CA1117512A - Zeolite synthesis - Google Patents

Zeolite synthesis

Info

Publication number
CA1117512A
CA1117512A CA000301357A CA301357A CA1117512A CA 1117512 A CA1117512 A CA 1117512A CA 000301357 A CA000301357 A CA 000301357A CA 301357 A CA301357 A CA 301357A CA 1117512 A CA1117512 A CA 1117512A
Authority
CA
Canada
Prior art keywords
sio2
reaction mixture
zsm
zeolite
alkali metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA000301357A
Other languages
English (en)
French (fr)
Inventor
Louis D. Rollmann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Oil Corp
Original Assignee
Mobil Oil Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mobil Oil Corp filed Critical Mobil Oil Corp
Application granted granted Critical
Publication of CA1117512A publication Critical patent/CA1117512A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/76—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/36—Steaming
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CA000301357A 1977-04-22 1978-04-18 Zeolite synthesis Expired CA1117512A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US78990177A 1977-04-22 1977-04-22
US789,901 1991-11-12

Publications (1)

Publication Number Publication Date
CA1117512A true CA1117512A (en) 1982-02-02

Family

ID=25149040

Family Applications (1)

Application Number Title Priority Date Filing Date
CA000301357A Expired CA1117512A (en) 1977-04-22 1978-04-18 Zeolite synthesis

Country Status (11)

Country Link
JP (1) JPS53134798A (xx)
AU (1) AU515185B2 (xx)
BE (1) BE866272A (xx)
CA (1) CA1117512A (xx)
DE (1) DE2817577A1 (xx)
FR (1) FR2442795A1 (xx)
GB (1) GB1588613A (xx)
IT (1) IT1095609B (xx)
NL (1) NL188568C (xx)
NZ (1) NZ186957A (xx)
ZA (1) ZA782292B (xx)

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0002899B1 (en) 1977-12-23 1983-03-16 The British Petroleum Company p.l.c. Method for preparing aluminosilicates and their use as catalyst supports and catalysts
EP0002900B1 (en) * 1977-12-23 1982-11-24 The British Petroleum Company p.l.c. Method for producing aluminosilicates and their use as catalysts and supports
NL7812162A (nl) * 1978-12-14 1980-06-17 Shell Int Research Werkwijze voor de bereiding van ferrieriet.
US4205053A (en) * 1979-02-01 1980-05-27 Mobil Oil Corporation Manufacture of nitrogenous zeolites
ZA80767B (en) * 1979-02-21 1981-09-30 Mobil Oil Corp Crystalline zeolitic synthesis and use thereof
NZ193928A (en) * 1979-06-11 1982-09-07 Mobil Oil Corp Preparation of large crystal zeolite zsm-5
DE3068017D1 (en) * 1979-07-12 1984-07-05 Mobil Oil Corp Method of preparing zeolite zsm-48, the zeolite so prepared and its use as catalyst for organic compound conversion
ZA803365B (en) * 1979-10-09 1981-05-27 Mobil Oil Corp Synthesis of large crystal zeolite zsm-5
NZ193929A (en) * 1979-10-09 1982-09-07 Mobil Oil Corp Preparation of large crystal zeolite zsm-5
CA1144137A (en) * 1979-12-26 1983-04-05 Donald A. Hickson Method for preparing crystalline zeolites
AU540104B2 (en) * 1980-01-10 1984-11-01 Mobil Oil Corp. Calytic reforming
DE3006471A1 (de) * 1980-02-21 1981-08-27 Basf Ag, 6700 Ludwigshafen Kristalline isotaktische zeolithe, verfahren zur herstellung derselben sowie deren verwendung als katalysatoren
CA1167071A (en) * 1980-03-15 1984-05-08 William J. Ball Process for the production of aromatic hydrocarbons
CA1157450A (en) * 1980-03-18 1983-11-22 Martin F.M. Post Process for the preparation of crystalline aluminium silicates, crystalline aluminium silicates so prepared and process for the production of an aromatic hydrocarbon mixture
CA1153867A (en) * 1980-05-16 1983-09-20 Michael A. M. Boersma Process for the preparation of crystalline silicates, crystalline silicates so prepared and process for carrying out catalytic reactions
US4309313A (en) * 1980-05-23 1982-01-05 W. R. Grace & Co. Synthesis of cesium-containing zeolite, CSZ-1
JPS577820A (en) * 1980-06-18 1982-01-16 Mitsubishi Heavy Ind Ltd Novel crystalline silicate and its manufacture
DE3139355A1 (de) * 1980-10-02 1982-06-09 Inui, Tomoyuki, Joyo Kristalliner aluminosilikatzeolit-katalysator und verfahren zur herstellung desselben
JPS57191222A (en) * 1981-05-13 1982-11-25 Mobil Oil Corp Crystalline zeolite substance, manufacture and conversion of organic raw material using same
JPS5891032A (ja) * 1981-11-26 1983-05-30 Toray Ind Inc ペンタシル型ゼオライトの製造法
NL8202992A (nl) * 1982-07-26 1984-02-16 Shell Int Research Werkwijze voor het ontparaffineren van koolwaterstofolien.
JPS5973427A (ja) * 1982-10-16 1984-04-25 Res Assoc Petroleum Alternat Dev<Rapad> 新規なゼオライト及びその製造方法
CA1281746C (en) * 1986-06-27 1991-03-19 Rene Bernard Lapierre Direct catalytic alkylation of mononuclear aromatics with lower alkanes
IL79906A (en) * 1986-09-01 1990-08-31 Yeda Res & Dev Crystalline aluminosilicate zeolite catalyst for the selective isomerization of xylene
JPH0360929U (xx) * 1989-10-18 1991-06-14
CZ299372B6 (cs) * 2005-09-23 2008-07-09 Výzkumný ústav anorganické chemie, a. s. Zpusob výroby zeolitu ZSM-5 s rízenou velikostí krystalu
CN104245584A (zh) * 2012-03-26 2014-12-24 东曹株式会社 具有均匀的中孔的mfi型沸石和用于制造其的方法
CZ306852B6 (cs) * 2016-03-15 2017-08-09 Unipetrol výzkumně vzdělávací centrum, a.s. Způsob výroby zeolitu ZSM-5 s vysokým podílem párů atomů hliníku

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3702886A (en) * 1969-10-10 1972-11-14 Mobil Oil Corp Crystalline zeolite zsm-5 and method of preparing the same
US3709979A (en) * 1970-04-23 1973-01-09 Mobil Oil Corp Crystalline zeolite zsm-11
US3832449A (en) * 1971-03-18 1974-08-27 Mobil Oil Corp Crystalline zeolite zsm{14 12
CA933911A (en) * 1971-03-18 1973-09-18 Mobil Oil Corporation Method of preparation for crystalline aluminosilicate zeolites
US4016245A (en) * 1973-09-04 1977-04-05 Mobil Oil Corporation Crystalline zeolite and method of preparing same
CA1064890A (en) * 1975-06-10 1979-10-23 Mae K. Rubin Crystalline zeolite, synthesis and use thereof

Also Published As

Publication number Publication date
FR2442795B1 (xx) 1985-03-01
IT1095609B (it) 1985-08-10
NL7804289A (nl) 1978-10-24
AU3523778A (en) 1979-10-25
GB1588613A (en) 1981-04-29
ZA782292B (en) 1979-12-27
JPS53134798A (en) 1978-11-24
BE866272A (fr) 1978-10-23
NZ186957A (en) 1979-10-25
JPS624326B2 (xx) 1987-01-29
IT7822609A0 (it) 1978-04-21
DE2817577A1 (de) 1978-10-26
AU515185B2 (en) 1981-03-19
NL188568C (nl) 1992-08-03
NL188568B (nl) 1992-03-02
FR2442795A1 (fr) 1980-06-27
DE2817577C2 (xx) 1988-08-04

Similar Documents

Publication Publication Date Title
CA1117512A (en) Zeolite synthesis
EP0018090B1 (en) Crystalline zeolite product constituting zsm-5/zsm-11 intermediates and its use for organic compound conversion
US4112056A (en) Preparation of zeolites
CA1119146A (en) Synthesis of zeolite zsm-11
US4296083A (en) Zeolite synthesis
US4100262A (en) Synthesis of zeolite ZSM-5
CA1064890A (en) Crystalline zeolite, synthesis and use thereof
EP0106478B1 (en) Crystalline gallosilicates, a process for producing them and their use as catalysts
CA1097309A (en) Crystalline zeolite zsm-34 and method of preparing the same
CA1170641A (en) Theta-1, a new crystalline silicate
US4104151A (en) Organic compound conversion over ZSM-23
US4021331A (en) Organic compound conversion by zeolite ZSM-20 catalysts
US4533649A (en) Method of preparing crystalline aluminosilicates
US4526879A (en) Synthesis of zeolite ZSM-5
US4300013A (en) Isomerization of xylenes
US4289607A (en) Catalytic conversion with crystalline zeolite product constituting ZSM-5/ZSM-11 intermediates
US5068096A (en) Synthesis of crystalline silicate MCM-47
EP0026963A1 (en) Method of producing large crystal zeolite ZSM-5 with controlled crystal size, and zeolite produced by this method
US4968650A (en) ZSM-5 catalysts having predominantly framework gallium, methods of their preparation, and use thereof
EP0011362B1 (en) Method for synthesis of zeolite zsm-5
US4323481A (en) Synthesis of molecular sieves using beta-diketones as organic templates
EP0021674A1 (en) Synthesis of large crystal zeolite ZSM-5 and zeolite so made
CA1214447A (en) Zeolite synthesis
NZ202185A (en) Zircono-and/or hafno-aluminosilicates having a pentasil structure,their preparation and use as olefin producing catalysts
US4105541A (en) Hydrocarbon conversion over zsm-38

Legal Events

Date Code Title Description
MKEX Expiry