CA1122914A - Process for upgrading heavy hydrocarbonaceous oils - Google Patents
Process for upgrading heavy hydrocarbonaceous oilsInfo
- Publication number
- CA1122914A CA1122914A CA347,549A CA347549A CA1122914A CA 1122914 A CA1122914 A CA 1122914A CA 347549 A CA347549 A CA 347549A CA 1122914 A CA1122914 A CA 1122914A
- Authority
- CA
- Canada
- Prior art keywords
- stream
- hydrogen donor
- residuum
- liquid
- temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003921 oil Substances 0.000 title claims abstract description 54
- 238000000034 method Methods 0.000 title claims abstract description 45
- 230000008569 process Effects 0.000 title claims abstract description 44
- 239000000852 hydrogen donor Substances 0.000 claims abstract description 90
- 239000000463 material Substances 0.000 claims abstract description 76
- 238000009835 boiling Methods 0.000 claims abstract description 69
- 239000007788 liquid Substances 0.000 claims abstract description 38
- 238000004517 catalytic hydrocracking Methods 0.000 claims abstract description 10
- 238000004064 recycling Methods 0.000 claims abstract description 10
- 230000005484 gravity Effects 0.000 claims abstract description 6
- 239000001257 hydrogen Substances 0.000 claims description 36
- 229910052739 hydrogen Inorganic materials 0.000 claims description 36
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 35
- 238000005336 cracking Methods 0.000 claims description 26
- 150000002431 hydrogen Chemical class 0.000 claims description 22
- 239000002243 precursor Substances 0.000 claims description 19
- 239000010779 crude oil Substances 0.000 claims description 13
- 239000010426 asphalt Substances 0.000 claims description 11
- 238000000629 steam reforming Methods 0.000 claims description 8
- 238000006243 chemical reaction Methods 0.000 claims description 7
- 239000007789 gas Substances 0.000 description 28
- 238000005984 hydrogenation reaction Methods 0.000 description 13
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
- 239000000047 product Substances 0.000 description 12
- 229930195733 hydrocarbon Natural products 0.000 description 10
- 150000002430 hydrocarbons Chemical class 0.000 description 10
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 9
- 229910052799 carbon Inorganic materials 0.000 description 7
- 239000003054 catalyst Substances 0.000 description 7
- 238000004508 fractional distillation Methods 0.000 description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- 239000004215 Carbon black (E152) Substances 0.000 description 6
- 238000009903 catalytic hydrogenation reaction Methods 0.000 description 6
- 239000000571 coke Substances 0.000 description 6
- 238000004821 distillation Methods 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- 238000004227 thermal cracking Methods 0.000 description 6
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 239000000386 donor Substances 0.000 description 4
- 239000000295 fuel oil Substances 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 239000012263 liquid product Substances 0.000 description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 239000005864 Sulphur Substances 0.000 description 3
- 238000004939 coking Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000005194 fractionation Methods 0.000 description 3
- 150000002790 naphthalenes Chemical class 0.000 description 3
- 238000005292 vacuum distillation Methods 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 239000002737 fuel gas Substances 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000004949 mass spectrometry Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 239000003345 natural gas Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 238000002407 reforming Methods 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- -1 Lloydminster) Substances 0.000 description 1
- 239000008186 active pharmaceutical agent Substances 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000004231 fluid catalytic cracking Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000005504 petroleum refining Methods 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 239000011819 refractory material Substances 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000003079 shale oil Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000011269 tar Substances 0.000 description 1
- 239000011275 tar sand Substances 0.000 description 1
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical class C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
- C10G47/32—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions in the presence of hydrogen-generating compounds
- C10G47/34—Organic compounds, e.g. hydrogenated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/06—Gasoil
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Priority Applications (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA347,549A CA1122914A (en) | 1980-03-04 | 1980-03-04 | Process for upgrading heavy hydrocarbonaceous oils |
| JP2852881A JPS56136893A (en) | 1980-03-04 | 1981-03-02 | Improvement of heavy hydrocarbon oil |
| DE8181300887T DE3171175D1 (en) | 1980-03-04 | 1981-03-03 | Process for upgrading heavy hydrocarbonaceous oils |
| EP19810300887 EP0035864B1 (en) | 1980-03-04 | 1981-03-03 | Process for upgrading heavy hydrocarbonaceous oils |
| MX18620681A MX158978A (es) | 1980-03-04 | 1981-03-03 | Procedimiento para mejorar la calidad de hidrocarburos pesados |
| NL8101051A NL8101051A (nl) | 1980-03-04 | 1981-03-04 | Werkwijze voor het verbeteren van de kwaliteit van zware koolwaterstoffen. |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA347,549A CA1122914A (en) | 1980-03-04 | 1980-03-04 | Process for upgrading heavy hydrocarbonaceous oils |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1122914A true CA1122914A (en) | 1982-05-04 |
Family
ID=4116462
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA347,549A Expired CA1122914A (en) | 1980-03-04 | 1980-03-04 | Process for upgrading heavy hydrocarbonaceous oils |
Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP0035864B1 (enrdf_load_html_response) |
| JP (1) | JPS56136893A (enrdf_load_html_response) |
| CA (1) | CA1122914A (enrdf_load_html_response) |
| DE (1) | DE3171175D1 (enrdf_load_html_response) |
| MX (1) | MX158978A (enrdf_load_html_response) |
| NL (1) | NL8101051A (enrdf_load_html_response) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20160145505A1 (en) * | 2014-11-24 | 2016-05-26 | Husky Oil Operations Limited | Partial upgrading system and method for heavy hydrocarbons |
| US10077334B2 (en) | 2015-08-06 | 2018-09-18 | Instituto Mexicano Del Petróleo | Use of polymers as heterogeneous hydrogen donors in the upgrading of heavy and extra-heavy crudes |
| US10793784B2 (en) | 2017-07-10 | 2020-10-06 | Instituto Mexicano Del Petroleo | Procedure for preparation of improved solid hydrogen transfer agents for processing heavy and extra-heavy crude oils and residues, and resulting product |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4363716A (en) * | 1981-02-26 | 1982-12-14 | Greene Marvin I | Cracking of heavy carbonaceous liquid feedstocks utilizing hydrogen donor solvent |
| US4395324A (en) * | 1981-11-02 | 1983-07-26 | Mobil Oil Corporation | Thermal cracking with hydrogen donor diluent |
| ZA845721B (en) * | 1983-08-01 | 1986-03-26 | Mobil Oil Corp | Process for visbreaking resids in the presence of hydrogen-donor materials |
| CA1246481A (en) * | 1984-03-20 | 1988-12-13 | Frank Souhrada | Coking residuum in the presence of hydrogen donor |
| CA1222471A (en) * | 1985-06-28 | 1987-06-02 | H. John Woods | Process for improving the yield of distillables in hydrogen donor diluent cracking |
| JPH03294390A (ja) * | 1990-04-12 | 1991-12-25 | Idemitsu Kosan Co Ltd | 原油の精製方法 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB708244A (en) * | 1950-04-04 | 1954-05-05 | Anglo Iranian Oil Co Ltd | Improvements relating to the catalytic desulphurisation of petroleum hydrocarbons |
| BE529891A (enrdf_load_html_response) * | 1953-07-01 | |||
| GB758413A (en) * | 1953-11-18 | 1956-10-03 | Exxon Research Engineering Co | Improvements in or relating to process for cracking gas oils to gasoline |
| US2953513A (en) * | 1956-03-05 | 1960-09-20 | Exxon Research Engineering Co | Hydrogen donor diluent cracking process |
| US4115246A (en) * | 1977-01-31 | 1978-09-19 | Continental Oil Company | Oil conversion process |
-
1980
- 1980-03-04 CA CA347,549A patent/CA1122914A/en not_active Expired
-
1981
- 1981-03-02 JP JP2852881A patent/JPS56136893A/ja active Granted
- 1981-03-03 EP EP19810300887 patent/EP0035864B1/en not_active Expired
- 1981-03-03 DE DE8181300887T patent/DE3171175D1/de not_active Expired
- 1981-03-03 MX MX18620681A patent/MX158978A/es unknown
- 1981-03-04 NL NL8101051A patent/NL8101051A/nl not_active Application Discontinuation
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20160145505A1 (en) * | 2014-11-24 | 2016-05-26 | Husky Oil Operations Limited | Partial upgrading system and method for heavy hydrocarbons |
| US10081769B2 (en) * | 2014-11-24 | 2018-09-25 | Husky Oil Operations Limited | Partial upgrading system and method for heavy hydrocarbons |
| US10077334B2 (en) | 2015-08-06 | 2018-09-18 | Instituto Mexicano Del Petróleo | Use of polymers as heterogeneous hydrogen donors in the upgrading of heavy and extra-heavy crudes |
| US10793784B2 (en) | 2017-07-10 | 2020-10-06 | Instituto Mexicano Del Petroleo | Procedure for preparation of improved solid hydrogen transfer agents for processing heavy and extra-heavy crude oils and residues, and resulting product |
Also Published As
| Publication number | Publication date |
|---|---|
| DE3171175D1 (en) | 1985-08-08 |
| JPS56136893A (en) | 1981-10-26 |
| EP0035864B1 (en) | 1985-07-03 |
| MX158978A (es) | 1989-04-05 |
| EP0035864A3 (en) | 1981-10-07 |
| EP0035864A2 (en) | 1981-09-16 |
| NL8101051A (nl) | 1981-10-01 |
| JPH0258316B2 (enrdf_load_html_response) | 1990-12-07 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |