CA1096556A - Flexible microporous cellulosic membranes and methods of formation and use thereof - Google Patents
Flexible microporous cellulosic membranes and methods of formation and use thereofInfo
- Publication number
- CA1096556A CA1096556A CA316,347A CA316347A CA1096556A CA 1096556 A CA1096556 A CA 1096556A CA 316347 A CA316347 A CA 316347A CA 1096556 A CA1096556 A CA 1096556A
- Authority
- CA
- Canada
- Prior art keywords
- membrane
- membranes
- cellulose
- polymers
- formation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000012528 membrane Substances 0.000 title claims abstract description 57
- 238000000034 method Methods 0.000 title claims description 15
- 230000015572 biosynthetic process Effects 0.000 title claims description 4
- 229920000642 polymer Polymers 0.000 claims abstract description 28
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000000020 Nitrocellulose Substances 0.000 claims abstract description 17
- FJWGYAHXMCUOOM-QHOUIDNNSA-N [(2s,3r,4s,5r,6r)-2-[(2r,3r,4s,5r,6s)-4,5-dinitrooxy-2-(nitrooxymethyl)-6-[(2r,3r,4s,5r,6s)-4,5,6-trinitrooxy-2-(nitrooxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-3,5-dinitrooxy-6-(nitrooxymethyl)oxan-4-yl] nitrate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O)O[C@H]1[C@@H]([C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@@H](CO[N+]([O-])=O)O1)O[N+]([O-])=O)CO[N+](=O)[O-])[C@@H]1[C@@H](CO[N+]([O-])=O)O[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O FJWGYAHXMCUOOM-QHOUIDNNSA-N 0.000 claims abstract description 17
- 229920001220 nitrocellulos Polymers 0.000 claims abstract description 17
- 239000000203 mixture Substances 0.000 claims abstract description 16
- 229920002301 cellulose acetate Polymers 0.000 claims abstract description 13
- 238000001471 micro-filtration Methods 0.000 claims abstract description 12
- 229920001282 polysaccharide Polymers 0.000 claims abstract description 10
- 239000005017 polysaccharide Substances 0.000 claims abstract description 10
- 150000004676 glycans Chemical class 0.000 claims abstract description 8
- 239000011148 porous material Substances 0.000 claims description 27
- 238000005266 casting Methods 0.000 claims description 11
- KXJGSNRAQWDDJT-UHFFFAOYSA-N 1-acetyl-5-bromo-2h-indol-3-one Chemical compound BrC1=CC=C2N(C(=O)C)CC(=O)C2=C1 KXJGSNRAQWDDJT-UHFFFAOYSA-N 0.000 claims description 10
- 238000001914 filtration Methods 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 4
- 238000009826 distribution Methods 0.000 claims description 2
- 239000006194 liquid suspension Substances 0.000 claims 1
- 150000002148 esters Chemical class 0.000 abstract description 2
- 229920002678 cellulose Polymers 0.000 description 13
- 239000001913 cellulose Substances 0.000 description 13
- 239000002904 solvent Substances 0.000 description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 235000019441 ethanol Nutrition 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000000108 ultra-filtration Methods 0.000 description 4
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- -1 polysaccharide ethers Chemical class 0.000 description 3
- 238000001223 reverse osmosis Methods 0.000 description 3
- 230000001954 sterilising effect Effects 0.000 description 3
- 238000004659 sterilization and disinfection Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229920001661 Chitosan Polymers 0.000 description 2
- 229920000869 Homopolysaccharide Polymers 0.000 description 2
- 239000003570 air Substances 0.000 description 2
- 239000012620 biological material Substances 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 239000000706 filtrate Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- 229920001131 Pulp (paper) Polymers 0.000 description 1
- 239000012080 ambient air Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000012612 commercial material Substances 0.000 description 1
- 238000010960 commercial process Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 125000004093 cyano group Chemical group *C#N 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000006193 liquid solution Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005374 membrane filtration Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/08—Polysaccharides
- B01D71/12—Cellulose derivatives
- B01D71/22—Cellulose ethers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/08—Polysaccharides
- B01D71/12—Cellulose derivatives
- B01D71/14—Esters of organic acids
- B01D71/16—Cellulose acetate
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/08—Polysaccharides
- B01D71/12—Cellulose derivatives
- B01D71/20—Esters of inorganic acids, e.g. cellulose nitrate
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/14—Ultrafiltration; Microfiltration
- B01D61/147—Microfiltration
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US85277677A | 1977-11-18 | 1977-11-18 | |
| US852,776 | 1977-11-18 | ||
| US953,377 | 1977-11-21 | ||
| US05/953,377 US4220477A (en) | 1978-10-23 | 1978-10-23 | Flexible microporous cellulosic membranes and methods of formation and use thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1096556A true CA1096556A (en) | 1981-03-03 |
Family
ID=27127086
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA316,347A Expired CA1096556A (en) | 1977-11-18 | 1978-11-16 | Flexible microporous cellulosic membranes and methods of formation and use thereof |
Country Status (8)
| Country | Link |
|---|---|
| JP (1) | JPS5490082A (de) |
| BR (1) | BR7807556A (de) |
| CA (1) | CA1096556A (de) |
| DE (1) | DE2849863C3 (de) |
| FR (1) | FR2409077A1 (de) |
| GB (1) | GB2009031B (de) |
| IE (1) | IE47585B1 (de) |
| IT (1) | IT7851950A0 (de) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19613484A1 (de) * | 1996-04-04 | 1997-10-09 | Buna Sow Leuna Olefinverb Gmbh | Formmassen zur Herstellung von Gastrennmembranen |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE329117C (de) * | 1916-08-21 | 1920-11-15 | Richard Zsigmondy Dr | Membranfilter und Verfahren zu deren Herstellung |
| DE1017596B (de) * | 1956-07-04 | 1957-10-17 | Membranfiltergesellschaft Sart | Verfahren und Vorrichtung zur kontinuierlichen Herstellung von Membranfiltern |
| JPS5538366B2 (de) * | 1974-03-13 | 1980-10-03 | ||
| GB1430323A (en) * | 1974-03-20 | 1976-03-31 | Chem Systems | Process for the preparation of asymmetric reverse osmosis membranes |
-
1978
- 1978-11-09 GB GB7843859A patent/GB2009031B/en not_active Expired
- 1978-11-16 CA CA316,347A patent/CA1096556A/en not_active Expired
- 1978-11-17 JP JP14122278A patent/JPS5490082A/ja active Granted
- 1978-11-17 FR FR7832489A patent/FR2409077A1/fr active Granted
- 1978-11-17 DE DE2849863A patent/DE2849863C3/de not_active Expired
- 1978-11-17 IE IE2266/78A patent/IE47585B1/en unknown
- 1978-11-17 IT IT7851950A patent/IT7851950A0/it unknown
- 1978-11-17 BR BR7807556A patent/BR7807556A/pt unknown
Also Published As
| Publication number | Publication date |
|---|---|
| BR7807556A (pt) | 1979-07-24 |
| JPS5490082A (en) | 1979-07-17 |
| FR2409077B1 (de) | 1984-11-16 |
| IE782266L (en) | 1979-05-18 |
| DE2849863B2 (de) | 1981-03-12 |
| GB2009031B (en) | 1982-03-10 |
| DE2849863C3 (de) | 1982-06-24 |
| DE2849863A1 (de) | 1979-05-31 |
| IT7851950A0 (it) | 1978-11-17 |
| IE47585B1 (en) | 1984-05-02 |
| JPS5634132B2 (de) | 1981-08-08 |
| FR2409077A1 (fr) | 1979-06-15 |
| GB2009031A (en) | 1979-06-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US3526588A (en) | Macromolecular fractionation process | |
| US3580841A (en) | Ultrathin semipermeable membrane | |
| US4188418A (en) | Separation process | |
| US6056903A (en) | Preparation of polyethersulfone membranes | |
| US3957651A (en) | Microporous polyester membranes and polymer assisted phase inversion process for their manufacture | |
| US4735193A (en) | Separation of a monosaccharide with mixed matrix membranes | |
| Li et al. | Chitosan-poly (vinyl alcohol)/poly (acrylonitrile)(CS–PVA/PAN) composite pervaporation membranes for the separation of ethanol–water solutions | |
| JPH02135134A (ja) | 水・アルコール混合液分離用膜 | |
| US4160791A (en) | Polycarbonate membranes and production thereof | |
| US3878276A (en) | Cellulose acetate blend membranes | |
| US4026978A (en) | Method of making asymmetric cellulose triacetate membranes | |
| US4220477A (en) | Flexible microporous cellulosic membranes and methods of formation and use thereof | |
| CA1216110A (en) | Porous regenerated cellulose membrane and process for the preparation thereof | |
| CA1096556A (en) | Flexible microporous cellulosic membranes and methods of formation and use thereof | |
| JPH0379053B2 (de) | ||
| Takai et al. | Filtration and permeation characteristics of bacterial cellulose composite | |
| JPH0536092B2 (de) | ||
| EP0146655B1 (de) | Verfahren zur Trennung von Gemischen aus Wasser und einer organischen Verbindungund selektiv wasserdurchlassende Membran | |
| Okuno et al. | Behaviour of permeation and separation for aqueous organic acid solutions through poly (vinyl chloride) and poly [(vinyl chloride)‐co‐(vinyl acetate)] membranes | |
| JPS6291543A (ja) | 多層の微孔性膜の製造方法 | |
| Nishioka et al. | Permeability through cellulose membranes grafted with vinyl monomers in a homogeneous system I. Diffusive permeability through acrylonitrile grafted cellulose membranes | |
| JPS60250049A (ja) | ポリスルホン微孔濾過膜の製法 | |
| US5132059A (en) | Process for producing a polyvinyl formal ultrafiltration membrane | |
| US3731816A (en) | Substituted cellulose in grain form and a method of producing the same | |
| WO1992005865A1 (fr) | Film de filtrage |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |