CA1192398A - Chemical heat amplification in thermal transfer printing - Google Patents
Chemical heat amplification in thermal transfer printingInfo
- Publication number
- CA1192398A CA1192398A CA000441819A CA441819A CA1192398A CA 1192398 A CA1192398 A CA 1192398A CA 000441819 A CA000441819 A CA 000441819A CA 441819 A CA441819 A CA 441819A CA 1192398 A CA1192398 A CA 1192398A
- Authority
- CA
- Canada
- Prior art keywords
- ink
- ribbon
- exothermic
- layer
- heat
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 230000003321 amplification Effects 0.000 title claims abstract description 33
- 238000003199 nucleic acid amplification method Methods 0.000 title claims abstract description 33
- 239000000126 substance Substances 0.000 title claims abstract description 29
- 238000010023 transfer printing Methods 0.000 title claims abstract description 26
- 239000000463 material Substances 0.000 claims abstract description 92
- 238000006243 chemical reaction Methods 0.000 claims abstract description 51
- 230000008018 melting Effects 0.000 claims abstract description 17
- 238000002844 melting Methods 0.000 claims abstract description 17
- 239000007787 solid Substances 0.000 claims abstract description 6
- 150000002978 peroxides Chemical class 0.000 claims abstract description 5
- 238000000034 method Methods 0.000 claims description 24
- 238000007639 printing Methods 0.000 claims description 21
- -1 azo compound Chemical class 0.000 claims description 12
- 238000010438 heat treatment Methods 0.000 claims description 11
- 238000000354 decomposition reaction Methods 0.000 claims description 7
- DGZUEIPKRRSMGK-UHFFFAOYSA-N quadricyclane Chemical compound C1C2C3C2C2C3C12 DGZUEIPKRRSMGK-UHFFFAOYSA-N 0.000 claims description 7
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 claims description 6
- 230000008569 process Effects 0.000 claims description 5
- 239000000758 substrate Substances 0.000 claims description 5
- ZHNUHDYFZUAESO-UHFFFAOYSA-N Formamide Chemical compound NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 claims description 4
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 claims description 4
- QYZFTMMPKCOTAN-UHFFFAOYSA-N n-[2-(2-hydroxyethylamino)ethyl]-2-[[1-[2-(2-hydroxyethylamino)ethylamino]-2-methyl-1-oxopropan-2-yl]diazenyl]-2-methylpropanamide Chemical compound OCCNCCNC(=O)C(C)(C)N=NC(C)(C)C(=O)NCCNCCO QYZFTMMPKCOTAN-UHFFFAOYSA-N 0.000 claims description 4
- 239000005977 Ethylene Substances 0.000 claims description 3
- 229940087305 limonene Drugs 0.000 claims description 3
- 235000001510 limonene Nutrition 0.000 claims description 3
- 229910052757 nitrogen Inorganic materials 0.000 claims description 3
- LVZWSLJZHVFIQJ-UHFFFAOYSA-N Cyclopropane Chemical compound C1CC1 LVZWSLJZHVFIQJ-UHFFFAOYSA-N 0.000 claims description 2
- XOZUGNYVDXMRKW-AATRIKPKSA-N azodicarbonamide Chemical class NC(=O)\N=N\C(N)=O XOZUGNYVDXMRKW-AATRIKPKSA-N 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- 230000006872 improvement Effects 0.000 claims description 2
- 229920005596 polymer binder Polymers 0.000 claims description 2
- 239000002491 polymer binding agent Substances 0.000 claims description 2
- RRKODOZNUZCUBN-CCAGOZQPSA-N (1z,3z)-cycloocta-1,3-diene Chemical compound C1CC\C=C/C=C\C1 RRKODOZNUZCUBN-CCAGOZQPSA-N 0.000 claims 1
- VULCFZQVCFIKNK-UHFFFAOYSA-N (4-phenylcyclohexyl)benzene Chemical compound C1CC(C=2C=CC=CC=2)CCC1C1=CC=CC=C1 VULCFZQVCFIKNK-UHFFFAOYSA-N 0.000 claims 1
- 239000003086 colorant Substances 0.000 claims 1
- 230000036647 reaction Effects 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 abstract description 5
- 230000008859 change Effects 0.000 abstract description 3
- 239000000539 dimer Substances 0.000 abstract description 3
- 239000013638 trimer Substances 0.000 abstract description 3
- 239000000178 monomer Substances 0.000 abstract 1
- 239000000976 ink Substances 0.000 description 102
- 239000000203 mixture Substances 0.000 description 13
- 239000011230 binding agent Substances 0.000 description 9
- 239000000654 additive Substances 0.000 description 7
- 230000000996 additive effect Effects 0.000 description 7
- 239000003517 fume Substances 0.000 description 7
- 229910052751 metal Inorganic materials 0.000 description 7
- 239000002184 metal Substances 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- 239000006227 byproduct Substances 0.000 description 5
- 150000002500 ions Chemical class 0.000 description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 230000002411 adverse Effects 0.000 description 4
- 239000006229 carbon black Substances 0.000 description 4
- 229910002056 binary alloy Inorganic materials 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 239000004020 conductor Substances 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 231100000252 nontoxic Toxicity 0.000 description 3
- 230000003000 nontoxic effect Effects 0.000 description 3
- 229910021332 silicide Inorganic materials 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229920002799 BoPET Polymers 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 239000005041 Mylar™ Substances 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000010408 film Substances 0.000 description 2
- 238000007648 laser printing Methods 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 229920001470 polyketone Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- FVBUAEGBCNSCDD-UHFFFAOYSA-N silicide(4-) Chemical compound [Si-4] FVBUAEGBCNSCDD-UHFFFAOYSA-N 0.000 description 2
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 2
- WLHJCCUFRCTNRZ-UHFFFAOYSA-N (1-phenylcyclohexyl)benzene Chemical compound C1CCCCC1(C=1C=CC=CC=1)C1=CC=CC=C1 WLHJCCUFRCTNRZ-UHFFFAOYSA-N 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 241000725101 Clea Species 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 239000002033 PVDF binder Substances 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 241000206607 Porphyra umbilicalis Species 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 230000035508 accumulation Effects 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 238000003491 array Methods 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000003857 carboxamides Chemical class 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 238000004737 colorimetric analysis Methods 0.000 description 1
- 229940125904 compound 1 Drugs 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- LQYWWEJSNSRQPT-UHFFFAOYSA-N cycloocta-1,3-diene Chemical compound C1=CC=CCCCC1.C1=CC=CCCCC1 LQYWWEJSNSRQPT-UHFFFAOYSA-N 0.000 description 1
- 239000004914 cyclooctane Substances 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- 229920003223 poly(pyromellitimide-1,4-diphenyl ether) Polymers 0.000 description 1
- 229920002492 poly(sulfone) Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 238000001149 thermolysis Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 238000007738 vacuum evaporation Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/382—Contact thermal transfer or sublimation processes
- B41M5/392—Additives, other than colour forming substances, dyes or pigments, e.g. sensitisers, transfer promoting agents
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/913—Material designed to be responsive to temperature, light, moisture
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/914—Transfer or decalcomania
Landscapes
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Thermal Transfer Or Thermal Recording In General (AREA)
- Impression-Transfer Materials And Handling Thereof (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US454,814 | 1982-12-30 | ||
| US06/454,814 US4491432A (en) | 1982-12-30 | 1982-12-30 | Chemical heat amplification in thermal transfer printing |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1192398A true CA1192398A (en) | 1985-08-27 |
Family
ID=23806227
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000441819A Expired CA1192398A (en) | 1982-12-30 | 1983-11-24 | Chemical heat amplification in thermal transfer printing |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US4491432A (enExample) |
| EP (1) | EP0113017B1 (enExample) |
| JP (1) | JPS59124883A (enExample) |
| CA (1) | CA1192398A (enExample) |
| DE (1) | DE3377345D1 (enExample) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4549824A (en) * | 1983-12-30 | 1985-10-29 | International Business Machines Corporation | Ink additives for efficient thermal ink transfer printing processes |
| US4525722A (en) * | 1984-02-23 | 1985-06-25 | International Business Machines Corporation | Chemical heat amplification in thermal transfer printing |
| US4692044A (en) * | 1985-04-30 | 1987-09-08 | International Business Machines Corporation | Interface resistance and knee voltage enhancement in resistive ribbon printing |
| DE3766305D1 (de) * | 1986-07-11 | 1991-01-03 | Siemens Ag | Thermo-transfer-druckeinrichtung. |
| US4822643A (en) * | 1987-06-30 | 1989-04-18 | Minnesota Mining And Manufacturing Company | Thermal transfer imaging system |
| DE3736728A1 (de) * | 1987-10-29 | 1989-05-11 | Siemens Ag | Druckertinte |
| US4897310A (en) * | 1987-12-15 | 1990-01-30 | Siemens Aktiengesellschaft | Inking ribbon for transferring color under the influence of heat |
| JPH01171983A (ja) * | 1987-12-28 | 1989-07-06 | Matsushita Electric Ind Co Ltd | 熱転写シート |
| US5264279A (en) * | 1989-09-19 | 1993-11-23 | Dai Nippon Insatsu Kabushiki Kaisha | Composite thermal transfer sheet |
| DE3941517A1 (de) * | 1989-12-15 | 1991-06-27 | Siemens Ag | Thermotransferfarbband |
| US5546114A (en) * | 1991-09-18 | 1996-08-13 | Tektronix, Inc. | Systems and methods for making printed products |
| US5512930A (en) * | 1991-09-18 | 1996-04-30 | Tektronix, Inc. | Systems and methods of printing by applying an image enhancing precoat |
| US5139598A (en) * | 1991-10-11 | 1992-08-18 | Minnesota Mining And Manufacturing Company | Vapor deposited multi-layered films--a method of preparation and use in imaging |
| US5236739A (en) * | 1991-10-11 | 1993-08-17 | Minnesota Mining And Manufacturing Company | Vapor deposited multi-layered films--a method of preparation |
| US5352651A (en) * | 1992-12-23 | 1994-10-04 | Minnesota Mining And Manufacturing Company | Nanostructured imaging transfer element |
| US5747217A (en) * | 1996-04-03 | 1998-05-05 | Minnesota Mining And Manufacturing Company | Laser-induced mass transfer imaging materials and methods utilizing colorless sublimable compounds |
| US5691098A (en) * | 1996-04-03 | 1997-11-25 | Minnesota Mining And Manufacturing Company | Laser-Induced mass transfer imaging materials utilizing diazo compounds |
| US6607871B1 (en) * | 1999-09-27 | 2003-08-19 | Fuji Photo Film Co., Ltd. | Image recording medium |
| US6569600B2 (en) * | 2001-03-30 | 2003-05-27 | Eastman Kodak Company | Optical recording material |
| US6969578B2 (en) * | 2002-08-19 | 2005-11-29 | Eastman Kodak Company | Optical recording material |
| TWI401301B (zh) * | 2010-10-06 | 2013-07-11 | Univ Nat Cheng Kung | 燒結成型之組成物及燒結成型方法 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1560885A (en) * | 1920-06-29 | 1925-11-10 | Walter Richard | Method of making alloys |
| US2982619A (en) * | 1957-04-12 | 1961-05-02 | Roger A Long | Metallic compounds for use in hightemperature applications |
| DE2100611C3 (de) * | 1970-01-09 | 1978-05-03 | Ing. C. Olivetti & C., S.P.A., Ivrea, Turin (Italien) | Elektrothermische Druckvorrichtung |
| US3787210A (en) * | 1971-09-30 | 1974-01-22 | Ncr | Laser recording technique using combustible blow-off |
| US3962513A (en) * | 1974-03-28 | 1976-06-08 | Scott Paper Company | Laser transfer medium for imaging printing plate |
| JPS55102402A (en) * | 1979-01-30 | 1980-08-05 | Nakamura Suikan:Kk | Condensing method for steam component in intake of ring type water pump and condenser for its steam component |
| US4268368A (en) * | 1980-03-24 | 1981-05-19 | International Business Machines Corporation | Electrophoretical method for selectively reinking resistive ribbon thermal transfer printing ribbons |
-
1982
- 1982-12-30 US US06/454,814 patent/US4491432A/en not_active Expired - Fee Related
-
1983
- 1983-11-14 JP JP58212625A patent/JPS59124883A/ja active Granted
- 1983-11-22 DE DE8383111648T patent/DE3377345D1/de not_active Expired
- 1983-11-22 EP EP83111648A patent/EP0113017B1/en not_active Expired
- 1983-11-24 CA CA000441819A patent/CA1192398A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0377792B2 (enExample) | 1991-12-11 |
| EP0113017A2 (en) | 1984-07-11 |
| JPS59124883A (ja) | 1984-07-19 |
| US4491432A (en) | 1985-01-01 |
| EP0113017A3 (en) | 1985-08-28 |
| DE3377345D1 (en) | 1988-08-18 |
| EP0113017B1 (en) | 1988-07-13 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEC | Expiry (correction) | ||
| MKEX | Expiry |