CA1131947A - Corrosion-protection layer for heat-resistant alloys - Google Patents
Corrosion-protection layer for heat-resistant alloysInfo
- Publication number
- CA1131947A CA1131947A CA287,309A CA287309A CA1131947A CA 1131947 A CA1131947 A CA 1131947A CA 287309 A CA287309 A CA 287309A CA 1131947 A CA1131947 A CA 1131947A
- Authority
- CA
- Canada
- Prior art keywords
- protective
- article
- corrosion
- elements
- alloy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 51
- 239000000956 alloy Substances 0.000 title claims abstract description 51
- 239000011241 protective layer Substances 0.000 claims abstract description 51
- 230000001681 protective effect Effects 0.000 claims abstract description 36
- 239000000126 substance Substances 0.000 claims abstract description 35
- 239000010410 layer Substances 0.000 claims abstract description 15
- 239000000463 material Substances 0.000 claims abstract description 10
- 150000001639 boron compounds Chemical class 0.000 claims abstract description 7
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052796 boron Inorganic materials 0.000 claims abstract description 6
- 150000001875 compounds Chemical class 0.000 claims abstract description 6
- 238000002485 combustion reaction Methods 0.000 claims abstract description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 34
- 239000000203 mixture Substances 0.000 claims description 27
- 238000000034 method Methods 0.000 claims description 23
- 229910052759 nickel Inorganic materials 0.000 claims description 18
- 238000007669 thermal treatment Methods 0.000 claims description 15
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 14
- 239000002245 particle Substances 0.000 claims description 11
- 229910052715 tantalum Inorganic materials 0.000 claims description 9
- 239000011651 chromium Substances 0.000 claims description 8
- 238000009792 diffusion process Methods 0.000 claims description 8
- 239000007789 gas Substances 0.000 claims description 8
- 229910052742 iron Inorganic materials 0.000 claims description 8
- 229910052804 chromium Inorganic materials 0.000 claims description 7
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 7
- 150000002910 rare earth metals Chemical class 0.000 claims description 7
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 claims description 6
- 239000008151 electrolyte solution Substances 0.000 claims description 6
- 239000007787 solid Substances 0.000 claims description 6
- 239000003792 electrolyte Substances 0.000 claims description 5
- 230000001590 oxidative effect Effects 0.000 claims description 5
- 239000006104 solid solution Substances 0.000 claims description 5
- 239000000243 solution Substances 0.000 claims description 5
- 229910000601 superalloy Inorganic materials 0.000 claims description 5
- 239000000725 suspension Substances 0.000 claims description 5
- 229910017052 cobalt Inorganic materials 0.000 claims description 4
- 239000010941 cobalt Substances 0.000 claims description 4
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 239000012300 argon atmosphere Substances 0.000 claims description 3
- GVPFVAHMJGGAJG-UHFFFAOYSA-L cobalt dichloride Chemical compound [Cl-].[Cl-].[Co+2] GVPFVAHMJGGAJG-UHFFFAOYSA-L 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- ZLXPLDLEBORRPT-UHFFFAOYSA-M [NH4+].[Fe+].[O-]S([O-])(=O)=O Chemical compound [NH4+].[Fe+].[O-]S([O-])(=O)=O ZLXPLDLEBORRPT-UHFFFAOYSA-M 0.000 claims description 2
- 239000007864 aqueous solution Substances 0.000 claims description 2
- 150000001868 cobalt Chemical class 0.000 claims description 2
- 239000006185 dispersion Substances 0.000 claims description 2
- 229910021332 silicide Inorganic materials 0.000 claims 5
- FVBUAEGBCNSCDD-UHFFFAOYSA-N silicide(4-) Chemical compound [Si-4] FVBUAEGBCNSCDD-UHFFFAOYSA-N 0.000 claims 5
- 229910021357 chromium silicide Inorganic materials 0.000 claims 3
- 229910021334 nickel silicide Inorganic materials 0.000 claims 3
- RUFLMLWJRZAWLJ-UHFFFAOYSA-N nickel silicide Chemical compound [Ni]=[Si]=[Ni] RUFLMLWJRZAWLJ-UHFFFAOYSA-N 0.000 claims 3
- 229910021586 Nickel(II) chloride Inorganic materials 0.000 claims 2
- 229910000831 Steel Inorganic materials 0.000 claims 2
- KTVIXTQDYHMGHF-UHFFFAOYSA-L cobalt(2+) sulfate Chemical compound [Co+2].[O-]S([O-])(=O)=O KTVIXTQDYHMGHF-UHFFFAOYSA-L 0.000 claims 2
- NFFIWVVINABMKP-UHFFFAOYSA-N methylidynetantalum Chemical compound [Ta]#C NFFIWVVINABMKP-UHFFFAOYSA-N 0.000 claims 2
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 claims 2
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 claims 2
- 239000010959 steel Substances 0.000 claims 2
- 229910003468 tantalcarbide Inorganic materials 0.000 claims 2
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims 2
- 238000005260 corrosion Methods 0.000 abstract description 8
- 230000007797 corrosion Effects 0.000 abstract description 8
- 239000011159 matrix material Substances 0.000 abstract description 7
- 230000001427 coherent effect Effects 0.000 abstract description 2
- 239000011162 core material Substances 0.000 description 11
- 230000002401 inhibitory effect Effects 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 238000005245 sintering Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 238000011282 treatment Methods 0.000 description 3
- 229910019878 Cr3Si Inorganic materials 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 238000000137 annealing Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 229910001026 inconel Inorganic materials 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- UOACKFBJUYNSLK-XRKIENNPSA-N Estradiol Cypionate Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H](C4=CC=C(O)C=C4CC3)CC[C@@]21C)C(=O)CCC1CCCC1 UOACKFBJUYNSLK-XRKIENNPSA-N 0.000 description 1
- 229910005347 FeSi Inorganic materials 0.000 description 1
- 229910001030 Iron–nickel alloy Inorganic materials 0.000 description 1
- 229910000990 Ni alloy Inorganic materials 0.000 description 1
- JQGGAELIYHNDQS-UHFFFAOYSA-N Nic 12 Natural products CC(C=CC(=O)C)c1ccc2C3C4OC4C5(O)CC=CC(=O)C5(C)C3CCc2c1 JQGGAELIYHNDQS-UHFFFAOYSA-N 0.000 description 1
- 206010037660 Pyrexia Diseases 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 230000001464 adherent effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000005255 carburizing Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 230000005294 ferromagnetic effect Effects 0.000 description 1
- 125000001475 halogen functional group Chemical group 0.000 description 1
- 230000005291 magnetic effect Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 238000001465 metallisation Methods 0.000 description 1
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 230000003313 weakening effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D15/00—Electrolytic or electrophoretic production of coatings containing embedded materials, e.g. particles, whiskers, wires
- C25D15/02—Combined electrolytic and electrophoretic processes with charged materials
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C30/00—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process
- C23C30/005—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process on hard metal substrates
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01D—NON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
- F01D5/00—Blades; Blade-carrying members; Heating, heat-insulating, cooling or antivibration means on the blades or the members
- F01D5/12—Blades
- F01D5/28—Selecting particular materials; Particular measures relating thereto; Measures against erosion or corrosion
- F01D5/288—Protective coatings for blades
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Mechanical Engineering (AREA)
- Organic Chemistry (AREA)
- General Engineering & Computer Science (AREA)
- Electrochemistry (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
- Turbine Rotor Nozzle Sealing (AREA)
- Powder Metallurgy (AREA)
- Electroplating And Plating Baths Therefor (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH1308276A CH599352A5 (enrdf_load_stackoverflow) | 1976-10-15 | 1976-10-15 | |
| CH13082/76 | 1976-10-15 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1131947A true CA1131947A (en) | 1982-09-21 |
Family
ID=4389133
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA287,309A Expired CA1131947A (en) | 1976-10-15 | 1977-09-22 | Corrosion-protection layer for heat-resistant alloys |
Country Status (6)
| Country | Link |
|---|---|
| JP (1) | JPS5386645A (enrdf_load_stackoverflow) |
| CA (1) | CA1131947A (enrdf_load_stackoverflow) |
| CH (1) | CH599352A5 (enrdf_load_stackoverflow) |
| DE (2) | DE7634200U1 (enrdf_load_stackoverflow) |
| FR (1) | FR2367833A1 (enrdf_load_stackoverflow) |
| SE (1) | SE7711357L (enrdf_load_stackoverflow) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5712050A (en) * | 1991-09-09 | 1998-01-27 | General Electric Company | Superalloy component with dispersion-containing protective coating |
| EP2700738A4 (en) * | 2011-04-19 | 2014-11-19 | Nihon Parkerizing | COATING FILM FOR METAL MATERIALS FROM A CORROSION-RESISTANT ALLOY AND METHOD FOR THE PRODUCTION THEREOF |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2083076B (en) * | 1980-07-02 | 1984-06-13 | Baj Vickers Ltd | Composite electrodeposited coating and a method of forming such a coating |
| CA1217433A (en) * | 1983-08-29 | 1987-02-03 | Westinghouse Electric Corporation | Combustion turbine blade with varying coating |
| BE903377A (fr) * | 1984-10-05 | 1986-04-04 | Baj Ltd | Revetements metalliques protecteurs |
| DE3716935A1 (de) * | 1987-05-20 | 1988-12-01 | Mtu Muenchen Gmbh | Verfahren zur herstellung von oxidations- und heissgaskorrosionsschutzschichten |
| US5316866A (en) * | 1991-09-09 | 1994-05-31 | General Electric Company | Strengthened protective coatings for superalloys |
| CA2076091A1 (en) * | 1991-09-09 | 1993-03-10 | Edward H. Goldman | Superalloy component with dispersion-containing protective coatings, and method of preparation |
| EP1674662A1 (de) * | 2004-12-23 | 2006-06-28 | Siemens Aktiengesellschaft | Elektrolyt für die Abscheidung einer Legierung und Verfahren zur elektrolytischen Abscheidung |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS495817A (enrdf_load_stackoverflow) * | 1972-05-08 | 1974-01-19 | ||
| JPS54862B2 (enrdf_load_stackoverflow) * | 1972-10-06 | 1979-01-17 | ||
| DE2348362B2 (de) * | 1973-09-26 | 1978-09-28 | Daimler-Benz Ag, 7000 Stuttgart | Verfahren zur Verbesserung der Eigenschaften von galvanisch abgeschiedenen dicken Dispersionsüberzügen |
| JPS5128531A (ja) * | 1974-09-04 | 1976-03-10 | Riken Piston Ring Ind Co Ltd | Taimamokinzokuzairyo |
-
1976
- 1976-10-15 CH CH1308276A patent/CH599352A5/xx not_active IP Right Cessation
- 1976-10-29 DE DE19767634200 patent/DE7634200U1/de not_active Expired
- 1976-10-29 DE DE19762649388 patent/DE2649388A1/de not_active Ceased
-
1977
- 1977-09-22 CA CA287,309A patent/CA1131947A/en not_active Expired
- 1977-10-10 SE SE7711357A patent/SE7711357L/ not_active Application Discontinuation
- 1977-10-12 FR FR7730671A patent/FR2367833A1/fr active Granted
- 1977-10-12 JP JP12160577A patent/JPS5386645A/ja active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5712050A (en) * | 1991-09-09 | 1998-01-27 | General Electric Company | Superalloy component with dispersion-containing protective coating |
| EP2700738A4 (en) * | 2011-04-19 | 2014-11-19 | Nihon Parkerizing | COATING FILM FOR METAL MATERIALS FROM A CORROSION-RESISTANT ALLOY AND METHOD FOR THE PRODUCTION THEREOF |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2367833A1 (fr) | 1978-05-12 |
| CH599352A5 (enrdf_load_stackoverflow) | 1978-05-31 |
| JPS5386645A (en) | 1978-07-31 |
| DE7634200U1 (de) | 1979-01-25 |
| SE7711357L (sv) | 1978-04-16 |
| DE2649388A1 (de) | 1978-04-20 |
| FR2367833B1 (enrdf_load_stackoverflow) | 1981-11-20 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |