CA1072977A - Process for sulfonation and apparatus therefor - Google Patents
Process for sulfonation and apparatus thereforInfo
- Publication number
- CA1072977A CA1072977A CA256,974A CA256974A CA1072977A CA 1072977 A CA1072977 A CA 1072977A CA 256974 A CA256974 A CA 256974A CA 1072977 A CA1072977 A CA 1072977A
- Authority
- CA
- Canada
- Prior art keywords
- stage
- reaction
- liquid
- gas
- stream
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000006277 sulfonation reaction Methods 0.000 title claims abstract description 16
- 238000000034 method Methods 0.000 title claims description 13
- 238000006243 chemical reaction Methods 0.000 claims abstract description 97
- 150000002894 organic compounds Chemical class 0.000 claims abstract description 18
- 239000007795 chemical reaction product Substances 0.000 claims abstract description 10
- 239000011541 reaction mixture Substances 0.000 claims abstract description 5
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 claims description 70
- 239000007788 liquid Substances 0.000 claims description 57
- 239000007789 gas Substances 0.000 claims description 47
- 239000000376 reactant Substances 0.000 claims description 21
- 238000001816 cooling Methods 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 15
- 230000000630 rising effect Effects 0.000 claims description 9
- 230000000694 effects Effects 0.000 claims description 7
- 239000011261 inert gas Substances 0.000 claims description 7
- 238000005670 sulfation reaction Methods 0.000 claims description 5
- 239000000543 intermediate Substances 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 3
- 230000001180 sulfating effect Effects 0.000 claims description 3
- 239000002826 coolant Substances 0.000 claims 6
- 239000003701 inert diluent Substances 0.000 claims 2
- 239000007791 liquid phase Substances 0.000 claims 2
- 239000007792 gaseous phase Substances 0.000 claims 1
- 239000010408 film Substances 0.000 description 18
- 239000000498 cooling water Substances 0.000 description 11
- 150000001875 compounds Chemical class 0.000 description 7
- 150000001298 alcohols Chemical class 0.000 description 5
- 125000004432 carbon atom Chemical group C* 0.000 description 5
- 235000014113 dietary fatty acids Nutrition 0.000 description 5
- 239000000194 fatty acid Substances 0.000 description 5
- 229930195729 fatty acid Natural products 0.000 description 5
- 150000004665 fatty acids Chemical class 0.000 description 5
- 239000000047 product Substances 0.000 description 4
- 239000010409 thin film Substances 0.000 description 4
- 239000012467 final product Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000007858 starting material Substances 0.000 description 3
- 230000019635 sulfation Effects 0.000 description 3
- 125000002947 alkylene group Chemical group 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 238000007086 side reaction Methods 0.000 description 2
- KEQGZUUPPQEDPF-UHFFFAOYSA-N 1,3-dichloro-5,5-dimethylimidazolidine-2,4-dione Chemical compound CC1(C)N(Cl)C(=O)N(Cl)C1=O KEQGZUUPPQEDPF-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- XTHPWXDJESJLNJ-UHFFFAOYSA-N chlorosulfonic acid Substances OS(Cl)(=O)=O XTHPWXDJESJLNJ-UHFFFAOYSA-N 0.000 description 1
- 239000000567 combustion gas Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000011552 falling film Substances 0.000 description 1
- 238000010574 gas phase reaction Methods 0.000 description 1
- 150000002483 hydrogen compounds Chemical class 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 230000036632 reaction speed Effects 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- HIFJUMGIHIZEPX-UHFFFAOYSA-N sulfuric acid;sulfur trioxide Chemical compound O=S(=O)=O.OS(O)(=O)=O HIFJUMGIHIZEPX-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/247—Suited for forming thin films
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J10/00—Chemical processes in general for reacting liquid with gaseous media other than in the presence of solid particles, or apparatus specially adapted therefor
- B01J10/02—Chemical processes in general for reacting liquid with gaseous media other than in the presence of solid particles, or apparatus specially adapted therefor of the thin-film type
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/2415—Tubular reactors
- B01J19/2425—Tubular reactors in parallel
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B45/00—Formation or introduction of functional groups containing sulfur
- C07B45/02—Formation or introduction of functional groups containing sulfur of sulfo or sulfonyldioxy groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
- C07C303/24—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of esters of sulfuric acids
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Treating Waste Gases (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Gas Separation By Absorption (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP50089069A JPS5214725A (en) | 1975-07-21 | 1975-07-21 | Method of sulfonation and its apparatus |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1072977A true CA1072977A (en) | 1980-03-04 |
Family
ID=13960554
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA256,974A Expired CA1072977A (en) | 1975-07-21 | 1976-07-14 | Process for sulfonation and apparatus therefor |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US4086256A (enExample) |
| JP (1) | JPS5214725A (enExample) |
| AU (1) | AU501918B2 (enExample) |
| BE (1) | BE844311A (enExample) |
| CA (1) | CA1072977A (enExample) |
| DE (1) | DE2631973C2 (enExample) |
| ES (2) | ES449954A1 (enExample) |
| FR (1) | FR2318846A1 (enExample) |
| GB (2) | GB1511794A (enExample) |
| IN (1) | IN145625B (enExample) |
| IT (1) | IT1065098B (enExample) |
| NL (1) | NL181576C (enExample) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5390219A (en) * | 1977-01-17 | 1978-08-08 | Kao Corp | Sulfonation process and its apparatus |
| IT1166068B (it) * | 1979-02-23 | 1987-04-29 | Ballestra Chim | Procedimento perfezionato per la solfonazione a film in un reattore multitubolare a reattore multitubolare atto a realizare detto procedimento |
| DE3416668A1 (de) * | 1984-05-05 | 1985-11-07 | Henkel KGaA, 4000 Düsseldorf | Verfahren zur chlorierung und sulfochlorierung von organischen verbindungen |
| MY160341A (en) | 2008-10-16 | 2017-02-28 | Atotech Deutschland Gmbh | Metal plating additive, and method for plating substrates and products therefrom. |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2923728A (en) * | 1957-11-19 | 1960-02-02 | Du Pont | Process of reacting organic compounds with sulfur trioxide |
| NL136773C (enExample) * | 1960-07-04 | |||
| GB1103441A (en) * | 1964-10-20 | 1968-02-14 | Richard James Brooks | Continuous sulfonation process |
| GB1229477A (enExample) * | 1967-06-26 | 1971-04-21 | ||
| DE1926795A1 (de) * | 1969-05-24 | 1970-11-26 | Metallgesellschaft Ag | Sulfierverfahren |
| DE2107968C2 (de) * | 1970-02-23 | 1982-05-19 | Costruzioni Meccaniche G. Mazzoni S.p.A., Busto Arsizio, Varese | Verfahren zur Sulfonierung und Sulfatierung organischer Verbindungen mit Schwefeltrioxyd und Vorrichtung zur Durchführung dieses Verfahrens |
| JPS4948409B1 (enExample) * | 1970-07-31 | 1974-12-21 | ||
| CA998825A (en) * | 1972-08-30 | 1976-10-26 | Allied Chemical Corporation | Process and apparatus for reacting a thin liquid film with a gas |
| JPS5341130B2 (enExample) * | 1972-11-13 | 1978-10-31 | ||
| DE2353297C3 (de) * | 1973-10-24 | 1982-05-06 | Lion Corp., Tokyo | Verfahren zur isothermen Sulfonierung oder Sulfatierung organischer Verbindungen |
-
1975
- 1975-07-21 JP JP50089069A patent/JPS5214725A/ja active Granted
-
1976
- 1976-07-07 IN IN1203/CAL/76A patent/IN145625B/en unknown
- 1976-07-12 US US05/704,613 patent/US4086256A/en not_active Expired - Lifetime
- 1976-07-13 GB GB29091/76A patent/GB1511794A/en not_active Expired
- 1976-07-13 GB GB43068/77A patent/GB1511795A/en not_active Expired
- 1976-07-14 CA CA256,974A patent/CA1072977A/en not_active Expired
- 1976-07-16 DE DE2631973A patent/DE2631973C2/de not_active Expired
- 1976-07-19 ES ES449954A patent/ES449954A1/es not_active Expired
- 1976-07-20 BE BE2055197A patent/BE844311A/xx not_active IP Right Cessation
- 1976-07-21 FR FR7622241A patent/FR2318846A1/fr active Granted
- 1976-07-21 IT IT25552/76A patent/IT1065098B/it active
- 1976-07-21 NL NLAANVRAGE7608088,A patent/NL181576C/xx not_active IP Right Cessation
- 1976-07-21 AU AU16096/76A patent/AU501918B2/en not_active Expired
-
1977
- 1977-09-01 ES ES462048A patent/ES462048A1/es not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| ES449954A1 (es) | 1977-12-01 |
| GB1511794A (en) | 1978-05-24 |
| IT1065098B (it) | 1985-02-25 |
| AU501918B2 (en) | 1979-07-05 |
| FR2318846A1 (fr) | 1977-02-18 |
| GB1511795A (en) | 1978-05-24 |
| AU1609676A (en) | 1978-01-26 |
| ES462048A1 (es) | 1978-06-01 |
| DE2631973C2 (de) | 1983-12-22 |
| DE2631973A1 (de) | 1977-02-10 |
| NL181576B (nl) | 1987-04-16 |
| US4086256A (en) | 1978-04-25 |
| FR2318846B1 (enExample) | 1979-06-08 |
| IN145625B (enExample) | 1985-01-05 |
| NL181576C (nl) | 1987-09-16 |
| NL7608088A (nl) | 1977-01-25 |
| JPS5214725A (en) | 1977-02-03 |
| JPS5530704B2 (enExample) | 1980-08-13 |
| BE844311A (fr) | 1976-11-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |