CA1204079A - Composite ion exchange membranes - Google Patents

Composite ion exchange membranes

Info

Publication number
CA1204079A
CA1204079A CA000379454A CA379454A CA1204079A CA 1204079 A CA1204079 A CA 1204079A CA 000379454 A CA000379454 A CA 000379454A CA 379454 A CA379454 A CA 379454A CA 1204079 A CA1204079 A CA 1204079A
Authority
CA
Canada
Prior art keywords
film
ion exchange
layers
membrane
equivalent weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA000379454A
Other languages
English (en)
French (fr)
Inventor
Bobby R. Ezzell
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Chemical Co
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=22568049&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=CA1204079(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Priority to CA000443988A priority Critical patent/CA1208171A/en
Priority to CA000443987A priority patent/CA1203509A/en
Application granted granted Critical
Publication of CA1204079A publication Critical patent/CA1204079A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B13/00—Diaphragms; Spacing elements
    • C25B13/04—Diaphragms; Spacing elements characterised by the material
    • C25B13/08—Diaphragms; Spacing elements characterised by the material based on organic materials
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
    • C08J5/2275—Heterogeneous membranes
    • C08J5/2281—Heterogeneous membranes fluorine containing heterogeneous membranes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/34—Simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine, e.g. by chlor-alkali electrolysis
    • C25B1/46—Simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine, e.g. by chlor-alkali electrolysis in diaphragm cells
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C08J2327/18—Homopolymers or copolymers of tetrafluoroethylene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Metallurgy (AREA)
  • Electrochemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
CA000379454A 1980-06-11 1981-06-10 Composite ion exchange membranes Expired CA1204079A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CA000443988A CA1208171A (en) 1980-06-11 1983-12-21 Composite ion exchange membranes
CA000443987A CA1203509A (en) 1980-06-11 1983-12-21 Composite ion exchange membranes

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US06/158,423 US4337137A (en) 1980-06-11 1980-06-11 Composite ion exchange membranes
US158,423 1993-11-29

Related Child Applications (2)

Application Number Title Priority Date Filing Date
CA000443987A Division CA1203509A (en) 1980-06-11 1983-12-21 Composite ion exchange membranes
CA000443988A Division CA1208171A (en) 1980-06-11 1983-12-21 Composite ion exchange membranes

Publications (1)

Publication Number Publication Date
CA1204079A true CA1204079A (en) 1986-05-06

Family

ID=22568049

Family Applications (1)

Application Number Title Priority Date Filing Date
CA000379454A Expired CA1204079A (en) 1980-06-11 1981-06-10 Composite ion exchange membranes

Country Status (11)

Country Link
US (1) US4337137A (US08197722-20120612-C00042.png)
EP (1) EP0041734B2 (US08197722-20120612-C00042.png)
JP (1) JPS5725332A (US08197722-20120612-C00042.png)
KR (3) KR850000053B1 (US08197722-20120612-C00042.png)
AR (1) AR244732A1 (US08197722-20120612-C00042.png)
AT (1) ATE11154T1 (US08197722-20120612-C00042.png)
AU (1) AU543107B2 (US08197722-20120612-C00042.png)
BR (1) BR8103720A (US08197722-20120612-C00042.png)
CA (1) CA1204079A (US08197722-20120612-C00042.png)
DE (1) DE3168123D1 (US08197722-20120612-C00042.png)
ZA (1) ZA813905B (US08197722-20120612-C00042.png)

Families Citing this family (45)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4804727A (en) * 1980-06-11 1989-02-14 The Dow Chemical Company Process to produce novel fluorocarbon vinyl ethers and resulting polymers
BR8202397A (pt) * 1981-05-01 1983-04-12 Du Pont Composito membrana/eletrodo celula eletroquimica processo para eletrolise de um cloreto de metal alcalino em uma celula eletroquimica
BR8202395A (pt) * 1981-05-01 1983-04-12 Du Pont Conjunto composto membrana/eletrodo celula eletroquimica e processo para eletrolise
US4544471A (en) * 1981-11-02 1985-10-01 E. I. Du Pont De Nemours And Company Electrolytic cell with cation exchange membrane having high equivalent weight component
EP0097646B1 (en) * 1982-01-04 1988-08-31 E.I. Du Pont De Nemours And Company Coextruded multilayer cation exchange membranes
US4834922A (en) * 1982-02-04 1989-05-30 The Dow Chemical Company Process to produce novel fluorocarbon vinyl ethers and resulting polymers
JPS58199884A (ja) * 1982-05-18 1983-11-21 Asahi Glass Co Ltd 改良された電解用陽イオン交換膜
US4871703A (en) * 1983-05-31 1989-10-03 The Dow Chemical Company Process for preparation of an electrocatalyst
US4610764A (en) * 1984-02-07 1986-09-09 Asahi Glass Company Ltd. Electrolytic cation exchange membrane
JPS60251290A (ja) * 1984-05-29 1985-12-11 Asahi Glass Co Ltd 水酸化カリウムの製造方法
US4686120A (en) * 1985-02-22 1987-08-11 E. I. Du Pont De Nemours And Company Multilayer cation exchange membrane
US4784900A (en) * 1985-05-31 1988-11-15 University Of Bath Method for sizing polytretrafluoroethylene fabrics
US4650551A (en) * 1985-05-31 1987-03-17 The Dow Chemical Company Supported ion exchange membrane films
US5110385A (en) * 1985-05-31 1992-05-05 The Dow Chemical Company Method for forming polymer composite films using a removable substrate
US4650711A (en) * 1985-05-31 1987-03-17 The Dow Chemical Company Method for sizing polytetrafluoroethylene fabrics
US4784882A (en) * 1985-05-31 1988-11-15 The Dow Chemical Company Method for forming composite polymer films
US5114515A (en) * 1985-05-31 1992-05-19 The Dow Chemical Company Method for forming polymer composite films using removable substrates
US4610762A (en) * 1985-05-31 1986-09-09 The Dow Chemical Company Method for forming polymer films having bubble release surfaces
JPH07101053B2 (ja) * 1985-07-30 1995-11-01 大豊工業株式会社 平軸受の選択嵌合方法
US4670123A (en) * 1985-12-16 1987-06-02 The Dow Chemical Company Structural frame for an electrochemical cell
US4668372A (en) * 1985-12-16 1987-05-26 The Dow Chemical Company Method for making an electrolytic unit from a plastic material
US4668371A (en) * 1985-12-16 1987-05-26 The Dow Chemical Company Structural frame for an electrochemical cell
US4666579A (en) * 1985-12-16 1987-05-19 The Dow Chemical Company Structural frame for a solid polymer electrolyte electrochemical cell
US4666580A (en) * 1985-12-16 1987-05-19 The Dow Chemical Company Structural frame for an electrochemical cell
US4698243A (en) * 1986-06-20 1987-10-06 The Dow Chemical Company Method for sizing and hydrolyzing polytetrafluoroethylene fabrics, fibers, yarns, or threads
US4778723A (en) * 1986-06-20 1988-10-18 The Dow Chemical Company Method for sizing polytetrafluoroethylene fibers, yarn, or threads
US4731263A (en) * 1986-09-26 1988-03-15 The Dow Chemical Company Method for the preparation of ionomer films
US4738741A (en) * 1986-12-19 1988-04-19 The Dow Chemical Company Method for forming an improved membrane/electrode combination having interconnected roadways of catalytically active particles
US4889577A (en) * 1986-12-19 1989-12-26 The Dow Chemical Company Method for making an improved supported membrane/electrode structure combination wherein catalytically active particles are coated onto the membrane
US4752370A (en) * 1986-12-19 1988-06-21 The Dow Chemical Company Supported membrane/electrode structure combination wherein catalytically active particles are coated onto the membrane
US5039389A (en) * 1986-12-19 1991-08-13 The Dow Chemical Company Membrane/electrode combination having interconnected roadways of catalytically active particles
US4940525A (en) * 1987-05-08 1990-07-10 The Dow Chemical Company Low equivalent weight sulfonic fluoropolymers
US4859745A (en) * 1987-12-22 1989-08-22 The Dow Chemical Company Stratified fibrous fluoropolymer compositions and process for forming such fluoropolymers
US5013414A (en) * 1989-04-19 1991-05-07 The Dow Chemical Company Electrode structure for an electrolytic cell and electrolytic process used therein
EP0518942A4 (en) * 1990-03-06 1993-10-20 The Dow Chemical Company Electrochromic device
US5281680A (en) * 1993-01-14 1994-01-25 E. I. Du Pont De Nemours And Company Polymerization of fluorinated copolymers
CH691209A5 (de) * 1993-09-06 2001-05-15 Scherrer Inst Paul Herstellungsverfahren für einen Polmerelektrolyten und elektrochemische Zelle mit diesem Polymerelektrolyten.
US5433861A (en) * 1993-09-17 1995-07-18 The Dow Chemical Company Permanent deformation and use of sulfonated halopolymer articles
US5654109A (en) * 1995-06-30 1997-08-05 The Dow Chemical Company Composite fuel cell membranes
US5882810A (en) * 1996-03-08 1999-03-16 The Dow Chemicalcompany Active layer for membrane electrode assembly
JP2003515236A (ja) 1999-11-17 2003-04-22 ネア・パワー・システムズ・インコーポレイテッド シリコン基板および／またはゾルゲル法で誘導された担体構造を有する燃料電池
US6624328B1 (en) 2002-12-17 2003-09-23 3M Innovative Properties Company Preparation of perfluorinated vinyl ethers having a sulfonyl fluoride end-group
US7348088B2 (en) * 2002-12-19 2008-03-25 3M Innovative Properties Company Polymer electrolyte membrane
EP3299495B1 (en) * 2015-05-18 2020-06-03 Asahi Kasei Kabushiki Kaisha Ion exchange membrane
US10734660B2 (en) 2016-03-10 2020-08-04 Nissan North America, Inc. Functionalized carbon layer for membrane degradation mitigation under fuel cell operating conditions

Family Cites Families (36)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3114778A (en) * 1963-12-17 Fluorinated vinyl ethers and their
US2393967A (en) * 1942-12-24 1946-02-05 Du Pont Process for polymerizing tetrafluoroethylene
US2559752A (en) * 1951-03-06 1951-07-10 Du Pont Aqueous colloidal dispersions of polymers
US2593583A (en) * 1951-03-14 1952-04-22 Du Pont Method for coagulating aqueous dispersions of polytetrafluoroethylene
US3041317A (en) * 1960-05-02 1962-06-26 Du Pont Fluorocarbon sulfonyl fluorides
US3242218A (en) * 1961-03-29 1966-03-22 Du Pont Process for preparing fluorocarbon polyethers
DE1249247B (de) * 1961-04-25 1967-09-07 E. I. Du Pont De Nemours And Company, Wilmington, Del. (V. St. A.) Verfahren zur Herstellung von Perfluorolefinpolyäthern
US3250806A (en) * 1962-04-05 1966-05-10 Du Pont Fluorocarbon ethers of tetrafluoroethylene epoxide
US3450684A (en) * 1963-07-24 1969-06-17 Du Pont Fluorocarbon polyethers
US3301893A (en) * 1963-08-05 1967-01-31 Du Pont Fluorocarbon ethers containing sulfonyl groups
US3282875A (en) * 1964-07-22 1966-11-01 Du Pont Fluorocarbon vinyl ether polymers
US3536733A (en) * 1967-08-10 1970-10-27 Du Pont Method for the preparation of halogenated epoxides
US3560568A (en) * 1968-11-26 1971-02-02 Du Pont Preparation of sulfonic acid containing fluorocarbon vinyl ethers
US3784399A (en) * 1971-09-08 1974-01-08 Du Pont Films of fluorinated polymer containing sulfonyl groups with one surface in the sulfonamide or sulfonamide salt form and a process for preparing such
US4192725A (en) * 1971-10-21 1980-03-11 Diamond Shamrock Corporation Electrolytic production of high purity alkali metal hydroxide
BE790369A (fr) * 1971-10-21 1973-04-20 Diamond Shamrock Corp Procede et appareil pour la preparation d'hydroxydes de metaux alcalins de haute purete dans une cuve electrolytique.
US3976549A (en) * 1973-02-26 1976-08-24 Hooker Chemicals & Plastics Corporation Electrolysis method
US4035255A (en) * 1973-05-18 1977-07-12 Gerhard Gritzner Operation of a diaphragm electrolylytic cell for producing chlorine including feeding an oxidizing gas having a regulated moisture content to the cathode
US4035254A (en) * 1973-05-18 1977-07-12 Gerhard Gritzner Operation of a cation exchange membrane electrolytic cell for producing chlorine including feeding an oxidizing gas having a regulated moisture content to the cathode
DE2437395C3 (de) * 1973-10-15 1979-02-08 E.I. Du Pont De Nemours And Co., Wilmington, Del. (V.St.A.) Folie aus fluorhaltigen Polymeren mit Sulfonylgruppen enthaltenden Seitenketten
US3969285A (en) * 1973-12-17 1976-07-13 E. I. Du Pont De Nemours And Company Heat-treated fluorocarbon sulfonylamine cation permselectivity
US4166014A (en) * 1973-12-27 1979-08-28 Tokuyama Soda Kabushiki Kaisha Electrolytic diaphragms, and method of electrolysis using the same
JPS551351B2 (US08197722-20120612-C00042.png) * 1974-03-07 1980-01-12
US3909378A (en) * 1974-06-21 1975-09-30 Du Pont Composite cation exchange membrane and use thereof in electrolysis of an alkali metal halide
JPS5187183A (en) * 1975-01-30 1976-07-30 Asahi Chemical Ind Yoionkokanmaku oyobi sonoseizohoho
JPS5820048B2 (ja) * 1975-07-04 1983-04-21 ナカミチ株式会社 ジドウイチギメソウチ
US4151053A (en) * 1975-07-09 1979-04-24 Asahi Kasei Kogyo Kabushiki Kaisha Cation exchange membrane preparation and use thereof
GB1518387A (en) * 1975-08-29 1978-07-19 Asahi Glass Co Ltd Fluorinated cation exchange membrane and use thereof in electrolysis of an alkali metal halide
JPS5833249B2 (ja) * 1975-09-19 1983-07-19 旭硝子株式会社 含フツ素陽イオン交換樹脂膜
JPS5248598A (en) * 1975-10-17 1977-04-18 Asahi Glass Co Ltd Method for producing alkali hydroxide
US4126588A (en) * 1975-12-30 1978-11-21 Asahi Glass Company Ltd. Fluorinated cation exchange membrane and use thereof in electrolysis of alkali metal halide
DE2618457A1 (de) * 1976-03-31 1977-10-13 Champion Spark Plug Co Halbleitender keramischer koerper
MX145160A (es) * 1976-05-21 1982-01-12 Diamond Shamrock Corp Metodo para formar una membrana sobre un electrodo foraminoso de celda de diafragma normal
JPS6014110B2 (ja) * 1976-06-18 1985-04-11 旭硝子株式会社 水酸化アルカリの製造方法
US4131740A (en) * 1977-04-20 1978-12-26 E. I. Du Pont De Nemours And Company Alkyl perfluoro-ω-fluoroformyl esters and their preparation
US4197179A (en) * 1978-07-13 1980-04-08 The Dow Chemical Company Electrolyte series flow in electrolytic chlor-alkali cells

Also Published As

Publication number Publication date
BR8103720A (pt) 1982-03-02
EP0041734B2 (en) 1990-01-24
JPH0148292B2 (US08197722-20120612-C00042.png) 1989-10-18
EP0041734B1 (en) 1985-01-09
ZA813905B (en) 1983-01-26
JPS5725332A (en) 1982-02-10
DE3168123D1 (en) 1985-02-21
ATE11154T1 (de) 1985-01-15
EP0041734A1 (en) 1981-12-16
AU7160881A (en) 1981-12-17
AU543107B2 (en) 1985-04-04
KR850000052B1 (ko) 1985-02-14
KR840001538B1 (ko) 1984-10-04
KR830006474A (ko) 1983-09-24
KR850001472A (ko) 1985-02-18
AR244732A1 (es) 1993-11-30
US4337137A (en) 1982-06-29
KR850000053B1 (ko) 1985-02-14

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Legal Events

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