FR2433974A2 - Produit composite catalytique destine notamment a l'oxydation des mercaptans contenus dans un distillat de petrole corrosif - Google Patents

Produit composite catalytique destine notamment a l'oxydation des mercaptans contenus dans un distillat de petrole corrosif

Info

Publication number
FR2433974A2
FR2433974A2 FR7918690A FR7918690A FR2433974A2 FR 2433974 A2 FR2433974 A2 FR 2433974A2 FR 7918690 A FR7918690 A FR 7918690A FR 7918690 A FR7918690 A FR 7918690A FR 2433974 A2 FR2433974 A2 FR 2433974A2
Authority
FR
France
Prior art keywords
composite product
oxidation
catalytic composite
oil distillate
corrosive oil
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7918690A
Other languages
English (en)
Other versions
FR2433974B2 (fr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Honeywell UOP LLC
Original Assignee
UOP LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US05/927,318 external-priority patent/US4206079A/en
Priority claimed from US05/927,317 external-priority patent/US4157312A/en
Application filed by UOP LLC filed Critical UOP LLC
Publication of FR2433974A2 publication Critical patent/FR2433974A2/fr
Application granted granted Critical
Publication of FR2433974B2 publication Critical patent/FR2433974B2/fr
Granted legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1825—Ligands comprising condensed ring systems, e.g. acridine, carbazole
    • B01J31/183—Ligands comprising condensed ring systems, e.g. acridine, carbazole with more than one complexing nitrogen atom, e.g. phenanthroline
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0239—Quaternary ammonium compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1616—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
    • C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
    • C10G27/10—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen in the presence of metal-containing organic complexes, e.g. chelates, or cationic ion-exchange resins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B01J2531/0241—Rigid ligands, e.g. extended sp2-carbon frameworks or geminal di- or trisubstitution
    • B01J2531/025—Ligands with a porphyrin ring system or analogues thereof, e.g. phthalocyanines, corroles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/50—Complexes comprising metals of Group V (VA or VB) as the central metal
    • B01J2531/56—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)

Abstract

L'invention a pour objet un produit composite catalytique comprenant un catalyseur d'oxydation des mercaptans à base de chélate métallique et un composé d'ammonium quaternaire appliqués par imprégnation sur un support adsorbant solide, le composé d'ammonium quaternaire répondant à la formule générale :
FR7918690A 1978-07-24 1979-07-19 Produit composite catalytique destine notamment a l'oxydation des mercaptans contenus dans un distillat de petrole corrosif Granted FR2433974A2 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US05/927,318 US4206079A (en) 1978-02-24 1978-07-24 Catalytic composite particularly useful for the oxidation of mercaptans contained in a sour petroleum distillate
US05/927,317 US4157312A (en) 1978-02-24 1978-07-24 Catalytic composite particularly useful for the oxidation of mercaptans contained in a sour petroleum distillate

Publications (2)

Publication Number Publication Date
FR2433974A2 true FR2433974A2 (fr) 1980-03-21
FR2433974B2 FR2433974B2 (fr) 1984-08-24

Family

ID=27129942

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7918690A Granted FR2433974A2 (fr) 1978-07-24 1979-07-19 Produit composite catalytique destine notamment a l'oxydation des mercaptans contenus dans un distillat de petrole corrosif

Country Status (20)

Country Link
AT (1) AT374818B (fr)
AU (1) AU530970B2 (fr)
BR (1) BR7904695A (fr)
CA (1) CA1124223A (fr)
DE (1) DE2927685A1 (fr)
DK (1) DK310279A (fr)
EG (1) EG14061A (fr)
ES (1) ES482760A2 (fr)
FR (1) FR2433974A2 (fr)
GB (1) GB2027359B (fr)
HU (1) HU179813B (fr)
IT (1) IT1122275B (fr)
MX (1) MX154990A (fr)
NL (1) NL7904951A (fr)
NO (1) NO160493C (fr)
PH (1) PH14933A (fr)
RO (1) RO77061A (fr)
SE (1) SE436696B (fr)
SU (1) SU1095873A3 (fr)
YU (1) YU40569B (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102012202622A1 (de) * 2012-02-21 2013-08-22 Wacker Chemie Ag Katalysator zur Carbonylierung carbonylierbarer Verbindungen in der Gasphase
MD4420C1 (ro) * 2012-06-26 2017-02-28 Оп "Matricon" Ооо Aplicarea componentelor grele întunecate ale petrolului în calitate de catalizator la purificarea oxidativă de hidrogen sulfurat şi mercaptani uşori a compoziţiilor de hidrocarburi şi procedeu de purificare a compoziţiilor de hidrocarburi

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3164544A (en) * 1963-02-26 1965-01-05 Sun Oil Co Oxidative sweetening with base and quaternary ammonium compound
FR1602191A (fr) * 1968-12-31 1970-10-19
FR2338322A1 (fr) * 1976-01-14 1977-08-12 Uop Inc Procede perfectionne d'adoucissement de distillats hydrocarbones corrosifs
US4087378A (en) * 1977-01-18 1978-05-02 Uop Inc. Preparation of a supported metal phthalocyanine
US4098681A (en) * 1976-08-12 1978-07-04 Uop Inc. Oxidation of mercaptans in a petroleum distillate with a supported metal phthalocyanine catalyst
US4124494A (en) * 1978-01-11 1978-11-07 Uop Inc. Treating a petroleum distillate with a supported metal phthalocyanine and an alkanolamine hydroxide
US4124493A (en) * 1978-02-24 1978-11-07 Uop Inc. Catalytic oxidation of mercaptan in petroleum distillate including alkaline reagent and substituted ammonium halide

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2988500A (en) * 1959-03-13 1961-06-13 Universal Oil Prod Co Treatment of hydrocarbon distillates
US4028269A (en) * 1975-08-21 1977-06-07 Uop Inc. Process for the preparation of a solid bed catalyst system

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3164544A (en) * 1963-02-26 1965-01-05 Sun Oil Co Oxidative sweetening with base and quaternary ammonium compound
FR1602191A (fr) * 1968-12-31 1970-10-19
FR2338322A1 (fr) * 1976-01-14 1977-08-12 Uop Inc Procede perfectionne d'adoucissement de distillats hydrocarbones corrosifs
US4098681A (en) * 1976-08-12 1978-07-04 Uop Inc. Oxidation of mercaptans in a petroleum distillate with a supported metal phthalocyanine catalyst
US4087378A (en) * 1977-01-18 1978-05-02 Uop Inc. Preparation of a supported metal phthalocyanine
US4124494A (en) * 1978-01-11 1978-11-07 Uop Inc. Treating a petroleum distillate with a supported metal phthalocyanine and an alkanolamine hydroxide
FR2414537A1 (fr) * 1978-01-11 1979-08-10 Uop Inc Perfectionnements aux procedes de traitement de distillats corrosifs
US4124493A (en) * 1978-02-24 1978-11-07 Uop Inc. Catalytic oxidation of mercaptan in petroleum distillate including alkaline reagent and substituted ammonium halide
FR2418270A1 (fr) * 1978-02-24 1979-09-21 Uop Inc Procede de traitement de distillats corrosifs de petrole

Also Published As

Publication number Publication date
CA1124223A (fr) 1982-05-25
MX154990A (es) 1988-01-18
DE2927685C2 (fr) 1987-03-26
PH14933A (en) 1982-01-29
HU179813B (en) 1982-12-28
AT374818B (de) 1984-06-12
YU179179A (en) 1983-02-28
SE7906183L (sv) 1980-01-25
NO160493B (no) 1989-01-16
ES482760A2 (es) 1980-07-01
NL7904951A (nl) 1980-01-28
NO160493C (no) 1989-04-26
YU40569B (en) 1986-02-28
IT7924574A0 (it) 1979-07-23
AU530970B2 (en) 1983-08-04
EG14061A (en) 1983-03-31
DE2927685A1 (de) 1980-02-07
FR2433974B2 (fr) 1984-08-24
IT1122275B (it) 1986-04-23
AU4820279A (en) 1980-01-31
GB2027359B (en) 1982-10-06
SU1095873A3 (ru) 1984-05-30
GB2027359A (en) 1980-02-20
ATA501079A (de) 1983-10-15
BR7904695A (pt) 1980-05-13
NO792430L (no) 1980-01-25
RO77061A (fr) 1982-03-24
DK310279A (da) 1980-01-25
SE436696B (sv) 1985-01-21

Similar Documents

Publication Publication Date Title
ATE17566T1 (de) Verfahren und katalytische zusammensetzung zur herstellung von aldehyden, und so erhaltene aldehyde.
FR2359190A1 (fr) Procede de fabrication de liants pour vernissage par electrophorese
FR2289481A1 (fr) Composition catalytique pour l'oxydation en phase vapeur d'aldehydes non satures
ATE38992T1 (de) Herstellung von uebergangsmetallkomplexen.
IE792013L (en) 1,2,4-triazol-1-yl compound
FR2433974A2 (fr) Produit composite catalytique destine notamment a l'oxydation des mercaptans contenus dans un distillat de petrole corrosif
IT1131399B (it) Additivo per oli lubrificanti per il controllo della ossidazione e corrosione,formato dalla reazione di alchilfenolo,zolfo,metallo alcalino-terroso e olefina
FR2438030A1 (fr) Nouveaux derives de choline, destines notamment a la determination de l'activite cholinesterasique
FR2429229A1 (fr) Procede pour preparer des polyolefines
MX156110A (es) Mejoras a convertidor para la refinacion de metales liquidos
FR2359131A1 (fr) Agents cardiovasculaires a base de thiazoles
EP0038047A3 (fr) Catalyseur de craquage, procédé de passivation et composés de germanium
ATE171091T1 (de) Compound-dip-verfahren für metalldosen
AU5996890A (en) Improved catalyst and process for sweetening a sour hydrocarbon stream
BE850181A (fr) Procede d'oxydation catalytique d'hydrocarbures halogenes comportant de 2 a 4 atomes de carbone
ATE17228T1 (de) Verfahren zur oxydation von vinylbenzenverbindungen zu beta-phenylaldehyden.
DE69004041D1 (de) Verfahren für die Behandlung von neuem oder gebrauchtem Graphitpulver zur Verbesserung seiner Effektivität als Träger für katalytische Metalle.
FI812264L (fi) Foerfarande foer kontinuerlig direkt smaeltning av metalliskt bly ur sulfidiskt blykoncentrat
NO982240D0 (no) FremgangsmÕte ved oksidering av organiske substrater i nµrvµr av metallkomplekser av tetra-, penta-, og heksakooridinerte ligander, samt oksidasjonskatalysatorer inneholdende disse
LU79649A1 (fr) Compositions pour l'agriculture,a base d'acide aminomethylenephosphonique,renfermant un compose de thiol inhibant la corrosion de surfaces metalliques
PT82590B (pt) Processo de preparacao de 4-oxido-2-carboxipirazinas
FR2435483A1 (fr) Catalyseur pour la preparation du polyethylene
DK172289D0 (da) Fremgangsmaade til fremstilling af 3-amino-2,2,4,4-tetramethylthietan ved leuckardt-reaktionen
JPS5547649A (en) Production polysulfide
KR910007574A (ko) 방향족 니트로화합물의 환원반응용 합금촉매