CA1192023A - Procede pour l'hydrodesulfuration d'un gaz contenant de l'oxygene et des composes organiques du soufre - Google Patents
Procede pour l'hydrodesulfuration d'un gaz contenant de l'oxygene et des composes organiques du soufreInfo
- Publication number
- CA1192023A CA1192023A CA000428824A CA428824A CA1192023A CA 1192023 A CA1192023 A CA 1192023A CA 000428824 A CA000428824 A CA 000428824A CA 428824 A CA428824 A CA 428824A CA 1192023 A CA1192023 A CA 1192023A
- Authority
- CA
- Canada
- Prior art keywords
- gas
- catalyst
- oxygen
- hydrogen
- sulfur
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000007789 gas Substances 0.000 title claims abstract description 45
- 238000000034 method Methods 0.000 title claims abstract description 20
- 229910052760 oxygen Inorganic materials 0.000 title claims abstract description 17
- 239000001301 oxygen Substances 0.000 title claims abstract description 17
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title claims abstract description 16
- 229910052717 sulfur Inorganic materials 0.000 title claims description 9
- 239000011593 sulfur Substances 0.000 title claims description 9
- -1 sulfur organic compounds Chemical class 0.000 title abstract 2
- 239000003054 catalyst Substances 0.000 claims abstract description 59
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims abstract description 35
- 239000001257 hydrogen Substances 0.000 claims abstract description 18
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 18
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 17
- 229910052763 palladium Inorganic materials 0.000 claims abstract description 17
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 16
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 16
- 150000002898 organic sulfur compounds Chemical class 0.000 claims abstract description 13
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910017052 cobalt Inorganic materials 0.000 claims abstract description 8
- 239000010941 cobalt Substances 0.000 claims abstract description 8
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000011733 molybdenum Substances 0.000 claims abstract description 8
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 8
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 8
- 229910052751 metal Inorganic materials 0.000 claims abstract description 5
- 239000002184 metal Substances 0.000 claims abstract description 5
- 239000000203 mixture Substances 0.000 claims abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 13
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 claims description 12
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 11
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
- 238000006243 chemical reaction Methods 0.000 claims description 7
- 229910000037 hydrogen sulfide Inorganic materials 0.000 claims description 7
- 239000000377 silicon dioxide Substances 0.000 claims description 4
- 150000002894 organic compounds Chemical class 0.000 claims description 2
- 239000003345 natural gas Substances 0.000 abstract description 4
- 230000015572 biosynthetic process Effects 0.000 abstract description 2
- 238000006392 deoxygenation reaction Methods 0.000 abstract description 2
- 238000003786 synthesis reaction Methods 0.000 abstract description 2
- 238000001035 drying Methods 0.000 abstract 1
- 238000002407 reforming Methods 0.000 abstract 1
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 7
- RAOIDOHSFRTOEL-UHFFFAOYSA-N tetrahydrothiophene Chemical compound C1CCSC1 RAOIDOHSFRTOEL-UHFFFAOYSA-N 0.000 description 7
- WHDPTDWLEKQKKX-UHFFFAOYSA-N cobalt molybdenum Chemical compound [Co].[Co].[Mo] WHDPTDWLEKQKKX-UHFFFAOYSA-N 0.000 description 5
- DDTIGTPWGISMKL-UHFFFAOYSA-N molybdenum nickel Chemical compound [Ni].[Mo] DDTIGTPWGISMKL-UHFFFAOYSA-N 0.000 description 5
- 229910003294 NiMo Inorganic materials 0.000 description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 238000005470 impregnation Methods 0.000 description 3
- 125000001741 organic sulfur group Chemical group 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- CETBSQOFQKLHHZ-UHFFFAOYSA-N Diethyl disulfide Chemical compound CCSSCC CETBSQOFQKLHHZ-UHFFFAOYSA-N 0.000 description 2
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 238000006477 desulfuration reaction Methods 0.000 description 2
- 230000023556 desulfurization Effects 0.000 description 2
- ALVPFGSHPUPROW-UHFFFAOYSA-N dipropyl disulfide Chemical compound CCCSSCCC ALVPFGSHPUPROW-UHFFFAOYSA-N 0.000 description 2
- DNJIEGIFACGWOD-UHFFFAOYSA-N ethanethiol Chemical compound CCS DNJIEGIFACGWOD-UHFFFAOYSA-N 0.000 description 2
- 125000001183 hydrocarbyl group Chemical group 0.000 description 2
- 150000002941 palladium compounds Chemical class 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 150000003464 sulfur compounds Chemical class 0.000 description 2
- 150000003568 thioethers Chemical class 0.000 description 2
- 230000009466 transformation Effects 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- 238000004438 BET method Methods 0.000 description 1
- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- HTIRHQRTDBPHNZ-UHFFFAOYSA-N Dibutyl sulfide Chemical compound CCCCSCCCC HTIRHQRTDBPHNZ-UHFFFAOYSA-N 0.000 description 1
- QMMFVYPAHWMCMS-UHFFFAOYSA-N Dimethyl sulfide Chemical compound CSC QMMFVYPAHWMCMS-UHFFFAOYSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 235000013844 butane Nutrition 0.000 description 1
- WQAQPCDUOCURKW-UHFFFAOYSA-N butanethiol Chemical class CCCCS WQAQPCDUOCURKW-UHFFFAOYSA-N 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 238000004939 coking Methods 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- LJSQFQKUNVCTIA-UHFFFAOYSA-N diethyl sulfide Chemical compound CCSCC LJSQFQKUNVCTIA-UHFFFAOYSA-N 0.000 description 1
- 150000002019 disulfides Chemical class 0.000 description 1
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 238000007327 hydrogenolysis reaction Methods 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 239000003077 lignite Substances 0.000 description 1
- 230000007257 malfunction Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical class CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 239000003129 oil well Substances 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- JKDRQYIYVJVOPF-FDGPNNRMSA-L palladium(ii) acetylacetonate Chemical compound [Pd+2].C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O JKDRQYIYVJVOPF-FDGPNNRMSA-L 0.000 description 1
- GPNDARIEYHPYAY-UHFFFAOYSA-N palladium(ii) nitrate Chemical compound [Pd+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O GPNDARIEYHPYAY-UHFFFAOYSA-N 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- SUVIGLJNEAMWEG-UHFFFAOYSA-N propane-1-thiol Chemical class CCCS SUVIGLJNEAMWEG-UHFFFAOYSA-N 0.000 description 1
- 238000000629 steam reforming Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- PTISTKLWEJDJID-UHFFFAOYSA-N sulfanylidenemolybdenum Chemical class [Mo]=S PTISTKLWEJDJID-UHFFFAOYSA-N 0.000 description 1
- 235000013616 tea Nutrition 0.000 description 1
- 230000001052 transient effect Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/148—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound
- C07C7/163—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound by hydrogenation
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Water Supply & Treatment (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Catalysts (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
- Industrial Gases (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR82/09210 | 1982-05-25 | ||
| FR8209210A FR2527473A1 (fr) | 1982-05-25 | 1982-05-25 | Procede pour l'hydrodesulfuration d'un gaz contenant de l'oxygene et des composes organiques du soufre |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1192023A true CA1192023A (fr) | 1985-08-20 |
Family
ID=9274380
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000428824A Expired CA1192023A (fr) | 1982-05-25 | 1983-05-25 | Procede pour l'hydrodesulfuration d'un gaz contenant de l'oxygene et des composes organiques du soufre |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US4505880A (enExample) |
| EP (1) | EP0095395B1 (enExample) |
| JP (1) | JPS58215488A (enExample) |
| CA (1) | CA1192023A (enExample) |
| DE (1) | DE3361056D1 (enExample) |
| FR (1) | FR2527473A1 (enExample) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6140807A (ja) * | 1984-08-03 | 1986-02-27 | Hitachi Ltd | アルゴンガスの精製方法および装置 |
| US4892717A (en) * | 1985-07-31 | 1990-01-09 | Union Oil Company Of California | Gas treating process |
| DE3534709C1 (en) * | 1985-09-28 | 1987-04-02 | Ruetgerswerke Ag | Process for obtaining heterocycle-free aromatic compounds |
| KR960010082B1 (ko) * | 1988-09-26 | 1996-07-25 | 니혼 파이오닉스 가부시끼가이샤 | 기체성 수소화물의 정제방법 |
| JP2717494B2 (ja) * | 1992-07-17 | 1998-02-18 | 三菱電機株式会社 | 回転磁気ヘッド装置 |
| US5849256A (en) * | 1996-04-26 | 1998-12-15 | Engelhard Corporation | Method for oxidizing carbon monoxide in a gas stream containing oxidizable sulphur compounds |
| AU2005305204B2 (en) * | 2004-11-09 | 2010-04-22 | Fluor Technologies Corporation | Configurations and methods for SOx removal in oxygen-containing gases |
| JP5033829B2 (ja) * | 2008-08-27 | 2012-09-26 | 株式会社神鋼環境ソリューション | 消化ガスの脱酸素方法及び装置 |
| RU2402515C1 (ru) * | 2009-04-01 | 2010-10-27 | Открытое акционерное общество "Нижнекамскнефтехим" | Способ очистки низших алканов |
| CA2709722A1 (en) * | 2010-07-15 | 2012-01-15 | Alakh Prasad | Integrated biogas cleaning a system to remove water, siloxanes, sulfur, oxygen, chlorides, and volatile organic compounds |
| CN102433181B (zh) * | 2010-09-29 | 2014-03-12 | 中国石油化工股份有限公司 | 煤矿区煤层气催化脱氧的方法 |
| DE102016116306A1 (de) * | 2016-09-01 | 2018-03-01 | Thyssenkrupp Ag | Verfahren und Vorrichtung zum Entfernen von organischen Schwefelverbindungen aus wasserstoffreichen Gasen |
| WO2018173143A1 (ja) * | 2017-03-22 | 2018-09-27 | 日揮株式会社 | 天然ガスの処理装置 |
| CN111744355B (zh) * | 2020-05-19 | 2022-02-01 | 福建省气柜设备安装有限公司 | 一种工业混合气体的脱硫方法及脱硫装置 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB340016A (en) * | 1929-09-16 | 1930-12-16 | Ig Farbenindustrie Ag | A process for the catalytic desulphurization of gases |
| US3420618A (en) * | 1965-07-06 | 1969-01-07 | Catalysts & Chem Inc | Gas purification by hydrogenation |
| US4175928A (en) * | 1975-12-05 | 1979-11-27 | Conoco Methanation Company | Hydrodesulfurization purification process for coal gasification |
| DE2731611B2 (de) * | 1977-07-13 | 1979-11-22 | Loi Industrieofenanlagen Gmbh, 4300 Essen | Verfahren zum Erzeugen weitgehend schwefelfreier Brenngase bei der Gewinnung von Schutzgasen aus schwefelhaltigen Rohgasen |
| US4181503A (en) * | 1978-10-30 | 1980-01-01 | United Technologies Corporation | Process for alternately steam reforming sulfur containing hydrocarbons that vary in oxygen content |
| US4260840A (en) * | 1980-01-11 | 1981-04-07 | Exxon Research & Engineering Co. | Butene-1 containing feed purification process(CS-165) |
| FR2521448A1 (fr) * | 1982-02-15 | 1983-08-19 | Inst Francais Du Petrole | Procede pour l'hydrodesulfuration de gaz naturel contenant des composes organiques du soufre et de l'oxygene |
-
1982
- 1982-05-25 FR FR8209210A patent/FR2527473A1/fr active Granted
-
1983
- 1983-02-15 US US06/466,689 patent/US4505880A/en not_active Expired - Fee Related
- 1983-04-28 EP EP83400856A patent/EP0095395B1/fr not_active Expired
- 1983-04-28 DE DE8383400856T patent/DE3361056D1/de not_active Expired
- 1983-05-25 CA CA000428824A patent/CA1192023A/fr not_active Expired
- 1983-05-25 JP JP58093340A patent/JPS58215488A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| EP0095395A1 (fr) | 1983-11-30 |
| EP0095395B1 (fr) | 1985-10-23 |
| FR2527473B1 (enExample) | 1984-12-14 |
| US4505880A (en) | 1985-03-19 |
| DE3361056D1 (en) | 1985-11-28 |
| FR2527473A1 (fr) | 1983-12-02 |
| JPS58215488A (ja) | 1983-12-14 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEC | Expiry (correction) | ||
| MKEX | Expiry |