CA1116770A - Antifouling and antisliming coating material - Google Patents
Antifouling and antisliming coating materialInfo
- Publication number
- CA1116770A CA1116770A CA000323399A CA323399A CA1116770A CA 1116770 A CA1116770 A CA 1116770A CA 000323399 A CA000323399 A CA 000323399A CA 323399 A CA323399 A CA 323399A CA 1116770 A CA1116770 A CA 1116770A
- Authority
- CA
- Canada
- Prior art keywords
- coating material
- set forth
- copper
- resin
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000576 coating method Methods 0.000 title claims abstract description 77
- 239000011248 coating agent Substances 0.000 title claims abstract description 76
- 239000000463 material Substances 0.000 title claims abstract description 69
- 230000003373 anti-fouling effect Effects 0.000 title claims abstract description 34
- 239000010949 copper Substances 0.000 claims abstract description 69
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 68
- 229910052802 copper Inorganic materials 0.000 claims abstract description 68
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 33
- 239000003822 epoxy resin Substances 0.000 claims abstract description 28
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 28
- 229920005862 polyol Polymers 0.000 claims abstract description 28
- 150000003077 polyols Chemical class 0.000 claims abstract description 28
- 150000003839 salts Chemical class 0.000 claims abstract description 5
- 229920005989 resin Polymers 0.000 claims description 43
- 239000011347 resin Substances 0.000 claims description 43
- 239000004593 Epoxy Substances 0.000 claims description 23
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 12
- 239000003795 chemical substances by application Substances 0.000 claims description 10
- 239000002245 particle Substances 0.000 claims description 9
- 239000012535 impurity Substances 0.000 claims description 6
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 claims description 4
- 229920001451 polypropylene glycol Polymers 0.000 claims description 3
- 150000001338 aliphatic hydrocarbons Chemical group 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims 1
- 239000000203 mixture Substances 0.000 abstract description 54
- 238000009472 formulation Methods 0.000 abstract description 37
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical class C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 abstract description 7
- 239000013505 freshwater Substances 0.000 abstract description 3
- 239000010695 polyglycol Substances 0.000 abstract description 3
- 229920000151 polyglycol Polymers 0.000 abstract description 2
- 229920003319 Araldite® Polymers 0.000 description 17
- 238000012360 testing method Methods 0.000 description 16
- 239000003973 paint Substances 0.000 description 9
- 150000001412 amines Chemical class 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- -1 e.g. Chemical group 0.000 description 7
- AGGKEGLBGGJEBZ-UHFFFAOYSA-N tetramethylenedisulfotetramine Chemical compound C1N(S2(=O)=O)CN3S(=O)(=O)N1CN2C3 AGGKEGLBGGJEBZ-UHFFFAOYSA-N 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- KUBDPQJOLOUJRM-UHFFFAOYSA-N 2-(chloromethyl)oxirane;4-[2-(4-hydroxyphenyl)propan-2-yl]phenol Chemical compound ClCC1CO1.C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 KUBDPQJOLOUJRM-UHFFFAOYSA-N 0.000 description 5
- 239000004952 Polyamide Substances 0.000 description 5
- 239000011152 fibreglass Substances 0.000 description 5
- 238000002386 leaching Methods 0.000 description 5
- 229920002647 polyamide Polymers 0.000 description 5
- 239000013535 sea water Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 241000894006 Bacteria Species 0.000 description 3
- 241000195493 Cryptophyta Species 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 3
- 235000019441 ethanol Nutrition 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 230000002035 prolonged effect Effects 0.000 description 3
- 239000000523 sample Substances 0.000 description 3
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 description 2
- AHDSRXYHVZECER-UHFFFAOYSA-N 2,4,6-tris[(dimethylamino)methyl]phenol Chemical compound CN(C)CC1=CC(CN(C)C)=C(O)C(CN(C)C)=C1 AHDSRXYHVZECER-UHFFFAOYSA-N 0.000 description 2
- LCFVJGUPQDGYKZ-UHFFFAOYSA-N Bisphenol A diglycidyl ether Chemical compound C=1C=C(OCC2OC2)C=CC=1C(C)(C)C(C=C1)=CC=C1OCC1CO1 LCFVJGUPQDGYKZ-UHFFFAOYSA-N 0.000 description 2
- 241000700670 Bryozoa Species 0.000 description 2
- 241001416092 Buteo buteo Species 0.000 description 2
- 229920013683 Celanese Polymers 0.000 description 2
- 241000238586 Cirripedia Species 0.000 description 2
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 2
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 2
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 2
- 241001505295 Eros Species 0.000 description 2
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 2
- 150000008064 anhydrides Chemical class 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 238000005253 cladding Methods 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 229910001431 copper ion Inorganic materials 0.000 description 2
- 239000011928 denatured alcohol Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 125000003700 epoxy group Chemical group 0.000 description 2
- 230000009969 flowable effect Effects 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- QOHMWDJIBGVPIF-UHFFFAOYSA-N n',n'-diethylpropane-1,3-diamine Chemical compound CCN(CC)CCCN QOHMWDJIBGVPIF-UHFFFAOYSA-N 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 229960001124 trientine Drugs 0.000 description 2
- DMYOHQBLOZMDLP-UHFFFAOYSA-N 1-[2-(2-hydroxy-3-piperidin-1-ylpropoxy)phenyl]-3-phenylpropan-1-one Chemical compound C1CCCCN1CC(O)COC1=CC=CC=C1C(=O)CCC1=CC=CC=C1 DMYOHQBLOZMDLP-UHFFFAOYSA-N 0.000 description 1
- 241000243818 Annelida Species 0.000 description 1
- 241000206761 Bacillariophyta Species 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 239000005751 Copper oxide Substances 0.000 description 1
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 1
- 241000282326 Felis catus Species 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 241001600072 Hydroides Species 0.000 description 1
- 239000002841 Lewis acid Substances 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 241000237852 Mollusca Species 0.000 description 1
- 241000237536 Mytilus edulis Species 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 241000131858 Siboglinidae Species 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- 229920001079 Thiokol (polymer) Polymers 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- LHIJANUOQQMGNT-UHFFFAOYSA-N aminoethylethanolamine Chemical compound NCCNCCO LHIJANUOQQMGNT-UHFFFAOYSA-N 0.000 description 1
- 239000002519 antifouling agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 150000004699 copper complex Chemical class 0.000 description 1
- 229910000431 copper oxide Inorganic materials 0.000 description 1
- PUHAKHQMSBQAKT-UHFFFAOYSA-L copper;butanoate Chemical compound [Cu+2].CCCC([O-])=O.CCCC([O-])=O PUHAKHQMSBQAKT-UHFFFAOYSA-L 0.000 description 1
- 230000002498 deadly effect Effects 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 150000002118 epoxides Chemical group 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 150000007517 lewis acids Chemical class 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 235000020638 mussel Nutrition 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 125000000466 oxiranyl group Chemical group 0.000 description 1
- 238000006385 ozonation reaction Methods 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000003797 solvolysis reaction Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- UBOXGVDOUJQMTN-UHFFFAOYSA-N trichloroethylene Natural products ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
- C08G59/22—Di-epoxy compounds
- C08G59/226—Mixtures of di-epoxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1606—Antifouling paints; Underwater paints characterised by the anti-fouling agent
- C09D5/1612—Non-macromolecular compounds
- C09D5/1618—Non-macromolecular compounds inorganic
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US886,951 | 1978-03-15 | ||
| US05/886,951 US4197233A (en) | 1978-03-15 | 1978-03-15 | Anti-fouling and anti-sliming coating material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1116770A true CA1116770A (en) | 1982-01-19 |
Family
ID=25390134
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000323399A Expired CA1116770A (en) | 1978-03-15 | 1979-03-14 | Antifouling and antisliming coating material |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US4197233A (https=) |
| JP (1) | JPS54129033A (https=) |
| BR (1) | BR7901574A (https=) |
| CA (1) | CA1116770A (https=) |
| DE (1) | DE2910020A1 (https=) |
| DK (1) | DK106479A (https=) |
| ES (1) | ES478659A1 (https=) |
| FR (1) | FR2419965A1 (https=) |
| GB (1) | GB2016474B (https=) |
| IT (1) | IT1111999B (https=) |
| NL (1) | NL7902033A (https=) |
| PT (1) | PT69351A (https=) |
| SE (1) | SE446008B (https=) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0046354B1 (en) * | 1980-08-15 | 1983-10-05 | Scott Bader Company Limited | Coating compositions |
| JPS6049770U (ja) * | 1983-09-13 | 1985-04-08 | 小室 徳太郎 | 防汚性漁網 |
| JPS61118468A (ja) * | 1984-11-13 | 1986-06-05 | Dainippon Toryo Co Ltd | 塗料組成物 |
| JPS61264066A (ja) * | 1985-05-17 | 1986-11-21 | Neos Co Ltd | 陸性腹足類用防除塗料 |
| WO1989010947A1 (en) * | 1988-05-13 | 1989-11-16 | Advanced Polymer Systems, Inc. | Protective coating for boat hulls and method of applying the same |
| JPH024872A (ja) * | 1988-06-22 | 1990-01-09 | Sanyuu Bussan Kk | 銅微粉末固定化による殺菌・防汚・防臭方法 |
| ES2068911T3 (es) * | 1988-07-28 | 1995-05-01 | Ciba Geigy Ag | Combinaciones de flexibilizadores para resinas epoxi. |
| US5202390A (en) * | 1988-07-28 | 1993-04-13 | Ciba-Geigy Corporation | Butadiene/polar comonomer copolymer and aromatic reactive end group-containing prepolymer |
| CA2005414C (en) * | 1988-12-19 | 1999-09-28 | Joseph M. Wentzell | Copper marine cladding composition |
| US5760103A (en) * | 1990-10-31 | 1998-06-02 | Joseph M. Wentzell | Copper marine cladding composition |
| US5284682A (en) * | 1992-09-03 | 1994-02-08 | American Marine Coatings, Inc. | Copper/nickel epoxy coating and application process as antifouling agent |
| US5403390A (en) * | 1994-03-11 | 1995-04-04 | Spera; Richard J. | Cuprous sulfide marine antifoulant paint |
| DE19750128A1 (de) * | 1997-11-13 | 1999-05-20 | Volkswagen Ag | Verfahren zur Behandlung der Oberfläche von Metallen oder Legierungen auf mikrobizide Wirksamkeit |
| PL354994A1 (en) | 1999-10-26 | 2004-03-22 | Dennis A. Guritza | Bio-supportive matrices, methods of making and using the same |
| US6555228B2 (en) | 2000-10-16 | 2003-04-29 | Dennis A. Guritza | Bio-supportive medium, and methods of making and using the same |
| US7147921B2 (en) * | 2003-04-04 | 2006-12-12 | Ppg Industries Ohio, Inc. | Anti-fouling coatings containing silica-coated copper |
| US7022750B2 (en) * | 2003-04-04 | 2006-04-04 | Ppg Industries Ohio, Inc. | Anti-fouling coating containing copper and graphite |
| US7421965B2 (en) * | 2004-04-30 | 2008-09-09 | The Yokohama Rubber Co., Ltd. | Flexible buoy |
| US8701585B1 (en) | 2011-02-03 | 2014-04-22 | Lloyd W. Seaman | Boat hull and method of making |
| JP5702503B1 (ja) * | 2014-09-16 | 2015-04-15 | 日本ペイントマリン株式会社 | 乾燥塗膜の形成方法、及びそれに用いる塗料 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE569339A (https=) * | 1957-07-31 | |||
| US3219505A (en) * | 1961-05-22 | 1965-11-23 | Herman W Hilding | Process for the prevention of marine growth |
| US3299169A (en) * | 1961-09-18 | 1967-01-17 | Dow Chemical Co | Elastomeric epoxy resin |
| GB1062324A (en) * | 1963-04-15 | 1967-03-22 | Nippon Oil & Fats Company Ltd | Anti-fouling paint |
| NO128713B (https=) * | 1967-07-03 | 1974-01-02 | Takeda Chemical Industries Ltd | |
| US3993707A (en) * | 1973-10-23 | 1976-11-23 | Pacific Vegetable Oil Corporation | Composition for coating wet surfaces or surfaces immersed in water |
| US3983075A (en) * | 1974-06-21 | 1976-09-28 | Kennecott Copper Corporation | Copper filled conductive epoxy |
-
1978
- 1978-03-15 US US05/886,951 patent/US4197233A/en not_active Expired - Lifetime
-
1979
- 1979-03-12 GB GB7908560A patent/GB2016474B/en not_active Expired
- 1979-03-14 PT PT69351A patent/PT69351A/pt unknown
- 1979-03-14 NL NL7902033A patent/NL7902033A/xx not_active Application Discontinuation
- 1979-03-14 IT IT20982/79A patent/IT1111999B/it active
- 1979-03-14 DE DE19792910020 patent/DE2910020A1/de not_active Withdrawn
- 1979-03-14 BR BR7901574A patent/BR7901574A/pt unknown
- 1979-03-14 SE SE7902303A patent/SE446008B/sv not_active IP Right Cessation
- 1979-03-14 CA CA000323399A patent/CA1116770A/en not_active Expired
- 1979-03-15 ES ES478659A patent/ES478659A1/es not_active Expired
- 1979-03-15 JP JP3100379A patent/JPS54129033A/ja active Granted
- 1979-03-15 FR FR7906564A patent/FR2419965A1/fr active Granted
- 1979-03-15 DK DK106479A patent/DK106479A/da not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| DE2910020A1 (de) | 1979-09-20 |
| FR2419965A1 (fr) | 1979-10-12 |
| ES478659A1 (es) | 1979-07-01 |
| JPS54129033A (en) | 1979-10-06 |
| FR2419965B1 (https=) | 1981-12-04 |
| GB2016474B (en) | 1982-11-24 |
| SE7902303L (sv) | 1979-09-16 |
| SE446008B (sv) | 1986-08-04 |
| DK106479A (da) | 1979-09-16 |
| NL7902033A (nl) | 1979-09-18 |
| JPS6224468B2 (https=) | 1987-05-28 |
| IT1111999B (it) | 1986-01-13 |
| PT69351A (en) | 1979-04-01 |
| BR7901574A (pt) | 1979-10-16 |
| GB2016474A (en) | 1979-09-26 |
| US4197233A (en) | 1980-04-08 |
| IT7920982A0 (it) | 1979-03-14 |
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| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |