CA1187135A - Fuel cell - Google Patents
Fuel cellInfo
- Publication number
- CA1187135A CA1187135A CA000420396A CA420396A CA1187135A CA 1187135 A CA1187135 A CA 1187135A CA 000420396 A CA000420396 A CA 000420396A CA 420396 A CA420396 A CA 420396A CA 1187135 A CA1187135 A CA 1187135A
- Authority
- CA
- Canada
- Prior art keywords
- fuel cell
- lithium titanate
- electrolyte
- cell according
- lithium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000446 fuel Substances 0.000 title claims abstract description 44
- 239000003792 electrolyte Substances 0.000 claims abstract description 74
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims abstract description 41
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 41
- 229910052744 lithium Inorganic materials 0.000 claims abstract description 41
- 239000000203 mixture Substances 0.000 claims abstract description 26
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims abstract description 21
- 229910010272 inorganic material Inorganic materials 0.000 claims abstract description 16
- 239000011147 inorganic material Substances 0.000 claims abstract description 16
- 239000007800 oxidant agent Substances 0.000 claims abstract description 12
- 230000001590 oxidative effect Effects 0.000 claims abstract description 12
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims abstract description 4
- 229910052751 metal Inorganic materials 0.000 claims abstract description 3
- 239000002184 metal Substances 0.000 claims abstract description 3
- 239000000463 material Substances 0.000 claims description 25
- 239000000835 fiber Substances 0.000 claims description 21
- 229910003002 lithium salt Inorganic materials 0.000 claims description 10
- 159000000002 lithium salts Chemical class 0.000 claims description 10
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 9
- NJLLQSBAHIKGKF-UHFFFAOYSA-N dipotassium dioxido(oxo)titanium Chemical compound [K+].[K+].[O-][Ti]([O-])=O NJLLQSBAHIKGKF-UHFFFAOYSA-N 0.000 claims description 9
- 239000000843 powder Substances 0.000 claims description 5
- 150000003839 salts Chemical class 0.000 claims description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- 239000001257 hydrogen Substances 0.000 claims description 4
- 239000002737 fuel gas Substances 0.000 claims description 3
- 238000002844 melting Methods 0.000 claims description 3
- 230000008018 melting Effects 0.000 claims description 3
- 239000011368 organic material Substances 0.000 claims 1
- 238000000034 method Methods 0.000 description 10
- 229910052700 potassium Inorganic materials 0.000 description 9
- 239000011591 potassium Substances 0.000 description 9
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 8
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 8
- 239000007789 gas Substances 0.000 description 7
- 238000010438 heat treatment Methods 0.000 description 7
- 229910052808 lithium carbonate Inorganic materials 0.000 description 7
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
- -1 alkaline earth metal carbonates Chemical class 0.000 description 6
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 description 6
- 239000011159 matrix material Substances 0.000 description 6
- 238000005245 sintering Methods 0.000 description 6
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 5
- 229910002092 carbon dioxide Inorganic materials 0.000 description 4
- YQNQTEBHHUSESQ-UHFFFAOYSA-N lithium aluminate Chemical compound [Li+].[O-][Al]=O YQNQTEBHHUSESQ-UHFFFAOYSA-N 0.000 description 4
- 238000000465 moulding Methods 0.000 description 4
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 3
- 150000008064 anhydrides Chemical class 0.000 description 3
- 239000001569 carbon dioxide Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 229910013596 LiOH—H2O Inorganic materials 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 238000002441 X-ray diffraction Methods 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- OJYGBLRPYBAHRT-UHFFFAOYSA-N alphachloralose Chemical compound O1C(C(Cl)(Cl)Cl)OC2C(O)C(C(O)CO)OC21 OJYGBLRPYBAHRT-UHFFFAOYSA-N 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- IIPYXGDZVMZOAP-UHFFFAOYSA-N lithium nitrate Chemical compound [Li+].[O-][N+]([O-])=O IIPYXGDZVMZOAP-UHFFFAOYSA-N 0.000 description 2
- GLXDVVHUTZTUQK-UHFFFAOYSA-M lithium;hydroxide;hydrate Chemical compound [Li+].O.[OH-] GLXDVVHUTZTUQK-UHFFFAOYSA-M 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 229910000027 potassium carbonate Inorganic materials 0.000 description 2
- 235000015320 potassium carbonate Nutrition 0.000 description 2
- 239000011819 refractory material Substances 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- 238000011105 stabilization Methods 0.000 description 2
- LLZRNZOLAXHGLL-UHFFFAOYSA-J titanic acid Chemical compound O[Ti](O)(O)O LLZRNZOLAXHGLL-UHFFFAOYSA-J 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- 239000003570 air Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 229910000288 alkali metal carbonate Inorganic materials 0.000 description 1
- 150000008041 alkali metal carbonates Chemical class 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000003034 coal gas Substances 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 150000004677 hydrates Chemical class 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- NPWKAIACYUAHML-UHFFFAOYSA-N lithium nickel(2+) oxygen(2-) Chemical compound [Li+].[O-2].[Ni+2] NPWKAIACYUAHML-UHFFFAOYSA-N 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 229910000480 nickel oxide Inorganic materials 0.000 description 1
- 239000012811 non-conductive material Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 150000003109 potassium Chemical class 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- VEALVRVVWBQVSL-UHFFFAOYSA-N strontium titanate Chemical compound [Sr+2].[O-][Ti]([O-])=O VEALVRVVWBQVSL-UHFFFAOYSA-N 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 150000003609 titanium compounds Chemical class 0.000 description 1
- 229910000349 titanium oxysulfate Inorganic materials 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0289—Means for holding the electrolyte
- H01M8/0295—Matrices for immobilising electrolyte melts
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/14—Fuel cells with fused electrolytes
- H01M8/141—Fuel cells with fused electrolytes the anode and the cathode being gas-permeable electrodes or electrode layers
- H01M8/142—Fuel cells with fused electrolytes the anode and the cathode being gas-permeable electrodes or electrode layers with matrix-supported or semi-solid matrix-reinforced electrolyte
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/14—Fuel cells with fused electrolytes
- H01M2008/147—Fuel cells with molten carbonates
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0048—Molten electrolytes used at high temperature
- H01M2300/0051—Carbonates
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Fuel Cell (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14014/82 | 1982-01-29 | ||
| JP57014014A JPS58131662A (ja) | 1982-01-29 | 1982-01-29 | 燃料電池 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1187135A true CA1187135A (en) | 1985-05-14 |
Family
ID=11849334
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000420396A Expired CA1187135A (en) | 1982-01-29 | 1983-01-27 | Fuel cell |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US4480017A (en, 2012) |
| EP (1) | EP0090913B1 (en, 2012) |
| JP (1) | JPS58131662A (en, 2012) |
| CA (1) | CA1187135A (en, 2012) |
| DE (1) | DE3365500D1 (en, 2012) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS603870A (ja) * | 1983-06-21 | 1985-01-10 | Agency Of Ind Science & Technol | 溶融炭酸塩型燃料電池 |
| JPS6074268A (ja) * | 1983-09-30 | 1985-04-26 | Agency Of Ind Science & Technol | 燃料電池用電解質マトリツクス材の製造方法 |
| JPH01186561A (ja) * | 1988-01-14 | 1989-07-26 | Hitachi Ltd | 燃料電池 |
| US4895774A (en) * | 1988-02-17 | 1990-01-23 | Kabushiki Kaisha Toshiba | Molten carbonate fuel cell |
| US5316555A (en) * | 1992-11-03 | 1994-05-31 | Institute Of Gas Technology | Molten carbonate fuel cell electrolyte toughening |
| US5529856A (en) * | 1993-01-14 | 1996-06-25 | Electric Power Research Institute | Fuel cell having solidified plasma components |
| US5580673A (en) * | 1993-01-19 | 1996-12-03 | Energy Research Corporation | Carbonate fuel cell matrix |
| US6793711B1 (en) | 1999-12-07 | 2004-09-21 | Eltron Research, Inc. | Mixed conducting membrane for carbon dioxide separation and partial oxidation reactions |
| JP4073868B2 (ja) * | 2001-07-20 | 2008-04-09 | アルテアナノ インコーポレイテッド | チタン酸リチウムの製造方法 |
| EP1282180A1 (en) | 2001-07-31 | 2003-02-05 | Xoliox SA | Process for producing Li4Ti5O12 and electrode materials |
| JP2003201487A (ja) * | 2002-01-10 | 2003-07-18 | Toyota Motor Corp | 燃料電池用燃料ガス |
| DE10247997A1 (de) * | 2002-10-15 | 2004-05-06 | Mtu Cfc Solutions Gmbh | Elektrolytmatrix, insbesondere für eine Schmelzkarbonatbrennstoffzelle und Verfahren zur Herstellung einer solchen |
| USD567763S1 (en) | 2004-07-01 | 2008-04-29 | Matsushita Electric Industrial Co., Ltd. | Fuel cell |
| EP2156489A2 (en) | 2007-03-30 | 2010-02-24 | Altairnano, Inc | Method for preparing a lithium ion cell |
| US9627728B2 (en) | 2011-11-04 | 2017-04-18 | Siemens Aktiengesellschaft | Rechargeable anion battery cell using a molten salt electrolyte |
| US20130115528A1 (en) * | 2011-11-04 | 2013-05-09 | Chun Lu | Rechargeable anion battery cell using a molten salt electrolyte |
| EP3060605A1 (en) | 2013-10-21 | 2016-08-31 | Ticona GmbH | Intrinsic low friction polyoxymethylene |
| CN119931278A (zh) | 2017-03-10 | 2025-05-06 | 塞拉尼斯销售德国有限公司 | 聚酯聚合物组合物 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4216278A (en) * | 1979-02-23 | 1980-08-05 | General Electric Company | Process of making electrolyte structure for molten carbonate fuel cells |
| US4279971A (en) * | 1979-11-05 | 1981-07-21 | General Electric Company | Electrolyte structure with strontium titanate matrix for molten carbonate fuel cells |
| US4317865A (en) * | 1980-09-24 | 1982-03-02 | United Technologies Corporation | Ceria matrix material for molten carbonate fuel cell |
| US4411968A (en) * | 1981-09-30 | 1983-10-25 | United Technologies Corporation | Molten carbonate fuel cell integral matrix tape and bubble barrier |
-
1982
- 1982-01-29 JP JP57014014A patent/JPS58131662A/ja active Granted
-
1983
- 1983-01-25 DE DE8383100650T patent/DE3365500D1/de not_active Expired
- 1983-01-25 EP EP83100650A patent/EP0090913B1/en not_active Expired
- 1983-01-26 US US06/461,256 patent/US4480017A/en not_active Expired - Fee Related
- 1983-01-27 CA CA000420396A patent/CA1187135A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| EP0090913A1 (en) | 1983-10-12 |
| DE3365500D1 (en) | 1986-10-02 |
| JPS58131662A (ja) | 1983-08-05 |
| US4480017A (en) | 1984-10-30 |
| EP0090913B1 (en) | 1986-08-27 |
| JPH0258744B2 (en, 2012) | 1990-12-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA1187135A (en) | Fuel cell | |
| Zhu et al. | Innovative solid carbonate–ceria composite electrolyte fuel cells | |
| US5595832A (en) | Molten carbonate fuel cell | |
| US4436794A (en) | Molten carbonate fuel cell | |
| Antolini | The stability of LiAlO2 powders and electrolyte matrices in molten carbonate fuel cell environment | |
| KR100499651B1 (ko) | 고온연료전지용전기화학적활성소자 | |
| WO1992015122A1 (en) | Solid state fuel cell and process for the production thereof | |
| US4708917A (en) | Molten carbonate cathodes and method of fabricating | |
| CA2038408C (en) | Carbonate fuel cell anodes | |
| US6420062B1 (en) | Double layer cathode for molten carbonate fuel cells and method for producing the same | |
| US6379830B1 (en) | Solid electrolyte fuel cell having anode comprising metal oxide particles in a porous platinum layer | |
| KR19990082774A (ko) | 가스혼합물중의산소분리에사용되는세라믹물질 | |
| EP0090141A2 (en) | Fused carbonate fuel cell | |
| KR20230070461A (ko) | 페로브스카이트 구조, 제조 방법, 및 전극 및 고체 산화물 셀에서의 적용 | |
| CN1395332A (zh) | 一种LiCo O2型阴极材料及其制备方法 | |
| JPS58119161A (ja) | 溶融塩燃料電池用電極の製造法 | |
| JPS62176063A (ja) | 溶融炭酸塩型燃料電池の電解質タイルの製法 | |
| KR100236275B1 (ko) | 용융탄산염 연료전지용 공기극 제조방법 | |
| CN104157881B (zh) | 一种双钙钛矿型阳极材料及其制备方法 | |
| JPH0350387B2 (en, 2012) | ||
| JPS6216513B2 (en, 2012) | ||
| JPH0227786B2 (en, 2012) | ||
| JPH0548581B2 (en, 2012) | ||
| JPS6017865A (ja) | 溶融塩燃料電池 | |
| JPH01120774A (ja) | 溶融炭酸塩型燃料電池の電解質タイルの製法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEC | Expiry (correction) | ||
| MKEX | Expiry |