CA1201576A - Method and plant for obtaining deuterium-enriched water - Google Patents
Method and plant for obtaining deuterium-enriched waterInfo
- Publication number
- CA1201576A CA1201576A CA000408381A CA408381A CA1201576A CA 1201576 A CA1201576 A CA 1201576A CA 000408381 A CA000408381 A CA 000408381A CA 408381 A CA408381 A CA 408381A CA 1201576 A CA1201576 A CA 1201576A
- Authority
- CA
- Canada
- Prior art keywords
- water
- deuterium
- plant
- container
- synthesis gas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910001868 water Inorganic materials 0.000 title claims abstract description 138
- 229910052805 deuterium Inorganic materials 0.000 title claims abstract description 114
- YZCKVEUIGOORGS-OUBTZVSYSA-N Deuterium Chemical compound [2H] YZCKVEUIGOORGS-OUBTZVSYSA-N 0.000 title claims abstract description 113
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 111
- 238000000034 method Methods 0.000 title claims description 27
- XLYOFNOQVPJJNP-ZSJDYOACSA-N Heavy water Chemical compound [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 claims abstract description 98
- 239000007789 gas Substances 0.000 claims abstract description 85
- 230000015572 biosynthetic process Effects 0.000 claims abstract description 58
- 238000003786 synthesis reaction Methods 0.000 claims abstract description 58
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 42
- 239000001257 hydrogen Substances 0.000 claims abstract description 42
- 239000000203 mixture Substances 0.000 claims abstract description 35
- 239000002351 wastewater Substances 0.000 claims abstract description 28
- 150000002431 hydrogen Chemical class 0.000 claims abstract description 14
- 239000013505 freshwater Substances 0.000 claims abstract description 10
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 28
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 18
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 18
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 17
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 16
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 11
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 9
- 239000001569 carbon dioxide Substances 0.000 claims description 9
- 229910021529 ammonia Inorganic materials 0.000 claims description 8
- 229910052757 nitrogen Inorganic materials 0.000 claims description 8
- 229930195733 hydrocarbon Natural products 0.000 claims description 6
- 150000002430 hydrocarbons Chemical class 0.000 claims description 6
- -1 steam Substances 0.000 claims description 6
- 239000004215 Carbon black (E152) Substances 0.000 claims description 5
- 230000000779 depleting effect Effects 0.000 claims description 4
- 241000196324 Embryophyta Species 0.000 description 82
- 238000004519 manufacturing process Methods 0.000 description 18
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 12
- 239000003054 catalyst Substances 0.000 description 10
- 238000011084 recovery Methods 0.000 description 8
- 238000010586 diagram Methods 0.000 description 6
- 241000195493 Cryptophyta Species 0.000 description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 230000003197 catalytic effect Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000005660 chlorination reaction Methods 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- BHMLFPOTZYRDKA-IRXDYDNUSA-N (2s)-2-[(s)-(2-iodophenoxy)-phenylmethyl]morpholine Chemical compound IC1=CC=CC=C1O[C@@H](C=1C=CC=CC=1)[C@H]1OCCNC1 BHMLFPOTZYRDKA-IRXDYDNUSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 241000134884 Ericales Species 0.000 description 1
- 241001547070 Eriodes Species 0.000 description 1
- 241000282297 Methana Species 0.000 description 1
- 241001163743 Perlodes Species 0.000 description 1
- 238000007036 catalytic synthesis reaction Methods 0.000 description 1
- 238000003889 chemical engineering Methods 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 150000001975 deuterium Chemical class 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 230000000155 isotopic effect Effects 0.000 description 1
- 229910000480 nickel oxide Inorganic materials 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 1
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 1
- 229920000136 polysorbate Polymers 0.000 description 1
- 238000004886 process control Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B4/00—Hydrogen isotopes; Inorganic compounds thereof prepared by isotope exchange, e.g. NH3 + D2 → NH2D + HD
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH4929/81-4 | 1981-07-30 | ||
| CH4929/81A CH655081A5 (de) | 1981-07-30 | 1981-07-30 | Verfahren zur herstellung von mit deuterium angereichertem wasser bei der gewinnung von wasserstoff. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1201576A true CA1201576A (en) | 1986-03-11 |
Family
ID=4284988
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000408381A Expired CA1201576A (en) | 1981-07-30 | 1982-07-29 | Method and plant for obtaining deuterium-enriched water |
Country Status (7)
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PL161104B1 (pl) * | 1989-06-09 | 1993-05-31 | Sposób wzbogacania wody w skladniki wody ciezkiej PL | |
| PL161105B1 (pl) * | 1989-06-09 | 1993-05-31 | Sposób wzbogacania wody naturalnej w tlen-18 PL | |
| US5468462A (en) * | 1993-12-06 | 1995-11-21 | Atomic Energy Of Canada Limited | Geographically distributed tritium extraction plant and process for producing detritiated heavy water using combined electrolysis and catalytic exchange processes |
| AT500986B1 (de) | 2004-11-04 | 2007-07-15 | Voestalpine Schienen Gmbh | Verfahren zum verbinden von schienen durch reibschweissen |
| EP2101897A1 (en) * | 2007-01-09 | 2009-09-23 | GE Healthcare UK Limited | Process for recovery of water isotopologues from impure water |
| CA2690161A1 (en) * | 2007-06-15 | 2008-12-18 | Ge Healthcare Uk Limited | Process for recovery of water isotopologues |
| US20110027165A1 (en) * | 2009-07-29 | 2011-02-03 | Stuart Andrew T B | Distributed pre-enrichment method and apparatus for production of heavy water |
| US20110027166A1 (en) * | 2009-07-29 | 2011-02-03 | Stuart Andrew T B | Chlorate and chlorine dioxide systems adapted for the production of deuterium enriched water |
| US9670064B1 (en) | 2012-09-27 | 2017-06-06 | Consolidated Nuclear Security, LLC | Production of heavy water |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH616602A5 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1975-09-22 | 1980-04-15 | Sulzer Ag | |
| CH620176A5 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1976-05-13 | 1980-11-14 | Sulzer Ag | |
| DE3033290A1 (de) * | 1980-09-01 | 1982-03-25 | Gebrüder Sulzer AG, 8401 Winterthur | Verfahren zur herstellung von mit deuterium angereichertem wasser bei der gewinnung von wasserstoff |
-
1981
- 1981-07-30 CH CH4929/81A patent/CH655081A5/de not_active IP Right Cessation
- 1981-08-28 DE DE8181106732T patent/DE3166854D1/de not_active Expired
- 1981-08-28 AT AT81106732T patent/ATE9983T1/de active
- 1981-08-28 EP EP81106732A patent/EP0070919B1/de not_active Expired
-
1982
- 1982-07-12 JP JP57121110A patent/JPS5827624A/ja active Granted
- 1982-07-27 US US06/402,226 patent/US4504460A/en not_active Expired - Fee Related
- 1982-07-29 CA CA000408381A patent/CA1201576A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| CH655081A5 (de) | 1986-03-27 |
| US4504460A (en) | 1985-03-12 |
| EP0070919A1 (de) | 1983-02-09 |
| ATE9983T1 (de) | 1984-11-15 |
| DE3166854D1 (en) | 1984-11-29 |
| EP0070919B1 (de) | 1984-10-24 |
| JPH0427162B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1992-05-11 |
| JPS5827624A (ja) | 1983-02-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Rae | Selecting heavy water processes | |
| US20030113244A1 (en) | Method for producing carbon monoxide by reverse conversion with an adapted catalyst | |
| CA1201576A (en) | Method and plant for obtaining deuterium-enriched water | |
| US3310376A (en) | Process for combined production of ammonia and urea | |
| CN101108724A (zh) | 以含氚轻水(重水)为原料提取纯氚的生产方法 | |
| CN102574681A (zh) | 用于重水生产的分布式预富集方法和系统 | |
| KR100808706B1 (ko) | 중수 제조 방법 및 장치 | |
| EP0853608A1 (en) | Process for the ammonia and methanol co-production | |
| US4123508A (en) | Apparatus and method for manufacturing deuterium enriched water | |
| US3349126A (en) | Integrated ammonia and urea process | |
| CN107473223A (zh) | 一种采用氮循环的co深冷分离系统及其方法 | |
| US4564515A (en) | Method for separating at least one heavy isotope from a hydrogen-containing medium | |
| CN113428861B (zh) | 一种甲烷与硫化氢重整制氢工艺 | |
| AU2023296338A1 (en) | Shift condensate treatment system and process | |
| US4426370A (en) | Method for the preparation of deuterium-enriched water in the preparation of hydrogen | |
| US4414195A (en) | Method for the preparation of deuterium-enriched water | |
| CN109847555B (zh) | 一种基于水合物法回收催化干气中多种气体的装置及方法 | |
| CN208635426U (zh) | 一种利用液化天然气冷能的塔顶进料焦炉煤气回收系统 | |
| NL1013016C2 (nl) | Werkwijze en inrichting voor het bereiden van ammoniak in een kringloopstroom onder toepassing van keramische membranen. | |
| UA57714C2 (uk) | Спосіб одержання метанолу | |
| US3336113A (en) | Hydrogen isotope exchange processes | |
| Alguacil et al. | Innovative processes in the production of inorganic bases and derived salts of current interest | |
| CN221514450U (zh) | 一种天然气制氢的系统 | |
| CN1272618A (zh) | 利用水合物分离提浓氢气的方法 | |
| CN217838400U (zh) | 合成氨装置氢回收利用系统 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |