CA1073040A - Secondary battery or cell with composite electrode - Google Patents
Secondary battery or cell with composite electrodeInfo
- Publication number
- CA1073040A CA1073040A CA263,563A CA263563A CA1073040A CA 1073040 A CA1073040 A CA 1073040A CA 263563 A CA263563 A CA 263563A CA 1073040 A CA1073040 A CA 1073040A
- Authority
- CA
- Canada
- Prior art keywords
- accordance
- cation
- graphite
- cell
- permeable barrier
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000002131 composite material Substances 0.000 title claims abstract description 11
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 67
- 239000000376 reactant Substances 0.000 claims abstract description 67
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 63
- 239000011593 sulfur Substances 0.000 claims abstract description 63
- 230000004888 barrier function Effects 0.000 claims abstract description 56
- 239000005077 polysulfide Substances 0.000 claims abstract description 41
- 150000008117 polysulfides Polymers 0.000 claims abstract description 41
- 229920001021 polysulfide Polymers 0.000 claims abstract description 38
- 229910052783 alkali metal Inorganic materials 0.000 claims abstract description 25
- 239000000203 mixture Substances 0.000 claims abstract description 25
- 150000001340 alkali metals Chemical class 0.000 claims abstract description 24
- 238000006243 chemical reaction Methods 0.000 claims abstract description 24
- 239000004020 conductor Substances 0.000 claims abstract description 17
- 238000010349 cathodic reaction Methods 0.000 claims abstract description 16
- 150000003839 salts Chemical class 0.000 claims abstract description 16
- 239000007788 liquid Substances 0.000 claims abstract description 13
- 238000012546 transfer Methods 0.000 claims abstract description 12
- 230000006872 improvement Effects 0.000 claims abstract description 11
- 229920006395 saturated elastomer Polymers 0.000 claims abstract description 11
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 57
- 229910002804 graphite Inorganic materials 0.000 claims description 52
- 239000010439 graphite Substances 0.000 claims description 52
- 239000000463 material Substances 0.000 claims description 51
- 239000002184 metal Substances 0.000 claims description 42
- 229910052751 metal Inorganic materials 0.000 claims description 42
- 239000006260 foam Substances 0.000 claims description 16
- 150000002739 metals Chemical class 0.000 claims description 16
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 8
- LJCFOYOSGPHIOO-UHFFFAOYSA-N antimony pentoxide Chemical compound O=[Sb](=O)O[Sb](=O)=O LJCFOYOSGPHIOO-UHFFFAOYSA-N 0.000 claims description 7
- 150000002500 ions Chemical class 0.000 claims description 6
- 239000011244 liquid electrolyte Substances 0.000 claims description 6
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 claims description 6
- 229910052982 molybdenum disulfide Inorganic materials 0.000 claims description 6
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 5
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 5
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 claims description 5
- 229910052787 antimony Inorganic materials 0.000 claims description 5
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 5
- NFYLSJDPENHSBT-UHFFFAOYSA-N chromium(3+);lanthanum(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Cr+3].[La+3] NFYLSJDPENHSBT-UHFFFAOYSA-N 0.000 claims description 5
- 229910052744 lithium Inorganic materials 0.000 claims description 5
- 230000007704 transition Effects 0.000 claims description 5
- 239000011148 porous material Substances 0.000 claims description 4
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 3
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
- 229910052715 tantalum Inorganic materials 0.000 claims description 3
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims description 3
- 229910001887 tin oxide Inorganic materials 0.000 claims description 3
- 239000010936 titanium Substances 0.000 claims description 3
- 229910052719 titanium Inorganic materials 0.000 claims description 3
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims 4
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims 4
- 229910052797 bismuth Inorganic materials 0.000 claims 4
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims 4
- 229910021397 glassy carbon Inorganic materials 0.000 claims 4
- 230000000737 periodic effect Effects 0.000 claims 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims 2
- 229910000480 nickel oxide Inorganic materials 0.000 claims 2
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 claims 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims 2
- 210000004027 cell Anatomy 0.000 description 37
- 238000013461 design Methods 0.000 description 20
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 13
- 239000007784 solid electrolyte Substances 0.000 description 12
- 238000000034 method Methods 0.000 description 10
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 7
- 230000008569 process Effects 0.000 description 7
- 229910052708 sodium Inorganic materials 0.000 description 7
- 239000011734 sodium Substances 0.000 description 7
- 239000000758 substrate Substances 0.000 description 6
- 239000010935 stainless steel Substances 0.000 description 5
- 229910001220 stainless steel Inorganic materials 0.000 description 5
- -1 e.g. Substances 0.000 description 4
- 239000003792 electrolyte Substances 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 229910045601 alloy Inorganic materials 0.000 description 3
- 239000000956 alloy Substances 0.000 description 3
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical compound BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 3
- 150000001768 cations Chemical class 0.000 description 3
- 238000007599 discharging Methods 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 150000004763 sulfides Chemical class 0.000 description 3
- ODPOAESBSUKMHD-UHFFFAOYSA-L 6,7-dihydrodipyrido[1,2-b:1',2'-e]pyrazine-5,8-diium;dibromide Chemical compound [Br-].[Br-].C1=CC=[N+]2CC[N+]3=CC=CC=C3C2=C1 ODPOAESBSUKMHD-UHFFFAOYSA-L 0.000 description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
- XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical compound [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 description 2
- 239000005630 Diquat Substances 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 229910052810 boron oxide Inorganic materials 0.000 description 2
- 229910052794 bromium Inorganic materials 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 2
- ZLCCLBKPLLUIJC-UHFFFAOYSA-L disodium tetrasulfane-1,4-diide Chemical compound [Na+].[Na+].[S-]SS[S-] ZLCCLBKPLLUIJC-UHFFFAOYSA-L 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000007772 electrode material Substances 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 229910021645 metal ion Inorganic materials 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- UTEAJUQTEFBYOE-UHFFFAOYSA-N methane;molecular bromine Chemical compound C.C.C.C.C.C.C.C.C.C.C.C.C.C.C.C.BrBr UTEAJUQTEFBYOE-UHFFFAOYSA-N 0.000 description 2
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 2
- 229910001948 sodium oxide Inorganic materials 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- XAGFODPZIPBFFR-BJUDXGSMSA-N Aluminum-26 Chemical compound [26Al] XAGFODPZIPBFFR-BJUDXGSMSA-N 0.000 description 1
- 229910000873 Beta-alumina solid electrolyte Inorganic materials 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 241001663154 Electron Species 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 101100114417 Neurospora crassa (strain ATCC 24698 / 74-OR23-1A / CBS 708.71 / DSM 1257 / FGSC 987) con-13 gene Proteins 0.000 description 1
- 101100168115 Neurospora crassa (strain ATCC 24698 / 74-OR23-1A / CBS 708.71 / DSM 1257 / FGSC 987) con-6 gene Proteins 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- LEHOTFFKMJEONL-UHFFFAOYSA-N Uric Acid Chemical compound N1C(=O)NC(=O)C2=C1NC(=O)N2 LEHOTFFKMJEONL-UHFFFAOYSA-N 0.000 description 1
- TVWHNULVHGKJHS-UHFFFAOYSA-N Uric acid Natural products N1C(=O)NC(=O)C2NC(=O)NC21 TVWHNULVHGKJHS-UHFFFAOYSA-N 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 210000003850 cellular structure Anatomy 0.000 description 1
- 229910021525 ceramic electrolyte Inorganic materials 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 229940117975 chromium trioxide Drugs 0.000 description 1
- GAMDZJFZMJECOS-UHFFFAOYSA-N chromium(6+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Cr+6] GAMDZJFZMJECOS-UHFFFAOYSA-N 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000011532 electronic conductor Substances 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000005816 glass manufacturing process Methods 0.000 description 1
- 239000007770 graphite material Substances 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- XZYHDXZNNDZXSR-UHFFFAOYSA-N n-(1,1-dioxothiolan-3-yl)-n-methyl-2-[(4-phenyl-5-pyridin-4-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide Chemical compound N=1N=C(C=2C=CN=CC=2)N(C=2C=CC=CC=2)C=1SCC(=O)N(C)C1CCS(=O)(=O)C1 XZYHDXZNNDZXSR-UHFFFAOYSA-N 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000012286 potassium permanganate Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 235000010344 sodium nitrate Nutrition 0.000 description 1
- 239000004317 sodium nitrate Substances 0.000 description 1
- HYHCSLBZRBJJCH-UHFFFAOYSA-N sodium polysulfide Chemical compound [Na+].S HYHCSLBZRBJJCH-UHFFFAOYSA-N 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229940116269 uric acid Drugs 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/36—Accumulators not provided for in groups H01M10/05-H01M10/34
- H01M10/39—Accumulators not provided for in groups H01M10/05-H01M10/34 working at high temperature
- H01M10/3909—Sodium-sulfur cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Secondary Cells (AREA)
- Battery Electrode And Active Subsutance (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/653,858 US3993503A (en) | 1976-01-30 | 1976-01-30 | Secondary battery or cell with composite electrode |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1073040A true CA1073040A (en) | 1980-03-04 |
Family
ID=24622565
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA263,563A Expired CA1073040A (en) | 1976-01-30 | 1976-10-18 | Secondary battery or cell with composite electrode |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US3993503A (Direct) |
| JP (1) | JPS5295033A (Direct) |
| CA (1) | CA1073040A (Direct) |
| DE (1) | DE2649810C3 (Direct) |
| FR (1) | FR2339965A1 (Direct) |
| GB (1) | GB1569115A (Direct) |
Families Citing this family (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4076903A (en) * | 1975-08-06 | 1978-02-28 | British Railways Board | Alkali metal-sulphur cells |
| JPS5258823A (en) * | 1975-11-11 | 1977-05-14 | Kogyo Gijutsuin | Sodiummsulfur battery |
| GB1528672A (en) * | 1976-02-18 | 1978-10-18 | Chloride Silent Power Ltd | Sodium sulphur cells |
| US4243733A (en) * | 1976-12-20 | 1981-01-06 | Chloride Silent Power Limited | Electrode structures |
| GB1540869A (en) * | 1976-12-20 | 1979-02-14 | Chloride Silent Power Ltd | Electrode structures |
| US4048394A (en) * | 1977-02-28 | 1977-09-13 | Ford Motor Company | Secondary battery or cell with vitreous carbon coated graphite current collector |
| US4166156A (en) * | 1977-02-28 | 1979-08-28 | Ford Motor Company | Secondary battery or cell with pyrolytic graphite coated graphite current collector |
| US4091151A (en) * | 1977-09-15 | 1978-05-23 | Ford Motor Company | Secondary battery or cell with improved rechargeability |
| IN148314B (Direct) * | 1977-09-19 | 1981-01-10 | Chloride Silent Power Ltd | |
| DE3028836C2 (de) * | 1980-07-30 | 1986-04-17 | Brown, Boveri & Cie Ag, 6800 Mannheim | Elektrochemische Speicherzelle |
| EP0061861B1 (en) * | 1981-03-18 | 1986-02-26 | Chloride Silent Power Limited | Cathode electrode structures for sodium sulphur cells and their manufacture |
| US4528253A (en) * | 1984-09-21 | 1985-07-09 | The United States Of America As Represented By The Secretary Of The Navy | High performance molten nitrate cell |
| DE3507697A1 (de) * | 1985-03-05 | 1986-09-11 | Brown, Boveri & Cie Ag, 6800 Mannheim | Elektrochemische speicherzelle |
| DE3615238A1 (de) * | 1986-05-06 | 1987-11-12 | Bbc Brown Boveri & Cie | Elektrochemische speicherzelle |
| US5506072A (en) * | 1995-02-14 | 1996-04-09 | Eric B. Griffen | Reversible high energy capacity metal-sulfur battery and method of making same |
| US5552244A (en) * | 1995-02-14 | 1996-09-03 | Eric Blair Griffen | Reversible high energy capacity metal-sulfur battery and method of making same |
| US5578393A (en) * | 1995-03-10 | 1996-11-26 | United States Advanced Battery Consortium | Thermal contact sheet for high temperature batteries |
| DE69709740T2 (de) * | 1996-06-14 | 2002-08-22 | Moltech Corp., Tucson | Zusammensetzung verwendbar in elektrolyten für sekundär batteriezellen |
| US6210831B1 (en) | 1997-12-19 | 2001-04-03 | Moltech Corporation | Cathodes comprising electroactive sulfur materials and secondary batteries using same |
| US6110619A (en) | 1997-12-19 | 2000-08-29 | Moltech Corporation | Electrochemical cells with cationic polymers and electroactive sulfur compounds |
| KR100307453B1 (ko) * | 1999-02-19 | 2001-09-26 | 김순택 | 리튬이온 2차 전지의 음극 |
| US8828108B2 (en) * | 2008-07-15 | 2014-09-09 | Bruce McGill | Apparatus, system, and method for producing energy using a stream of liquid alkali metal |
| US8012223B2 (en) | 2008-07-15 | 2011-09-06 | Mcgill Bruce | Apparatus, system, and method for producing energy using an alkalai metal |
| RU2559832C2 (ru) * | 2010-07-01 | 2015-08-10 | Графтек Интернэшнл Холдингз Инк. | Графитовый электрод |
| CN103384013B (zh) | 2010-07-01 | 2015-09-02 | 格拉弗技术国际控股有限公司 | 石墨电极 |
| TWI525881B (zh) * | 2010-12-30 | 2016-03-11 | 財團法人工業技術研究院 | 具低穿透率之有機無機混成之複合質子交換膜 |
| DE102012203057A1 (de) * | 2012-02-28 | 2013-08-29 | Sgl Carbon Se | Stromkollektor für eine Alkali-Schwefel-Zelle |
| AU2015215105B2 (en) * | 2014-02-07 | 2019-04-04 | Basf Se | Electrode unit for an electrochemical device |
| EP3182480A1 (de) * | 2015-12-14 | 2017-06-21 | Basf Se | Vorrichtung zur speicherung elektrischer energie sowie verfahren zu deren montage und inbetriebnahme und zu deren betrieb |
| KR101803240B1 (ko) * | 2017-06-28 | 2017-11-29 | 국방과학연구소 | 고체전해질을 사용한 용융 리튬-황 전지 및 이의 제작 방법 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3672994A (en) * | 1971-01-04 | 1972-06-27 | Gen Electric | Sodium-sulfur cell with third electrode |
| US3740268A (en) * | 1972-01-17 | 1973-06-19 | Gen Electric | Method of charging sodium-sulfur cell |
| US3749603A (en) * | 1972-04-17 | 1973-07-31 | Dow Chemical Co | Alkali metal/sulfur battery having a cathodic current collector coated with molybdenum disulfide |
| JPS5224972B2 (Direct) * | 1972-10-19 | 1977-07-05 | ||
| GB1461071A (en) * | 1973-01-03 | 1977-01-13 | Electricity Council | Electrochemical cells having a liquid alkali metal electrode electrochemical cells having a liquid alkali metal electrode and solid |
| GB1505987A (en) * | 1974-05-01 | 1978-04-05 | Secretary Industry Brit | Electric cells |
-
1976
- 1976-01-30 US US05/653,858 patent/US3993503A/en not_active Expired - Lifetime
- 1976-10-18 CA CA263,563A patent/CA1073040A/en not_active Expired
- 1976-10-22 FR FR7632009A patent/FR2339965A1/fr active Granted
- 1976-10-29 JP JP12959776A patent/JPS5295033A/ja active Granted
- 1976-10-29 GB GB45055/76A patent/GB1569115A/en not_active Expired
- 1976-10-29 DE DE2649810A patent/DE2649810C3/de not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5295033A (en) | 1977-08-10 |
| FR2339965A1 (fr) | 1977-08-26 |
| US3993503A (en) | 1976-11-23 |
| DE2649810B2 (de) | 1981-02-12 |
| GB1569115A (en) | 1980-06-11 |
| FR2339965B1 (Direct) | 1979-02-23 |
| JPS5733836B2 (Direct) | 1982-07-19 |
| DE2649810C3 (de) | 1982-01-21 |
| DE2649810A1 (de) | 1977-08-04 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA1073040A (en) | Secondary battery or cell with composite electrode | |
| CA1089531A (en) | Secondary battery or cell with polysulfide wettable electrode | |
| CA1073525A (en) | Secondary battery or cell with dual electrode | |
| US4069372A (en) | Electric accumulator with a solid electrolyte | |
| CA1060090A (en) | Alkali metal/sulfur battery or cell with single phase sulfur electrode | |
| US3966492A (en) | Sodium sulfur battery or cell with improved ampere-hour capacity | |
| CA1054671A (en) | Alkali metal/sulfur cell with gas fuel cell electrode | |
| CA1062773A (en) | Energy conversion devices with improved electrode shapes | |
| USRE30353E (en) | Electric accumulator with a solid electrolyte | |
| US3847667A (en) | Alkali metal-porous conductive carbon battery having a molten alkali metal chloraluminate electrolyte | |
| US4064325A (en) | Electric storage batteries | |
| CA1073041A (en) | Secondary battery with separate charge and discharge zones | |
| EP3284134A1 (en) | Sodium-aluminum battery with sodium ion conductive ceramic separator | |
| US4038465A (en) | Sodium sulfur battery or cell with external storage | |
| US3969138A (en) | Sodium-aluminum halide, sulfur battery | |
| US4002806A (en) | Secondary battery or cell | |
| CA1042982A (en) | Process for recharging secondary batteries | |
| US3988163A (en) | Sodium-mixture of metal halides, sulfur battery | |
| US4166156A (en) | Secondary battery or cell with pyrolytic graphite coated graphite current collector | |
| US4749634A (en) | High temperature storage battery | |
| US4048394A (en) | Secondary battery or cell with vitreous carbon coated graphite current collector | |
| US4004946A (en) | Sealed lithium-chlorine cell | |
| GB2121597A (en) | Sodium - sodium nitrate cell | |
| Foulkes et al. | Sodium‐sulphur cells | |
| Sudworth | High temperature batteries |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |