CA1200943A - Process for producing water-exchanging, non-toxic polymer material based on acrylamide/n,n'-methylene- bisacrylamide - Google Patents
Process for producing water-exchanging, non-toxic polymer material based on acrylamide/n,n'-methylene- bisacrylamideInfo
- Publication number
- CA1200943A CA1200943A CA000369885A CA369885A CA1200943A CA 1200943 A CA1200943 A CA 1200943A CA 000369885 A CA000369885 A CA 000369885A CA 369885 A CA369885 A CA 369885A CA 1200943 A CA1200943 A CA 1200943A
- Authority
- CA
- Canada
- Prior art keywords
- water
- acrylamide
- weight
- soil
- methylene bisacrylamide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims abstract description 30
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 title claims abstract description 27
- 239000002861 polymer material Substances 0.000 title claims abstract description 20
- ZIUHHBKFKCYYJD-UHFFFAOYSA-N n,n'-methylenebisacrylamide Chemical compound C=CC(=O)NCNC(=O)C=C ZIUHHBKFKCYYJD-UHFFFAOYSA-N 0.000 title claims abstract description 16
- 231100000252 nontoxic Toxicity 0.000 title claims abstract description 9
- 230000003000 nontoxic effect Effects 0.000 title claims abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 36
- 239000000178 monomer Substances 0.000 claims description 15
- 239000002689 soil Substances 0.000 claims description 14
- 239000008187 granular material Substances 0.000 claims description 13
- 238000012360 testing method Methods 0.000 claims description 12
- 238000010521 absorption reaction Methods 0.000 claims description 10
- 239000002245 particle Substances 0.000 claims description 10
- 239000007795 chemical reaction product Substances 0.000 claims description 8
- 238000007334 copolymerization reaction Methods 0.000 claims description 7
- 239000000047 product Substances 0.000 claims description 7
- 239000003505 polymerization initiator Substances 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 5
- 238000006116 polymerization reaction Methods 0.000 claims description 5
- 238000004132 cross linking Methods 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 4
- 125000000864 peroxy group Chemical group O(O*)* 0.000 claims description 2
- 238000003756 stirring Methods 0.000 claims description 2
- 150000003512 tertiary amines Chemical class 0.000 claims description 2
- 229920002401 polyacrylamide Polymers 0.000 claims 10
- 239000003795 chemical substances by application Substances 0.000 claims 4
- 230000003750 conditioning effect Effects 0.000 claims 2
- 238000009877 rendering Methods 0.000 claims 2
- 229920003176 water-insoluble polymer Polymers 0.000 claims 2
- 125000000129 anionic group Chemical group 0.000 claims 1
- 239000003337 fertilizer Substances 0.000 claims 1
- 239000000945 filler Substances 0.000 claims 1
- 239000000575 pesticide Substances 0.000 claims 1
- 229920000642 polymer Polymers 0.000 abstract description 5
- 230000000704 physical effect Effects 0.000 abstract description 2
- 239000000499 gel Substances 0.000 description 7
- 229920001577 copolymer Polymers 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 description 3
- 239000004576 sand Substances 0.000 description 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 150000003926 acrylamides Chemical class 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- MTPJEFOSTIKRSS-UHFFFAOYSA-N 3-(dimethylamino)propanenitrile Chemical compound CN(C)CCC#N MTPJEFOSTIKRSS-UHFFFAOYSA-N 0.000 description 1
- 229920006063 Lamide® Polymers 0.000 description 1
- 239000006004 Quartz sand Substances 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 229920006322 acrylamide copolymer Polymers 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- LFINSDKRYHNMRB-UHFFFAOYSA-N diazanium;oxido sulfate Chemical compound [NH4+].[NH4+].[O-]OS([O-])(=O)=O LFINSDKRYHNMRB-UHFFFAOYSA-N 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
- 125000005395 methacrylic acid group Chemical class 0.000 description 1
- MYWUZJCMWCOHBA-VIFPVBQESA-N methamphetamine Chemical compound CN[C@@H](C)CC1=CC=CC=C1 MYWUZJCMWCOHBA-VIFPVBQESA-N 0.000 description 1
- HKJIIHGOQMKEAV-UHFFFAOYSA-N methanol;prop-2-enamide Chemical compound OC.NC(=O)C=C HKJIIHGOQMKEAV-UHFFFAOYSA-N 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- KKFHAJHLJHVUDM-UHFFFAOYSA-N n-vinylcarbazole Chemical compound C1=CC=C2N(C=C)C3=CC=CC=C3C2=C1 KKFHAJHLJHVUDM-UHFFFAOYSA-N 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000867 polyelectrolyte Polymers 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/52—Amides or imides
- C08F220/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
- C08F220/56—Acrylamide; Methacrylamide
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH2250/80-5 | 1980-03-21 | ||
| CH225080A CH643569A5 (de) | 1980-03-21 | 1980-03-21 | Verfahren zur herstellung von wasseraustauschendem, nicht-toxischem polymermaterial auf basis acrylamid/n,n'-methylenbisacrylamid. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1200943A true CA1200943A (en) | 1986-02-18 |
Family
ID=4229376
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000369885A Expired CA1200943A (en) | 1980-03-21 | 1981-02-02 | Process for producing water-exchanging, non-toxic polymer material based on acrylamide/n,n'-methylene- bisacrylamide |
Country Status (9)
| Country | Link |
|---|---|
| EP (1) | EP0037138A3 (enrdf_load_html_response) |
| JP (1) | JPS56145908A (enrdf_load_html_response) |
| AU (1) | AU537812B2 (enrdf_load_html_response) |
| CA (1) | CA1200943A (enrdf_load_html_response) |
| CH (1) | CH643569A5 (enrdf_load_html_response) |
| ES (1) | ES8201606A1 (enrdf_load_html_response) |
| IL (1) | IL61973A (enrdf_load_html_response) |
| IN (1) | IN153454B (enrdf_load_html_response) |
| ZA (1) | ZA81521B (enrdf_load_html_response) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0122797B2 (en) | 1983-04-14 | 1994-05-18 | Mitsui Petrochemical Industries, Ltd. | Process for producing granular, water-swellable crosslinked acrylic copolymer, and its use |
| JPS6063209A (ja) * | 1983-09-16 | 1985-04-11 | Mitsui Petrochem Ind Ltd | 水膨潤性架橋重合体の製法 |
| US4579578A (en) * | 1983-06-04 | 1986-04-01 | Chemical Discoveries S.A. | Plant growing media |
| DE68913894T2 (de) * | 1988-10-21 | 1994-09-22 | Canon Kk | Verfahren zur Herstellung eines Polymergels, Polymergel und Stellglied, das dieses benutzt. |
| JP2697782B2 (ja) * | 1995-03-10 | 1998-01-14 | 工業技術院長 | 変位速度またはひずみ速度計測方法およびそれに用いる装置 |
| RU2192434C2 (ru) * | 2000-07-17 | 2002-11-10 | Ивановский государственный химико-технологический университет | Способ получения водорастворимых (со)полимеров акрилового ряда |
| UA67354U (uk) * | 2011-11-24 | 2012-02-10 | Людмила Дмитрівна Желдак | Водорозчинний лінійний гетероланцюговий диполімер |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2801984A (en) * | 1955-08-15 | 1957-08-06 | American Cyanamid Co | Resin-forming composition for stabilization of soil and process of using same |
| US3212577A (en) * | 1959-07-09 | 1965-10-19 | Sinclair Research Inc | Method for decreasing the permeability of a permeable well area |
| SE306073B (enrdf_load_html_response) * | 1962-04-18 | 1968-11-18 | Pharmacia Ab | |
| US3545130A (en) * | 1967-07-21 | 1970-12-08 | Dow Chemical Co | Soil conditioning and erosion control |
-
1980
- 1980-03-21 CH CH225080A patent/CH643569A5/de not_active IP Right Cessation
-
1981
- 1981-01-23 IL IL61973A patent/IL61973A/xx unknown
- 1981-01-26 ZA ZA00810521A patent/ZA81521B/xx unknown
- 1981-01-27 IN IN85/CAL/81A patent/IN153454B/en unknown
- 1981-01-29 AU AU66695/81A patent/AU537812B2/en not_active Ceased
- 1981-02-02 CA CA000369885A patent/CA1200943A/en not_active Expired
- 1981-02-06 ES ES499191A patent/ES8201606A1/es not_active Expired
- 1981-02-27 JP JP2709781A patent/JPS56145908A/ja active Pending
- 1981-03-11 EP EP81200276A patent/EP0037138A3/de not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| AU537812B2 (en) | 1984-07-12 |
| EP0037138A3 (de) | 1982-04-21 |
| JPS56145908A (en) | 1981-11-13 |
| IL61973A (en) | 1984-04-30 |
| ES499191A0 (es) | 1982-01-01 |
| EP0037138A2 (de) | 1981-10-07 |
| CH643569A5 (de) | 1984-06-15 |
| IL61973A0 (en) | 1981-02-27 |
| AU6669581A (en) | 1981-09-24 |
| ES8201606A1 (es) | 1982-01-01 |
| ZA81521B (en) | 1982-02-24 |
| IN153454B (enrdf_load_html_response) | 1984-07-14 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |