CA1158586A - Upgrading gasoline derived from synthesis gas - Google Patents
Upgrading gasoline derived from synthesis gasInfo
- Publication number
- CA1158586A CA1158586A CA000387722A CA387722A CA1158586A CA 1158586 A CA1158586 A CA 1158586A CA 000387722 A CA000387722 A CA 000387722A CA 387722 A CA387722 A CA 387722A CA 1158586 A CA1158586 A CA 1158586A
- Authority
- CA
- Canada
- Prior art keywords
- process according
- low grade
- feedstock
- gasoline
- synthesis gas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 230000015572 biosynthetic process Effects 0.000 title claims abstract description 22
- 238000003786 synthesis reaction Methods 0.000 title claims abstract description 22
- 238000000034 method Methods 0.000 claims abstract description 28
- 239000003054 catalyst Substances 0.000 claims abstract description 26
- 229910000323 aluminium silicate Inorganic materials 0.000 claims abstract description 19
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 19
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 15
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 15
- 229910052733 gallium Inorganic materials 0.000 claims abstract description 12
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims abstract description 8
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910052794 bromium Inorganic materials 0.000 claims abstract description 8
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 4
- 239000007789 gas Substances 0.000 claims description 21
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 18
- 239000000203 mixture Substances 0.000 claims description 14
- 150000001768 cations Chemical class 0.000 claims description 10
- 238000006243 chemical reaction Methods 0.000 claims description 10
- 239000000377 silicon dioxide Substances 0.000 claims description 9
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 8
- 150000002259 gallium compounds Chemical class 0.000 claims description 7
- -1 gallium ions Chemical class 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 5
- 239000006227 byproduct Substances 0.000 claims description 4
- 230000003197 catalytic effect Effects 0.000 claims description 4
- 238000004821 distillation Methods 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 3
- 239000003209 petroleum derivative Substances 0.000 claims description 3
- 229920006395 saturated elastomer Polymers 0.000 claims description 3
- 229930195735 unsaturated hydrocarbon Natural products 0.000 claims description 3
- 238000004523 catalytic cracking Methods 0.000 claims description 2
- 238000001833 catalytic reforming Methods 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
- 238000004230 steam cracking Methods 0.000 claims description 2
- 238000004227 thermal cracking Methods 0.000 claims description 2
- 229910052593 corundum Inorganic materials 0.000 claims 2
- 229910001845 yogo sapphire Inorganic materials 0.000 claims 2
- 238000004517 catalytic hydrocracking Methods 0.000 claims 1
- 239000003921 oil Substances 0.000 claims 1
- 239000003245 coal Substances 0.000 abstract description 11
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 abstract description 6
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 abstract description 3
- 239000000047 product Substances 0.000 description 12
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- CHPZKNULDCNCBW-UHFFFAOYSA-N gallium nitrate Chemical compound [Ga+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O CHPZKNULDCNCBW-UHFFFAOYSA-N 0.000 description 6
- 150000001336 alkenes Chemical class 0.000 description 5
- 239000010779 crude oil Substances 0.000 description 5
- 239000010457 zeolite Substances 0.000 description 5
- 230000004913 activation Effects 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 239000012263 liquid product Substances 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- RWRDLPDLKQPQOW-UHFFFAOYSA-N Pyrrolidine Chemical compound C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 description 3
- 229910021536 Zeolite Inorganic materials 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- 229940044658 gallium nitrate Drugs 0.000 description 3
- 238000005470 impregnation Methods 0.000 description 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical class [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- AJNVQOSZGJRYEI-UHFFFAOYSA-N digallium;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Ga+3].[Ga+3] AJNVQOSZGJRYEI-UHFFFAOYSA-N 0.000 description 2
- 229910001195 gallium oxide Inorganic materials 0.000 description 2
- 238000005342 ion exchange Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910021645 metal ion Inorganic materials 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 125000003367 polycyclic group Chemical group 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 241001323490 Colias gigantea Species 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 239000003570 air Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 235000013844 butane Nutrition 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000001030 gas--liquid chromatography Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 229910052610 inosilicate Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical class CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 125000001477 organic nitrogen group Chemical group 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 150000003138 primary alcohols Chemical class 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G35/00—Reforming naphtha
- C10G35/04—Catalytic reforming
- C10G35/06—Catalytic reforming characterised by the catalyst used
- C10G35/095—Catalytic reforming characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB8033510 | 1980-10-17 | ||
| GB8033510 | 1980-10-17 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1158586A true CA1158586A (en) | 1983-12-13 |
Family
ID=10516732
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000387722A Expired CA1158586A (en) | 1980-10-17 | 1981-10-09 | Upgrading gasoline derived from synthesis gas |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US4444652A (OSRAM) |
| EP (1) | EP0050499B1 (OSRAM) |
| JP (1) | JPS5796086A (OSRAM) |
| AU (1) | AU544220B2 (OSRAM) |
| CA (1) | CA1158586A (OSRAM) |
| DE (1) | DE3169580D1 (OSRAM) |
| DK (1) | DK458881A (OSRAM) |
| IN (1) | IN157106B (OSRAM) |
| NO (1) | NO163236C (OSRAM) |
| ZA (1) | ZA817004B (OSRAM) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0382960B1 (en) * | 1989-02-17 | 1993-01-13 | Council of Scientific and Industrial Research | An improved reforming process for the catalytic conversion of petroleum fractions to a mixture of hydrocarbons rich in aromatics |
| JP2007270063A (ja) * | 2006-03-31 | 2007-10-18 | Nippon Oil Corp | 軽質炭化水素組成物の処理方法、並びに、芳香族炭化水素組成物、芳香族炭化水素、ガソリン及びナフサ |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1507778A (en) * | 1976-06-11 | 1978-04-19 | British Petroleum Co | Aromatising unsaturated hydrocarbons |
| US4049741A (en) * | 1975-09-18 | 1977-09-20 | Mobil Oil Corporation | Method for upgrading Fischer-Tropsch synthesis products |
| NL177015C (nl) * | 1976-12-16 | 1985-07-16 | Shell Int Research | Verbeterde werkwijze voor de bereiding van een aromatisch koolwaterstofmengsel. |
| GB1561590A (en) * | 1976-12-20 | 1980-02-27 | British Petroleum Co | Zeolites containing gallium |
| US4210521A (en) * | 1977-05-04 | 1980-07-01 | Mobil Oil Corporation | Catalytic upgrading of refractory hydrocarbon stocks |
| NL7805494A (nl) * | 1978-05-22 | 1979-11-26 | Shell Int Research | Kwaliteitsverbetering van fischer-tropsch produkten. |
| US4211640A (en) * | 1979-05-24 | 1980-07-08 | Mobil Oil Corporation | Process for the treatment of olefinic gasoline |
| GB2051855B (en) * | 1979-06-18 | 1983-09-14 | Sasol One Ltd | Converting coal into liquid products |
| IN154515B (OSRAM) * | 1979-08-07 | 1984-11-03 | British Petroleum Co | |
| US4276151A (en) * | 1979-10-19 | 1981-06-30 | Mobil Oil Corporation | Novel reforming catalysts |
-
1981
- 1981-10-09 ZA ZA817004A patent/ZA817004B/xx unknown
- 1981-10-09 CA CA000387722A patent/CA1158586A/en not_active Expired
- 1981-10-12 IN IN656/DEL/81A patent/IN157106B/en unknown
- 1981-10-14 US US06/311,465 patent/US4444652A/en not_active Expired - Fee Related
- 1981-10-15 AU AU76353/81A patent/AU544220B2/en not_active Ceased
- 1981-10-15 NO NO813481A patent/NO163236C/no unknown
- 1981-10-16 DK DK458881A patent/DK458881A/da not_active Application Discontinuation
- 1981-10-16 DE DE8181304850T patent/DE3169580D1/de not_active Expired
- 1981-10-16 JP JP56165576A patent/JPS5796086A/ja active Granted
- 1981-10-16 EP EP81304850A patent/EP0050499B1/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| DE3169580D1 (en) | 1985-05-02 |
| AU544220B2 (en) | 1985-05-23 |
| AU7635381A (en) | 1982-04-22 |
| NO163236B (no) | 1990-01-15 |
| DK458881A (da) | 1982-04-18 |
| IN157106B (OSRAM) | 1986-01-18 |
| JPH0148958B2 (OSRAM) | 1989-10-23 |
| EP0050499B1 (en) | 1985-03-27 |
| NO813481L (no) | 1982-04-19 |
| ZA817004B (en) | 1983-05-25 |
| JPS5796086A (en) | 1982-06-15 |
| EP0050499A2 (en) | 1982-04-28 |
| EP0050499A3 (en) | 1982-08-04 |
| US4444652A (en) | 1984-04-24 |
| NO163236C (no) | 1990-04-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4334114A (en) | Production of aromatic hydrocarbons from a mixed feedstock of C5 -C12 olefins and C3 -C4 hydrocarbons | |
| CA1181437A (en) | Production of aromatics from ethane and/or ethylene | |
| JP3178515B2 (ja) | 硫黄、窒素およびオレフィンが低減された改良ガソリンの生成方法 | |
| CA1174219A (en) | Preparation of new crystalline aluminosilicate for catalytic conversion of methanol and/or dimethyl ether to hydrocarbons | |
| US3827968A (en) | Aromatization process | |
| DE3887990T2 (de) | Dehydrogenierungskatalysator und dessen verwendung. | |
| EP0259954B1 (en) | Process for converting c2 to c12 aliphatics to aromatics over a zinc activated zeolite | |
| US4002557A (en) | Catalytic conversion of high metals feed stocks | |
| CA2004584A1 (en) | Process for preparation of lower aliphatic hydrocarbons | |
| EP0186949A1 (en) | Production of aromatics from ethane and/or ethylene | |
| US3843740A (en) | Production of aromatics | |
| US4835336A (en) | Method for suppressing hydrogenolysis of noble metal/low acidity zeolites | |
| NZ211949A (en) | Process for conversion of monohalomethane to c 2+ hydrocarbons | |
| US4861932A (en) | Aromatization process | |
| EP0400987B1 (en) | Process for the production of high-octane gasoline blending stock | |
| JPS59227976A (ja) | メタノ−ルまたはジメチルエ−テルまたはそれら両者のオレフイン類への転化方法 | |
| EP0127207B1 (en) | Process for the preparation of middle distillates | |
| CA1274853A (en) | Production of aromatics from ethane and/or ethylene | |
| JPH0572954B2 (OSRAM) | ||
| US5114565A (en) | Reforming naphtha with boron-containing large-pore zeolites | |
| EP0040015B1 (en) | Process for making olefins | |
| EP0273091B1 (en) | Process for isomerizing xylene | |
| CA1122228A (en) | Selective reaction of 1,4-disubstituted benzene compounds | |
| CA2285209A1 (en) | Improved catalyst composition useful for conversion of non-aromatic hydrocarbons to aromatics and light olefins | |
| CA1158586A (en) | Upgrading gasoline derived from synthesis gas |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |