contenant au moins un tensio-actif non i.onique des groupes (i), (ii~ et (iii), susdéfinis avec l'un des polymères non ioniques également défi.nis ci-dessus dans les proportions indiquées, on obtenait une meilleure innocuité tout en augmentant la détergence.
Ainsi, une composi-tion contenant 10% d'alkyléther de ylucosi-de vendu sous la marque de commerce TRITON CG-110-60 a une activité détergente équivalente à 1,25% de laurylsulfate de sodium et un point de demi-lyse de 1% alors qu'une composition contenant 8% du meme agent tensio-actif non ionique TRITO~
CG-110 avec l'hydroxyéthylcellulose (0,3%) a un pouvoir dé-tergent équiva~ent à celui d'une solution à 3% de lauryl-sulfate de sodium et un point de demi-lyse de 1,23%.
Les compositions de nettoyage conformes à l'i~ven-tion sont utilisables pour le nettoyage de la peau et les cheveux. Ces compositions contiennent de préférence 5 à 15%
dlagent tensio-actif non ionique~
Une application particulierement préférée est leur utilisation pour le nettoyage des peaux à problème telles que acnéiques ou à points noirs~
Les compositions de nettoyage ayant un effet sur le traitement de l'acné peuvent contenir en plus 1 à 15% en poids d'un peroxyde de benzoyle.
Selon une forme de réalisation préférée on peut adjoindre un antiseptique de façon à obtenir un produit trai- -tant utilisable dans le domaine dermatologique pour le net-toyage- des plaies, l'hygiène féminine intime, le trai-tement de l'ezcéma et nettement moins agressif que les produits de ce type existant déjà sur le marché.
Les agents antiseptiques utilisables dans cette forme de réalisation de l'invention sont des agents comlus en eux-mêmes et couramment utilisés dans les compositionc; anti-septiques. On peut citer ~ cet effet, le diiséthionated'hexamidine, le 2,4,4'-trichloro-2'-hydroxy biphényléther, la chlorhexidine, le digluconate de chlorhexidine, le chlorure de 4~benzalkonium, le 3,4,4'--trichlorocarbanilide, 1~ 8-hydro-xyquinoléine et ses sels, le chlorure de diméthyl alkylbenzyl-ammonium (alkyl étant un dérivé d'acide gras de coprah). ~es agents antisepti~les sont présents dans des quantités comprises entre 0,01 et 2,5% en poids par rapport au poids total de la composition.
Les compositions conformes ~ l'invention se presen-tent généralement sous forme de compositions aqueuses pouvant éventuellement contenir suivant l'application envisagée des solvants cosmétiquement acceptables et avoir un pH compris entre par exemple 3,5 et 8.
Ces compositions peuvent en particulier se présenter lorsqu'elles sont utilisées pour le traitement de la peau sous forme de.crème, de lai-t, d'émulsion, de gel, de solution aqueuse ou hydroalcoolique. Elles peuvent contenir en plus des adjuvants tels que des par~ums, des colorants, des agents conservateurs, des agents épaississants, des agents séques-trants, des agents émulsifiants, des filtres solaires ainsi que tout autre produit bien connu dans l'état de la technique et couramment utilisés pour former des compositions de ce type.
Les compositions destinées au nettoya~e des cheveux peuvent se présenter sous forme de solutions aqueuses ou hydroalcooliques, d'émulsions, de crèmes, de lait, de gel et éventuellement atre conditionnées en aérosol avec un agent propulseur tel que l'azote, le protoxyde d'azote, les hydro-carbures fluorochlorés du type ~IREO~ (marque de commerce) oules hydrocarbure~ saturés tels que le butane ou le E)ropane.
Une autre application possible des compositions selon l'invention est leur utilisation pour le démaquillage des yeux. Ces compositions contiennent de préférence des agents tensio-acti.fs no~ ionic~es choisis dans les groupes ti), (ii), et (iii) définis précédemment dans des proportions faibles partir de 0,3% en poids, de préférence jusqu'à 2%, en pré-sence éventuellement d'autres ag2nts tensio--actifs différents de ceux définis dans les groupes ~i~, (ii) et (iii).
Les exemples qui suivent sont destinés ~ illustrer l'invention sans pour autant présenter un caractère limitatif.
On a préparé la composition suivante:
TRITON CG-110-60 8%
TWEEN 20 (marque de commerce) 2%
Hydroxyéthylcellulose 0,3%
Diiséthionate d'hexamidine 0,05%
Eau q.s.p. 100, Cette composition est utilisée pour le lavage de la peau. Le point de demi-lyse est égal à 1,38% et la composi-tion a une détergence équivalente à 3% de laurylsulfate desodium.
On prépare la-composition antiseptique suivante:
TRITO~ CG-110-60 8% en M.A.
TWEE~ 20 2%
Hydroxyéthylcellulose 0,3%
Diiséthionate d'hexamidine 0,15%
IRGASA~ DP 300 ~marque de commerce) 0,10%
Eau et conservateur q.s.p. lOOo Cette composition est utilisée pour le lavage de la peau et a un effet antiseptique. Le point de clemi-lyse de la composition est de 1,31% et la composition est équivalente au test de détergence ~ une solution aqueuse de 2,5% de lauryl-sulfate de sodium.
On prépare la composition suivante:
TRITON CG-110-60 8% en M.A.
Hydroxyéthylcellulose 0,3%
Eau q.s.p. 100.
Cette composition est utilisée pour le la~age de la peau. Le polnt de demi-lyse est de 1,23% alors qu'une composition aqueuse de laurylsulfate de sodium ayant la m~me teneur en matière active, c'est-à-dire 8,3%, a un point de demi-lyse de 0,03%.
.
On prépare la composition suivante:
TRITO~ CG-110-60 8% en M.A.
Poly-~-alanine telle que décrite dans l'exemple de réference A 5% en M.A.
Eau q,s.p. 100.
Cette composition est utilisée pour le lavage de la peau, On constate que le point de demi-lyse est de 1,23%
de produit, alors qu'une composition ayant la même teneur en matière active, c'est-a-dire 13% en laurylsulfate de sodium, a un point de demi-lyse de 0,'014%.
On prépare la composition suivante-TRITO~ CG-110-60 5,78 g Hydroxyéthylcellulose 0,22 ~au q.s.p~ 100.
Le point de demi-lyse de cette composition est 1,84% de pxoduit.
~XEMPLE 6 Dioléate de méthylglucoside oxyéthyléné vendu sous la marque de commerce GLUCAMATE DOE 120 par la Société Amerchol 8 g ~WEEN 20 2 g p-hyd~oxybenzoate de méthyle 0,15 g Polyvinylpyrrolidone (PM environ 40.000) ~PVP K30 Gaf) i g Eau q.s.p. 100 g.
GLUCAMATE DOE 120 8 g Poly-~-alanine (telle que décrite dans l'exemple de reférence A) 2 g p-hydroxybenzoate de méthyle 0,15 g Eau q,s.p. 100 g.
EXE~PL~ 8 Alcoyl (C12) polyglycoside préparé selon l'exemple 4 du bre~et fran~ais ~o. 2.397.185 4 g 2 5 TWEE~ 20 2 g Hydroxyéthylcellulose 0,3 g p-hydroxybenzoate de méthyle 0,15 g Eau q.s.p. - 100 g.
M~thylcellulose 0,1 g TRITON CG-110-60 8 g en M.A.
TWEEN 20 2 y p-hydroxybenzoate de méthyle 0,15 g Eau q.s.p~ 100 g.
TRITON CG-110~60 6 g en M.A.
TWEE~ 20 2 g Polyvinylpyrrolidone 2 g Diiséthionate d'hexamidine 0,15 g Eau q~s.p. 100 g~
TRIT0~ CG-l~0 0,4 g en M.A.
Poly-~-alanine 0,5 g Hexylèneylycol 1 g Tampon phosphate H2KP04 0,1 g ~K2P04 ~3 g 1~ Chlorure de cétyldiméthyl-benzylammonium 0,1 g Parfum 0,1 g Eau q.sOp. 100 g.
Cette composition est utilisée comme lotion déma-quillante pour les yeux.
EXEMPLE DE REFERE~CE A
Pré~aration de_la ~ ani DO.
Dans un réacteur de 6 litres, muni d'un agitateur, d'une arrivée d'azote et d'un réfrigérant surmonté d'une garde à chlorure da calcium, on introduit 0,15 g de ~-phényl-~-naphtylamine et 2,5 litres de chlorobenzène~ La solution estalors chauffée à 80C et l'on ajoute 150 g d'acrylamide. A-pres dissolution complète du monomère et retour du mélange réactionnel ~ 80C, on ajoute une solution chaude de 3 g de sodium préalablement mis en solution dans 300 ml de tertio-butanol.
Un polymère insoluble dans le milieu reactionnel se forme rapidement et se dépose sur les parois du réacteur.
La reaction est maintenue 8 heures ~ 80Co En fin de réaction, le solvant est éliminé avant refroidissement et le polymère est alors dissous dans 1350 ml d'eau. La solution obtenue est ajustée à pH 6 pax de l'acide chlorhydrique concentré. 1a phase aqueuse précédente es-t lavée par 500 ml de chloroforme filtrée et concentrée à l'évaporateur rotatif sous pression réduite jusqu'à l'obtention de 350 g de résidu huileux. Le polymère pur est obtenu en versant lentement le concentrat aqueux dans 15 litres d'éthanol sous vive agitation puis en filtrant la poudre en suspensionO
On obtient ainsi après séchage 135 g d'une poudre ~lanche soit un rendement d-e 90%~
Viscosité : intrinsèque dans l'eau à 25C :
~n] = 0,121dl/g. 2 ~ 0 ml of water and 120 passages of the roller t6 minutes) ~
The residual sebum is revealed using vapors osmic acid. In a tight box, you release acid osmic which is left in contact with the sample for 5 minutes, this period of time is sufficient for the reaction tion with sebum is complete.
Measuring the intensity of the color of the stain is carried out by a visual method taking as a witness a solution of sodium lauryl sulfate with a content of lauryl-~ / O sodium sulfate. We compare the intensity of the stain of the composition ~ test ~ the intensity closest to the sodium lauryl sulfate solution. We use for this purpose control solutions at varying concentrations of lauryl-sodium sulfate.
The detergent activity is expressed in equivalent of sodium lauryl sulfate.
An object of the invention therefore consists of a cleaning composition containing at least certain surfactants non-ionic active agents associated with certain non-ionic polymers ionlques.
Another object of the invention is constituted by a cleaning process using the above composition.
The gentle cleaning composition according to the invention tion is essentially characterized by the fact ~ ulelle con-is in a cosmetically acceptable environment at least one nonionic surfactant selected from the group consisting by:
(i) the glucoside alkyl ethers corresponding to the formula:
C ~ OH ~ 2OH
OH ~ OEI t not in which R denotes an alkyl radical having 8 to 10 atoms carbon, n is 0, 1, 2, 3 or 4;
(ii) oxyethylenated methyl glucoside dioleate, (iii) alkyl or hydroxyalkyl polyglycosides having an alkyl radical having from 11 to 18 carbon atoms bone and a number of glycoside units between 3 and 25;
these compounds are more particularly described in the patent fran, cais ~ o, 2,397,185, and at least one nonionic polymer chosen from the group incorporated paro (i) alkylcelluloses;
(ii) polyhydroxyalkylcelluloses, ~ iii) poly- ~ -alanines, (iv) polyvinylpyrrolidone or the copolymers of vinylpyrrolidone with nonionic comonomers homo-polymers being preferred.
A ~ ent nonionic surfactant as defined above above is preferably used in a proportion of 0.3 15% by weight expressed as active ingredient compared to weight total composition, Non-ionic polymers are preferably used in proportions of between 0.1 and 10% by weight expressed in active ingredient relative to the total weight of the composition.
The alkylcellulose.s are chosen more particularly ment among methyl- and ethylcelluloses and polyhydroxy-alkylcellul.oses are chosen more particularly from polyhydroxyethyl-, hydroxypropylmethyl-, or hydroxypropyl-celluloses with a molecular weight between 60,000 and 1 ~ .000,000.
Poly- ~ -alanines are more particularly de-written in the patent ~ el ~ in 893,738 in the name of ~ emanderess.
These polymers contain from 50 to 100% of repeating units of formula:
CH - CH - C0 ~ ~
i ¦ l (II) _R3 R2 Rl -and from 0 to 50% of repeating units of the polyacrylamide type corresponding to the following formula _, _ - CH - C - _ ll (III) f ~ 1 in which R1 represents a hydrogen atom, or a radical taken from the group consisting of the following radicals before:
(i) - CI3: 2 ~ ~: 1 (ii) - C ~ 2H ' (iii) - (CH2) n, - CH3 or n 'is 0 or a number integer from 1 to 11, and (iv) - (CE2-CH2-O ~ m H o ~ m is included AT
~ 2 ~
between 1 and 10, and R2 and R3 represent a hydrogen atom or a methyl radical ~
These polymers are more particularly prepared by polymerization of acrylamide, as described in the patent American vet ~ o. 4,082,730. These polymers are preferably a molecular weight between 500 and 100,000 and more per particularly between 2,000 and 60,000.
The compositions according to the invention can contain other different non-ionic surfactants nonionic surfactants mentioned above.
These nonionic surfactants are chosen from polyoxyethylenated sorbitol fatty acid esters such as polyoxyethylenated sorbitan monolaurate containing 20 moles of oxide ethylene or the partial esters of fatty acid and oxyethylenated glycerol such as poly- glycerol monolaurate.
oxyethylenated.
Such surfactants are known in themselves.
same to be can aggressive and still lead to am-improving the properties of the cleaning composition form to the invention.
A preferred embodiment is constituted with compositions containing at least one surfactant non-ionic chosen in Groups (i) ~ (iii) defined above - -above associated with at least one nonionic polymer such as defined above and at least one nonionic surfactant that additional chosen from fatty acid esters of polyoxyethylenated sorbitol and partial acid esters oxyethylenated fats and glycerol defined above.
The Applicant has discovered in particular that q ~ 'with the compositions in accordance with the invention, containing at least a non-ionic surfactant of groups (i), (ii ~ and (iii), above defined with one of the nonionic polymers also challenge.nis above in the indicated proportions, we obtained better safety while increasing detergency.
Thus, a composition containing 10% alkyl ether of ylucosi-sold under the trade name TRITON CG-110-60 has a detergent activity equivalent to 1.25% of lauryl sulfate sodium and a 1% half-lysis point while a composition containing 8% of the same non-ionic surfactant TRITO ~
CG-110 with hydroxyethylcellulose (0.3%) has a tergent equivalent to that of a 3% solution of lauryl-sodium sulfate and a half lysis point of 1.23%.
The cleaning compositions in accordance with i ~ ven-can be used for cleaning the skin and hair. These compositions preferably contain 5 to 15%
non-ionic surfactant ~
A particularly preferred application is their use for cleaning problem skin such as acne or blackheads ~
Cleaning compositions having an effect on the acne treatment may contain more than 1 to 15% by weight a benzoyl peroxide.
According to a preferred embodiment, it is possible to add an antiseptic so as to obtain a processed product -both usable in the dermatological field for the net-wound care, intimate feminine hygiene, treatment of eczema and significantly less aggressive than the products of this type already existing on the market.
Antiseptic agents usable in this embodiment of the invention are agents included in themselves and commonly used in compositions; anti-septic tanks. We can cite ~ this effect, diisethionated'hexamidine, 2,4,4'-trichloro-2'-hydroxy biphenylether, chlorhexidine, chlorhexidine digluconate, chloride of 4 ~ benzalkonium, 3,4,4 '- trichlorocarbanilide, 1 ~ 8-hydro-xyquinoline and its salts, dimethyl alkylbenzyl chloride-ammonium (alkyl being a derivative of coconut fatty acid). ~ es antisepti agents ~ are present in quantities included between 0.01 and 2.5% by weight relative to the total weight of the composition.
The compositions according to the invention are presented generally try in the form of aqueous compositions which can possibly contain depending on the intended application of cosmetically acceptable solvents and have a pH understood between for example 3.5 and 8.
These compositions can in particular be presented when used for treating skin under form of cream, milk, emulsion, gel, solution aqueous or hydroalcoholic. They can also contain adjuvants such as par ~ ums, dyes, agents preservatives, thickening agents, drying agents-trants, emulsifiers, sun filters as well than any other product well known in the art and commonly used to form compositions of this type.
The compositions intended for cleaning the hair can be in the form of aqueous solutions or hydroalcoholic, emulsions, creams, milk, gel and possibly also packaged in aerosol with an agent propellant such as nitrogen, nitrous oxide, hydro-fluorochlorinated carbides of the type ~ IREO ~ (trade mark) or the saturated hydrocarbons ~ such as butane or E) ropane.
Another possible application of the compositions according to the invention is their use for removing makeup eyes. These compositions preferably contain no ~ ionic ~ es surfactants selected from the groups ti), (ii), and (iii) previously defined in small proportions from 0.3% by weight, preferably up to 2%, by pre-possibly other different surfactants of those defined in groups ~ i ~, (ii) and (iii).
The following examples are intended to illustrate the invention without however being limiting in nature.
The following composition was prepared:
TRITON CG-110-60 8%
TWEEN 20 (trademark) 2%
Hydroxyethylcellulose 0.3%
0.05% hexamidine diisethionate Water qs 100, This composition is used for washing the skin. The half-lysis point is equal to 1.38% and the composition tion has a detergency equivalent to 3% of sodium lauryl sulfate.
The following antiseptic composition is prepared:
TRITO ~ CG-110-60 8% in MA
TWEE ~ 20 2%
Hydroxyethylcellulose 0.3%
0.15% hexamidine diisethionate IRGASA ~ DP 300 ~ trademark) 0.10%
Water and preservative qs lOOo This composition is used for washing the skin and has an antiseptic effect. The point of clemi-lysis of the composition is 1.31% and the composition is equivalent to detergency test ~ a 2.5% aqueous solution of lauryl-sodium sulfate.
The following composition is prepared:
TRITON CG-110-60 8% in MA
Hydroxyethylcellulose 0.3%
Water qs 100.
This composition is used for the ~ age of the skin. The half-lysis polnt is 1.23% while a aqueous composition of sodium lauryl sulfate having the same active ingredient content, i.e. 8.3%, has a point of 0.03% half-lysis.
.
The following composition is prepared:
TRITO ~ CG-110-60 8% in MA
Poly- ~ -alanine as described in the example of reference A 5% in MA
Water q, sp 100.
This composition is used for washing the skin, We see that the half-lysis point is 1.23%
of product, whereas a composition having the same content of active ingredient, that is to say 13% in sodium lauryl sulfate, has a half-lysis point of 0.014%.
The following composition is prepared-TRITO ~ CG-110-60 5.78 g Hydroxyethylcellulose 0.22 ~ at qs ~ 100.
The half-lysis point of this composition is 1.84% of product.
~ XAMPLE 6 Oxyethylenated methylglucoside dioleate sold under GLUCAMATE DOE 120 by the Amerchol 8 g ~ WEEN 20 2 g p-hyd ~ methyl oxybenzoate 0.15 g Polyvinylpyrrolidone (PM about 40,000) ~ PVP K30 Gaf) ig Water qs 100 g.
GLUCAMATE DOE 120 8 g Poly- ~ -alanine (as described in reference example A) 2 g methyl p-hydroxybenzoate 0.15 g Water q, sp 100 g.
EXE ~ PL ~ 8 Alkoyl (C12) polyglycoside prepared according to the example 4 du bre ~ et fran ~ ais ~ o. 2,397,185 4 g 2 5 TWEE ~ 20 2 g Hydroxyethylcellulose 0.3 g methyl p-hydroxybenzoate 0.15 g Water qs - 100 g.
M ~ thylcellulose 0.1 g TRITON CG-110-60 8 g in MA
TWEEN 20 2 y methyl p-hydroxybenzoate 0.15 g Water qs ~ 100 g.
TRITON CG-110 ~ 60 6 g in MA
TWEE ~ 20 2 g Polyvinylpyrrolidone 2 g Hexamidine diisethionate 0.15 g Water q ~ sp 100 g ~
TRIT0 ~ CG-l ~ 0 0.4 g in MA
Poly- ~ -alanine 0.5 g Hexylene glycol 1 g Phosphate buffer H2KP04 0.1 g ~ K2P04 ~ 3 g 1 ~ Cetyldimethyl-benzylammonium chloride 0.1 g Perfume 0.1 g Water q.sOp. 100g.
This composition is used as a demotion lotion.
quillante for the eyes.
REFERENCE EXAMPLE ~ CE A
Pré ~ aration de_la ~ ani DO.
In a 6 liter reactor, fitted with an agitator, a nitrogen inlet and a cooler surmounted by a guard to calcium chloride, 0.15 g of ~ -phenyl- ~ is introduced naphthylamine and 2.5 liters of chlorobenzene ~ The solution is then heated to 80C and 150 g of acrylamide are added. AT-pres complete dissolution of the monomer and return of the mixture reaction ~ 80C, add a hot solution of 3 g of sodium previously dissolved in 300 ml of tertiary butanol.
A polymer insoluble in the reaction medium forms quickly and settles on the walls of the reactor.
The reaction is maintained for 8 hours ~ 80Co At the end of the reaction, the solvent is removed before cooling and the polymer is then dissolved in 1350 ml of water. The solution obtained is adjusted to pH 6 pax of concentrated hydrochloric acid. 1a previous aqueous phase is washed with 500 ml of chloroform filtered and concentrated in a pressurized rotary evaporator reduced until 350 g of oily residue is obtained. The pure polymer is obtained by slowly pouring the concentrate aqueous in 15 liters of ethanol with vigorous stirring and then filtering powder in suspensionO
135 g of a powder are thus obtained after drying.
~ lanche is a yield of 90% ~
Viscosity: intrinsic in water at 25C:
~ n] = 0.121dl / g.
Claims (21)
(i) les alkyléthers de glucoside répondant à la formule:
(I) dans laquelle R désigne un radical alkyle ayant 8 à 10 atomes de carbone, n'est égal à 0, 1, 2, 3 ou 4;
(ii) le dioléate de méthylglucoside oxyéthyléné;
(iii) les alcoyl ou hydroxyalcoyl polyglycosides com-portant un radical alcoyle ayant 11 à 18 atomes de carbone et un nombre de motifs glycosides compris entre 3 et 25 ou leurs mélanges;
au moins un polymère non ionique choisi dans le groupe consti-tué par:
(i) les alkylcelluloses;
(ii) les polyhydroxyalkylcelluloses;
(iii) les poly- .beta.-alanines;
(iv) la polyvinylpyrrolidone ou les copolymères de vinylpyrrolidone avec des comonomères non-ioniques, ou leurs mélanges. 1. Gentle cleaning composition characterized by fact that it contains in a cosmetically acceptable medium at least one nonionic surfactant chosen from the group consisting of:
(i) the glucoside alkyl ethers corresponding to the formula:
(I) in which R denotes an alkyl radical having 8 to 10 atoms of carbon, is not equal to 0, 1, 2, 3 or 4;
(ii) oxyethylenated methylglucoside dioleate;
(iii) alkyl or hydroxyalkyl polyglycosides carrying an alkyl radical having 11 to 18 carbon atoms and a number of glycoside units between 3 and 25 or their mixtures;
at least one nonionic polymer chosen from the group consisting of killed by:
(i) alkylcelluloses;
(ii) polyhydroxyalkylcelluloses;
(iii) poly- .beta.-alanines;
(iv) polyvinylpyrrolidone or the copolymers of vinylpyrrolidone with nonionic comonomers, or their mixtures.
(II) et de 0 à 50% de motifs répétitifs de formule (III) dans lesquelles R1 représente un atome d'hydrogène, ou un radi-cal choisi dans le groupe constitué par les radicaux suivants:
(iii) -(CH2)n, CH3 où n' est 0 ou un nombre entier de 1 à 11, et (iv) -(CH2-CH2-O)m? H où m est compris entre 1 et 10, et R2 et R3 représentent un atome d'hydrogène ou un radical méthyle. 5. Composition according to claim 1, characterized by the fact that the poly-.beta.-alanines are chosen from polymers comprising from 50 to 100% of repeating patterns of mule:
(II) and from 0 to 50% of repeating units of formula (III) in which R1 represents a hydrogen atom, or a radical cal chosen from the group consisting of the following radicals:
(iii) - (CH2) n, CH3 where n 'is 0 or an integer from 1 to 11, and (iv) - (CH2-CH2-O) m? H where m is between 1 and 10, and R2 and R3 represent a hydrogen atom or a methyl radical.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
LU84.416 | 1982-10-11 | ||
LU84416A LU84416A1 (en) | 1982-10-11 | 1982-10-11 | SOFT CLEANING COMPOSITION |
Publications (1)
Publication Number | Publication Date |
---|---|
CA1205747A true CA1205747A (en) | 1986-06-10 |
Family
ID=19729963
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA000438406A Expired CA1205747A (en) | 1982-10-11 | 1983-10-05 | Soft cleansing compound |
Country Status (11)
Country | Link |
---|---|
JP (1) | JPS59130210A (en) |
BE (1) | BE897961A (en) |
CA (1) | CA1205747A (en) |
CH (1) | CH658991A5 (en) |
DE (1) | DE3336760A1 (en) |
ES (1) | ES526357A0 (en) |
FR (1) | FR2534270B1 (en) |
GB (1) | GB2128627B (en) |
IT (1) | IT1160211B (en) |
LU (1) | LU84416A1 (en) |
NL (1) | NL8303471A (en) |
Families Citing this family (30)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2553660B1 (en) * | 1983-10-25 | 1986-01-03 | Oreal | COSMETIC CLEANING COMPOSITION IN PARTICULAR FOR EYE MAKE-UP REMOVAL |
LU85111A1 (en) * | 1983-12-01 | 1985-09-12 | Oreal | ANTI-ACNETIC COMPOSITION BASED ON BENZOYL PEROXIDE AND AT LEAST ONE SOLAR FILTER |
FR2564318B1 (en) * | 1984-05-15 | 1987-04-17 | Oreal | ANHYDROUS COMPOSITION FOR CLEANING THE SKIN |
LU85427A1 (en) | 1984-06-22 | 1986-01-24 | Oreal | NOVEL COMPOSITIONS FOR DELAYING THE APPEARANCE OF A FATTY ASPECT OF THE HAIR, AND USE THEREOF |
FR2589356B1 (en) * | 1985-10-31 | 1988-11-25 | Oreal | SOFT CLEANING COSMETIC COMPOSITION, PARTICULARLY FOR EYE MAKE-UP REMOVAL |
JP2534633B2 (en) * | 1987-07-20 | 1996-09-18 | 鐘紡株式会社 | Skin cosmetics for clean room |
MY105119A (en) * | 1988-04-12 | 1994-08-30 | Kao Corp | Low irritation detergent composition. |
LU87323A1 (en) * | 1988-08-25 | 1990-03-13 | Oreal | COMPOSITION FOR INDUCING AND STIMULATING HAIR GROWTH AND / OR BRAKING HAIR LOSS, BASED ON ALKYLPOLYGLYCOSIDE AND A PYRIMIDINE DERIVATIVE |
JPH0768115B2 (en) * | 1989-05-17 | 1995-07-26 | 花王株式会社 | Cleaning composition |
JPH0623087B2 (en) * | 1989-10-09 | 1994-03-30 | 花王株式会社 | Cleaning composition |
US5234618A (en) * | 1989-10-09 | 1993-08-10 | Kao Corporation | Liquid detergent composition |
GB8927956D0 (en) * | 1989-12-11 | 1990-02-14 | Unilever Plc | Detergent composition |
FR2660552B1 (en) * | 1990-04-06 | 1994-09-02 | Rhone Poulenc Sante | NEW ANTISEPTIC DRUGS. |
US5690920A (en) * | 1990-11-15 | 1997-11-25 | L'oreal | Foamable washing composition based on selected insoluble silicones and an alkylpolyglycoside, and cosmetic and dermatological uses thereof |
FR2669345B1 (en) * | 1990-11-15 | 1994-08-26 | Oreal | CLEANSING AND FOAMING COMPOSITION BASED ON INSOLUBLE SILICONES AND AN ALKYLPOLYGLYCOSIDE AND THEIR APPLICATION IN COSMETICS AND DERMATOLOGY. |
DE4110663A1 (en) * | 1991-04-03 | 1992-10-08 | Rewo Chemische Werke Gmbh | NEW AMMONIUM COMPOUNDS, PROCESS FOR THEIR PREPARATION AND THEIR USE AS CLEANING AGENTS, COSMETIC RAW MATERIALS AND SOFTWARE, IN PARTICULAR AS SOFTENER SPILLS FOR TISSUE |
US5246695A (en) * | 1991-04-03 | 1993-09-21 | Rewo Chemische Werke Gmbh | Use of alkylglycoside sulfosuccinates for the production of cosmetic preparations and cleaning agents |
FR2680103B1 (en) | 1991-08-07 | 1993-10-29 | Oreal | USE IN COSMETICS OR IN PHARMACY OF ALKYLPOLYGLYCOSIDES AND / OR GLUCOSE O-ACYLATED DERIVATIVES FOR THE TREATMENT OF HAIR LOSS. |
EP0538762B1 (en) * | 1991-10-22 | 1996-04-10 | Kao Corporation | Hair cosmetic |
FR2687069B1 (en) * | 1992-02-07 | 1995-06-09 | Oreal | COSMETIC COMPOSITION CONTAINING AT LEAST ONE SURFACTANT AGENT OF THE ALKYLPOLYGLYCOSIDE AND / OR POLYGLYCEROLE TYPE AND AT LEAST ONE URETHANE POLYETHER. |
DE4302315A1 (en) * | 1993-01-28 | 1994-08-04 | Henkel Kgaa | Surface active mixtures |
DE4319699A1 (en) * | 1993-06-16 | 1994-12-22 | Henkel Kgaa | Ultra mild surfactant blends |
DE4319700A1 (en) * | 1993-06-16 | 1994-12-22 | Henkel Kgaa | Ultra mild surfactant blends |
EP0739196A4 (en) * | 1993-10-06 | 1997-06-11 | Henkel Corp | Improving phenolic disinfectant cleaning compositions with alkylpolyglucoside surfactants |
US5681802A (en) * | 1994-06-01 | 1997-10-28 | Lever Brothers Company, Division Of Conopco, Inc. | Mild antimicrobial liquid cleansing formulations comprising buffering compound or compounds as potentiator of antimicrobial effectiveness |
US5728371A (en) * | 1996-04-29 | 1998-03-17 | L'oreal, S.A. | Skin protection, fragrance enhancing and vitamin delivery composition |
US5728372A (en) * | 1996-04-29 | 1998-03-17 | L'oreal, S.A. | Skin protection, fragrance enhancing and vitamin delivery composition |
DE19723733A1 (en) | 1997-06-06 | 1998-12-10 | Beiersdorf Ag | Cosmetic and dermatological emulsions containing alkyl glucosides and increased electrolyte concentrations |
DE10154628A1 (en) * | 2001-09-25 | 2003-04-10 | Beiersdorf Ag | Surfactant(s) for use in cosmetic or dermatological cleaning, comprise alkyl glucosides |
JP6177634B2 (en) * | 2013-09-13 | 2017-08-09 | クラシエホームプロダクツ株式会社 | Skin cleanser composition |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
LU60900A1 (en) * | 1970-05-12 | 1972-02-10 | ||
SE7407206L (en) * | 1973-06-04 | 1974-12-05 | Tennant Co | |
US4154706A (en) * | 1976-07-23 | 1979-05-15 | Colgate-Palmolive Company | Nonionic shampoo |
FR2397185A1 (en) * | 1977-05-18 | 1979-02-09 | Oreal | NON-IRRITANT COMPOSITION FOR EYE MAKE-UP REMOVAL |
FR2413084A1 (en) * | 1977-12-30 | 1979-07-27 | Oreal | COSMETIC COMPOSITION FOR EYE MAKE-UP REMOVAL |
LU81257A1 (en) * | 1979-05-15 | 1980-12-16 | Oreal | COSMETIC COMPOSITION FOR THE TREATMENT OF HAIR AND SKIN, CONTAINING SALSEPAREILLE EXTRACT |
FR2508795A1 (en) * | 1981-07-03 | 1983-01-07 | Oreal | COSMETIC COMPOSITIONS FOR THE TREATMENT OF HAIR AND SKIN CONTAINING POLYAMIDES |
-
1982
- 1982-10-11 LU LU84416A patent/LU84416A1/en unknown
-
1983
- 1983-10-05 CA CA000438406A patent/CA1205747A/en not_active Expired
- 1983-10-10 DE DE19833336760 patent/DE3336760A1/en active Granted
- 1983-10-10 IT IT68037/83A patent/IT1160211B/en active
- 1983-10-10 FR FR8316085A patent/FR2534270B1/en not_active Expired
- 1983-10-10 ES ES526357A patent/ES526357A0/en active Granted
- 1983-10-10 GB GB08327031A patent/GB2128627B/en not_active Expired
- 1983-10-10 NL NL8303471A patent/NL8303471A/en not_active Application Discontinuation
- 1983-10-10 BE BE0/211680A patent/BE897961A/en not_active IP Right Cessation
- 1983-10-11 JP JP58189779A patent/JPS59130210A/en active Granted
- 1983-10-11 CH CH5532/83A patent/CH658991A5/en not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
LU84416A1 (en) | 1984-05-10 |
GB2128627B (en) | 1987-01-14 |
JPH0336804B2 (en) | 1991-06-03 |
FR2534270B1 (en) | 1986-07-04 |
DE3336760C2 (en) | 1991-11-14 |
ES8601682A1 (en) | 1985-11-16 |
ES526357A0 (en) | 1985-11-16 |
BE897961A (en) | 1984-04-10 |
FR2534270A1 (en) | 1984-04-13 |
GB8327031D0 (en) | 1983-11-09 |
DE3336760A1 (en) | 1984-04-12 |
IT1160211B (en) | 1987-03-04 |
NL8303471A (en) | 1984-05-01 |
IT8368037A0 (en) | 1983-10-10 |
GB2128627A (en) | 1984-05-02 |
CH658991A5 (en) | 1986-12-31 |
JPS59130210A (en) | 1984-07-26 |
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