CA1082884A - Process for the extraction of alumina from aluminum- containing silicates - Google Patents
Process for the extraction of alumina from aluminum- containing silicatesInfo
- Publication number
- CA1082884A CA1082884A CA275,330A CA275330A CA1082884A CA 1082884 A CA1082884 A CA 1082884A CA 275330 A CA275330 A CA 275330A CA 1082884 A CA1082884 A CA 1082884A
- Authority
- CA
- Canada
- Prior art keywords
- aluminum
- alumina
- iron
- grams
- chloride hexahydrate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims abstract description 60
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 title claims abstract description 31
- 238000000605 extraction Methods 0.000 title claims abstract description 13
- 150000004760 silicates Chemical class 0.000 title claims abstract description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 50
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 34
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 34
- 229910052742 iron Inorganic materials 0.000 claims abstract description 25
- JGDITNMASUZKPW-UHFFFAOYSA-K aluminium trichloride hexahydrate Chemical compound O.O.O.O.O.O.Cl[Al](Cl)Cl JGDITNMASUZKPW-UHFFFAOYSA-K 0.000 claims abstract description 17
- 229940009861 aluminum chloride hexahydrate Drugs 0.000 claims abstract description 17
- 238000001354 calcination Methods 0.000 claims abstract description 12
- 238000004064 recycling Methods 0.000 claims abstract 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 50
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 28
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 13
- 239000007787 solid Substances 0.000 claims description 12
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 claims description 11
- 229910000041 hydrogen chloride Inorganic materials 0.000 claims description 11
- 239000007788 liquid Substances 0.000 claims description 10
- 239000012535 impurity Substances 0.000 claims description 8
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 7
- NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Substances OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 5
- 239000012074 organic phase Substances 0.000 claims description 4
- 239000002245 particle Substances 0.000 claims description 4
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 3
- 150000001805 chlorine compounds Chemical class 0.000 claims description 3
- SEGLCEQVOFDUPX-UHFFFAOYSA-N di-(2-ethylhexyl)phosphoric acid Chemical compound CCCCC(CC)COP(O)(=O)OCC(CC)CCCC SEGLCEQVOFDUPX-UHFFFAOYSA-N 0.000 claims description 3
- 150000003016 phosphoric acids Chemical class 0.000 claims description 3
- 239000007789 gas Substances 0.000 claims description 2
- 239000000243 solution Substances 0.000 claims 4
- 239000007864 aqueous solution Substances 0.000 claims 2
- 238000005406 washing Methods 0.000 claims 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 abstract description 18
- 239000002253 acid Substances 0.000 abstract description 11
- 238000002386 leaching Methods 0.000 abstract description 11
- 239000011780 sodium chloride Substances 0.000 abstract description 9
- 238000001556 precipitation Methods 0.000 abstract description 6
- 239000002994 raw material Substances 0.000 abstract description 4
- 230000008929 regeneration Effects 0.000 abstract description 2
- 238000011069 regeneration method Methods 0.000 abstract description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 27
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 17
- 239000000377 silicon dioxide Substances 0.000 description 13
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 12
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 8
- 239000000706 filtrate Substances 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 6
- 239000012452 mother liquor Substances 0.000 description 6
- 239000002244 precipitate Substances 0.000 description 6
- NTGONJLAOZZDJO-UHFFFAOYSA-M disodium;hydroxide Chemical compound [OH-].[Na+].[Na+] NTGONJLAOZZDJO-UHFFFAOYSA-M 0.000 description 5
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 4
- 229940063656 aluminum chloride Drugs 0.000 description 4
- 239000011575 calcium Substances 0.000 description 4
- 229910052791 calcium Inorganic materials 0.000 description 4
- 238000005119 centrifugation Methods 0.000 description 4
- 238000001914 filtration Methods 0.000 description 4
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 3
- 238000009626 Hall-Héroult process Methods 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 3
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
- 235000011941 Tilia x europaea Nutrition 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 150000001340 alkali metals Chemical class 0.000 description 3
- 239000000470 constituent Substances 0.000 description 3
- 238000010924 continuous production Methods 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- FBAFATDZDUQKNH-UHFFFAOYSA-M iron chloride Chemical compound [Cl-].[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-M 0.000 description 3
- 239000004571 lime Substances 0.000 description 3
- 239000011777 magnesium Substances 0.000 description 3
- 229910052749 magnesium Inorganic materials 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 229910001570 bauxite Inorganic materials 0.000 description 2
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 2
- 239000000292 calcium oxide Substances 0.000 description 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 2
- 230000029087 digestion Effects 0.000 description 2
- 239000000284 extract Substances 0.000 description 2
- 150000004687 hexahydrates Chemical class 0.000 description 2
- 239000003350 kerosene Substances 0.000 description 2
- 235000011147 magnesium chloride Nutrition 0.000 description 2
- 235000011007 phosphoric acid Nutrition 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 239000006228 supernatant Substances 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 229910001514 alkali metal chloride Inorganic materials 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- NZRRHVGPMNLSQH-UHFFFAOYSA-L bis(2-ethylhexyl) phosphate;iron(2+) Chemical compound [Fe+2].CCCCC(CC)COP([O-])(=O)OCC(CC)CCCC.CCCCC(CC)COP([O-])(=O)OCC(CC)CCCC NZRRHVGPMNLSQH-UHFFFAOYSA-L 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229910001610 cryolite Inorganic materials 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000003292 diminished effect Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 239000010433 feldspar Substances 0.000 description 1
- 239000012065 filter cake Substances 0.000 description 1
- 238000009291 froth flotation Methods 0.000 description 1
- DKAGJZJALZXOOV-UHFFFAOYSA-N hydrate;hydrochloride Chemical compound O.Cl DKAGJZJALZXOOV-UHFFFAOYSA-N 0.000 description 1
- 235000000396 iron Nutrition 0.000 description 1
- NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical class Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 description 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- RBWSWDPRDBEWCR-RKJRWTFHSA-N sodium;(2r)-2-[(2r)-3,4-dihydroxy-5-oxo-2h-furan-2-yl]-2-hydroxyethanolate Chemical compound [Na+].[O-]C[C@@H](O)[C@H]1OC(=O)C(O)=C1O RBWSWDPRDBEWCR-RKJRWTFHSA-N 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 239000010456 wollastonite Substances 0.000 description 1
- 229910052882 wollastonite Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F7/00—Compounds of aluminium
- C01F7/02—Aluminium oxide; Aluminium hydroxide; Aluminates
- C01F7/20—Preparation of aluminium oxide or hydroxide from aluminous ores using acids or salts
- C01F7/26—Preparation of aluminium oxide or hydroxide from aluminous ores using acids or salts with sulfuric acids or sulfates
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F7/00—Compounds of aluminium
- C01F7/02—Aluminium oxide; Aluminium hydroxide; Aluminates
- C01F7/20—Preparation of aluminium oxide or hydroxide from aluminous ores using acids or salts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G49/00—Compounds of iron
- C01G49/02—Oxides; Hydroxides
- C01G49/06—Ferric oxide [Fe2O3]
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Geology (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NO761136 | 1976-04-02 | ||
| NO761,136 | 1976-04-02 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1082884A true CA1082884A (en) | 1980-08-05 |
Family
ID=19882826
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA275,330A Expired CA1082884A (en) | 1976-04-02 | 1977-04-01 | Process for the extraction of alumina from aluminum- containing silicates |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US4110399A (OSRAM) |
| CA (1) | CA1082884A (OSRAM) |
| DK (1) | DK143877A (OSRAM) |
| FI (1) | FI771014A7 (OSRAM) |
| FR (1) | FR2360515A1 (OSRAM) |
| IS (1) | IS2386A7 (OSRAM) |
| SE (1) | SE7703590L (OSRAM) |
Families Citing this family (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2803483C2 (de) * | 1978-01-27 | 1982-08-05 | Standard-Messo Duisburg, Gesellschaft für Chemietechnik mbH & Co, 4100 Duisburg | Verfahren zur Herstellung von reinem Al↓2↓ O↓3↓ aus Aluminiumerzen |
| FR2426019A1 (fr) * | 1978-05-18 | 1979-12-14 | Pechiney Aluminium | Procede continu d'obtention d'alumine pure a partir d'une liqueur acide provenant de l'attaque chlorosulfurique d'un minerai alumineux et de purification de la liqueur debarrassee de l'alumine |
| NO147516C (no) * | 1979-02-13 | 1983-04-27 | Elkem Spigerverket As | Fremgangsmaate for utfelling av et rent aluminiumklorid fra loesninger som inneholder aluminium- og magnesiumioner. |
| NO143583C (no) * | 1979-02-13 | 1983-01-06 | Elkem Spigerverket As | Fremgangsmaate for utluting av silikater med syre. |
| NO790460L (no) * | 1979-02-13 | 1980-08-14 | Elkem Spigerverket As | Fremstilling av et rent aluminiumoksyd fra loesninger inneholdende opploeste aluminiumioner og jernioner |
| HU184318B (en) * | 1980-08-26 | 1984-08-28 | Tatabanyai Szenbanyak | Process for reducing iron content of raw materialsprocess for decreasing the iron content of raw mat containing iron, silicon and aluminium, as well aerials conta ining iron, silicon and aluminium ands for producing in the given case aluminium oxide for preparing iron oxide further in a given case aluminium oxide concentrate concentrate |
| US4339415A (en) * | 1980-12-05 | 1982-07-13 | Allied Corporation | Recovery of soluble alumina values from alumina bearing ores |
| DE3218996A1 (de) * | 1981-05-28 | 1982-12-16 | Alcan International Ltd., Montreal, Quebec | Verfahren zur gewinnung von aluminiumoxid aus einer festen ausgangsmischung, enthaltend alcl(pfeil abwaerts)3(pfeil abwaerts) und nacl |
| US4465659A (en) * | 1982-07-21 | 1984-08-14 | Atlantic Richfield Company | Aluminum production via the chlorination of partially calcined aluminum chloride hexahydrate |
| US6468483B2 (en) | 2000-02-04 | 2002-10-22 | Goldendale Aluminum Company | Process for treating alumina-bearing ores to recover metal values therefrom |
| CN101842504B (zh) | 2007-05-21 | 2012-11-14 | 奥贝特铝业有限公司 | 从铝土矿石中提取铝和铁的工艺 |
| JP2014508863A (ja) | 2011-03-18 | 2014-04-10 | オーバイト アルミナ インコーポレイテッド | アルミニウム含有材料から希土類元素を回収する方法 |
| EP2705169A4 (en) | 2011-05-04 | 2015-04-15 | Orbite Aluminae Inc | METHOD FOR RECOVERING RARE ELEMENTS FROM DIFFERENT OTHERS |
| CA2863755C (en) | 2011-06-03 | 2016-04-26 | Orbite Aluminae Inc. | Methods for preparing hematite |
| IN2014DN03007A (OSRAM) | 2011-09-16 | 2015-05-08 | Orbite Aluminae Inc | |
| US9023301B2 (en) | 2012-01-10 | 2015-05-05 | Orbite Aluminae Inc. | Processes for treating red mud |
| CA2903512C (en) | 2012-03-29 | 2017-12-05 | Orbite Technologies Inc. | Processes for treating fly ashes |
| CN102849765B (zh) * | 2012-04-10 | 2014-05-21 | 沈阳金博新技术产业有限公司 | 一种利用低品位铝土矿酸浸制取氧化铝的方法 |
| EP2676932B1 (de) * | 2012-06-20 | 2015-03-25 | Pleason Ventures LTD | Verfahren zur komplexen Verarbeitung von Bauxit |
| WO2014011455A1 (en) * | 2012-07-09 | 2014-01-16 | Kaonetics Technologies, Inc. | Method and apparatus for producing hydrogen and aluminum oxide from aluminum |
| BR112015000626A2 (pt) | 2012-07-12 | 2017-06-27 | Orbite Aluminae Inc | processos para preparação de óxido de titânio e outros produtos variados |
| RU2544725C1 (ru) * | 2012-07-20 | 2015-03-20 | Общество с ограниченной ответственностью "Объединенная Компания РУСАЛ Инженерно-технологический центр" | Способ кислотной переработки красных шламов |
| IN2015DN00743A (OSRAM) | 2012-07-20 | 2015-07-10 | Obsh Estvo S Ogranichennoy Otvetstvennostyu Obedinennaya Kompaniya Rusal Inzh T Ts | |
| CA2885255C (en) | 2012-09-26 | 2015-12-22 | Orbite Aluminae Inc. | Processes for preparing alumina and magnesium chloride by hc1 leaching of various materials |
| EP2920114A4 (en) | 2012-11-14 | 2016-03-02 | Orbite Aluminae Inc | PROCESS FOR PURIFYING ALUMINUM IONS |
| NO337196B1 (no) * | 2014-03-12 | 2016-02-08 | Nordic Mining Asa | En ny fremgangsmåte for fremstilling av alumina og karbonat fra aluminiumrike materialer med integrert CO2 utnyttelse |
| JP7593643B2 (ja) | 2019-01-16 | 2024-12-03 | マサチューセッツ インスティテュート オブ テクノロジー | 酸および塩基を含む反応スキーム、空間的に変化する化学組成勾配を含む反応器、ならびに関連システムおよび方法 |
| BR112021017931A2 (pt) | 2019-03-14 | 2021-11-16 | Massachusetts Inst Technology | Método, e, sistema |
| EP4313906A4 (en) | 2021-03-22 | 2025-02-19 | Sublime Systems, Inc. | Decarbonized cement blends |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3082062A (en) * | 1958-11-18 | 1963-03-19 | Rohm & Haas | Removal of ferric chloride from ironaluminum chloride solutions |
| US3240561A (en) * | 1962-06-04 | 1966-03-15 | Reynolds Metals Co | Production of alumina |
| US3240562A (en) * | 1962-06-04 | 1966-03-15 | Reynolds Metals Co | Process for the production of alumina |
| US3211521A (en) * | 1962-07-30 | 1965-10-12 | Little Inc A | Process for removing iron from acidic aluminum-containing solutions |
| US3320032A (en) * | 1962-09-05 | 1967-05-16 | Huber Corp J M | Extracting iron from aluminum salt solutions using bis(2-ethylhexyl) phosphoric acid |
| US3331662A (en) * | 1962-09-26 | 1967-07-18 | Huber Corp J M | Method of removing iron from aluminum sulfate solutions |
| NL299871A (OSRAM) * | 1962-10-31 | 1900-01-01 | ||
| FR1554586A (OSRAM) * | 1966-04-28 | 1969-01-24 | ||
| FR1558347A (OSRAM) * | 1967-10-25 | 1969-02-28 | ||
| US3586481A (en) * | 1968-10-16 | 1971-06-22 | Little Inc A | Method for extracting pure alpha-alumina from clays |
| US3816590A (en) * | 1971-03-18 | 1974-06-11 | Little Inc A | Method and apparatus for providing a pure concentrated aqueous solution of aluminum nitrate |
| BE791752A (fr) * | 1971-11-25 | 1973-05-22 | Pechiney Aluminium | Procede de traitement acide continu des argiles et schistes crus |
-
1977
- 1977-03-29 SE SE7703590A patent/SE7703590L/xx unknown
- 1977-03-30 US US05/782,826 patent/US4110399A/en not_active Expired - Lifetime
- 1977-03-31 FR FR7709815A patent/FR2360515A1/fr not_active Withdrawn
- 1977-04-01 DK DK143877A patent/DK143877A/da not_active IP Right Cessation
- 1977-04-01 FI FI771014A patent/FI771014A7/fi not_active Application Discontinuation
- 1977-04-01 IS IS2386A patent/IS2386A7/is unknown
- 1977-04-01 CA CA275,330A patent/CA1082884A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| IS2386A7 (is) | 1977-06-22 |
| FI771014A7 (OSRAM) | 1977-10-03 |
| SE7703590L (sv) | 1977-10-03 |
| US4110399A (en) | 1978-08-29 |
| FR2360515A1 (fr) | 1978-03-03 |
| DK143877A (da) | 1977-10-03 |
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