CA1124223A - Catalytic composite particularly useful for the oxidation of mercaptans contained in a sour petroleum distillate - Google Patents

Catalytic composite particularly useful for the oxidation of mercaptans contained in a sour petroleum distillate

Info

Publication number
CA1124223A
CA1124223A CA330,581A CA330581A CA1124223A CA 1124223 A CA1124223 A CA 1124223A CA 330581 A CA330581 A CA 330581A CA 1124223 A CA1124223 A CA 1124223A
Authority
CA
Canada
Prior art keywords
catalytic composite
chloride
quaternary ammonium
hydroxide
oxidation catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA330,581A
Other languages
English (en)
French (fr)
Inventor
Robert R. Frame
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Honeywell UOP LLC
Original Assignee
UOP LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US05/927,317 external-priority patent/US4157312A/en
Priority claimed from US05/927,318 external-priority patent/US4206079A/en
Application filed by UOP LLC filed Critical UOP LLC
Application granted granted Critical
Publication of CA1124223A publication Critical patent/CA1124223A/en
Expired legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1825Ligands comprising condensed ring systems, e.g. acridine, carbazole
    • B01J31/183Ligands comprising condensed ring systems, e.g. acridine, carbazole with more than one complexing nitrogen atom, e.g. phenanthroline
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235Nitrogen containing compounds
    • B01J31/0239Quaternary ammonium compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1616Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G27/00Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
    • C10G27/04Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
    • C10G27/10Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen in the presence of metal-containing organic complexes, e.g. chelates, or cationic ion-exchange resins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B01J2531/0241Rigid ligands, e.g. extended sp2-carbon frameworks or geminal di- or trisubstitution
    • B01J2531/025Ligands with a porphyrin ring system or analogues thereof, e.g. phthalocyanines, corroles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/50Complexes comprising metals of Group V (VA or VB) as the central metal
    • B01J2531/56Vanadium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84Metals of the iron group
    • B01J2531/845Cobalt

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)
CA330,581A 1978-07-24 1979-06-26 Catalytic composite particularly useful for the oxidation of mercaptans contained in a sour petroleum distillate Expired CA1124223A (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US05/927,317 US4157312A (en) 1978-02-24 1978-07-24 Catalytic composite particularly useful for the oxidation of mercaptans contained in a sour petroleum distillate
US05/927,318 US4206079A (en) 1978-02-24 1978-07-24 Catalytic composite particularly useful for the oxidation of mercaptans contained in a sour petroleum distillate
US927,318 1986-11-04
US927,317 1986-11-04

Publications (1)

Publication Number Publication Date
CA1124223A true CA1124223A (en) 1982-05-25

Family

ID=27129942

Family Applications (1)

Application Number Title Priority Date Filing Date
CA330,581A Expired CA1124223A (en) 1978-07-24 1979-06-26 Catalytic composite particularly useful for the oxidation of mercaptans contained in a sour petroleum distillate

Country Status (20)

Country Link
AT (1) AT374818B (sr)
AU (1) AU530970B2 (sr)
BR (1) BR7904695A (sr)
CA (1) CA1124223A (sr)
DE (1) DE2927685C2 (sr)
DK (1) DK310279A (sr)
EG (1) EG14061A (sr)
ES (1) ES482760A2 (sr)
FR (1) FR2433974A2 (sr)
GB (1) GB2027359B (sr)
HU (1) HU179813B (sr)
IT (1) IT1122275B (sr)
MX (1) MX154990A (sr)
NL (1) NL7904951A (sr)
NO (1) NO160493C (sr)
PH (1) PH14933A (sr)
RO (1) RO77061A (sr)
SE (1) SE436696B (sr)
SU (1) SU1095873A3 (sr)
YU (1) YU40569B (sr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102012202622A1 (de) * 2012-02-21 2013-08-22 Wacker Chemie Ag Katalysator zur Carbonylierung carbonylierbarer Verbindungen in der Gasphase
MD4420C1 (ro) * 2012-06-26 2017-02-28 Оп "Matricon" Ооо Aplicarea componentelor grele întunecate ale petrolului în calitate de catalizator la purificarea oxidativă de hidrogen sulfurat şi mercaptani uşori a compoziţiilor de hidrocarburi şi procedeu de purificare a compoziţiilor de hidrocarburi

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2988500A (en) * 1959-03-13 1961-06-13 Universal Oil Prod Co Treatment of hydrocarbon distillates
US3164544A (en) * 1963-02-26 1965-01-05 Sun Oil Co Oxidative sweetening with base and quaternary ammonium compound
FR1602191A (sr) * 1968-12-31 1970-10-19
US4028269A (en) * 1975-08-21 1977-06-07 Uop Inc. Process for the preparation of a solid bed catalyst system
ZA7740B (en) * 1976-01-14 1977-11-30 Uop Inc Improved process for sweetening sour hydrocarbon distillates
US4070307A (en) * 1976-08-12 1978-01-24 Uop Inc. Method of catalyst manufacture
US4087378A (en) * 1977-01-18 1978-05-02 Uop Inc. Preparation of a supported metal phthalocyanine
US4124494A (en) * 1978-01-11 1978-11-07 Uop Inc. Treating a petroleum distillate with a supported metal phthalocyanine and an alkanolamine hydroxide
US4124493A (en) * 1978-02-24 1978-11-07 Uop Inc. Catalytic oxidation of mercaptan in petroleum distillate including alkaline reagent and substituted ammonium halide

Also Published As

Publication number Publication date
SE436696B (sv) 1985-01-21
HU179813B (en) 1982-12-28
MX154990A (es) 1988-01-18
YU179179A (en) 1983-02-28
GB2027359B (en) 1982-10-06
DK310279A (da) 1980-01-25
AU530970B2 (en) 1983-08-04
BR7904695A (pt) 1980-05-13
NL7904951A (nl) 1980-01-28
ES482760A2 (es) 1980-07-01
EG14061A (en) 1983-03-31
AU4820279A (en) 1980-01-31
PH14933A (en) 1982-01-29
NO160493C (no) 1989-04-26
FR2433974B2 (sr) 1984-08-24
YU40569B (en) 1986-02-28
SU1095873A3 (ru) 1984-05-30
IT1122275B (it) 1986-04-23
SE7906183L (sv) 1980-01-25
IT7924574A0 (it) 1979-07-23
ATA501079A (de) 1983-10-15
GB2027359A (en) 1980-02-20
NO792430L (no) 1980-01-25
DE2927685A1 (de) 1980-02-07
NO160493B (no) 1989-01-16
FR2433974A2 (fr) 1980-03-21
AT374818B (de) 1984-06-12
DE2927685C2 (de) 1987-03-26
RO77061A (ro) 1982-03-24

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Publication Publication Date Title
US4157312A (en) Catalytic composite particularly useful for the oxidation of mercaptans contained in a sour petroleum distillate
US4290913A (en) Catalytic composite useful for the treatment of mercaptan-containing sour petroleum distillate
US4908122A (en) Process for sweetening a sour hydrocarbon fraction
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EP0394571B1 (en) Use of a novel catalytic composite for sweetening of sour petroleum distillate
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US4308169A (en) Method of reactivating a catalytic composite of a carrier material and a mercaptan oxidation catalyst
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Legal Events

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